Relevant bibliographies by topics / Asymmetric catalysis

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Academic literature on the topic 'Asymmetric catalysis'

Author: Grafiati
Published: 4 June 2021
Last updated: 25 July 2025

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Journal articles on the topic "Asymmetric catalysis"

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Ding, Bo, Qilin Xue, Hong-Gang Cheng, Qianghui Zhou, and Shihu Jia. "Recent Advances in Catalytic Nonenzymatic Kinetic Resolution of Tertiary Alcohols." Synthesis 54, no. 07 (2021): 1721–32. http://dx.doi.org/10.1055/a-1712-0912.

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AbstractThe kinetic resolution (KR) of racemates is one of the most widely used approaches to access enantiomerically pure compounds. Over the past two decades, catalytic nonenzymatic KR has gained popularity in the field of asymmetric synthesis due to the rapid development of chiral catalysts and ligands in asymmetric catalysis. Chiral tertiary alcohols are prevalent in a variety of natural products, pharmaceuticals, and biologically active chiral compounds. The catalytic nonenzymatic KR of racemic tertiary alcohols is a straightforward strategy to access enantioenriched tertiary alcohols. Th
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Baráth, Eszter. "Selective Reduction of Carbonyl Compounds via (Asymmetric) Transfer Hydrogenation on Heterogeneous Catalysts." Synthesis 52, no. 04 (2020): 504–20. http://dx.doi.org/10.1055/s-0039-1691542.

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Based on the ever-increasing demand for optically pure compounds, the development of efficient methods to produce such products is very important. Homogeneous asymmetric catalysis occupies a prominent position in the ranking of chemical transformations, with transition metals coordinated to chiral ligands being applied extensively for this purpose. However, heterogeneous catalysts have the ability to further extend the field of asymmetric transformations, because of their beneficial properties such as high stability, ease of separation and regeneration, and the possibility to apply them in con
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Khettar, Ibrahim, Alicja Malgorzata Araszczuk, and Rosaria Schettini. "Peptidomimetic-Based Asymmetric Catalysts." Catalysts 13, no. 2 (2023): 244. http://dx.doi.org/10.3390/catal13020244.

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Despite the great advantages of peptidomimetic scaffolds, there are only a few examples of their application in the field of asymmetric catalysis. Peptidomimetic scaffolds offer numerous advantages related to their easy preparation, modular and tunable structures, and biomimetic features, which make them well suited as chiral catalysts. This review underlines the structure–function relationship for catalytic properties towards efficient enantioselective catalysis.
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Ollevier, Thierry. "Iron bis(oxazoline) complexes in asymmetric catalysis." Catalysis Science & Technology 6, no. 1 (2016): 41–48. http://dx.doi.org/10.1039/c5cy01357g.

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Asymmetric reactions catalyzed by iron complexes have attracted considerable attention because iron is a ubiquitous, inexpensive, and environmentally benign metal. This overview charts the development and application of chiral iron bis(oxazoline) and pyridine-2,6-bis(oxazoline) catalysts through their most prominent and innovative uses in asymmetric catalysis, especially in Lewis acid and oxidation catalysis.
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Bhaskararao, Bangaru, and Raghavan B. Sunoj. "Two chiral catalysts in action: insights into cooperativity and stereoselectivity in proline and cinchona-thiourea dual organocatalysis." Chemical Science 9, no. 46 (2018): 8738–47. http://dx.doi.org/10.1039/c8sc03078b.

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Increasing use of two chiral catalysts in cooperative asymmetric catalysis in recent years raises some fundamental questions on chiral compatibility between the catalysts, modes of activation, and relative disposition of substrates within the chiral environment of the catalysts for effective asymmetric induction.
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Chen, Jianfeng, Xing Gong, Jianyu Li, et al. "Carbonyl catalysis enables a biomimetic asymmetric Mannich reaction." Science 360, no. 6396 (2018): 1438–42. http://dx.doi.org/10.1126/science.aat4210.

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Chiral amines are widely used as catalysts in asymmetric synthesis to activate carbonyl groups for α-functionalization. Carbonyl catalysis reverses that strategy by using a carbonyl group to activate a primary amine. Inspired by biological carbonyl catalysis, which is exemplified by reactions of pyridoxal-dependent enzymes, we developed an N-quaternized pyridoxal catalyst for the asymmetric Mannich reaction of glycinate with aryl N-diphenylphosphinyl imines. The catalyst exhibits high activity and stereoselectivity, likely enabled by enzyme-like cooperative bifunctional activation of the subst
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Kim, Byungjun, Yongjae Kim, and Sarah Yunmi Lee. "Stereoselective Michael Additions of Arylacetic Acid Derivatives by Asymmetric Organocatalysis." Synlett 33, no. 07 (2022): 609–16. http://dx.doi.org/10.1055/s-0041-1737323.

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AbstractBecause of the versatility of chiral 1,5-dicarbonyl structural motifs, the development of stereoselective Michael additions of arylacetic acid derivatives to electron-deficient alkenes is an important challenge. Over recent decades, an array of enantio- and diastereoselective methods of this type have been developed through the use of chiral organocatalysts. In this article, three distinct strategies in this research area are highlighted. Catalytic generation of either a chiral iminium electrophile (iminium catalysis) or a chiral enolate nucleophile (Lewis­ base catalysis) has allowed
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Zheng, Yidan, Tianze Liu, Jingyou Tai, and Ning Ma. "Recent Advances in Carbon-Based Catalysts for Heterogeneous Asymmetric Catalysis." Molecules 30, no. 12 (2025): 2643. https://doi.org/10.3390/molecules30122643.

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Carbon materials, including graphene, carbon nanotubes, and fullerenes, serve as effective supports for catalysts and play a pivotal role in heterogeneous asymmetric catalysis due to their unique properties and ability to create defined environments for catalytic reactions. Recent research has focused on developing novel carbon-based catalysts that combine the advantages of heterogeneous catalysis with enhanced stability and reusability. This review highlights the synthesis and catalytic applications of graphene, carbon nanotubes, and fullerenes as heterogeneous support materials in asymmetric
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Bergin, Enda. "Asymmetric catalysis." Annual Reports Section "B" (Organic Chemistry) 108 (2012): 353. http://dx.doi.org/10.1039/c2oc90003c.

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Chan, Albert S. C., and Tamio Hayashi. "Asymmetric catalysis." Tetrahedron: Asymmetry 17, no. 4 (2006): 479–80. http://dx.doi.org/10.1016/j.tetasy.2006.03.004.

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Dissertations / Theses on the topic "Asymmetric catalysis"

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Soni, Rina. "Studies in asymmetric catalysis." Thesis, University of Warwick, 2011. http://wrap.warwick.ac.uk/45868/.

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Derivatives of enantiomerically pure 1,2-cyclohexanediamine and 1,2- diphenylethanediamine have been synthesised and used as organocatalysts for asymmetric reactions. The derivatives of 1,2-diphenylethanediamine have been employed for C-C, C-N bond formation reactions to determine their efficacy and selectivity. Compound 278 has shown high efficiency and selectivity for addition of aldehydes to DEAD. Novel Ru-metal complexes containing enantiomerically pure N,N-dialkylated-1,2- diamine ligands have been synthesised. Complexes 299 and 302 were used to study asymmetric transfer hydrogenation of
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Laing, John Christopher Pettigrew. "Monophosphines in asymmetric catalysis." Thesis, University of Oxford, 1995. http://ora.ox.ac.uk/objects/uuid:c24d74bf-d5f9-4997-9c14-5aa419dfe8ba.

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This thesis described investigations into the synthesis and reactions of chiral monophosphines, in five chapters. Chapter 1 introduces asymmetric catalysis, Chapter 2 and 3 describe the synthesis of enantiomerically pure monophosphine via an oxide and borane route respectively. Chapter 4 describes the organometallic reactions of these monophosphines and Chapter 5 contains experimental details of the reactions. <strong>Chapter 1</strong> describes the importance of chirality and significant asymmetric processes. The literature methods of producing homochiral monophosphines are detailed. <strong
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Carter, Christabel Anne. "Asymmetric phase transfer catalysis : towards catalysts with a chiral anion." Thesis, University of Leeds, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.399654.

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Monti, Chiara. "Development of new catalysts for asymmetric catalysis via combinatorial chemistry." Thesis, University of Sheffield, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.398589.

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Konrad, Tina Maria. "Chiral phanephos derived catalysts and their application in asymmetric catalysis." Thesis, University of St Andrews, 2013. http://hdl.handle.net/10023/4499.

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The research presented in this thesis is a project funded by the EU-network of the Marie Curie project NANO-HOST in collaboration with partner institutes. The aims of this network are to develop innovative methods for the preparation, recovery and reuse of single-site, nanostructured catalytic materials, and further on apply them in combination with specifically engineered reactors for a sustainable production process for making high value fine chemicals. One part of this project was to prepare chiral diphosphine ligands and their complexes for currently challenging reactions, such as asymmetr
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Maciver, Eleanor E. "Asymmetric electrocyclic reactions." Thesis, University of Oxford, 2013. http://ora.ox.ac.uk/objects/uuid:17ba3cb0-0c62-406a-bed4-14c410a45918.

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Pericyclic reactions are a class of transformations that comprise sigmatropic rearrangements, group transfer reactions, cycloadditions and electrocyclic reactions. Since Woodward and Hoffmann rationalized the mechanism and stereochemistry of pericyclic reactions they have become powerful synthetic tools. Whilst sigmatropic rearrangements and cycloadditions are cornerstones of contemporary synthetic methodology, many electrocyclic reactions are not fully exploited currently; there are no general methods for the asymmetric catalysis of electrocyclic reactions and as a consequence, opportunities
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Allen, Joanne Victoria. "Recent advances in asymmetric catalysis." Thesis, Loughborough University, 1995. https://dspace.lboro.ac.uk/2134/27574.

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CHAPTER ONE reviews the literature, discussing aspects of transition metal mediated asymmetric catalysis in the presence of enantiomerically pure ligands. CHAPTER TWO discusses the asymmetric addition of dialkyl-zinc reagents to aromatic aldehydes. The work presented is particularly concerned with the design and construction of enantiomerically pure oxazoline ligands tethered to alcohols These ligands have proved effective in the acceleration of the alkylation reaction and are able to influence good levels of asymmetric induction in the resultant secondary alcohol products CHAPTER THREE examin
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Eaves, Richard. "Recoverable reagents for asymmetric catalysis." Thesis, University of Warwick, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.409789.

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Harding, Michael. "New concepts in asymmetric catalysis." Thesis, University of Sheffield, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.284768.

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Durrani, Jamie T. "Palladium catalysed asymmetric hydroxy- and alkoxycarbonylation of alkenes." Thesis, University of St Andrews, 2015. http://hdl.handle.net/10023/6276.

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Palladium catalysed asymmetric hydroxy- and alkoxycarbonylation reactions of alkenes have the potential to deliver valuable chiral carboxylic acid and ester building blocks from cheap feedstocks: alkenes, carbon monoxide and water (alcohols in the case of alkoxycarbonylation). Despite the attractive nature of these reactions, extensive research has so far been unable to produce effective catalysts which are capable of controlling both regio- and enantioselectivity. Building on exciting recent results involving the use of highly enantioselective palladium catalysts derived from Phanephos-type l
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Books on the topic "Asymmetric catalysis"

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Bosnich, B., ed. Asymmetric Catalysis. Springer Netherlands, 1985. http://dx.doi.org/10.1007/978-94-009-5177-8.

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P, Doyle Michael, ed. Asymmetric catalysis. JAI Press, 1997.

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B, Bosnich, North Atlantic Treaty Organization, and North Atlantic Treaty Organization. Scientific Affairs Division., eds. Asymmetric catalysis. M. Nijhoff, 1986.

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Yamamoto, Hisashi, Eric N. Jacobsen, and Andreas Pfaltz. Comprehensive asymmetric catalysis. Springer, 2011.

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1960-, Jacobsen Eric N., Pfaltz Andreas 1948-, and Yamamoto Hisashi, eds. Comprehensive asymmetric catalysis. Springer, 2004.

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1960-, Jacobsen Eric N., Pfaltz Andreas 1948-, and Yamamoto Hisashi, eds. Comprehensive asymmetric catalysis. Springer, 1999.

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P, Doyle Michael, ed. Asymmetric chemical transformations. JAI Press, 1995.

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Malhotra, Sanjay V., ed. Methodologies in Asymmetric Catalysis. American Chemical Society, 2004. http://dx.doi.org/10.1021/bk-2004-0880.

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Rueping, Magnus, Dixit Parmar, and Erli Sugiono. Asymmetric Brønsted Acid Catalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2015. http://dx.doi.org/10.1002/9783527694785.

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Maruoka, Keiji. Asymmetric phase transfer catalysis. Wiley-VCH, 2008.

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Book chapters on the topic "Asymmetric catalysis"

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Bosnich, B. "Asymmetric Oxidation." In Asymmetric Catalysis. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-5177-8_5.

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Bosnich, B. "Introduction." In Asymmetric Catalysis. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-5177-8_1.

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Bosnich, B. "General Principles." In Asymmetric Catalysis. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-5177-8_2.

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Bosnich, B. "Carbon-Hydrogen Bond Formation." In Asymmetric Catalysis. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-5177-8_3.

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Bosnich, B. "Carbon-Carbon Bond Formation." In Asymmetric Catalysis. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-5177-8_4.

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Bosnich, B. "Heterogeneous and Polymer Supported Catalysts." In Asymmetric Catalysis. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-5177-8_6.

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Bosnich, B. "Asymmetric Catalysis by Biochemical Systems." In Asymmetric Catalysis. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-5177-8_7.

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Bosnich, B. "Economic Significance of Asymmetric Catalysis." In Asymmetric Catalysis. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-5177-8_8.

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Bosnich, B. "Future Trends." In Asymmetric Catalysis. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-5177-8_9.

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Shibasaki, M. "Multifunctional Asymmetric Catalysis." In The Role of Natural Products in Drug Discovery. Springer Berlin Heidelberg, 2000. http://dx.doi.org/10.1007/978-3-662-04042-3_11.

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Conference papers on the topic "Asymmetric catalysis"

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Córdova, Armando, Enrique Díaz-Herrera, and Eusebio Juaristi. "Asymmetric Amino Acid Catalysis." In 2007. AIP, 2008. http://dx.doi.org/10.1063/1.2901846.

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Emmerson, Daniel P. G., Renaud Villard, Daniel A. Batsanov, Daniel J. A. K. Howard, Daniel R. Tooze, and Benjamin G. Davis. "CARBOHYDRATE MEDIATED ASYMMETRIC CATALYSIS." In XXIst International Carbohydrate Symposium 2002. TheScientificWorld Ltd, 2002. http://dx.doi.org/10.1100/tsw.2002.506.

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de Parrodi, Cecilia Anaya, Enrique Díaz-Herrera, and Eusebio Juaristi. "Chiral Nitrogen-Containing Ligands in Asymmetric Catalysis." In 2007. AIP, 2008. http://dx.doi.org/10.1063/1.2901851.

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Azeredo, Juliano, Antonio Braga, and Claudio Santi. "Solvent-Free Asymmetric Alcoxy-Selenylation of Styrenes using I2 / DMSO Catalytic System." In 1st International Electronic Conference on Catalysis Sciences. MDPI, 2020. http://dx.doi.org/10.3390/eccs2020-07563.

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Rosini, Carlo, Tommaso Mecca, and Stefano Superchi. "Preparation of new enantiopure atropisomeric b-aminoalcohols and their use in asymmetric catalysis: enantioselective addition of diethylzinc to aromatic aldehydes." In The 4th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01785.

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Liu, Min, Zhi-Ping Zhao, and Jian-Hui Li. "Ceramic Membrane Immobilized Salen Catalysts and Their Use in Asymmetric Catalytic Reactions." In International Conference on Chemical,Material and Food Engineering. Atlantis Press, 2015. http://dx.doi.org/10.2991/cmfe-15.2015.9.

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Zhimin, Ou, and Yang Gensheng. "Asymmetric Synthesis of Ethyl (R)-2-hydroxy-4-phenylbutyrate with Catalytic Antibody NB5 as Catalyst." In 2012 International Conference on Biomedical Engineering and Biotechnology (iCBEB). IEEE, 2012. http://dx.doi.org/10.1109/icbeb.2012.85.

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Rui, Miao, and Changjin Zhu. "Asymmetric Hydrogenation of , -unsaturated ester with Copper Catalyst." In 2015 International Conference on Industrial Technology and Management Science. Atlantis Press, 2015. http://dx.doi.org/10.2991/itms-15.2015.265.

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Goryunova, V. D., and L. O. Nindakova. "Asymmetric transfer hydrogenation over rhodium catalysts in the presence of chiral diamine." In INTERNATIONAL CONFERENCE ON PHYSICS AND CHEMISTRY OF COMBUSTION AND PROCESSES IN EXTREME ENVIRONMENTS (COMPHYSCHEM’20-21) and VI INTERNATIONAL SUMMER SCHOOL “MODERN QUANTUM CHEMISTRY METHODS IN APPLICATIONS”. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0033044.

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Malakar, Chandi, Guenter Helmchen, and Richa Gupta. "First Immobilized Catalysts for Iridium- Catalyzed Asymmetric Allylic Amination – Rate Enhancement by Immobilization." In 5th Annual International Conference on Chemistry, Chemical Engineering and Chemical Process (CCECP 2017). Global Science & Technology Forum (GSTF), 2017. http://dx.doi.org/10.5176/2301-3761_ccecp17.26.

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Reports on the topic "Asymmetric catalysis"

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Reilly, S. D., D. R. Click, S. K. Grumbine, B. L. Scott, and J. G. Watkins. Asymmetric catalysis in organic synthesis. Office of Scientific and Technical Information (OSTI), 1998. http://dx.doi.org/10.2172/677032.

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Ritzen, Jo. Europeanizing Universities: A Catalyst for Social Cohesion and Sustainable Economic Development. UNU-MERIT, 2025. https://doi.org/10.53330/szjm8526.

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This paper explores the transformative potential of intra-EU student mobility as a cornerstone for fostering social cohesion, economic resilience, and pan-European identity. By analyzing historical trajectories, policy frameworks (e.g., Erasmus+), and case studies from Denmark, the Netherlands, Germany, and Eastern Europe, we argue that achieving 50% intra-EU student mobility by 2035 could counteract nationalist fragmentation, address labor shortages, and catalyze innovation. However, systemic challenges—brain drain, political resistance, linguistic tensions, and funding inequities—necessitate
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Manna, Kuntal. Transition metal complexes of oxazolinylboranes and cyclopentadienyl-bis(oxazolinyl)borates: Catalysts for asymmetric olefin hydroamination and acceptorless alcohol decarbonylation. Office of Scientific and Technical Information (OSTI), 2012. http://dx.doi.org/10.2172/1082975.

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