Relevant bibliographies by topics / Azide Trapping

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  1. Journal articles
  2. Dissertations / Theses
  3. Books

Academic literature on the topic 'Azide Trapping'

Author: Grafiati
Published: 4 June 2021
Last updated: 1 February 2022

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Journal articles on the topic "Azide Trapping"

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Bock, Hans, та Ralph Dammel. "Gasphasen-Reaktionen, 58 [1, 2] β-Chlorethylazid: HCl-Eliminierung und Pyrolyse / Gas Phase Reactions, 58 [1, 2] β-Chloroethyl Azide: HCl Elimination and Pyrolysis". Zeitschrift für Naturforschung B 42, № 3 (1987): 301–7. http://dx.doi.org/10.1515/znb-1987-0309.

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The HCl elimination from β-chloroethyl azide (1-azido-2-chloroethane) over potassium tert. butanolate at 350 K in a low pressure flow system is optimized using PE spectroscopic real-time gas analysis. The highly explosive vinyl azide formed can be purified by cool-trapping the by-products. Its subsequent and virtually hazard-free pyrolysis yields 2H-azirine, which can be isolated at temperatures below 240 K.In contrast, the direct pyrolysis of β-chloroethyl azide requires temperatures above 710 K and results in a simultaneous split-off of both HCl and N2, yielding acetonitrile as the main ther
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Bott, Tina M., Bren Jordan Atienza, and F. G. West. "Azide trapping of metallocarbenes: generation of reactive C-acylimines and domino trapping with nucleophiles." RSC Adv. 4, no. 60 (2014): 31955–59. http://dx.doi.org/10.1039/c4ra06044j.

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3

Liang, Tsuei-Yun, and Gary B. Schuster. "Photolysis of 3-nitrophenyl azide: Trapping the reactive intermediates." Tetrahedron Letters 27, no. 29 (1986): 3325–28. http://dx.doi.org/10.1016/s0040-4039(00)84786-3.

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4

Pramanik, Suman, and Prasanta Ghorai. "Trapping of Azidocarbenium Ion: A Unique Route for Azide Synthesis." Organic Letters 16, no. 8 (2014): 2104–7. http://dx.doi.org/10.1021/ol5008235.

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5

Bott, Tina M., Bren Jordan Atienza, and West F. G. West F. G. "ChemInform Abstract: Azide Trapping of Metallocarbenes: Generation of Reactive C-Acylimines and Domino Trapping with Nucleophiles." ChemInform 46, no. 8 (2015): no. http://dx.doi.org/10.1002/chin.201508176.

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6

Kalyanaraman, B., E. G. Janzen, and R. P. Mason. "Spin trapping of the azidyl radical in azide/catalase/H2O2 and various azide/peroxidase/H2O2 peroxidizing systems." Journal of Biological Chemistry 260, no. 7 (1985): 4003–6. http://dx.doi.org/10.1016/s0021-9258(18)89222-5.

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7

Chahoua, Latifa, Alain Vigroux, Yvonne Chiang, and James C. Fishbein. "Formation and nucleophilic capture of N-nitrosiminium ions." Canadian Journal of Chemistry 77, no. 5-6 (1999): 1148–61. http://dx.doi.org/10.1139/v99-108.

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A study of the solvolysis of a series of (N-nitrosomethylamino)arylmethyl esters and azides and the products of nucleophilic trapping of the corresponding N-nitrosiminium ion intermediates in aqueous media, 25°C, ionic strength 1 M is reported. Structure-reactivity data for the forward and reverse reactions have been obtained. In three cases, the rate constants for reactions of the cations with nucleophiles have been measured directly by laser flash photolysis. The data allow a comparison of the degree to which the N-methyl-N-nitroso functionality enhances cation stability from a thermodynamic
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8

Snider, Barry B., and Jeremy R. Duvall. "Termination of Mn(III)-Based Oxidative Cyclizations by Trapping with Azide." Organic Letters 6, no. 8 (2004): 1265–68. http://dx.doi.org/10.1021/ol049805s.

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9

Luu, Thanh, Robert McDonald, and Rik R. Tykwinski. "Regioselective Trapping of Terminal Di-, Tri-, and Tetraynes with Benzyl Azide." Organic Letters 8, no. 26 (2006): 6035–38. http://dx.doi.org/10.1021/ol062522a.

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10

Topczewski, Joseph, and Matthew Porter. ""It’s a (Kinetic) Trap!" – Selectively Differentiating Allylic Azide Isomers." Synlett 29, no. 12 (2018): 1537–42. http://dx.doi.org/10.1055/s-0037-1609479.

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Allylic azides are known to undergo the Winstein rearrangement and are often isolated as an equilibrating mixture of isomers. While this process has been known for almost 60 years, very few synthetic applications of this process have been reported. The absence of methods exploiting these intermediates likely stems from a paucity of approaches for gaining the required selectivity to differentiate the isomers. Our lab has made some progress in leveraging this unusual reaction into practical synthetic methodology. Presented herein is a summary of our lab’s recent accomplishments in selectively tr
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Dissertations / Theses on the topic "Azide Trapping"

1

Leopold, Samuel Harris. "Photogeneration of Aryloxenium Ions: Photolysis of 4-acetoxy-4-(4'-methylphenyl)-2,5-cyclohexadienone in Acetonitrile as a Precursor." Miami University Honors Theses / OhioLINK, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=muhonors1210088217.

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2

Maury, Julien. "Nouveaux développements en chimie radicalaire des dialkylzincs : études mécanistiques et applications en synthèse." Thesis, Aix-Marseille, 2012. http://www.theses.fr/2012AIXM4351.

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Le travail présenté dans ce mémoire de thèse concerne pour l'essentiel, l'utilisation des dialkylzincs en tant que médiateurs de réactions radicalaires. La particularité de ces organométalliques réside dans le fait qu'ils sont, d'une part, de très bons précurseurs de radicaux alkyle en présence d'oxygène, et d'autre part, qu'ils peuvent subir des réactions de substitution homolytique bimoléculaire permettant de passer au cours d'une même réaction d'une espèce radicalaire à une espèce organométallique. Ainsi, les dialkylzincs sont de très bons médiateurs de réactions radicalaires et polaires en
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Books on the topic "Azide Trapping"

1

Nguyen, Thach-Mien Duong. Decomposition kinetics and azide trapping of ester derivative of A C, N-acetyl-N-acetoxy-2-amino- -carboline. 2002.

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2

Nguyen, Thach-Mien Duong. Decomposition kinetics and azide trapping of ester derivative of A C, N-acetyl-N-acetoxy-2-amino- -carboline. 2002.

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Journal articles
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