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Dissertations / Theses on the topic 'Asymmetric oxidation'

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Published: 4 June 2021

Last updated: 25 July 2025

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1

Heer, Jag Paul. "New methods of asymmetric oxidation." Thesis, University of Liverpool, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.484195.

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2

Elliott, Claire. "Novel electrochemical systems for asymmetric oxidation." Thesis, Loughborough University, 2011. https://dspace.lboro.ac.uk/2134/8491.

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Organic reactions, which can be carried out in water and in the absence of heavy metals, are becoming more important today due to concerns over safety and environmental impact. Thus if an oxidation reaction can be carried out, where the oxidant is generated in-situ using electrolysis, then this is advantageous over existing systems that use strong or large volumes of stoichiometric oxidant and solvent, that cannot be recycled. In this thesis a wide variety of conditions and methods for producing enantiomerically enriched epoxides and sulfoxides have been reported using both electrochemically g

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3

Tolhurst, Keith F. "Asymmetric allylic and progargylic oxidation reactions." Thesis, University of Nottingham, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.285642.

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4

Hayward, Mark M. "Asymmetric allylic and propargylic oxidation reactions." Thesis, University of Nottingham, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.252006.

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5

Tucker, S. C. "Towards novel ligands for catalytic asymmetric oxidation." Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.242038.

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6

Green, Stuart D. "Combinatorial approaches to catalysts for asymmetric oxidation." Thesis, University of Newcastle Upon Tyne, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.327227.

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7

Drago, Carmelo. "Combinatorial approaches to catalysis for asymmetric sulfide oxidation." Thesis, University of Sheffield, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.422111.

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8

葉耀宗 and Yiu-chung Yip. "Asymmetric epoxidation of unfunctionalized olefins catalyzed by chiralketones." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1996. http://hub.hku.hk/bib/B31236406.

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9

Walker, Emma-Jane. "New methods for the discovery of asymmetric oxidation catalysts." Thesis, University of Sheffield, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.485084.

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10

Wailes, J. Steven. "Novel chiral ketones as catalysts for asymmetric oxidation reactions." Thesis, University of Nottingham, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.364652.

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11

Maddrell, Samuel James. "The application of organonitrile compounds to asymmetric synthesis." Thesis, University of Exeter, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.294473.

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12

Pietikäinen, Pekka. "Mn-salen catalyzed asymmetric epoxidation : search for new oxidation systems." Helsinki : University of Helsinki, 2001. http://ethesis.helsinki.fi/julkaisut/mat/kemia/vk/pietikainen/.

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13

黃文健 and Man-kin Wong. "Design and synthesis of chiral ketones for catalytic asymmetric epoxidation of unfunctionalized olefins." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1996. http://hub.hku.hk/bib/B31236285.

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14

Panchgalle, S. P. "Organocatalytic asymmetric synthesis of bioactive molecules and oxidation studies in ionic liquids." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2009. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2767.

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15

Parker, Phillip. "New systems for catalytic asymmetric epoxidation." Thesis, Loughborough University, 2009. https://dspace.lboro.ac.uk/2134/5442.

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This thesis describes the catalytic asymmetric epoxidation of olefins mediated by chiral iminum salts. The first chapter introduces some of the most novel and effective catalytic asymmetric methods for preparing chiral oxiranes. The second chapter is divided into three sections. The first section of chapter two is dedicated to our efforts to develop new aqueous oxidative conditions using both hydrogen peroxide and sodium hypochlorite as efficient, green oxidants that remove the temperature boundaries observed with the use of Oxone® as the stoichiometric oxidant. A wider range of available temp

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16

何麗薇 and Lai-mei Ho. "Asymmetric epoxidation of olefins catalyzed by chiral iminium salts generated in situ from amines and aldehydes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2001. http://hub.hku.hk/bib/B31226048.

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17

Zhang, Rui, and 張瑞. "Asymmetric organic oxidation by chiral ruthenium complexes containing D2 and D4 symmetric porphyrinato ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2000. http://hub.hku.hk/bib/B42576246.

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18

Zhang, Rui. "Asymmetric organic oxidation by chiral ruthenium complexes containing D2 and D4 symmetric porphyrinato ligands." Click to view the E-thesis via HKUTO, 2000. http://sunzi.lib.hku.hk/hkuto/record/B42576246.

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19

Ho, Chun-yu, and 何振宇. "Asymmetric epoxidation of olefins and cyclization reactions catalyzed by amines." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2005. http://hub.hku.hk/bib/B45014814.

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20

Qin, Bo. "Development of novel low-oxidation state main group catalysis : gallium & aluminium." Thesis, University of Edinburgh, 2016. http://hdl.handle.net/1842/21997.

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This PhD thesis is focused on the development of novel catalysis with low-oxidation main group species, mainly based on the group 13 element gallium, a relatively abundant, inexpensive, and low-toxic metal. Gallium in its stable high-oxidation state ‘+III’ is a commonly used Lewis acid catalyst in organic synthesis. In contrast, gallium in its less stable low-oxidation state ‘+I’ is under-explored, but may display both acceptor and donor properties at a single site (ambiphilicity). Based on the hypothesis that potentially ambiphilic gallium(I) –oxidatively generated in situ from gallium(0) usi

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21

馮偉康 and Wai-hong Fung. "Catalytic and asymmetric organic oxidations by chiral oxoruthenium(IV)and cis- dioxoruthenium(VI) complexes with nitrogen donor ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1998. http://hub.hku.hk/bib/B31236881.

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22

Dewkar, G. K. "Asymmetric synthesis of bioactive molecules and synthetic methods involving oxidation of N-H, O-H bonds and oxidative halogenation of arenes and alkenes." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2003. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2870.

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23

Elhussein, Magdi Awadalla Mohamed. "Synthetic Studies towards (+)-Pancratistatin Using an Asymmetric Conjugate addition and Oxidation of Amine to Amide as Key steps." 京都大学 (Kyoto University), 2009. http://hdl.handle.net/2433/124043.

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24

Tsang, W. C. Peter 1975. "High oxidation state molybdenum and tungsten imido alkylidene and metallacycle chemistry : catalytic asymmetric olefin metathesis and mechanistic investigation." Thesis, Massachusetts Institute of Technology, 2004. http://hdl.handle.net/1721.1/30064.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2004.<br>Vita.<br>Includes bibliographical references.<br>Enantiomerically pure molybdenum imido alkylidene complexes of the type Mo(NAr)(CHCMe₂Ph)[Ar'](THF), which contained 3,3'-diaryl (Ar' = Mes (21), Ph (22)) substituted binaphtholate ligands, were prepared and structurally characterized. Complex 21 was a trigonal bipyramidal anti alkylidene complex; both 21 and 22 were anti-THF adducts. Temperature and concentration dependent enantioselective desymmetrization of prochiral trienes by catalyst 21 afforded five- and

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25

Griffen, Julia Anne. "Underexploited (ipso, ortho) microbial arene dihydroxylation : uses in synthesis & catalysis." Thesis, University of Bath, 2013. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.619147.

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This thesis sought to expand upon the synthetic application of the underexploited ipso, ortho diene cis-diol microbial arene oxidation product from benzoic acid. The microbial oxidation of benzoic acid by mutant strains of bacteria to give the ipso, otho diene cis-diol may be considered to be a green and clean method. This biocatalytic route yields large quantities of an enantiopure chiral building block, which is not assessable via traditional synthetic methods. The fermentation product has seen application towards the synthesis of aminocylitols, which have been tested for their biological ac

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26

Engqvist, Magnus. "Direct Amino Acid-Catalyzed Enantioselective α-Oxidation Reactions and Asymmetric de novo Synthesis of Carbohydrates". Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-449.

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The ability of amino acids to form nucleophilic enamines with aldehydes and ketones has been used in the development of asymmetric α-oxidation reactions with electrophilic oxidizing agents. Singlet molecular oxygen has for the first time been asymmetrically incorporated into aldehydes and ketones, and the products were isolated as their corresponding diols in good yields and ee’s. Organocatalytic α-oxidations of cyclic ketones with iodosobenzene and N-sulfonyloxaziridine were also possible and furnished after reduction the product diols in generally low yields and in low to good ee’s. Amino ac

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27

Kurlemann, Nils. "Evaluation of C-C-bond coupling enzymes as reversibly immobilised biocatalysts and for the application in a coupled asymmetric alkene oxidation." Berlin mbv, 2008. http://d-nb.info/990627527/04.

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28

Lifchits, Olga [Verfasser], Benjamin [Akademischer Betreuer] List та Hans-Günther [Akademischer Betreuer] Schmalz. "Organocatalytic Approaches to Asymmetric Oxidation : Epoxidation of α-Branched Enals and α-Benzoyloxylation of Carbonyl Compounds / Olga Lifchits. Gutachter: Benjamin List ; Hans-Günther Schmalz". Köln : Universitäts- und Stadtbibliothek Köln, 2012. http://d-nb.info/1038226295/34.

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29

Jahier, Claire. "Polyoxométallates dendritiques énantiopurs recyclables pour la catalyse asymétrique." Thesis, Bordeaux 1, 2010. http://www.theses.fr/2010BOR14093/document.

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Les polyoxométallates (POMs) dendritiques constituent une catégorie de catalyseursrelativement nouvelle. L’association d’un dendrimère avec un polyoxométallate permet debénéficier des propriétés catalytiques intéressantes des POMs et de pouvoir modifier cespropriétés en variant la structure du dendrimère. Une variété de composés hybrides POMsdendritiques a été préparée par formation de liaisons ioniques entre une unité POM anioniqueachirale et des cations dendritiques énantiopurs. Ces composés se sont montrés très efficacespour la catalyse d’oxydation asymétrique, avec une stéréosélectivité si

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30

Huang, Weisheng. "Catalytic asymmetric cyclopropanation and oxidation of tri-, di- and monofluoromethyl styrenes Rhodium catalysed enantioselective synthesis of mono-(halo)-methyl-cyclopropanes Catalytic enantioselective synthesis of highly functionalized difluoromethylated cyclopropanes General catalytic enantioselective access to monohalomethyl and trifluoromethyl cyclopropanes Catalytic asymmetric synthesis of α,α-difluoromethylated and α-fluoromethylated tertiary alcohols". Thesis, Normandie, 2019. http://www.theses.fr/2019NORMIR25.

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Ce manuscrit décrit la synthèse énantiosélective de cyclopropanes trifluorométhylés, difluorométhylés et mono-halométhylés hautement fonctionnalisés. Cette synthèse repose sur la cyclopropanation d’alcènes. De plus, la synthèse d’alcools tertiaires difluorométhylés à partir des oléfines fluorées correspondantes suivant un processus de dihydroxylation asymétrique est décrite. Ce manuscrit se découpe en 3 chapitres. Le premier chapitre décrit la première synthèse catalytique asymétrique de cyclopropanes difluorométhylés en utilisant le Rh₂((S)-BTPCP)₄ comme catalyseur pour la réaction de cyclopr

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31

Jiang, Tuo. "Palladium(II)-Catalyzed Oxidative Carbocyclization : Stereoselective Formation of C–C and C–B Bonds." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-108669.

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Transition metal catalysis has emerged as one of the most versatile methods for the selective formation of carbon–carbon and carbon–heteroatom bonds. In particular, oxidative carbon–carbon bond forming reactions have been widely studied due to their atom economic feature. This thesis has been focused on the development of new palladium(II)-catalyzed carbocyclization reactions under oxidative conditions. The first part of the thesis describes the palladium(II)-catalyzed oxidative carbocyclization-borylation and -arylation of enallenes. In these reactions, the (σ-alkyl)palladium(II) intermediate

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32

More, Jesse D. More Jesse D. More Jesse D. "1. A convenient and advantageous protocol for the oxidation of alcohols with o-iodoxybenzoic acid (IBX) ; 2. Asymmetric formal synthesis of polyoxin C ; 3. Synthetic studies toward octosyl acid A /." Diss., Connect to a 24 p. preview or request complete full text in PDF format. Access restricted to UC campuses, 2004. http://wwwlib.umi.com/cr/ucsd/fullcit?p3123661.

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33

Cecil, Alexander Richard Liam. "Asymmetric oxidative cyclisation of dienes." Thesis, University of Southampton, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.402065.

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34

Aybey, Asuman. "Synthesis Of Chiral Lactones Via The Baeyer Villiger Oxidation Of Cyclic Aromatic Acetoxy Ketones Novel Annulation Reactions Of 2-propynyl-1,3-dicarbonyl Compounds To Form Pyrroles Addition Of Acyl Phosphonates To Diethyl Cyanophosphonate (depc)." Phd thesis, METU, 2008. http://etd.lib.metu.edu.tr/upload/3/12610293/index.pdf.

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Chiral Baeyer-Villiger (BV) oxidation of cyclic ketones allows rapid access to asymmetric lactones as valuable intermediates in organic chemistry and frequently encountered precursors in enantioselective synthesis. In the first part, BV oxidation of functionalized ketones, especially cyclic &amp<br>#61537<br>-hydroxy and acetoxy ketones is described which could be a straightforward route to the &amp<br>#61537<br>-hydroxy lactones and &amp<br>#61537<br>-hydroxyalkanoic acid derivatives. The &amp<br>#61537<br>-acetoxylation of indanone, tetralone and chromanone derivatives by using Mn(OAc)3 fol

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35

McConville, Gareth James. "Asymmetric oxidations/reductions and their applications in synthesis." Thesis, Queen's University Belfast, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.246467.

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36

Srour, Hassan. "Catalyse avec des métalloporphyrines : oxydation asymétrique et transfert de carbènes." Phd thesis, Université Rennes 1, 2013. http://tel.archives-ouvertes.fr/tel-00910073.

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La mission centrale de la chimie verte est d'inventer de nouveaux procédés non polluants pour remplacer les technologies peu favorables à l'environnement. L'emploi de métaux de transition relativement non toxiques en quantités catalytiques associés à des ligands chiraux a permis de réaliser une avancée dans le domaine de la synthèse asymétrique. Dans ce travail, nous avons mis en évidence la possibilité de l'utilisation du peroxyde d'hydrogène, un oxydant vert et économique, en association avec des métalloporphyrines hydrosolubles (Fe, Mn) pour effectuer des réactions d'oxydation asymétrique (

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37

Abada, Zahra. "Synthèse de porphyrines chirales : application en oxydation asymétrique et application antiparasitaire et anticancéreuse." Thesis, Paris 11, 2012. http://www.theses.fr/2012PA114806.

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Les molécules chirales représentent environ 60% des médicaments présents sur le marché pharmaceutique et plus de 80% des médicaments en développement avec plus de 150 milliards de dollars de chiffre d’affaire pour l’année 2002. Les intermédiaires chiraux sont fortement demandés dans l’industrie pharmaceutique atteignant 15 milliards de dollars de chiffre d’affaire en 2009. D’autres domaines en sont demandeurs avec une répartition d’environ 15% dans l’agrochimie et 5% pour la parfumerie. L’obtention de composés d’intérêt pharmaceutique de façon asymétrique est un réel défi et une réelle nécessi

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38

Coffinier, Romain. "Nouveaux iodanes chiraux pour des réactions d’oxygénation asymétriques." Thesis, Bordeaux 1, 2013. http://www.theses.fr/2013BOR14974/document.

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Ces travaux concernent le développement de nouveaux iodanes chiraux et leur application à des réactions d’oxygénation asymétriques. Ces réactifs à base d’iode hypervalent constituent une alternative intéressante aux réactifs à base de métaux lourds en termes de réactivité et de toxicité. La première partie de ce travail a été consacrée à la synthèse de nouvelles structures originales C 2 -symétriques énantiopures de type S alen. Un criblage de conditions oxydantes a ensuite montré que seul le 3,3-diméthyldioxirane (DMDO) permet une oxydation propre et sélective de ces iodoarènes en iodanes-λ5

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39

Bosset, Cyril. "Synthèse d’iodanes biaryliques chiraux : application à des réactions d’oxygénation asymétrique." Thesis, Bordeaux 1, 2013. http://www.theses.fr/2013BOR14983/document.

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La chimie des dérivés à base d’iode hypervalent, également appelés iodanes, connaît depuis la fin des années 1990 un essor important qui s’explique par leurs conditions d’utilisation douces et leur faible toxicité comparée à celle des réactifs à base de métaux lourds. Plus récemment, des versions chirales de ces réactifs font l’objet de nombreuses recherches. Dans ce contexte, une première partie de ces travaux de thèse a consisté à développer de nouveaux iodanes chiraux basés sur un squelette biarylique atropoiso-mériquement pur de type soit 1,1’-binaphtyle, soit 5,5’,6,6’,7,7’,8,8’-octahydro

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40

Craveiro, Marcus Vinicius. "Estudos visando à síntese assimétrica de indanos através de reações de contração de anel promovidas por tálio(III)." Universidade de São Paulo, 2004. http://www.teses.usp.br/teses/disponiveis/46/46135/tde-08082016-183730/.

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Esta dissertação apresenta estudos visando à síntese de indanos oticamente ativos, através da contração de anel de 3-alquenóis promovida por tálio(III). Dois novos sais de tálio(III) foram preparados - o (S)-(-)-triacetoxipropionato de tálio (TTAP) e o tripropionato de tálio (TTP) - a partir do triacetato de tálio (TTA) e dos ácidos (S)-(-)-2-acetoxipropiônico e propiônico, respectivamente. A ciclização do isopulegol foi realizada com TTAP e com TTP, em rendimentos similares aos obtidos com TTA e com trinitrato de tálio (TTN). O rearranjo oxidativo do 2-(3,4-diidronaftalen-1-il)-etanol, que é

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41

Crosby, Natasha M. "The role of oxidation in hyperglycemia-mediated erythrocyte phospholipid asymmetry." [Bloomington, Ind.] : Indiana University, 2009. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3344761.

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Thesis (Ph. D.)--Indiana University, Dept. of Biology, 2009.<br>Title from PDF t.p. (viewed Oct. 8, 2009). Source: Dissertation Abstracts International, Volume: 70-02, Section: B, page: 0830. Adviser: David L. Daleke.

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42

Drouet, Fleur. "Synthèse énantiosélective d'1,2 et 1,3-diamines et Développement de réactions multicomposants dans des conditions oxydantes." Phd thesis, Université Paris Sud - Paris XI, 2011. http://tel.archives-ouvertes.fr/tel-00823407.

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Ce projet scientifique porte sur le développement de nouvelles voies d'accès à des composés azotés hautement fonctionnalisés en s'adaptant aux principes de chimie verte. Tout d'abord, une réaction d'Ugi quatre composants à partir d'alcools a été étudiée. L'utilisation de dérivés de l'iode hypervalent comme oxydant en quantités stoechiométriques ou catalytiques a permis de réaliser un processus one-pot oxydation d'alcools/réaction d'Ugi efficace. Par la suite, une nouvelle réaction de Mannich quatre composants, réalisée en présence d'un acide phosphorique dérivé du BINOL, a permis l'accès à des

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43

Hamze, Khalil. "Baeyer-Villiger monooxygenases d'Acinetobacter : réactions biocatalysées et dédoublements cinétiques dynamiques." Thesis, Aix-Marseille, 2014. http://www.theses.fr/2014AIXM4311/document.

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L'oxydation de Baeyer-Villiger (BV) par voie enzymatique est une méthode efficace pour obtenir de lactones sous forme énantiomériquement pure. Les Baeyer-Villiger Monooxygénases (BVMO) sont ainsi capables d'oxyder de nombreux substrats avec une stéréospécificité remarquable.Nous avons recherché de nouvelles enzymes dans le génome de deux souches appartenant au genre Acinetobacter, A. baylyi ADP1 et A. baumannii AYE. Six gènes ont été clonés dans E. coli. Leur profil de substrat a été étudié en utilisant des cellules entières de ce microorganisme recombinant comme biocatalyseur. Quatre enzymes

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44

Hallman, Kristina. "Asymmetric Catalysis : Ligand Design and Conformational Studies." Doctoral thesis, KTH, Chemistry, 2001. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3275.

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<p>This thesis deals with the design of ligands for efficientasymmetric catalysis and studies of the conformation of theligands in the catalytically active complexes. All ligandsdeveloped contain chiral oxazoline heterocycles.</p><p>The conformations of hydroxy- and methoxy-substitutedpyridinooxazolines and bis(oxazolines) during Pd-catalysedallylic alkylations were investigated using crystallography,2D-NMR techniques and DFT calculations. A stabilising OH-Pdinteraction was discovered which might explain the differencein reactivity between the hydroxy- and methoxy-containingligands. The confor

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45

Ahmad, Anees. "Exploring the iodine(III)-mediated ring contraction: new substrates, novel conditions and asymmetric reactions." Universidade de São Paulo, 2015. http://www.teses.usp.br/teses/disponiveis/46/46136/tde-29092015-145020/.

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In the first section this thesis includes the reactivity of various oxygen-containing benzofused cyclic alkenes with HTIB (Hydroxy(tosyloxy)iodobenzene). Instead of getting ring contraction products, 2H-chromene resulted in 4H-chromenes together with trans-addition products. Only cis-addition products were isolated from 4-methyl-2H-chromene. Ring contraction was observed in dihydrobenzoxepines and 2,2-dimethyl-2H-chromenes giving functionalized chromanes and benzofurans, respectively. In the second part, the ring contraction of 1,2-dihydronaphthalenes using HTIB was expanded to substrates be

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46

Bhunnoo, Riaz A. "Permanganate promoted bi-directional oxidative cyclisation (Part 1) ; Permanganate-mediated asymmetric dihydroxylation (Part 2)." Thesis, University of Southampton, 2005. https://eprints.soton.ac.uk/426926/.

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47

Ratajczak, Fabien. "Synthèse et réactivité de nitroxydes chiraux." Université Joseph Fourier (Grenoble), 1997. http://www.theses.fr/1997GRE10134.

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Les nitroxydes sont des radicaux libres qui sont reduits en hydroxylamine ou oxydes en sel d'oxoammonium par des processus monoelectroniques reversibles. Les sels d'oxoammonium formes in situ oxydent notamment les alcools primaires et secondaires dans des conditions douces, catalytiques, et sont chimio et regioselectifs. Pour tester leurs potentialites en synthese asymetriques, deux methodes de synthese de nitroxydes chiraux a axe de symetrie c#2 ont ete mises au point. La premiere methode, originale, met en jeu la formation de dienolates en ,' d'aminodiesters suivie de leur reaction avec des

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48

Hamze, Khalil. "Baeyer-Villiger monooxygenases d'Acinetobacter : réactions biocatalysées et dédoublements cinétiques dynamiques." Electronic Thesis or Diss., Aix-Marseille, 2014. http://www.theses.fr/2014AIXM4311.

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L'oxydation de Baeyer-Villiger (BV) par voie enzymatique est une méthode efficace pour obtenir de lactones sous forme énantiomériquement pure. Les Baeyer-Villiger Monooxygénases (BVMO) sont ainsi capables d'oxyder de nombreux substrats avec une stéréospécificité remarquable.Nous avons recherché de nouvelles enzymes dans le génome de deux souches appartenant au genre Acinetobacter, A. baylyi ADP1 et A. baumannii AYE. Six gènes ont été clonés dans E. coli. Leur profil de substrat a été étudié en utilisant des cellules entières de ce microorganisme recombinant comme biocatalyseur. Quatre enzymes

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Fung, Wai-hong. "Catalytic and asymmetric organic oxidations by chiral oxoruthenium(IV) and cis- dioxoruthenium(VI) complexes with nitrogen donor ligands /." Hong Kong : University of Hong Kong, 1998. http://sunzi.lib.hku.hk/hkuto/record.jsp?B19481688.

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Paraskar, A. S. "Enantioselective synthesis of bioactive molecules via metalcatalyzed asymmetric reductions, oxidations of alkenes and addition by nucleophiles onto imines." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2005. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2464.

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