Academic literature on the topic 'Aryl halides'

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Journal articles on the topic "Aryl halides"

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Baik, Woonphil, Wanqiang Luan, Hyun Joo Lee, Cheol Hun Yoon, Sangho Koo, and Byeong Hyo Kim. "Efficient one-pot transformation of aminoarenes to haloarenes using halodimethylisulfonium halides generated in situ." Canadian Journal of Chemistry 83, no. 3 (2005): 213–19. http://dx.doi.org/10.1139/v05-026.

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Halodimethylsulfonium halide 1, which is readily formed in situ from hydrohaloic acid and DMSO, is a good nucleophilic halide. This activated nucleophilic halide rapidly converts aryldiazonium salt prepared in situ by the same hydrohaloic acid and nitrite ion to aryl chlorides, bromides, or iodides in good yield. The combined action of nitrite ion and hydrohaloic acid in DMSO is required for the direct transformation of aromatic amines, which results in the production of aryl halides within 1 h. Substituted compounds with electron-donating or -withdrawing groups or sterically hindered aromatic
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Bhat, Balkrishen, and A. P. Bhaduri. "Grignard Reaction of 2-Substituted-3-Cyanoquinolines." Zeitschrift für Naturforschung B 40, no. 7 (1985): 990–95. http://dx.doi.org/10.1515/znb-1985-0724.

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Abstract Grignard reactions of 2-morpholino and 2-methylthio-3-cyanoquinoline, 2-chloro-3-cyanoquinoline, 2-chloro-3-cyano-6-methoxyquinoline and 2-chloro-3-cyano-7-methylquinoline with alkyl or aryl magnesium halides have been studied. It was found that 2-morpholino and 2-methylthio- 3-cyanoquinolines gave 1,4-addition products followed by rapid aromatisation. 2-Chloro-3- cyanoquinoline with alkyl magnesium halides furnished 1,4-addition products but with aryl magnesium halides 1,4- and 1,2-addition products were obtained. The cyano group of 4-aryl-2-chloro- 3-cyano-1,4-dihydroquinolines was
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Kabalka, G. W., Z. Wu, and Y. Ju. "Use of organoboron halides in organic synthesis." Pure and Applied Chemistry 75, no. 9 (2003): 1231–37. http://dx.doi.org/10.1351/pac200375091231.

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Several new organic transformations have been achieved utilizing boron halide reagents. Aryl aldehydes are conveniently converted to gem-dichloromethylbenzenes using boron trichloride. Aryl aldehydes are alkylated by alkylboron chlorides in a Grignard-like fashion to generate the corresponding arylalkanols or alkylboron chlorides. Aryl aldehydes react with divinylboron halides (generated via the haloboration of alkynes) to produce 1,5-di-halo-1,4-dienes in excellent yields.
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Ying, Jun, Zhengjie Le, Zhi-Peng Bao, and Xiao-Feng Wu. "Palladium-catalyzed double carbonylation of propargyl amines and aryl halides to access 1-aroyl-3-aryl-1,5-dihydro-2H-pyrrol-2-ones." Organic Chemistry Frontiers 7, no. 8 (2020): 1006–10. http://dx.doi.org/10.1039/d0qo00007h.

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Brian, Ptoton Mnangat, and Peter Musau. "Synthesis, Reactivity and Stability of Aryl Halide Protecting Groups towards Di-Substituted Pyridines." Indonesian Journal of Chemistry 16, no. 1 (2018): 53. http://dx.doi.org/10.22146/ijc.21177.

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This paper reports the synthesis and reactivity of different Benzyl derivative protecting groups. The synthesis and stability of Benzyl halides, 4-methoxybenzyl halides, 3,5-dimethoxybenzyl halides, 3,4-dimethoxybenzyl halides, 3,4,5-trimethoxybenzyl halide protecting groups and their reactivity towards nitrogen atom of a di-substituted pyridine ring in formation of pyridinium salts is also reported.
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Nelson, David J., and Feliu Maseras. "Steric effects determine the mechanisms of reactions between bis(N-heterocyclic carbene)-nickel(0) complexes and aryl halides." Chemical Communications 54, no. 75 (2018): 10646–49. http://dx.doi.org/10.1039/c8cc06379f.

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Liu, Xiaosong, Yunfei Song, Wei Zhang, et al. "Correction: Tracking intramolecular energy redistribution dynamics in aryl halides: the effect of halide mass." RSC Advances 8, no. 55 (2018): 31303. http://dx.doi.org/10.1039/c8ra90073f.

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Quesnel, Jeffrey S., Alexander Fabrikant, and Bruce A. Arndtsen. "A flexible approach to Pd-catalyzed carbonylations via aroyl dimethylaminopyridinium salts." Chemical Science 7, no. 1 (2016): 295–300. http://dx.doi.org/10.1039/c5sc02949j.

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Larina, E. V., A. A. Kurokhtina, N. A. Lagoda, and A. F. Schmidt. "Distinguishing between Linear and Non-Linear (Cooperative) Substrate Activation Mechanisms in the Sonogashira Reaction under “Ligand-Free” and “Copper-Free” Conditions." Кинетика и катализ 64, no. 6 (2023): 737–48. http://dx.doi.org/10.31857/s0453881123060102.

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The results are presented on the comparative studies of the differential selectivity patterns in the Sonogashira reaction with a pair of competing aryl acetylenes in the “ligand-free” and “copper-free” conditions when varying the nature and concentration of aryl halides and base. The revealed sensitivity of the differential selectivity of competing aryl acetylenes to aryl halide nature unambiguously indicated that the substrates were activated through linear mechanism from kinetic view. An absence of any influence of the nature and concentration of the base on the differential selectivity of c
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Leadbeater, Nicholas E., and Riina K. Arvela. "Fast and Easy Halide Exchangein Aryl Halides." Synlett, no. 8 (2003): 1145–48. http://dx.doi.org/10.1055/s-2003-39887.

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Dissertations / Theses on the topic "Aryl halides"

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Paleologou, Michael. "Aryl halides and metabolites : new approaches to quantitation." Thesis, McGill University, 1990. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=74598.

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A novel reaction for the dehalogenation of aryl halides is discussed in terms of its stoichiometry, mechanism, yields and potential for analytical purposes. The active dehalogenation reagent can be prepared through the reaction of molten potassium with polyethylene glycols (MW $>$ 200), in the absence of oxygen, to form the corresponding potassium glycolate, a powerful nucleophilic agent. This reaction is applied to the determination of PCBs in waste oils. Following dechlorination, the reaction sample is analyzed for chloride using a flow-injection analysis system employing a novel thin-layer
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Cropper, Paul Edward. "A kinetic template effect in arylphosphonium salt formation." Thesis, Sheffield Hallam University, 1988. http://shura.shu.ac.uk/19513/.

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This thesis describes studies of a "kinetic template effect" which assists the formation of arylphosphonium salts from aryl halides and tertiary phosphines in the presence of a transition metal halide catalyst in refluxing ethanol. The "kinetic template effect" arises from the presence in the aryl halide of a limited range of orthosubstituents capable of intramolecular coordination with the metal at a critical stage of the reaction. In Chapter One, the "kinetic template effect" is compared with the better known "thermodynamic template effect". Earlier work on related "kinetic template effects"
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Mo, Jun. "Palladium catalyzed heck arylation of electron-rich olefins by aryl halides." Thesis, University of Liverpool, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.433729.

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Ferretti, Antonio. "Kinetic and mechanistic studies of Pd-catalyzed amination of aryl halides." Thesis, Imperial College London, 2009. http://hdl.handle.net/10044/1/5483.

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The Pd-catalyzed amination of aryl halides (Buchwald-Hartwig amination) has become a versatile and widely used technology to synthesize and produce aromatic amines relevant in pharmaceutical and agrochemical industries. The aim of the work presented in this thesis is to achieve a better mechanistic understanding of this reaction. The methodologies used were not traditional and focused on kinetic studies, carried out using in-situ tools, mainly reaction calorimetry. Reactions using different amines have been considered: the kinetic behaviour of a straight-chain primary amine (n-hexylamine) was
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Piller, Fabian Michel. "LiCl-Mediated Direct Insertion of Magnesium Into Aryl, Heteroaryl and Benzylic Halides." Diss., lmu, 2010. http://nbn-resolving.de/urn:nbn:de:bvb:19-114123.

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Senecal, Todd D. (Todd Dale). "Carbon-trifluoromethyl bond forming reactions and palladium-catalyzed cyanation of (hetero)aryl halides." Thesis, Massachusetts Institute of Technology, 2013. http://hdl.handle.net/1721.1/82321.

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Thesis (Ph. D. in Organic Chemistry)--Massachusetts Institute of Technology, Dept. of Chemistry, 2013.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references.<br>Chapter 1 Nucleophilic trifluoromethyl sources were systematically examined in stoichiometric palladium experiments to determine the most efficient class of reagents for transmetallation. In conjunction with reductive elimination studies, this led to the development of the first system for the trifluoromethylation of aryl chlorides. Chapter 2 A method for the oxidative trifluoromethylation of (hetero)aryl boro
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Kuvayskaya, Anastasia, and Aleksey Vasiliev. "Use of Suzuki Coupling Reaction for Synthesis of Functionalized Materials." Digital Commons @ East Tennessee State University, 2019. https://dc.etsu.edu/asrf/2019/schedule/162.

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Hybrid materials synthesized by grafting of organic molecules onto silica surface have found numerous applications in chemistry, biochemistry, and chemical engineering. In particular, the functionalization of silica gel can be accomplished by various surface reactions of immobilized boronic acids. Suzuki coupling has been chosen due to several advantages, such as mild reaction conditions, tolerance to the aqueous environment, and high yields of the products. The objective of this work was to determine the most effective reaction conditions for modifying porous hybrid materials with large speci
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Hayashi, Sayuri. "Studise on New Synthetic Reactions of Unsaturated Alcohols and Amines with Aryl Halides under Palladium Catalysis." 京都大学 (Kyoto University), 2010. http://hdl.handle.net/2433/120815.

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Iwasaki, Masayuki. "Studies on New Synthetic Reactions of Aryl Halides with Homoallyl Alcohols or Triazoles under Palladium Catalysis." 京都大学 (Kyoto University), 2010. http://hdl.handle.net/2433/131891.

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Smith, Craig R. "Metal-Catalyzed Reactions of Ethene: Asymmetric Hydrovinylation and Palladacycle-Mediated Low Pressure Vinylation of Aryl and Vinyl Halides." The Ohio State University, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=osu1274734379.

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Books on the topic "Aryl halides"

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White, William. The application of polystyrene bound tin hydride to a continuous flow reactor system for the reduction of alkyl and aryl halides. 1990.

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Zou, Dong. Nucleophilic substitution at the spp2s carbon of aryl halides by using nickel acylate complexes. 1994.

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Book chapters on the topic "Aryl halides"

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Röschenthaler, G. V. "From Aryl Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145173.ch127.

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Huber, F. "By Reaction with Aryl Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145234.ch151.

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Kanner, B. "By Reaction with Aryl Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145234.ch76.

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Kanner, B. "By Reaction with Aryl Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145234.ch98.

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Schareina, Thomas, and Matthias Beller. "Copper-Catalyzed Cyanations of Aryl Halides and Related Compounds." In Copper-Mediated Cross-Coupling Reactions. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118690659.ch9.

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Yamamoto, Yoshihiko. "Catalytic Alkyne Hydroarylation Using Arylboron Reagents, Aryl Halides, and Congeners." In Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds. Wiley-VCH Verlag GmbH & Co. KGaA, 2017. http://dx.doi.org/10.1002/9783527697649.ch8.

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Poller, R. C. "By Reaction with Alkyl Halides Having Alkenyl or Aryl Substituents." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145234.ch120.

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Alayrac, Carole, and Annie-Claude Gaumont. "Copper-Catalyzed Formation of C-P Bonds with Aryl Halides." In Copper-Mediated Cross-Coupling Reactions. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118690659.ch3.

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Brill, T. B. "By Oxidative Addition of Alkyl and Aryl Halides to the Metals." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145180.ch96.

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Li, Wanfang, and Xiao-Feng Wu. "Palladium-Catalyzed Carbonylative Synthesis of Six-Membered Heterocycles from Aryl Halides." In Topics in Heterocyclic Chemistry. Springer International Publishing, 2015. http://dx.doi.org/10.1007/7081_2015_150.

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Conference papers on the topic "Aryl halides"

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Nunes, Vanessa Lóren, (PG) Ingryd Cristina de Oliveira, and Olga S. do Rêgo Barros. "Copper(I)-Senelenophene-2-carboxylate Catalyzed Cross- Coupling of Aryl or alkyl Thiols And Aryl Halides." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0177-1.

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Reports on the topic "Aryl halides"

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Bedi, Vaibhav, Puja K. Mahajan, and Nitin T. Patil. Gold Catalysis: A New Contender for Cross-Coupling Reactions with Aryl Halides. The Israel Chemical Society, 2023. http://dx.doi.org/10.51167/acm00038.

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