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Journal articles on the topic 'Aryl sulphides'

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Published: 5 June 2025

Last updated: 1 August 2025

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1

CAPEILLÈRE-BLANDIN, Chantal, Christelle MARTIN, Nicoletta GAGGERO, Piero PASTA, Giacomo CARREA, and Stefano COLONNA. "Sulphoxidation reaction catalysed by myeloperoxidase from human leucocytes." Biochemical Journal 335, no. 1 (1998): 27–33. http://dx.doi.org/10.1042/bj3350027.

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The oxidation of alkyl aryl sulphides by myeloperoxidase (MPO) at the expense of hydrogen peroxide was investigated under steady-state conditions. The sulphide concentration effect was studied under saturating H2O2 concentrations at pH 5.0 and 20 °C. The kinetic constants, kcat and Km, of the different substrates were determined and the values were in the 1–10 s-1 range and around 43±26 µM respectively, whatever the sulphide considered. In the case of p-substituted thioanisoles, the oxidation rate was dependent upon the substituent effect. The correlation of log(kcat) with the substituent cons

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2

H., H. Adavi, A. Kusanur R. та V. Kulkarni M. "α-Cleavage during the oxidation of benzazolyl-4-coumarinomethyl sulphides". Journal of Indian Chemical Society Vol. 81, Nov 2004 (2004): 981–85. https://doi.org/10.5281/zenodo.5833651.

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Department of Chemistry, Karnatak University, Dharwad-580 003, India <em>E-mail </em>: drmvk274@yahoo.co.in <em>Manuscript received 23 July 2003, revised 16 February 2004, accepted 11 June 2004</em> 2-Mercapto benzazoles (2) have been reacted with various 4-bromomethylcoumarins (1) to obtain diheteroaryl sulphides (3). The attempted oxidation of benzoxazolyl sulphides (3) has resulted in α-cleavage of C-S bond leading to the formation of 4-methyl coumarins (5) and benzoxazolone (6). The benzthiazolyl sulphides (4) were found to be oxidised to corresponding sulphones (4). All the newly sy

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3

G., MANGALAM, and MEENAKSHI SUNDARAM SUBBIAB. "Kinetics and Mechanism of the Oxidation of Aryl Methyl Sulphides with Pyridinium Dichromate." Journal of Indian Chemical Society Vol. 68, Feb 1991 (1991): 77–80. https://doi.org/10.5281/zenodo.5954236.

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Department of Chemistry. Faculty of Engineering & Technology, Annamalai University, Annamalainagar 608 002 <em>Manuscript received 7 November 1989, revised 24 August 1990, accepted 26 January 7997</em> Kinetics of the oxidation of aryl methyl sulphides (CH,SAr) with PDC yielding sulpboxides were Investigated in aqueous acetic acid medium. The rate equation, <sup>\(\nu\)</sup>=<sup>\(\kappa\)</sup> [sulphide)[oxidant] was found to be valid. The observed substituent effect is explained by an electrophlllc attack of PDC oxygen on sulphide, leading to a polar transition state. T

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4

V., BALIAH, and UMA M. "Influence of ortho-Substituents on the + M and - M Effects of SCH3 Group in Aryl Methyl Sulphides. A Study by Dipole Moments." Journal of Indian Chemical Society Vol. 69, Jan 1992 (1992): 21–23. https://doi.org/10.5281/zenodo.5991471.

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Department of Chemistry, Annamalai University, Annsmalainagat-008 002 <em>Manuscript received 10 April 1991, revised 12 September 1991, accepted 7 January 1992</em> The dipole moments of twelve aryl methyl sulphides have been determined. The effect of mono-<em>ortho</em>- and di-<em>ortho-</em>substitution on the +M and -M effects of the SCH, group has been analysed by a comparison of the observed and calculated dipole moments of aryl methyl sulphides A single substituent ortho to SCH, group is found to cause a slight steric enhancement of both the donor and acceptor resonances of SCH, Di

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5

Baeza, J., J. Freer, and H. Mansilla. "Mass spectra of 2-indanyl aryl sulphides." Organic Mass Spectrometry 20, no. 1 (1985): 70–72. http://dx.doi.org/10.1002/oms.1210200116.

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6

N., ANJANEYULU, BALIAH V., and GANAPATHY K. "Palladium(II) Chloride Complexes of some Aryl Methyl Sulphides. Synthesis and their Electronic Spectral Studies." Journal Of Indian Chemical Society Vol. 67, Aug 1990 (1990): 673–75. https://doi.org/10.5281/zenodo.6236470.

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Department of Chemistry, Annamalai University, Annamalainagar-608 002 <em>Manuscript received 21 August 1989, accepted 11 May 1990</em> Palladium(II) Chloride Complexes of some Aryl Methyl Sulphides. Synthesis and their Electronic Spectral Studies  

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7

van Zwieten, P. A., and H. O. Huisman. "Synthesis and physiological properties of some heterocyclic-aromatic sulphides and sulphones: II. Synthesis of some aryl-pyrimidyl, aryl-thiazolyl and aryl-thienyl sulphides." Recueil des Travaux Chimiques des Pays-Bas 81, no. 7 (2010): 554–64. http://dx.doi.org/10.1002/recl.19620810703.

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8

P., V. V. SATYANARAYANA, N. MALLESWARA RAO B., and V. RAMANA G. "Kinetics and Mechanism of Oxidation of some Aryl Methyl Sulphides by Thallium(III) in Aqueous Acetic Acid." Journal of Indian Chemical Society Vol. 66, Mar 1989 (1989): 198–200. https://doi.org/10.5281/zenodo.6139067.

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Department of Chemistry, Nagarjuna University, Nagarjuanagar-522 510 <em>Manuscript received 5 July 1988, revised 13 October 1988, accepted 14 December 1988</em> Kinetics and Mechanism of Oxidation of some Aryl Methyl Sulphides by Thallium(III) in Aqueous Acetic Acid

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9

Holland, Herbert L., Heike Pöpperl, Ronald W. Ninniss, and P. Chinna Chenchaiah. "The oxidation of organic sulphides by Mortierellaisabellina. 2. Effects of substituents on the stereochemistry of sulphoxide formation." Canadian Journal of Chemistry 63, no. 5 (1985): 1118–20. http://dx.doi.org/10.1139/v85-189.

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A series of para-substituted alkyl aryl sulphides has been transformed stereoselectively to the sulphoxide by incubation with the fungus Mortierellaisabellina. The enantiomeric purity of the products was dependent on the nature of substitution in the aromatic ring and at sulphur. Comparisons of the enantiomeric purities obtained from sulphides with para substituents of the same steric size but different electronic properties indicate that the stereoselectivity of S oxidation is susceptible to electron withdrawing or donating factors. This conclusion lends credence to a stepwise oxidation mecha

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10

V., BALIAH, GANAPATHY K., and ANJANEYULU N. "Palladium(II) Chloride Complexes of some Aryl Methyl Sulphides. Part-2. Substituent Effect on Pd-S and Pd-CI Stretching Frequencies." Journal of Indian Chemical Society Vol. 63, Nov 1986 (1986): 990–91. https://doi.org/10.5281/zenodo.6297139.

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Department of Chemistry, A nnamalai University, Annamalainagar-608 002 <em>Manuscript received 11 January 1985, revised 18 August 1986, accepted 5 September 1986</em> Palladium(II) Chloride Complexes of some Aryl Methyl Sulphides. Part-2. Substituent Effect on Pd-S and Pd-CI Stretching Frequencies.

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11

Wenkert, Ernest, Michele E. Shepard, and Andrew T. McPhail. "Oxidative addition of aryl sulphides to low-valent nickel species." Journal of the Chemical Society, Chemical Communications, no. 17 (1986): 1390. http://dx.doi.org/10.1039/c39860001390.

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12

Anand, O. N., Vijay Kumar, V. P. Malik, and R. P. S. Bist. "Load-carrying characteristics of reaction films of alkyl aryl sulphides." Wear 154, no. 2 (1992): 349–59. http://dx.doi.org/10.1016/0043-1648(92)90164-4.

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13

van Zwieten, P. A., J. A. van Velthuijsen, and H. O. Huisman. "Synthesis and physiological properties of some heterocyclic-aromatic sulphides and sulphones. I. Synthesis of some aryl-pyridyl sulphides." Recueil des Travaux Chimiques des Pays-Bas 80, no. 10 (2010): 1066–74. http://dx.doi.org/10.1002/recl.19610801004.

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14

Bergman, Åke, and Carl Axel Wachtmeister. "Phase transfer mediated synthesis of radiolabelled alkyl aryl ethers and sulphides." Journal of Labelled Compounds and Radiopharmaceuticals 24, no. 8 (1987): 925–30. http://dx.doi.org/10.1002/jlcr.2580240807.

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15

Goux, Catherine, Paul Lhoste, and Denis Sinou. "Synthesis of allyl aryl sulphides by palladium(0)-mediated alkylation of thiols." Tetrahedron Letters 33, no. 52 (1992): 8099–102. http://dx.doi.org/10.1016/s0040-4039(00)74729-0.

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16

Debasish, Kundu, and C. Ranu Brindaban. "Ionic liquid as base and phase transfer agent A green protocol for the synthesis of diaryI sulphides in water." Journal of Indian Chemical Society Vol. 90, Oct 2013 (2013): 1761–65. https://doi.org/10.5281/zenodo.5791897.

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Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata-700 032, India <em>E-mail</em> : ocbcr@iacs.res.in Fax : 91-33-24732805 <em>Manuscript received 09 July 2013, accepted 11 July 2013</em> A basic ionic liquid, 1-methyl-3-butylimidazolium hydroxide, [BMIm]OH, acts as a base and phase transfer agent in the copper-catalysed ligand free <em>S</em>-arylation in water. A variety of iodo and bromoaryl compounds undergo coupling with aryl and heteroaryl thiols in presence of this ionic liquid in water to provide the corresponding diary!/ aryl-heteroar

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17

Miotti, Umberto. "Oxygen exchange between sulphoxides and sulphides. Part 3. The HCl-catalysed reduction of aryl methyl sulphoxides by dialkyl sulphides in aqueous methanol." Journal of the Chemical Society, Perkin Transactions 2, no. 5 (1991): 617. http://dx.doi.org/10.1039/p29910000617.

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18

Srinivasan, Chockalingam, Seenivasan Rajagopal, and Arunachalam Chellamani. "Mechanism of picolinic-acid-catalysed chromium(VI) oxidation of alkyl aryl and diphenyl sulphides." Journal of the Chemical Society, Perkin Transactions 2, no. 11 (1990): 1839. http://dx.doi.org/10.1039/p29900001839.

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19

Gnanaraj, George Allen, Seenivasan Rajagopal, Chockalingam Srinivasan, and Kasi Pitchumani. "Reductive quenching of excited states of chromium(III)-polypyridyl complexes with alkyl aryl sulphides." Tetrahedron 49, no. 21 (1993): 4721–40. http://dx.doi.org/10.1016/s0040-4020(01)81300-4.

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20

Chellamani, Arunachalam, Nainamohamed Ismail Alhaji, and Seenivasan Rajagopal. "Kinetics and mechanism of (salen)MnIII–catalysed hydrogen peroxide oxidation of alkyl aryl sulphides." Journal of Physical Organic Chemistry 20, no. 4 (2007): 255–63. http://dx.doi.org/10.1002/poc.1160.

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21

Riad, Y., Adel N. Asaad, G. A. S. Gohar, and A. A. Abdallah. "Kinetics and Mechanism of the Change of the 4-Nitrobenzylthio-System into 4,4′-Diformylazoxybenzene in Alkaline Dioxane-Water Media." Zeitschrift für Naturforschung A 40, no. 11 (1985): 1128–32. http://dx.doi.org/10.1515/zna-1985-1109.

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Sodium hydroxide reacts with α -(4-nitrobenzylthio)-acetic acid in aqueous-dioxane media to give 4,4'-diformylazoxybenzene as the main product besides 4,4'-dicarboxyazoxybenzene and a nitrone acid. This reaction was kinetically studied in presence of excess of alkali in different dioxane-water media at different temperatures. It started by a fast reversible a-proton abstraction step followed by two consecutive irreversible first-order steps forming two intermediates (α -hydroxy, 4-nitrosobenzylthio)-acetic acid and 4-nitrosobenzaldehyde. The latter underwent a Cannizzaro's reaction, the produc

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22

Chan, Ming Fai, and Michael E. Garst. "Oxidative S-dealkylation of tert-butyl aryl sulphides: a novel route to 3-substituted-3H-1,2-benzodithioles." Journal of the Chemical Society, Chemical Communications, no. 7 (1991): 540. http://dx.doi.org/10.1039/c39910000540.

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23

Silvestri, R., M. Artico, B. Bruno, et al. "Synthesis and Biological Evaluation of 5H-Indolo [3,2-b][1,5]Benzothiazepine Derivatives, Designed as Conformationally Constrained Analogues of the Human Immunodeficiency Virus Type 1 Reverse Transcriptase Inhibitor L-737,126." Antiviral Chemistry and Chemotherapy 9, no. 2 (1998): 139–48. http://dx.doi.org/10.1177/095632029800900205.

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In the presence of sodium hydride, reaction of aryldisulphides with ethyl esters of indole-2-carboxylic acids furnished ethyl 3-arylthioindole-2-carboxy-lates, which were cyclized intramolecularly to afford 5 H-indolo[3,2-b][1,5]benzothiazepin-6(7 H)-ones or hydrolysed in alkaline medium to give 3-arylthioindole-2-carboxylic acids. These acids, also obtained by the action of aryldisulphides on indole-2-carboxylic acids, afforded tetracyclic 5 H-indolo [3,2-b][1,5]benzothiazepin-6(7 H)-ones upon treatment with EDCI–DMAP. Transformation of cyclic sulphides into the required sulphones was achieve

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24

Mohan, Hari. "Effect of electron-withdrawing power of the substituted group on•OH radical reaction with substituted aryl sulphides: A pulse radiolysis study." Journal of Chemical Sciences 114, no. 6 (2002): 749–58. http://dx.doi.org/10.1007/bf02708868.

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25

Ram, Vishnu J., and Arnold J. Vlietinck. "Chemotherapeutical agents.VII. Synthesis and pesticidal activities of sulphides and sulphones derived from bis[4-aryl-1,2,4-triazoline-5-thione-3-yl]alkane and 5-phenyl-1,3,4-oxadiazole-2-thione." Journal of Heterocyclic Chemistry 25, no. 1 (1988): 253–56. http://dx.doi.org/10.1002/jhet.5570250141.

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26

Singh, Neha, Richa Khare, and Krishna Srivastava. "Triton B Mediated One-Pot Synthesis of Thiocarbonic Ester Derivatives in Non-Aqueous Medium." Asian Journal of Chemistry 31, no. 9 (2019): 1989–92. http://dx.doi.org/10.14233/ajchem.2019.22025.

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A differentiated series of thiocarbonic acid esters have been synthesized and characterized in good to excellent yields with the help of thiols, carbon di sulphide and alkyl/aryl halides in DMSO with benzyl trimethylammonium hydroxide where Triton B acts as a catalyst. This method is safer and efficient as compared to other conventional methods.

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27

Bialski, Alec M., Corinne E. Luthe, Jenny L. Fong, and Norman G. Lewis. "Sulphite-promoted delignification of wood: identification of paucidisperse lignosulphonates." Canadian Journal of Chemistry 64, no. 7 (1986): 1286–94. http://dx.doi.org/10.1139/v86-221.

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Paucidisperse lignosulphonates, previously described as a distinct group of compounds called "hemilignins" [Formula: see text] were conclusively shown to be a complex mixture of monomeric (C9) sulphonic acids. Since these compounds are rapidly solubilized only during the early stages of delignification from softwoods (≤30% lignin removal), it can be concluded that they are selectively removed from the secondary wall and not from the middle lamella. This result gives chemical support to the hypothesis that morphological differences in lignin structure exist. It is proposed that the generation o

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28

Ren, Qiangqiang, Song Hu, Qingwei Hu, et al. "Waste Tire Heat Treatment to Prepare Sulfur Self-Doped Char: Operando Insight into Activation Mechanisms Based on the Char Structures Evolution." Processes 9, no. 9 (2021): 1622. http://dx.doi.org/10.3390/pr9091622.

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Waste tire (WT) can be heat-treated to be high-quality sulfur self-doped char via pyrolysis and K2FeO4-assisted activation processes. This work aimed at further studying the activation mechanisms based on the char structures evolution by operando experimental method. Activation treatment process (from 50 °C to 800 °C and then held for 3 h) was divided into six typical stages (S1–S6) and consisted of carbonization process (S1–S4) and effective activation process (S4–S6). During the carbonization process, the specific capacitance only increased from 0.2 F/g to 12.4 F/g, aromatic ring systems and

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29

Gerbal-Chaloin, Sabine, Lydiane Pichard-Garcia, Jean-Michel Fabre, et al. "Role of CYP3A4 in the regulation of the aryl hydrocarbon receptor by omeprazole sulphide." Cellular Signalling 18, no. 5 (2006): 740–50. http://dx.doi.org/10.1016/j.cellsig.2005.07.007.

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30

Suckling, Ian D. "Enhanced Cleavage of β-Aryl Ether Bonds in Lignin Model Compounds During Sulphite-Anthraquinone Pulping". Journal of Wood Chemistry and Technology 8, № 1 (1988): 43–71. http://dx.doi.org/10.1080/02773818808070670.

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31

Osakada, Kohtaro, Meguru Maeda, Yoshiyuki Nakamura, Takakazu Yamamoto, and Akio Yamamoto. "Reversible oxidative addition and reductive elimination of diaryl sulphide involving C–S bond cleavage and formation: exchange of two aryl groups in aryl(arylthiolato)nickel complexes having tertiary phosphine ligands." J. Chem. Soc., Chem. Commun., no. 6 (1986): 442–43. http://dx.doi.org/10.1039/c39860000442.

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32

Ferreira, Patricia, Milagros Medina, Francisco Guillén, María Jesús Martínez, Willem J. H. Van Berkel, and Ángel T. Martínez. "Spectral and catalytic properties of aryl-alcohol oxidase, a fungal flavoenzyme acting on polyunsaturated alcohols." Biochemical Journal 389, no. 3 (2005): 731–38. http://dx.doi.org/10.1042/bj20041903.

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Spectral and catalytic properties of the flavoenzyme AAO (aryl-alcohol oxidase) from Pleurotus eryngii were investigated using recombinant enzyme. Unlike most flavoprotein oxidases, AAO does not thermodynamically stabilize a flavin semiquinone radical and forms no sulphite adduct. AAO catalyses the oxidative dehydrogenation of a wide range of unsaturated primary alcohols with hydrogen peroxide production. This differentiates the enzyme from VAO (vanillyl-alcohol oxidase), which is specific for phenolic compounds. Moreover, AAO is optimally active in the pH range of 5–6, whereas VAO has an opti

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33

Bhojane, Jeevan Manohar, Sachin Ashok Sarode, and Jayashree Milind Nagarkar. "Aryl diazonium salt and thioacetamide: a catalyst free, efficient blend of an inexpensive arylating agent with “S” surrogate for sulphide synthesis." RSC Advances 6, no. 93 (2016): 90046–50. http://dx.doi.org/10.1039/c6ra12557c.

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34

Crampton, Michael R., and Anthony J. Holmes. "Kinetic and equilibrium studies of ?-adduct formation and substitution in the reactions of sulphite ions with some alkyl and aryl ethers and thioethers." Journal of Physical Organic Chemistry 11, no. 11 (1998): 787–92. http://dx.doi.org/10.1002/(sici)1099-1395(1998110)11:11<787::aid-poc38>3.0.co;2-0.

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35

Wang, Yuna, Zaojuan Qi, Yanning Niu, Hua Feng, Enrico Benassi, and Bo Qian. "Selective oxidative intermolecular carbosulphenylation of aryl alkenes with thiols and nucleophiles via a 1,2-dithioethane intermediate." Chemical Communications, 2021. http://dx.doi.org/10.1039/d1cc02517a.

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36

porcu, stefania, Maria Chiara Cabua, Viktoria Velichko, et al. "Insights into the reactivity of 2-hydroxycyclobutanones with thiols corroborated by quantum chemical DFT investigations, NMR and Raman analysis." Synthesis, July 28, 2022. http://dx.doi.org/10.1055/a-1912-1096.

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A general strategy for the synthesis of 2-substituted cyclobutanone sulphides via a tandem Brønsted acid catalysed nucleophile addition/ring-contraction/C3-C4 ring-expansion reaction sequence has been exploited. The procedure led to a wide panel of four membered cyclic ketones in good to excellent yields and with broad substrate scope. Mechanistic aspects and kinetic parameters were investigated by quantum chemical DFT calculations allowing us to rationalize the different reactivity of 2-aryl- and 2-alkyl- substituted 2-hydroxycyclobutanones towards thiol nucleophiles in reactions mediated by

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37

Jesse, Adenola Oluwasegun. "Fourier Transform Infrared Spectroscopy Analysis of Allium sativum L. and Nymphaea lotus L." Asian Journal of Applied Chemistry Research, July 13, 2020, 7–24. http://dx.doi.org/10.9734/ajacr/2020/v6i230155.

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The use of Fourier Transforms Infrared Spectroscopy (FTIR) in screening secondary metabolites provides valuable information on qualitative, quantitative and the pattern of the biologically active compounds. The present study was carried out to identify functional groups present in water, methanol and n-hexane extracts of Allium sativum and Nymphaea lotus. It was revealed that Allium sativum and Nymphaea lotus possess numerous secondary metabolites {A. sativum L. (isothiocynate, acid halide, conjugated aldehyde, imine/oxime, halo compound, conjugated amine, alphaticprimary amine, aldehyde, anhy

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38

Chakraborty, Moumita, Antu Mondal, Anwesha Ghosh, Alakananda Mahapatra, Tapan Kumar Mondal, and Shyamal Kumar Chattopadhyay. "Synthesis, crystal structure and sulphide ion sensing study of a Cu(II) complex of aroyl hydrazone." Polyhedron, November 2024, 117294. http://dx.doi.org/10.1016/j.poly.2024.117294.

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39

Nkongolo, K. K., G. Spiers, P. Beckett, and R. Narendrula-Kotha. "Effects of Phytoremediation on Microbial Biomass, Composition, and Function in a Sulphide-Rich Tailing From a Metal-Contaminated Region." Frontiers in Environmental Science 10 (July 22, 2022). http://dx.doi.org/10.3389/fenvs.2022.908633.

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Mining activities lead to serious land deterioration and large scale mine waste generation. Reclamation has been carried out on several technogenic materials to encourage the development of soils. To date no detailed studies have been conducted to assess if soil developed in reclaimed tailings can be suitable for microbial community sustainability and associated plant population. This study investigated if 1) soil metal contamination affects microbial biomass and composition in sulphide tailings and 2) phytoremediation of tailing increases microbial abundance, diversity, and function. Microbia

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