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Journal articles on the topic 'Azaacène'

Author: Grafiati

Published: 25 May 2024

Last updated: 31 July 2025

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1

Jakobi, Dörthe, André Schumann, and Rainer Beckert. "Integrating the fluorene substructure into azaacenes: syntheses of novel fluorophores." Zeitschrift für Naturforschung B 73, no. 7 (2018): 493–500. http://dx.doi.org/10.1515/znb-2018-0023.

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Abstract In this study, we report on the syntheses of novel angular fused azaacenes. For this purpose, the synthesis of the bis-diamine 2 (TABEF) could be shortened and optimized. The condensation reaction of 2 with different types of 1,2-diketones yielded new azaacene derivatives of types 10, 11 and 12. Analogously, 2 was cyclized with thionyl chloride to give the piazthiol derivative 13. The optical and electrochemical properties of all new compounds were investigated by UV/Vis absorption, fluorescence emission spectroscopy and cyclovoltammetric measurements.

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2

Hayashi, Hironobu, and Hiroko Yamada. "On-Surface Synthesis of Acene-Based Molecules and Nanostructures." ECS Meeting Abstracts MA2025-01, no. 18 (2025): 1296. https://doi.org/10.1149/ma2025-01181296mtgabs.

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Polyacenes and polyazaacenes have attracted significant attention because of their potential applications in material science, particularly their expected magnetic properties, which make them promising for device applications. However, synthesizing polyacenes/azaacenes is challenging due to their low solubility and stability. To address these issues, we utilize “thermal and photochemical precursor methods”. Briefly, bicyclo[2.2.2]octadiene(BCOD)-fused acenes can be converted to the corresponding acenes by the thermally induced retro-Diels-Alder reaction, while alpha-diketone-type precursors ca

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3

Elter, Maximilian, Lukas Ahrens, Stella M. Luo, et al. "Cata ‐Annulated Azaacene Bisimides." Chemistry – A European Journal 27, no. 48 (2021): 12284–88. http://dx.doi.org/10.1002/chem.202101573.

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4

Wen, Keke, Xiao Pan, Songyan Feng, Wenpeng Wu, Xugeng Guo, and Jinglai Zhang. "Improving the electron transport performance by changing side chains in sulfur-containing azaacenes: a combined theoretical investigation on free molecules and an adsorption system." New Journal of Chemistry 43, no. 14 (2019): 5414–22. http://dx.doi.org/10.1039/c8nj06408c.

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5

Guevara-Level, Patricia, Simon Pascal, Olivier Siri, and Denis Jacquemin. "First principles investigation of the spectral properties of neutral, zwitterionic, and bis-cationic azaacenes." Physical Chemistry Chemical Physics 21, no. 41 (2019): 22910–18. http://dx.doi.org/10.1039/c9cp04835a.

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6

Wang, Zongrui, Renping Li, Kexiang Zhao, et al. "A co-crystallization strategy toward high-performance n-type organic semiconductors through charge transport switching from p-type planar azaacene derivatives." Journal of Materials Chemistry C 10, no. 7 (2022): 2757–62. http://dx.doi.org/10.1039/d1tc04610a.

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7

Gu, Pei-Yang, Zilong Wang, Fang-Xing Xiao, et al. "An ambipolar azaacene as a stable photocathode for metal-free light-driven water reduction." Materials Chemistry Frontiers 1, no. 3 (2017): 495–98. http://dx.doi.org/10.1039/c6qm00113k.

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8

Gu, Pei-Yang, Guangfeng Liu, Jun Zhao, et al. "Understanding the structure-determining solid fluorescence of an azaacene derivative." Journal of Materials Chemistry C 5, no. 34 (2017): 8869–74. http://dx.doi.org/10.1039/c7tc03089d.

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Three different single crystal forms of an azaacene derivative with different fluorescence quantum yields have been obtained and the relationship between their structures and fluorescence have been studied.

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9

Wang, Zilong, Zongrui Wang, Yecheng Zhou, et al. "Structure engineering: extending the length of azaacene derivatives through quinone bridges." Journal of Materials Chemistry C 6, no. 14 (2018): 3628–33. http://dx.doi.org/10.1039/c8tc00628h.

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10

An, Cunbin, Xin Guo, and Martin Baumgarten. "Highly Ordered Phenanthroline-Fused Azaacene." Crystal Growth & Design 15, no. 11 (2015): 5240–45. http://dx.doi.org/10.1021/acs.cgd.5b00701.

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11

Müller, Matthias, Silke Koser, Olena Tverskoy, Frank Rominger, Jan Freudenberg, and Uwe H. F. Bunz. "Thiadiazolo‐Azaacenes." Chemistry – A European Journal 25, no. 24 (2019): 6082–86. http://dx.doi.org/10.1002/chem.201900462.

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12

Das, Rajorshi, Michael Linseis, Stefan M. Schupp, Franciska S. Gogesch, Lukas Schmidt-Mende, and Rainer F. Winter. "Organic binary charge-transfer compounds of 2,2′ : 6′,2′′ : 6′′,6-trioxotriphenylamine and a pyrene-annulated azaacene as donors." RSC Advances 13, no. 6 (2023): 3652–60. http://dx.doi.org/10.1039/d2ra07322f.

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Three binary charge-transfer (CT) compounds resulting from the donor 2,2′ : 6′,2′′ : 6′′,6-trioxotriphenylamine (TOTA) and the acceptors F4TCNQ and F4BQ and of a pyrene-annulated azaacene (PAA) with the acceptor F4TCNQ are reported.

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13

Zhao, Jianfeng, Kai Chen, Bing Yang, et al. "Surficial nanoporous carbon with high pyridinic/pyrrolic N-Doping from sp3/sp2-N-rich azaacene dye for lithium storage." RSC Advances 7, no. 85 (2017): 53770–77. http://dx.doi.org/10.1039/c7ra07850a.

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Dye to carbon: Two rationally designed pyridinic/pyrrolic N-doped porous carbons as anodic materials could be achieved by carbonizing π-conjugated azaacene dye born with high ratio sp<sup>3</sup>/sp<sup>2</sup>-N.

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14

Mora‐Fuentes, Juan P., Ilias Papadopoulos, Dominik Thiel, et al. "Singlet Fission in Pyrene‐Fused Azaacene Dimers." Angewandte Chemie International Edition 59, no. 3 (2019): 1113–17. http://dx.doi.org/10.1002/anie.201911529.

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15

Ahrens, Lukas, Julian Butscher, Victor Brosius, et al. "Azaacene Dimers: Acceptor Materials with a Twist." Chemistry – A European Journal 26, no. 2 (2019): 412–18. http://dx.doi.org/10.1002/chem.201904683.

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16

Mora‐Fuentes, Juan P., Ilias Papadopoulos, Dominik Thiel, et al. "Singlet Fission in Pyrene‐Fused Azaacene Dimers." Angewandte Chemie 132, no. 3 (2019): 1129–33. http://dx.doi.org/10.1002/ange.201911529.

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17

Mateos-Martín, Javier, Marco Carini, Manuel Melle-Franco, and Aurelio Mateo-Alonso. "Increasing and dispersing strain in pyrene-fused azaacenes." Chemical Communications 56, no. 77 (2020): 11457–60. http://dx.doi.org/10.1039/d0cc04735j.

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18

Gu, Pei-Yang, Zilong Wang, and Qichun Zhang. "Azaacenes as active elements for sensing and bio applications." Journal of Materials Chemistry B 4, no. 44 (2016): 7060–74. http://dx.doi.org/10.1039/c6tb02052f.

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19

More, Sandeep, Sunil Choudhary, Alexander Higelin, Ingo Krossing, Manuel Melle-Franco, and Aurelio Mateo-Alonso. "Twisted pyrene-fused azaacenes." Chemical Communications 50, no. 16 (2014): 1976. http://dx.doi.org/10.1039/c3cc48742c.

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20

Wu, Yuechao, Yi Jin, Jianguo Xu, Yanwen Lv, and Jiangang Yu. "Recent Progress in the Synthesis and Applications of Azaacenes." Current Organic Chemistry 24, no. 8 (2020): 885–99. http://dx.doi.org/10.2174/1385272824999200427081309.

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Partial substitution of CH groups in the skeletons of linearly fused phenyl rings provides an appreciable possibility to tailor their properties. Among them, azaacenes induced from a partial substitution of oligoacenes by nitrogen are one of the most promising derivatives with a view of their potential application in organic electronic devices as a novel organic n-type semiconductor. Hence this review focuses on recent progress in the synthesis of azaacenes and their applications beyond organic field-effect transistors (OFETs) such as organic light-emitting diodes (OLEDs), phototransistors, ph

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21

Ding, Fangwei, Debin Xia, Congwu Ge, et al. "Indenone-fused N-heteroacenes." Journal of Materials Chemistry C 7, no. 45 (2019): 14314–19. http://dx.doi.org/10.1039/c9tc04962b.

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22

Inoue, Yuki, Daisuke Sakamaki, Yusuke Tsutsui, Masayuki Gon, Yoshiki Chujo, and Shu Seki. "Hash-Mark-Shaped Azaacene Tetramers with Axial Chirality." Journal of the American Chemical Society 140, no. 23 (2018): 7152–58. http://dx.doi.org/10.1021/jacs.8b02689.

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23

Intorp, Sebastian N., Manuel Hodecker, Matthias Müller, et al. "Quinoidal Azaacenes: 99 % Diradical Character." Angewandte Chemie 132, no. 30 (2020): 12496–501. http://dx.doi.org/10.1002/ange.201915977.

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24

Intorp, Sebastian N., Manuel Hodecker, Matthias Müller, et al. "Quinoidal Azaacenes: 99 % Diradical Character." Angewandte Chemie International Edition 59, no. 30 (2020): 12396–401. http://dx.doi.org/10.1002/anie.201915977.

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25

Ganschow, Michael, Silke Koser, Manuel Hodecker, et al. "Azaacenes Bearing Five-Membered Rings." Chemistry - A European Journal 24, no. 51 (2018): 13667–75. http://dx.doi.org/10.1002/chem.201802900.

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26

Müller, Matthias, Hilmar Reiss, Olena Tverskoy, Frank Rominger, Jan Freudenberg, and Uwe H. F. Bunz. "Stabilization by Benzannulation: Butterfly Azaacenes." Chemistry - A European Journal 24, no. 49 (2018): 12801–5. http://dx.doi.org/10.1002/chem.201803118.

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27

More, Sandeep, Rajesh Bhosale, and Aurelio Mateo-Alonso. "Low-LUMO Pyrene-Fused Azaacenes." Chemistry - A European Journal 20, no. 34 (2014): 10626–31. http://dx.doi.org/10.1002/chem.201304461.

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28

Zhang, Zhongbo, and Qichun Zhang. "Recent progress in well-defined higher azaacenes (n ≥ 6): synthesis, molecular packing, and applications." Materials Chemistry Frontiers 4, no. 12 (2020): 3419–32. http://dx.doi.org/10.1039/c9qm00656g.

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In this review, we will focus on the recent progress in the synthetic strategies, photo-electronic properties, molecular packing modes and applications of azaacenes (n ≥ 6) with single-crystal structures.

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29

Zhou, Pengxin, Lanlan Deng, Zengtao Han, Xiaolong Zhao, Zhe Zhang, and Shuhui Huo. "Benzo[de]isoquinoline-1,3-dione condensed asymmetric azaacenes as strong acceptors." RSC Advances 12, no. 21 (2022): 13480–86. http://dx.doi.org/10.1039/d2ra01074g.

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Three benzo[de]isoquinoline-1,3-dione (BQD) condensed asymmetric azaacenes, BQD-TZ, BQD-AP andBQD-PA, with different end groups, have been successfully synthesized and their structures were confirmed by single-crystal X-ray diffraction.

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30

Kang, Fangyuan, Jie Yang, and Qichun Zhang. "Recent progress in pyrazinacenes containing nonbenzenoid rings: synthesis, properties and applications." Journal of Materials Chemistry C 10, no. 7 (2022): 2475–93. http://dx.doi.org/10.1039/d1tc04340d.

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This review focuses on the recent progress in the inclusion of a nonbenzenoid ring into the π-backbone of azaacenes, which can largely tune absorption, energy levels, and antiaromaticity, and produce exciting size-dependent properties.

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31

Miao, Shaobin, Jason Ji, Lei Zhu, Christopher Klug, and Mark Smith. "Synthesis of Large Pyrene-Fused Azaacenes." Synthesis 47, no. 06 (2015): 871–74. http://dx.doi.org/10.1055/s-0034-1379965.

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32

Schleper, A., Constantin-Christian Voll, Jens Engelhart, and Timothy Swager. "Iptycene-Containing Azaacenes with Tunable Luminescence." Synlett 28, no. 20 (2017): 2783–89. http://dx.doi.org/10.1055/s-0036-1589503.

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An optimized route toward iptycene-capped, p-dibromo-quinoxalinophenazine was developed, increasing the yield significantly from literature procedures. New iptycene-containing symmetrical azaacenes were synthesized from this intermediate using Suzuki–Miyaura cross-coupling, and their photophysical properties were evaluated. Tuning the substituents allows modulating emission wavelengths across the visible spectrum. Substitution with 3-methoxy-2-methylthiophene exhibits a quantum yield of 35%. The (triisopropylsilyl)acetylene product has a quantum yield of 38% and serves as a model compound for

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33

More, Sandeep, Sunil Choudhary, Alexander Higelin, Ingo Krossing, Manuel Melle-Franco, and Aurelio Mateo-Alonso. "ChemInform Abstract: Twisted Pyrene-Fused Azaacenes." ChemInform 45, no. 11 (2014): no. http://dx.doi.org/10.1002/chin.201411108.

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34

Takeda, Takashi, Tomohiro Ikemoto, Shunsuke Yamamoto, et al. "Preparation, Electronic and Liquid Crystalline Properties of Electron-Accepting Azaacene Derivatives." ACS Omega 3, no. 10 (2018): 13694–703. http://dx.doi.org/10.1021/acsomega.8b01943.

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35

Chen, Chao, Huapeng Ruan, Zhongtao Feng, et al. "Crystalline Diradical Dianions of Pyrene‐Fused Azaacenes." Angewandte Chemie 132, no. 29 (2020): 11892–97. http://dx.doi.org/10.1002/ange.202001842.

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36

Chen, Chao, Huapeng Ruan, Zhongtao Feng, et al. "Crystalline Diradical Dianions of Pyrene‐Fused Azaacenes." Angewandte Chemie International Edition 59, no. 29 (2020): 11794–99. http://dx.doi.org/10.1002/anie.202001842.

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37

Min, Yang, Chuandong Dou, Hongkun Tian, Yanhou Geng, Jun Liu, and Lixiang Wang. "n-Type Azaacenes Containing B←N Units." Angewandte Chemie 130, no. 7 (2018): 2018–22. http://dx.doi.org/10.1002/ange.201712986.

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38

Hahn, Sebastian, Silke Koser, Manuel Hodecker, et al. "Phenylene Bridged Cyclic Azaacenes: Dimers and Trimers." Chemistry - A European Journal 24, no. 27 (2018): 6968–74. http://dx.doi.org/10.1002/chem.201705704.

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39

Min, Yang, Chuandong Dou, Hongkun Tian, Yanhou Geng, Jun Liu, and Lixiang Wang. "n-Type Azaacenes Containing B←N Units." Angewandte Chemie International Edition 57, no. 7 (2018): 2000–2004. http://dx.doi.org/10.1002/anie.201712986.

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40

Gozalvez, Cristian, Jose L. Zafra, Akinori Saeki, Manuel Melle-Franco, Juan Casado, and Aurelio Mateo-Alonso. "Charge transport modulation in pseudorotaxane 1D stacks of acene and azaacene derivatives." Chemical Science 10, no. 9 (2019): 2743–49. http://dx.doi.org/10.1039/c8sc04845b.

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Acenes have received a lot of attention because of their inherent and tunable absorbing, emissive, and charge transport properties for electronic, photovoltaic, and singlet fission applications, among others.

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41

Kotwica, Kamil, Ireneusz Wielgus, and Adam Proń. "Azaacenes Based Electroactive Materials: Preparation, Structure, Electrochemistry, Spectroscopy and Applications—A Critical Review." Materials 14, no. 18 (2021): 5155. http://dx.doi.org/10.3390/ma14185155.

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This short critical review is devoted to the synthesis and functionalization of various types of azaacenes, organic semiconducting compounds which can be considered as promising materials for the fabrication of n-channel or ambipolar field effect transistors (FETs), components of active layers in light emitting diodes (LEDs), components of organic memory devices and others. Emphasis is put on the diversity of azaacenes preparation methods and the possibility of tuning their redox and spectroscopic properties by changing the C/N ratio, modifying the nitrogen atoms distribution mode, functionali

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42

Zeplichal, Marc, Joshua Gies, Johannes Bernd, et al. "Fluorinated Azaacenes: Efficient Syntheses, Structures, and Electrochemical Properties." Journal of Fluorine Chemistry 257-258 (May 2022): 109960. http://dx.doi.org/10.1016/j.jfluchem.2022.109960.

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43

Engelhart, Jens U., Benjamin D. Lindner, Olena Tverskoy, Frank Rominger, and Uwe H. F. Bunz. "Large Azaacenes: Pyridine Rings Reacting Like Carbonyl Groups." Organic Letters 14, no. 4 (2012): 1008–11. http://dx.doi.org/10.1021/ol203334u.

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44

Li, Junbo, Shao Chen, Zilong Wang, and Qichun Zhang. "Pyrene-fused Acenes and Azaacenes: Synthesis and Applications." Chemical Record 16, no. 3 (2016): 1518–30. http://dx.doi.org/10.1002/tcr.201600015.

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45

Gu, Pei-Yang, Ning Wang, Anyang Wu, et al. "An Azaacene Derivative as Promising Electron-Transport Layer for Inverted Perovskite Solar Cells." Chemistry - An Asian Journal 11, no. 15 (2016): 2135–38. http://dx.doi.org/10.1002/asia.201600856.

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46

Ganschow, Michael, Silke Koser, Sebastian Hahn, Frank Rominger, Jan Freudenberg, and Uwe H. F. Bunz. "Dibenzobarrelene-Based Azaacenes: Emitters in Organic Light-Emitting Diodes." Chemistry - A European Journal 23, no. 18 (2017): 4415–21. http://dx.doi.org/10.1002/chem.201605820.

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47

Liao, Hailiang, Chengyi Xiao, Mahesh Kumar Ravva, et al. "Fused Pyrazine‐ and Carbazole‐Containing Azaacenes: Synthesis and Properties." ChemPlusChem 84, no. 9 (2019): 1257–62. http://dx.doi.org/10.1002/cplu.201900383.

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48

Müller, Matthias, Silke Koser, Olena Tverskoy, Frank Rominger, Jan Freudenberg, and Uwe H. F. Bunz. "Cover Feature: Thiadiazolo‐Azaacenes (Chem. Eur. J. 24/2019)." Chemistry – A European Journal 25, no. 24 (2019): 6041. http://dx.doi.org/10.1002/chem.201901123.

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49

Min, Yang, Chuandong Dou, Dan Liu, Huanli Dong, and Jun Liu. "Quadruply B←N-Fused Dibenzo-azaacene with High Electron Affinity and High Electron Mobility." Journal of the American Chemical Society 141, no. 42 (2019): 17015–21. http://dx.doi.org/10.1021/jacs.9b09640.

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50

Min, Yang, Changshuai Dong, Hongkun Tian, Jun Liu, and Lixiang Wang. "B←N-Incorporated Dibenzo-azaacenes as n-Type Thermoelectric Materials." ACS Applied Materials & Interfaces 13, no. 28 (2021): 33321–27. http://dx.doi.org/10.1021/acsami.1c08514.

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