Academic literature on the topic 'Azeotropic distillation'

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Journal articles on the topic "Azeotropic distillation"

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Taipabu, Muhammad Ikhsan, Wei Wu, Karthickeyan Viswanathana, Nikmans Hattu, Ervina Rumpakwakra, and Micky Kololu. "SEPARATION OF ETHANOL-WATER AZEOTROPE MIXTURES USING EXTRACTIVE DISTILLATION METHOD." ALE Proceeding 6 (November 1, 2023): 198–203. http://dx.doi.org/10.30598/ale.6.2023.198-203.

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Extractive distillation is a specialized distillation process that involves adding an additional component (extractive agent or solvent/entrainer) to the mixture in order to alter the relative volatilities of the components and enable their separation, even when they form azeotropes. This technique is commonly used to separate azeotropic mixtures, such as ethanol-water azeotropes. The ethanol-water azeotrope is a well-known example, where the mixture contains around 95.6 wt% ethanol and 4.4 wt% water. Traditional distillation methods cannot separate these components efficiently due to the azeotropic behavior. However, extractive distillation offers a solution by introducing a third component (entrainer) that forms a ternary azeotrope, which has different properties compared to the binary azeotrope (ethanol-water). This study presents the effect of the operating parameters (e.g., column configuration, pressure, entrainer type) on energy consumption while the purity of ethanol is set to 99.5 wt%. Appropriate entrainers (i.e., glycerol, ethylene glycol) are chosen to extract water from methanol at different compositions. The optimum design of ethanol-water azeotrope separation is obtained by using sensitivity analysis in Aspen Plus simulation. The results indicate the trade-off between solvent and reboiler duty consumption. An advanced comparison study is recommended, including the mixing of both solvents as entrainer.
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Tien Thi, Luot. "ENTRAINER SELECTION FOR SEPARATION OF AZEOTROPIC MIXTURES BY DISTILLATION METHODS." Vietnam Journal of Science and Technology 56, no. 4A (October 19, 2018): 89. http://dx.doi.org/10.15625/2525-2518/56/4a/12952.

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Azeotropic or close – boiling mixtures often preclude conventional distillation as a method of separation. Instead, extractive or azeotropic distillations are commonly used to separate azeotropic or close – boiling mixtures. For the design of those separation units, selecting suitable entrainers (solvents) is a key step. The traditional method for solving this problem is to use experimentation which is time – consuming and expensive. Currently available selection criteria are inadequate. They contradict one another and often lead to incorrect conclusions. Indeed, for a minimum boiling azeotrope, the existing entrainer selection rules state that one should use a high boiling component that introduces no additional azeotrope (Benedict & Rubin, 1945), an intermediate boiling component that introduces no additional azeotrope (Hoffman, 1964), a component which introduces no distillation boundary between the azeotropic constituents (Doherty & Caldarola, 1985), and either a low boiling component that introduces no additional azeotrope or a component that introduces new minimum boiling azeotrope (Stichlmaric, Fair & Bravo, 1989).In this work, Aspen Plus simulator was used to propose an entrainer selection procedure based on the criteria: 1) A good entrainer is a component that eliminates the azeotrope easily (i.e. even when it’s concentration is small). 2) A component that yields high relative volatilities αAB between the two azeotrope constituents.
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Mahdi, Taha, Arshad Ahmad, Mohamed M. Nasef, and Adnan Ripin. "Simulation and Analysis of Process Behavior of Ultrasonic Distillation System for Separation Azeotropic Mixtures." Applied Mechanics and Materials 625 (September 2014): 677–79. http://dx.doi.org/10.4028/www.scientific.net/amm.625.677.

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The performance of an ultrasonic distillation (USD) system is evaluated in Aspen Plus simulation environment. To facilitate the flowsheet development, a mathematical model of a single stage USD developed using Aspen Custom Modeler software is exported to Aspen Plus process simulator. As a case study, the separation of ethanol-ethyl acetate mixture that is known to form azeotrope 55 mole % of ethyl acetate at minimum boiling point of 71.8oC is considered. Simulation results revealed the achievable purity of ethyl acetate of 99 mole % from azeotropic mixture, thus reinforcing the anticipated potentials of sonication phenomena in intensifying distillation process to overcome azeotropes.
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Sutijan, Sutijan, Megan Jobson, and Robin Smith. "Synthesis of Ternary Homogeneous Azeotropic Distillation Sequences: Entrainer Selection." ASEAN Journal of Chemical Engineering 12, no. 1 (August 6, 2012): 20. http://dx.doi.org/10.22146/ajche.49752.

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This paper presents a methodology for automatic selection of entrainers for separating binary azeotropic mixtures using homogeneous azeotropic distillation. A new classification system for ternary mixtures based on the termini of distillation boundaries and the type (stability) of products and azeotropes is proposed. The new characterisation system is able to link candidate entrainers to flowsheet structures which can facilitate the separation. Existing entrainer selection criteria are extended to accommodate other promising entrainers, including light, intermediate and heavy-boiling entrainers.
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Mahdi, Taha, Arshad Ahmad, Adnan Ripin, Mohamed Mahmoud Nasef, and Olagoke Oladokun. "Aspen Plus Simulation of Ultrasound Assisted Distillation for Separating Azeotropic Mixture." Advanced Materials Research 1113 (July 2015): 710–14. http://dx.doi.org/10.4028/www.scientific.net/amr.1113.710.

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Earlier works have proved the potentials of altering the vapor liquid equilibrium of azeotropic mixture by sonication phenomena. In this work a mathematical model of a single stage vapor-liquid equilibrium system developed in Aspen Custom Modeler is exported to Aspen Plus to represent one stage of ultrasonic flash distillation (USF). The USF modules are connected serially to mimic a distillation process. As a case study, the separation of ethanol-ethyl acetate mixture is considered. The final targeted composition of 99 mole % of ethyl acetate was achieved when 27 USF modules were used despite the fact that the mixture form azeotrope at 55 mole % ethyl acetate. The results reinforced the anticipated potentials of sonication phenomena in intensifying distillation process to overcome azeotropes, and provide useful insights for the development of a pilot-scaled facility that is currently under development.
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Fan, Zhi Dong, Xu Bin Zhang, Lu Yang Zhao, Wang Feng Cai, and Fu Min Wang. "Study on the Separation of Azeotrope of Tetrahydrofuran-Water Using a Combined Method of Extractive and General Distillation." Advanced Materials Research 803 (September 2013): 149–52. http://dx.doi.org/10.4028/www.scientific.net/amr.803.149.

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As an important solvent, tetrahydrofuran has broad applications. Due to its process of production, water will be mixed into the product and should be removed. However, tetrahydrofuran will form a minimum boiling azeotrope with water, which has a boiling point of 63.4°C, so general distillation can not separate them. Common methods to solve this include extractive distillation, pressure swing distillation, azeotropic distillation, pervaporation and so on. In this experiment, we coupled extractive distillation and general distillation, selecting ethylene glycol as the extractant, and successfully dehydrated the azeotrope. The mass fraction of water is reduced from 18% to less than 500ppm,which matches the requirement.
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Raper, D. "Azeotropic distillation apparatus." Journal of Applied Chemistry 1, no. 1 (April 19, 2007): 43–44. http://dx.doi.org/10.1002/jctb.5010010110.

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Tóth, András József, Ágnes Szanyi, Enikő Haaz, and Péter Mizsey. "Separation of Process Wastewater with Extractive Heterogeneous-Azeotropic Distillation." Hungarian Journal of Industry and Chemistry 44, no. 1 (October 1, 2016): 29–32. http://dx.doi.org/10.1515/hjic-2016-0003.

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Abstract The application of vapour-liquid equilibria-based separation alternatives can be extraordinarily complicated for the treatment of process wastewaters containing heterogeneous-azeotropic. Despite dissimilar successfully tested methods for separation, there is possibility to get better distillation method by enabling the separation of more and more specific process wastewater. Extractive heterogeneous-azeotropic distillation (EHAD) is a new advance in treatment of fine chemical wastewater showing special features to cope with the treatment of highly non-ideal mixtures. This method combines the worth of heterogeneous-azeotropic and extractive distillations in one apparatus without addition of any extra materials. The study of the separations of ternary component process wastewater from the fine chemical industry shows both in the modelled and experimental results that EHAD can be successfully applied. The measured and modelled compositions at extreme purities, that is, close to 0% or 100%, can be different because of the inaccuracies of the modelling. This highlights the paramount importance of the experiments if special extra-fine chemicals with almost no impurities, e.g. of pharmacopoeial quality are to be produced by special distillation technique. This study expands the application of EHAD technique, this new field is the separation of process wastewaters.
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Li, Jun, Jun Wang, Zhan Hua Ma, and Lan Yi Sun. "Environmental Performance Assessment for Heterogeneous Azeotropic Distillation Partitioned Distillation Column." Advanced Materials Research 485 (February 2012): 229–32. http://dx.doi.org/10.4028/www.scientific.net/amr.485.229.

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A heterogeneous azeotropic distillation partitioned distillation column (HADPDC) for alcohol dehydration was investigated compared to a conventional heterogeneous azeotropic distillation sequence (CHADS) from environmental performance perspective by using the software Aspen Plus. HADPDC can eliminate the condenser of the second column and decrease the degree of back-mixing. The optimal design of HADPDC guaranteed the minimum energy consumption, which is related to the minimum CO2 emissions.
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Widagdo, Soemantri, and Warren D. Seider. "Journal review. Azeotropic distillation." AIChE Journal 42, no. 1 (January 1996): 96–130. http://dx.doi.org/10.1002/aic.690420110.

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Dissertations / Theses on the topic "Azeotropic distillation"

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Thong, Dennis Y.-C. "Multicomponent azeotropic distillation design." Thesis, University of Manchester, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.488265.

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In ths work, new multicomponent feasibility, column design and column sequencing tools are proposed. These tools are particularly useful in the synthesis of distillation columns and column sequences that separate azeotropic mixtures, where they provide accurate design parameters as well as good estimates of product compositions for use in commercial simulators. Recent work on ternary mixtures has led to the development of a new criterion for establishing staged column feasibility. This new criterion provides a necessary and sufficient condition for staged-column feasibility, and a column design method is developed based on this criterion for the design of simple and complex columns. The column design method can be extended to describe non-ideal column operation as well as packed columns. The column design method is particularly useful in the design of columns that separate azeotropic mixtures as it provides accurate column specifications where conventional shortcut methods fail. A retrofit method for increasing throughput is also developed using the new feasibility criterion. A new feasibility test for product compositions from columns separating multicomponent mixtures is introduced. Unlike present methods, the new feasibility test requires only the specification of the principal mole fractions in both products. Visualisation is not required as feasibility is established numerically. The feasibility test is therefore applicable to mixtures with any number of components. The feasibility test is extended to identify feasible and potentially feasible classes of splits, which are defined by product regions instead of product compositions. Various classes of splits are then grouped according to type. A column design method for columns separating multicomponent azeotropic mixtures is developed. Based on a new criterion developed for application in ternary mixtures, the new column design method requires the specification of the principal mole fractions in both products. The design method is developed for two cases - columns that produce pure components and columns that perform general splits. In both cases a matrix of feasible operating parameters can be constructed, which can be used to identify favorouble operating parameters. The feasibility and column design methods are used to develop an algorithmic column sequence synthesis procedure for multi component azeotropic mixtures. Given a feed composition and product requirements, the synthesis procedure makes use of the feasibility test for classes of splits to generate a number of potentially feasible column sequences, each of which has an associated recycle superstructure. Feasible column sequences are then identified and the multi component column design methods are employed for every column in the sequence.
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Cairns, Brett P. (Brett Peter). "Three phase azeotropic distillation." Phd thesis, Department of Chemical Engineering, 1988. http://hdl.handle.net/2123/5908.

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Zimmerli, Urs. "Limit cycles in homogeneous azeotropic distillation." Zürich : ETH, Eidgenössische Technische Hochschule Zürich, 2001. http://e-collection.ethbib.ethz.ch/show?type=dipl&nr=15.

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Liu, Guilian. "Synthesis of multicomponent azeotropic distillation sequences." Thesis, University of Manchester, 2003. http://www.manchester.ac.uk/escholar/uk-ac-man-scw:230199.

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A large number of distillation sequences can be generated to separate a multicomponent azeotropic mixture. However, there is no systematic and efficient method for synthesising promising sequences, which also consider recycle connections and flowrates. In this work, a systematic procedure is developed for synthesising economically promising distillation sequences separating multicomponent homogeneous azeotropic mixtures. The procedure uses spherically approximated distillation boundaries, a shortcut column design method, and allows recycle and sequence alternatives to be screened. Both feasibility and design are addressed. Approximation of a distillation boundary as a spherical surface is a simple nonlinear, yet more accurate representation of the actual boundary than a linear approximation. For shortcut column design, azeotropes are treated as pseudocomponents and the relative volatilities of all singular points of the system are characterised, based on the transformation of vapour-liquid equilibrium behaviour in terms of pure components into that in terms of singular points. Once the relative volatilities of singular points are obtained, the classical Fenske-Underwood-Gilliland method can be used to design columns separating azeotropic mixtures. This method is extremely computationally efficient and can be applied to homogeneous azeotropic mixtures with any number of components; the results are useful for initialising rigorous simulations using commercial software and for assessing feasibility of proposed splits. Together with the spherical approximation of distillation boundaries, this shortcut method provides a basis for evaluating distillation sequences with recycles. Analysis of feasibility requirements of splits, component recovery requirements and the effects of recycles on the performance of proposed splits allows rules and procedures for selecting recycles to be proposed. Recycles with compositions of either singular points or mixtures of singular points are identified that are beneficial to the feasibility of sequences and the recovery of components. The principles are applicable to azeotropic mixtures with any number of components; using these procedures, recycle structures can be generated and are much simpler than the superstructures of recycle alternatives. The sequence synthesis procedure of Thong and Jobson (2001c) allows all potentially feasible sequences to be generated. To screen among these sequences, a split feasibility test and a two-step screening procedure are proposed. In the first step, feasibility of splits is tested efficiently and sequences containing either infeasible or sloppy splits are eliminated. In the second step, sequences containing sloppy splits are generated, based on the evaluation of sequences containing only feasible sharp splits. Using this procedure, the number of distillation sequences identified using the procedure of Thong and Jobson (2001c) can be significantly reduced. A systematic methodology is proposed for the synthesis and evaluation of multicomponent homogeneous azeotropic distillation sequences. The methodology is computationally efficient. It is demonstrated through a case study, the synthesis of distillation sequences separating a five-component mixture, in which two homogeneous azeotropes are formed, and for which over 5000 sequences producing pure component products can be generated. Using this methodology, only ten sequences are evaluated to identify three promising sequences. The evaluation of each sequence using the shortcut column design method is extremely efficient compared with that using the boundary value method.
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Hegely, Laszlo. "Improvement of Batch Distillation Separation of Azeotropic Mixtures." Phd thesis, Toulouse, INPT, 2013. http://oatao.univ-toulouse.fr/10671/1/hegely.pdf.

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Distillation is the most widespread method for separating liquid mixtures. The separation of azeotropic mixtures requires a special distillation method. My aim was to improve the batch distillation separation of azeotropic mixtures. A new algorithm was presented for the determination of product sequences of batch distillation of multicomponent azeotropic mixtures. Non-conventional configurations were studied by simulation with emphasis on closed operation. The effects of off-cut recycle on a six-batch separation process of a waste solvent mixture were also investigated. Batch extractive distillation was studied for the separation of two azeotropic mixtures. A new extractive policy was also proposed. A generalised model of batch heteroazeotropic distillation with variable decanter hold-up was developed. This model was extended for batch heterogeneous extractive distillation.
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Skouras-Iliopoulos, Efstathios. "Operation and feasibility of batch hetero-azeotropic distillation." Doctoral thesis, Norwegian University of Science and Technology, Department of Chemical Engineering, 2004. http://urn.kb.se/resolve?urn=urn:nbn:no:ntnu:diva-394.

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Separation of azeotropic mixtures is of great industrial importance and distillation is the dominating unit operation for such separations. However, the presence of azeotropes and non-idealities in the phase behaviour of such mixtures complicates the separation. In the pharmaceutical and fine/specialty chemical industry, the small-scale production and the requirement for flexibility indicates batch distillation as the best suited process. Among, various techniques to enhance distillation, heterogeneous azeotropic (heteroazeotropic) distillation is a very powerful and widely used one. Thus, there is a need for deeper understanding of the complex behaviour of the separation of heteroazeotropic mixtures in batch distillation columns.

This thesis is concerned with feasibility and operation aspects of heteroazeotropic distillation in different batch column configurations. Both conventional batch columns (rectifiers) and novel configurations (multivessel columns), with and without vapour bypass, are considered. The focus is on closed operations, without product removal. Batch time requirements for operation in all columns are provided for both zeotropic and heteroazeotropic mixtures. The advantages and drawbacks of each configuration are discussed and compared based on dynamic simulations. The configuration of the vapour stream in the middle vessel has an important effect on the time requirements of the process. Later on, a detailed analysis of the process is provided and previous published work concerning different operation modes and separation strategies is put under the right perspective. Simple control schemes are proposed for the practical operation of the columns and the realisation of the desired steady state results. The thesis ends with a detailed feasibility study of the process. The possibilities and limitations raised by different operational modes and separation strategies are illustrated. Simple feasibility conditions and entrainer selection rules are formulated that allow someone to investigate feasibility of the process in a systematic and comprehensive manner.

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Cranford, Richard John 1960. "Characterization and azeotropic distillation of crude wood oil." Thesis, The University of Arizona, 1989. http://hdl.handle.net/10150/277197.

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The batch distillation of crude wood oil by direct liquefaction was studied; azeotropic distillations and some characterization were also performed. It was found that 26-33 percent of the crude wood oil could be distilled by simple batch vacuum distillations with pressures from 50-300 mm Hg. With the use of ethylene glycol and glycerol 29-85 percent more oil was distilled partly due to the azeotrope formed which allows the oil to boil at a reduced pressure. The water liberated and the polymerization which took place during the distillations were studied. It was found that fluid catalytic cracking bottoms eliminates polymerization when it is co-distilled with the crude wood oil. A novel scheme for the separation of the phenolic fraction by azeotropic distillation is presented.
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Sutijan, Mr. "Synthesis and optimisation of ternary homogeneous azeotropic distillation flowsheets." Thesis, University of Manchester, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.506291.

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Hilmen, Eva-Katrine. "Separation of azeotropic mixtures : tools for analysis and studies on batch distillation operation." Doctoral thesis, Norwegian University of Science and Technology, Department of Chemical Engineering, 2000. http://urn.kb.se/resolve?urn=urn:nbn:no:ntnu:diva-513.

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Separation of azeotropic mixtures is a topic of great practical and industrial interest. Most liquid mixtures of organic components form nonideal systems. The presence of some specific groups, particularly polar groups (oxygen, nitrogen, chlorine and fluorine), often results in the formation of azeotropes. Azeotropic mixtures may often be effectively separated by distillation by adding a liquid material (entrainer) to the system.

For the development of separation processes for azeotropic mixtures, there is a need for insight into the fundamental phenomena of nonideal and azeotropic phase equilibria. This thesis includes a detailed survey on azeotropic phase equilibriumdiagrams of ernarymixtures. Diagram analysis is shown to be an efficient tool for prediction of feasible separations. As a simplifying concept it is proposed that all feasible structures of ternary azeotropic phase equilibrium diagrams can be qualitatively represented by a few elementary cells of which only four have so far been reported to exist. This greatly reduces the complexity of azeotropic istillation analysis and is a key to a simple evaluation of the possibilities and limitations of azeotropic mixtures separation.

Insights gained from continuous azeotropic distillation is extended to the operation of batch distillation with focus on the dynamics and control of multivessel and extractive batch distillation as processes for separating azeotropic mixtures. Practical implications of this renewed insight for the fine- and specialty chemical industries are given in the concluding pages of the thesis.

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Prayoonyong, Paritta. "Synthesis and design of ternary heterogeneous azeotropic distillation processes including advanced complex column configurations." Thesis, University of Manchester, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.506226.

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This thesis presents a novel methodology for synthesis of sequences separating ternary heterogeneous azeotropic mixtures employing distillation columns and decanters. Column design methods are developed for assessing feasibility of proposed separations and for identifying economically attractive designs of columns in sequences. Design methods for advanced and complex configurations of heterogeneous azeotropic columns exploit the boundary value method. The methods can be used for establishing product feasibility in a column and evaluating a column design on a basis of cost. A new design method is developed for columns with integrated decanters, in which the existence of two liquid phases is not limited to the decanter. For a column with multiple heterogeneous stages, multiple feasible designs can be generated, corresponding to different numbers of heterogeneous stages and various ratios of two liquid phases on the heterogeneous stages. The resulting feasible designs have different total numbers of stages and feed locations for a given set of product specifications and reflux ratio. The new design method is extended further for double-feed columns and columns with intermediate decanters. Case studies indicate that the presence of heterogeneous liquid in columns considerably improves the economic performance in some cases. The economic performance is also affected by the number of heterogeneous stages. The number of heterogeneous stages that leads to near-optimal designs can be determined using the new column design methods. For some mixtures, employing complex column configurations makes the separation feasible and provides significant cost savings. For other mixtures, the complex columns may not be as attractive as single-feed columns with integrated decanters. Column design details and other results form the column design methods are used successfully to initialise rigorous simulations and to facilitate simulation convergence.
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Books on the topic "Azeotropic distillation"

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1955-, Chien I.-Lung, ed. Design and control of distillation systems for separating azeotropes. Hoboken, N.J: Wiley, 2010.

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Królikowski, Lechosław J. Rejony wykonalnych rozdziałów homogenicznych mieszanin trójskładnikowych. Wrocław: Oficyna Wydawnicza Politechniki Wrocławskiej, 2010.

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Castillo, F. J. L. Synthesis of homogeneous azeotropic distillation sequences. Manchester: UMIST, 1997.

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Munir, A. Alcohols recovery and purification by azeotropic distillation. Manchester: UMIST, 1997.

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Georgoulaki, A. Simulation of heterogeneous azeotropic distillation-equilibriumand matrix calculations for ternary mixtures. Manchester: UMIST, 1994.

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Luyben, William L. Design and control of distillation systems for separating azeotropes. Hoboken, N.J: Wiley, 2010.

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Luyben, William L., and I.-Lung Chien. Design and Control of Distillation Systems for Separating Azeotropes. American Institute of Chemical Engineers, 2011.

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Luyben, William L., and I.-Lung Chien. Design and Control of Distillation Systems for Separating Azeotropes. Wiley & Sons, Incorporated, John, 2010.

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Design and Control of Distillation Systems for Separating Azeotropes. Wiley & Sons, Incorporated, John, 2010.

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Luyben, William L., and I.-Lung Chien. Design and Control of Distillation Systems for Separating Azeotropes. American Institute of Chemical Engineers, 2011.

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Book chapters on the topic "Azeotropic distillation"

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Criscuoli, Alessandra. "Azeotropic Distillation." In Encyclopedia of Membranes, 132–33. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-44324-8_40.

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Criscuoli, Alessandra. "Azeotropic Distillation." In Encyclopedia of Membranes, 1–2. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-40872-4_40-3.

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Nitsche, M., and R. Gbadamosi. "Extractive and Azeotropic Distillation." In Practical Column Design Guide, 153–64. Cham: Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-51688-2_5.

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Tang, Ke, Jiao Liu, and Jinjuan Xing. "Separation ofn-propanol–toluene azeotropic mixture by extractive distillation." In Advances in Energy Science and Equipment Engineering II, 1351–54. Taylor & Francis Group, 6000 Broken Sound Parkway NW, Suite 300, Boca Raton, FL 33487-2742: CRC Press, 2017. http://dx.doi.org/10.1201/9781315116174-97.

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Wang, Hai-qin, Ce Wang, Zu-bin Zhang, Feng-qi Li, and Xiao-dong Yan. "Mixture Design of Solvent for CO2-C2H6 Azeotrope in Extractive Distillation." In Proceedings of the 2021 International Petroleum and Petrochemical Technology Conference, 581–95. Singapore: Springer Singapore, 2022. http://dx.doi.org/10.1007/978-981-16-9427-1_55.

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Arlt, Wolfgang. "Azeotropic Distillation." In Distillation, 247–59. Elsevier, 2014. http://dx.doi.org/10.1016/b978-0-12-386878-7.00007-3.

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Lee, F. M., and R. W. Wytcherley. "DISTILLATION | Azeotropic Distillation." In Encyclopedia of Separation Science, 990–95. Elsevier, 2000. http://dx.doi.org/10.1016/b0-12-226770-2/00681-5.

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Lei, Z. "Azeotropic Distillation." In Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. Elsevier, 2017. http://dx.doi.org/10.1016/b978-0-12-409547-2.06018-2.

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Lei, Zhigang, Biaohua Chen, and Zhongwei Ding. "Azeotropic distillation." In Special Distillation Processes, 145–77. Elsevier, 2005. http://dx.doi.org/10.1016/b978-044451648-0/50003-3.

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Yu, Gangqiang, Chengna Dai, Zhigang Lei, and Biaohua Chen. "Azeotropic distillation." In Special Distillation Processes, 155–90. Elsevier, 2022. http://dx.doi.org/10.1016/b978-0-12-820507-5.00006-3.

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Conference papers on the topic "Azeotropic distillation"

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Lupachev, Egor V., Andrei V. Polkovnichenko, and Nikolai N. Kulov. "Purification of organic fluorine alcohols from azeotropic mixtures with non-fluorinated alcohols using extractive distillation." In INTERNATIONAL SCIENTIFIC-TECHNICAL SYMPOSIUM (ISTS) «IMPROVING ENERGY AND RESOURCE-EFFICIENT AND ENVIRONMENTAL SAFETY OF PROCESSES AND DEVICES IN CHEMICAL AND RELATED INDUSTRIES». The Kosygin State University of Russia, 2021. http://dx.doi.org/10.37816/eeste-2021-1-239-241.

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The extractive distillation process of 2,2,2-trifluoroethanol – isopropanol azeotropic mixture using N-methyl-2-pyrrolidone as a separating agent has been experimentally studied. The experiments were carried out on a batch column with regular packing. The results are shown that using this separating agent makes it possible to eliminate thermodynamic constraints imposed by binary azeotrope and to recover 2,2,2-trifluoroethanol with a purity of more than 0,99.
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Bekiaris, Nikolaos, George A. Meski, Cristian M. Radu, and Manfred Morari. "Multiple Steady States in Homogeneous Azeotropic Distillation." In 1993 American Control Conference. IEEE, 1993. http://dx.doi.org/10.23919/acc.1993.4793437.

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3

Iqbal, Asma, and Syed Akhlaq Ahmad. "Separating Iso-Propanol-Toluene mixture by azeotropic distillation." In 2ND INTERNATIONAL CONFERENCE ON CONDENSED MATTER AND APPLIED PHYSICS (ICC 2017). Author(s), 2018. http://dx.doi.org/10.1063/1.5032351.

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4

"Energy conservation of azeotropic distillation by internal heat integration." In Intersociety Energy Conversion Engineering Conference. Reston, Virigina: American Institute of Aeronautics and Astronautics, 1994. http://dx.doi.org/10.2514/6.1994-4160.

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5

Vargas Valle, Rosendo, Ma Guadalupe Lopez Lopez, and Enrique Quintero-Marquez. "Control of an azeotropic distillation process for anhydrous ethanol production." In 2011 21st International Conference on Electrical Communications and Computers (CONIELECOMP 2011). IEEE, 2011. http://dx.doi.org/10.1109/conielecomp.2011.5749345.

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Wijaya, Yovan, Herry Santoso, and Yansen Hartanto. "Process Control for Isopropanol-Water Separation via Azeotropic Distillation with Dividing Wall." In 2019 6th International Conference on Instrumentation, Control, and Automation (ICA). IEEE, 2019. http://dx.doi.org/10.1109/ica.2019.8916741.

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Lescisin, M., O. A. Jianu, M. A. Rosen, and K. Pope. "Azeotropic distillation of hydrochloric acid in the copper-chlorine cycle for hydrogen production." In 2017 IEEE International Conference on Smart Energy Grid Engineering (SEGE). IEEE, 2017. http://dx.doi.org/10.1109/sege.2017.8052819.

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8

Chuanbo Dai, Ruiduan Li, Yanjie Liu, and Hua Wang. "Notice of Retraction: Study on reconstruction of acetic anhydride azeotropic distillation column Internal parts." In 2011 2nd International Conference on Artificial Intelligence, Management Science and Electronic Commerce (AIMSEC 2011). IEEE, 2011. http://dx.doi.org/10.1109/aimsec.2011.6011341.

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Klinov, Alexander V., Ilsiya M. Davletbaeva, Alexander V. Malygin, Alina R. Khairullina, and Sergey E. Dulmaev. "Dehydration of alcohols by extractive rectification using boric acid aminoesters." In INTERNATIONAL SCIENTIFIC-TECHNICAL SYMPOSIUM (ISTS) «IMPROVING ENERGY AND RESOURCE-EFFICIENT AND ENVIRONMENTAL SAFETY OF PROCESSES AND DEVICES IN CHEMICAL AND RELATED INDUSTRIES». The Kosygin State University of Russia, 2021. http://dx.doi.org/10.37816/eeste-2021-1-49-53.

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Abstract:
Aminoethers of boric acid (AEBA) were studied as extractants for the separation of aqueous–alcoholic azeotropic mixtures by extractive distillation. The conditions of vapor–liquid equilibrium in aqueous solutions of ethanol in the presence of AEBA were studied. The division of AEBA molecules into group components was proposed, and previously unknown geometric parameters of the boron group and the energetic pair parameters of the boron group were determined within the framework of the UNIFAC model. The modeling of the extractive rectification process of an ethanol–water mixture with AEBA as extractant has been carried out.
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Geng, Pat, Aron Butler, William Studzinski, John Salyers, and Jeff Jetter. "Gasoline Simulated Distillation Profiles of U.S. Market Gasoline and Impacts on Vehicle Particulate Emissions." In Energy & Propulsion Conference & Exhibition. 400 Commonwealth Drive, Warrendale, PA, United States: SAE International, 2023. http://dx.doi.org/10.4271/2023-01-1632.

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Abstract:
<div class="section abstract"><div class="htmlview paragraph">A gasoline’s distillation profile is directly related to its hydrocarbon composition and the volatility (boiling points) of those hydrocarbons. Generally, the volatility profiles of U.S. market fuels are characterized using a very simple, low theoretical plate distillation separation, detailed in the ASTM D86 test method. Because of the physical chemistry properties of some compounds in gasoline, this simple still or retort distillation has some limitations: separating azeotropes, isomers, and heavier hydrocarbons. Chemists generally rely on chromatographic separations when more detailed and precise results are needed.</div><div class="htmlview paragraph">High-boiling aromatic compounds are the primary source of particulate emissions from spark ignited (SI), internal combustion engines (ICE), hence a detailed understanding and high-resolution separation of these heavy compounds is needed. This paper presents analysis of 159 U.S. market gasoline samples using D86 distillation and ASTM D6730 detailed hydrocarbon analysis (DHA). The samples ranged in Particulate Matter Index (PMI) from 0.925 to 2.540 or Particulate Evaluation Index (PEI) of 0.584 to 2.715. Additional analysis was performed on 80 of the samples using ASTM D7096, a chromatographic method, to generate higher resolution simulated distillation (SimDis) profiles. SimDis cutpoints (%-off values) in the range of T95 to T98 show good correlation to PMI and PEI, demonstrating that SimDis analysis can provide a useful assessment of the PM-formation tendency of market gasolines.</div></div>
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