Academic literature on the topic 'Arylsilanes'

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Journal articles on the topic "Arylsilanes"

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Liu, Zhizhou, Xianghui Shi, and Jianhua Cheng. "Selective homo- and cross-desilacoupling of aryl and benzyl primary silanes catalyzed by a barium complex." Dalton Transactions 49, no. 24 (2020): 8340–46. http://dx.doi.org/10.1039/d0dt01158d.

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The selective catalytic desilacoupling of primary arylsilanes with primary benzylsilane or arylsilanes was achieved by barium complex [(Tp<sup>Ad,iPr</sup>)Ba(CH<sub>2</sub>C<sub>6</sub>H<sub>4</sub>NMe<sub>2</sub>-o)].
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Sun, Dianming, Zhongjie Ren, Martin R. Bryce, and Shouke Yan. "Arylsilanes and siloxanes as optoelectronic materials for organic light-emitting diodes (OLEDs)." Journal of Materials Chemistry C 3, no. 37 (2015): 9496–508. http://dx.doi.org/10.1039/c5tc01638j.

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Arylsilanes and siloxanes have been extensively studied as components of OLEDs. In this review, we summarize the recent advances in the utilization of arylsilanes and siloxanes as fluorophore emitters, hosts for phosphor emitters, hole and exciton blocking materials, and as electron and hole transporting materials.
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Guo, Chenjun, Min Li, Jue Chen, and Yunjie Luo. "Highly selective redistribution of primary arylsilanes to secondary arylsilanes catalyzed by Ln(CH2C6H4NMe2-o)3@SBA-15." Chemical Communications 56, no. 1 (2020): 117–20. http://dx.doi.org/10.1039/c9cc07493g.

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The organometallic–inorganic hybrid materials Ln(CH<sub>2</sub>C<sub>6</sub>H<sub>4</sub>NMe<sub>2</sub>-o)<sub>3</sub>@SBA-15 (Ln = La, Y) were prepared, which demonstrated extremely high selectivity (&gt;99%) in catalyzing the redistribution of primary arylsilanes to secondary arylsilanes.
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Biedermann, Judith, H. Martin R. Wilkening, Frank Uhlig, and Ilie Hanzu. "Electrochemical properties of arylsilanes." Electrochemistry Communications 102 (May 2019): 13–18. http://dx.doi.org/10.1016/j.elecom.2019.03.010.

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Zhu, Fengxiang, and Xiao-Feng Wu. "Palladium-catalyzed construction of amidines from arylsilanes in the absence of a ligand under oxidative conditions." New Journal of Chemistry 42, no. 12 (2018): 10396–99. http://dx.doi.org/10.1039/c8nj01883a.

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Wu, Xin-Xing, Hao Ye, Guomin Jiang та Lanping Hu. "Domino Heck/Hiyama cross-coupling: trapping of the σ-alkylpalladium intermediate with arylsilanes". Organic & Biomolecular Chemistry 19, № 19 (2021): 4254–57. http://dx.doi.org/10.1039/d1ob00595b.

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Li, Wei-Ze, and Zhong-Xia Wang. "A nickel-catalyzed silylation reaction of alkyl aryl sulfoxides with silylzinc reagents." Organic & Biomolecular Chemistry 19, no. 23 (2021): 5082–86. http://dx.doi.org/10.1039/d1ob00840d.

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Luo, Haiqing, Qi Xie, Kai Sun, et al. "Rh(iii)-catalyzed C-7 arylation of indolines with arylsilanes via C–H activation." RSC Advances 9, no. 32 (2019): 18191–95. http://dx.doi.org/10.1039/c9ra04142g.

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Chakrabarty, Indradweep, Manjur O. Akram, Suprakash Biswas, and Nitin T. Patil. "Visible light mediated desilylative C(sp2)–C(sp2) cross-coupling reactions of arylsilanes with aryldiazonium salts under Au(i)/Au(iii) catalysis." Chemical Communications 54, no. 52 (2018): 7223–26. http://dx.doi.org/10.1039/c8cc03925a.

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Morstein, Johannes, Haiyun Hou, Chen Cheng, and John F. Hartwig. "Trifluoromethylation of Arylsilanes with [(phen)CuCF3 ]." Angewandte Chemie International Edition 55, no. 28 (2016): 8054–57. http://dx.doi.org/10.1002/anie.201601163.

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Dissertations / Theses on the topic "Arylsilanes"

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Robinson, Matthew Peter. "Ortho-substituted arylsilanes in oxidative gold catalysis." Thesis, University of Edinburgh, 2018. http://hdl.handle.net/1842/31394.

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Organometallic compounds derived from tin, boron, and zinc, have been used extensively in transition metal-catalysed cross-coupling, and continue to hold status as the go-to reagents to form new carbon-carbon bonds. Recently, organosilicon compounds have emerged as an attractive alternative to these established reagents, benefitting from low toxicity, low cost, and general ease of handling. While the fundamental reactivity of arylsilane reagents (Ar-SiR3) is well known, their role in transition metal-catalysed reactions is generally less well studied. This thesis comprises an investigation int
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Rousseau, Cyril. "Synthèse de C-aryl glycosides par voie intramoléculaire." Phd thesis, Université d'Orléans, 2002. http://tel.archives-ouvertes.fr/tel-00168483.

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De par leurs propriétés biologiques et leur structure remarquables, les C-aryl glycosides<br />ont suscité l'intérêt de nombreuses équipes de recherche. La création de la liaison Cglycosidique<br />de façon régio- et stéréocontrôlée constitue la principale difficulté de la synthèse<br />de ces composés.<br />L'objectif de ce travail est la mise au point d'une synthèse de C-aryl glycosides par voie<br />intramoléculaire. Nous avons développé une méthode de C-arylation intramoléculaire efficace<br />et stéréocontrôlée basée sur l'activation d'un glycoside de pentényle. Cette méthode a été<br />a
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Minge, Oliver. "Synthese und Charakterisierung wasserstoffreicher Arylsilane." [S.l. : s.n.], 2003. http://deposit.ddb.de/cgi-bin/dokserv?idn=969419066.

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Belaud-Rotureau, Mickaël. "Substitution nucléophile aromatique des acides benzoïques et naphtoïques ortho fluorés/méthoxylés non protégés (SNArAB) par les bases fortes (RLi, RMgX et R2NLi) en l'absence de catalyseur métallique." Phd thesis, Université du Maine, 2010. http://tel.archives-ouvertes.fr/tel-00510819.

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Dans le cadre d'un projet général d'étude de la réactivité des acides benzoïques non protégés avec les bases fortes, la réaction de substitution nucléophile aromatique des acides benzoïques ortho-fluorés et ortho-méthoxylés (SNArAB) avec les organolithiens et les réactifs de Grignard est étudiée pour la première fois de façon systématique. Une revue de la littérature de la réaction de Meyers (>1994) a été faite. Afin de réduire le taux d'addition 1,2 de l'organométallique sur le carboxylate conduisant à la formation de cétones, un groupe TMS a été introduit en ortho (C6) du carboxylate. Lors d
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Rayment, Elizabeth. "Synthetic and mechanistic studies of arylsilane oxidation." Thesis, University of Oxford, 2013. http://ora.ox.ac.uk/objects/uuid:ca3cfee8-305d-402a-bf6d-6417f7790289.

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In this thesis, we study arylsilane oxidation from both a synthetic and a mechanistic perspective. Building upon previous work within our group, we demonstrate in an early chapter that arylhydrosilanes are surprisingly reactive to oxidation. This disproves the previous assumptions of the Tamao oxidation and provides new insights into the mechanism of the reaction. Furthermore, we find that the best substrates for oxidation are arylmethoxysilanes, and we describe rapid and efficient syntheses for these compounds. A further chapter addresses applications of arylsilane oxidation to natural produc
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Li, Hui. "Sigma, Pi*-interaction in arylsilanes ; Chemical and physical properties of self-assembled monolayers ; Coating micro particles by selective withdrawal /." 2000. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&res_dat=xri:pqdiss&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&rft_dat=xri:pqdiss:9965112.

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Minge, Oliver [Verfasser]. "Synthese und Charakterisierung wasserstoffreicher Arylsilane / Oliver Minge." 2003. http://d-nb.info/969419066/34.

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Huang, Chiung-Hui, and 黃瓊慧. "Synthesis and Characterization of Carboline Substituted Arylsilane and Application in Blue Phosphorescent Organic Light Emitting Diodes." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/89260524432445895905.

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碩士<br>國立臺灣大學<br>化學研究所<br>104<br>We synthesized a series of carboline derivatives combined with tetraphenylsilane as host materials for blue phosphorescent organic light emitting diodes. In this thesis, we introduce tetraphenylsilane group to interrupt the conjugation length,and expect to maintain the high triplet energy and stable thermal properties. Additionly,we try to balance the electron and hole transporting abilities by adjusting the group numbers of carboline and carbazole.We also want to figure out the effect of position of nitrogen in carboline how to affect the device performance of
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Chang, Yung-Shen, and 張永燊. "Synthesis of Polymers Containing Pendent Arylsilane-Modified Carbazole and the Application on Blue Phosphorescent Polymer Light Emitting Diodes." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/hp36ag.

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碩士<br>國立臺灣大學<br>化學工程學研究所<br>100<br>In this study, polymers containing pendant emitting groups are synthesized and used as host materials for polymer light emitting diodes. By free radical polymerization, we synthesize a series of polymers containing pendant arylsilane-modified carbazole. Carbazole has good hole-transporting characteristic and high triplet energy gap. Arylsilane group could interrupt conjugation length and raise triplet energy level. The bulky arylsilane group could restrain polymer aggregation preventing guest self-quenching. The thermal stability, optical properties, electroc
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Pan, Yun-Wen, and 潘韵文. "Synthesis and Characterization of Polymers with 1,3- and 1,4-Bicarbazole-Substituted Arylsilane Derivatives as Host for Polymer Light Emitting Diodes." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/w5zadn.

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Book chapters on the topic "Arylsilanes"

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"Product Subclass 33: Arylsilanes." In Category 1, Organometallics, edited by Fleming and Ley. Georg Thieme Verlag, 2002. http://dx.doi.org/10.1055/sos-sd-004-00740.

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Oshima, K. "Birch Reduction of Arylsilanes." In Compounds of Groups 15 (As, Sb, Bi) and Silicon Compounds. Georg Thieme Verlag KG, 2002. http://dx.doi.org/10.1055/sos-sd-004-00804.

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Heaney, H., and S. Christie. "From Arylsilanes and Copper(I) Salts." In Compounds of Groups 12 and 11 (Zn, Cd, Hg, Cu, Ag, Au). Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-003-00313.

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Hopkinson, M. N., and V. Gouverneur. "Oxidative Arylation with Arylsilanes Using Selectfluor." In Compounds of Groups 12 and 11 (Zn, Cd, Hg, Cu, Ag, Au). Georg Thieme Verlag KG, 2011. http://dx.doi.org/10.1055/sos-sd-103-00065.

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Landais, Y. "Arylsilanes as Precursors of Cyclohexa-2,5-dienylsilanes." In Efficient Methods for Preparing Silicon Compounds. Elsevier, 2016. http://dx.doi.org/10.1016/b978-0-12-803530-6.00001-9.

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Somfai, P., and B. Seashore-Ludlow. "1.02 Organosilicon Reagents: Vinyl-, Alkynyl-, and Arylsilanes." In Comprehensive Organic Synthesis II. Elsevier, 2014. http://dx.doi.org/10.1016/b978-0-08-097742-3.00104-x.

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