Academic literature on the topic 'Aza-Piancatelli'

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Journal articles on the topic "Aza-Piancatelli"

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Zheng, Wen-Hua, Wu-Bang Tang, Kou-Sen Cao, and Shan-Shui Meng. "Boronic Acid Catalysis for Aza-Piancatelli Rearrangement." Synthesis 49, no. 16 (2017): 3670–75. http://dx.doi.org/10.1055/s-0036-1589040.

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A first example of boronic acid catalyzed intermolecular aza-Piancatelli rearrangement to access a wide range of trans-4,5-disubstituted cyclopentenones is described. The catalytic system can also be extended to intramolecular aza-Piancatelli rearrangement to afford a wide range of azaspirocycles. Good to excellent yields were obtained in an excellent diastereoselective manner.
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Patil, Nitin, and Amol Gade. "Catalytic Enantioselective Aza-Piancatelli Rearrangement." Synlett 28, no. 09 (2017): 1096–100. http://dx.doi.org/10.1055/s-0036-1558952.

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Li, Huilin, Rongbiao Tong, and Jianwei Sun. "Catalytic Enantioselective Aza-Piancatelli Rearrangement." Angewandte Chemie 128, no. 48 (2016): 15349–52. http://dx.doi.org/10.1002/ange.201607714.

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Li, Huilin, Rongbiao Tong, and Jianwei Sun. "Catalytic Enantioselective Aza-Piancatelli Rearrangement." Angewandte Chemie International Edition 55, no. 48 (2016): 15125–28. http://dx.doi.org/10.1002/anie.201607714.

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Lebœuf, David, Emmanuelle Schulz, and Vincent Gandon. "Calcium(II)-Catalyzed Aza-Piancatelli Reaction." Organic Letters 16, no. 24 (2014): 6464–67. http://dx.doi.org/10.1021/ol5032987.

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Marin, Lucile, Soufyan Jerhaoui, Emilie Kolodziej, et al. "Sulfoxide‐Controlled Stereoselective Aza‐Piancatelli Reaction." Advanced Synthesis & Catalysis 363, no. 17 (2021): 4277–82. http://dx.doi.org/10.1002/adsc.202100848.

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Veits, Gesine K., Donald R. Wenz, Leoni I. Palmer, André H. St. Amant, Jason E. Hein, and Javier Read de Alaniz. "Cascade rearrangement of furylcarbinols with hydroxylamines: practical access to densely functionalized cyclopentane derivatives." Organic & Biomolecular Chemistry 13, no. 31 (2015): 8465–69. http://dx.doi.org/10.1039/c5ob00944h.

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The aza-Piancatelli rearrangement with hydroxylamines to 4-aminocyclopentenones is described. Subsequent transformations highlight the versatility of the cyclopentene scaffold and the value of the hydroxylamine in this transformation.
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Hammersley, Gabrielle R., Meghan F. Nichol, Helena C. Steffens, Jose M. Delgado, Gesine K. Veits, and Javier Read de Alaniz. "Enantioselective PCCP Brønsted acid-catalyzed aza-Piancatelli rearrangement." Beilstein Journal of Organic Chemistry 15 (July 12, 2019): 1569–74. http://dx.doi.org/10.3762/bjoc.15.160.

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An enantioselective aza-Piancatelli rearrangement has been developed using a chiral Brønsted acid based on pentacarboxycyclopentadiene (PCCP). This reaction provides rapid access to valuable chiral 4-amino-2-cyclopentenone building blocks from readily available starting material and is operationally simple.
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Shen, Bin, Qianwen He, Shunxi Dong, Xiaohua Liu, and Xiaoming Feng. "A chiral cobalt(ii) complex catalyzed enantioselective aza-Piancatelli rearrangement/Diels–Alder cascade reaction." Chemical Science 11, no. 15 (2020): 3862–67. http://dx.doi.org/10.1039/d0sc00542h.

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An asymmetric aza-Piancatelli rearrangement/Diels–Alder cascade reaction between 2-furylcarbinols and N-(furan-2-ylmethyl)anilines was realized by using a chiral N,N′-dioxide/cobalt(ii) complex catalyst.
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Palmer, L., and J. Read de Alaniz. "Dysprosium(III) Triflate Catalyzed Aza-Piancatelli Rearrangement." Synfacts 2011, no. 11 (2011): 1264. http://dx.doi.org/10.1055/s-0031-1289300.

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Dissertations / Theses on the topic "Aza-Piancatelli"

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Marin, Lucile. "Réaction d’aza-Piancatelli : nouvelles applications, version diastéréosélective et utilisation en synthèse totale." Thesis, Université Paris-Saclay (ComUE), 2018. http://www.theses.fr/2018SACLS206.

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Grâce à leurs multiples sites de fonctionnalisation, les cyclopenténones sont des intermédiaires particulièrement utiles dans la synthèse de produits naturels d’intérêt thérapeutique. En particulier, les composés 4-aminocyclopenténones permettent l’accès au motif aminocyclopentitol présent dans des molécules bioactives telles que le peramivir, la pactamycine, ou encore la trehazoline. L’une des méthodes les plus efficaces pour accéder aux 4-aminocyclopenténones est la réaction de cyclisation d’aza-Piancatelli. Cette réaction est basée sur le réarrangement de 2-furylcarbinols en présence d’un n
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