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Dissertations / Theses on the topic 'Azidi'

Author: Grafiati

Published: 9 March 2023

Last updated: 31 July 2025

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1

LO, CONTE Mauro. "SINTESI DI BIOISOSTERI DEGLI OLIGOMANNOSI CON POTENZIALE ATTIVITA’ ANTITUBERCOLARE." Doctoral thesis, Università degli studi di Ferrara, 2010. http://hdl.handle.net/11392/2389182.

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Mycobacterium tuberculosis is the cause of the deadly infectious disease, tuberculosis (TB). According to the World Health Organization, nearly one–third of the world's population has been exposed to the tuberculosis pathogen and nearly 1.6 million deaths result every year. TB is, in addition, the leading infectious killer of people living with HIV/AIDS. Recent outbreaks of drug-resistant TB in many industrialized nations have led to a new interest in the disease, and basic research and drug development have again become priorities. The Mycobacterium organism possesses a complex cell wal

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2

Merkel, Roswitha. "Untersuchung zur Synthese und Eigenschaften von komplexen Oligospiroketalen." Phd thesis, Universität Potsdam, 2014. http://opus.kobv.de/ubp/volltexte/2015/7256/.

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Es ist in dieser Arbeit gelungen, starre Oligospiroketal(OSK)-Stäbe als Grundbausteine für komplexe 2D- und 3D-Systeme zu verwenden. Dazu wurde ein difunktionalisierter starrer Stab synthetisiert, der mit seines Gleichen und anderen verzweigten Funktionalisierungseinheiten in Azid-Alkin-Klickreaktionen eingesetzt wurde. An zwei über Klickreaktion verknüpften OSK-Stäben konnten mittels theoretischer Berechnungen Aussagen über die neuartige Bimodalität der Konformation getroffen werden. Es wurde dafür der Begriff Gelenkstab eingeführt, da die Moleküle um ein Gelenk gedreht sowohl gestreckt als a

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3

Okumu, Antony A. "Development of a Safe and Efficient Alkyl Azide Synthesis using Arylsulfonyl Azide." Youngstown State University / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1290962115.

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4

Mackay, Fiona S. "Photoactive platinum azide anticancer complexes." Thesis, University of Edinburgh, 2006. http://hdl.handle.net/1842/11085.

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Photoactive platinum compounds have the potential to reduce some of the debilitating side-effects associated with conventional chemotherapeutics, such as cisplatin. Stable, inert platinum(IV) compounds which are reduced to active platinum(II) species only upon irradiation, could provide a site-specific treatment. The Pt<sup>IV</sup> azide complexes, <i>cis, trans, cis-</i>[Pt(N<sub>3</sub>)<sub>2</sub>(OH)<sub>2</sub>(NH<sub>3</sub>)<sub>2</sub>] and <i>cis, trans-</i>[Pt(en)(N<sub>3</sub>)<sub>2</sub>, have previously been shown to be stable in the dark but reduced to Pt<sup>II</sup> upon irr

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5

Dang, Thao P. "Biomimetic Modeling of the Nitrogen-centered Radical Postulated to occur during the Inhibition of Ribonucleotide Reductases by 2'-Azido-2'-deoxynucleotides." FIU Digital Commons, 2010. http://digitalcommons.fiu.edu/etd/318.

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Ribonucleotide reductases (RNR) are essential enzymes that catalyze the reduction of ribonucleotides to 2'-deoxyribonucleotides, which is a critical step that produces precursors for DNA replication and repair. The inactivation of RNR, logically, would discontinue producing the precursors of the DNA of viral or cancer cells, which then would consequently end the cycle of DNA replication. Among different compounds that were found to be inhibitors of RNR, 2'-azido-2'-deoxynucleotide diphosphates (N3NDPs) have been investigated in depth as potent inhibitors of RNR. Decades of investigation has su

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6

Bolton, R. E. "Azide decomposition in natural product synthesis." Thesis, Imperial College London, 1986. http://hdl.handle.net/10044/1/37947.

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7

Wong, Sang K. "Pharmaceutical studies on aromatic azido compounds." Thesis, Aston University, 1986. http://publications.aston.ac.uk/12461/.

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8

Schöffler, Claudia. "Propargylazide als Ausgangsmaterialien für Umlagerungsreaktionen und Heterocyclensynthesen." [S.l. : s.n.], 2000. http://deposit.ddb.de/cgi-bin/dokserv?idn=964562138.

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9

Firdous, Samia. "Synthesis and Reactions of α-Azido Alcohols". Doctoral thesis, Universitätsbibliothek Chemnitz, 2012. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-86012.

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Die vorliegende Arbeit beschäftigt sich mit der Untersuchung von a-Azidoalkoholen, welche über die Reaktion von aliphatischen sowie aromatischen Aldehyden mit HN3 leicht zugänglich sind und die im Gleichgewicht mit den jeweiligen Ausgangsstoffen vorliegen. Bei Raumtemperatur stellt sich dieses Gleichgewicht sehr schnell ein und man erhält spezifische Konzentrationen an Eduktaldehyd, Stickstoffwasserstoffsäure und a-Azidoalkohol. Die Reaktion von Aldehyden mit HN3 generiert dabei ein neues Chriralitätszentrum, wodurch die Umsetzung chiraler Aldehyde, wie z. B. von Zuckerderivaten, zwei anomere

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10

Canbolat, Eylem. "Organocatalytic Resolution Of Racemic Alpha Azido Ketones." Master's thesis, METU, 2012. http://etd.lib.metu.edu.tr/upload/12614602/index.pdf.

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Chiral cyclic alpha azido ketones are very important compounds in organic chemistry. Because, the reduced forms of them are amino alcohols and these amino alcohols are interesting compounds for their biological activities. They have some pharmaceutical activities such as: potassium channel open up properties, treatment of central nervous system, antihypertensive properties, the agent of dopamin receptor activator, hypolipemic agent and dopamine agonist. These types of compounds have highly acidic alpha-protons, and many kinds of reactions can be performed with them. In this study, mainly, sel

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11

Wutke, Jens. "Synthesen und Reaktionen von Ethinylaziden." Doctoral thesis, Universitätsbibliothek Chemnitz, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-61560.

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Gegenstand der vorliegenden Arbeit sind Versuche zur Synthese von 1-Azido-1 alkinen (Ethinylaziden). Diese instabilen Verbindungen zersetzen sich leicht unter Stickstoffabspaltung zu hochreaktiven Carbenen, welche mit verschiedenen Reagenzien, explizit Tolan, Cyclooctin, DMSO sowie DMF, abgefangen werden konnten. Obwohl eine direkte spektroskopische Beobachtung der Titelverbindungen mittels Tieftemperatur-NMR-Spektroskopie nicht verwirklicht werden konnte, gelang der eindeutige Nachweis von Ethinylaziden via deren 1,3-dipolarer Cycloaddition mit dem hochgespannten cyclischen Alkin Cyclooctin.

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12

Aubauer, Christoph. "Halogen-, Azid- und Koordinationsverbindungen des Phosphors." Diss., [S.l.] : [s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=963037900.

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13

Seoane, Gustavo A. "Synthesis of pyrrolizidine diols via azide-diene cycloadditions." Diss., Virginia Polytechnic Institute and State University, 1988. http://hdl.handle.net/10919/81012.

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The generality of the [4+1] annulation methodology in the context of natural product synthesis was demonstrated by extending its applicability to the heteroatom (nitrogen) case thus allowing access to the alkaloid field. This novel methodology involved the intramolecular union of a hypovalent nitrogen atom equivalent and a conjugated diene to afford a pyrroline ring. The flexibility of this strategy was exemplified by the formal synthesis of ring-A oxygenated pyrrolizidine alkaloids platynecine 8, turneforcidine 9, hastanecine 10, and dihydroxyheliotridane 11. The key features of this techno

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14

Copeland, Christopher N. II. "Modified Conditions for Acyl Azide and Carbamate Synthesis." Youngstown State University / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1473765784542178.

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15

Banert, Klaus. "Umlagerungen organischer Azide : Reaktionsmechanismen und Anwendungen in der Synthese /." Rheinfelden [etc.] : Schäuble, 1993. http://opac.nebis.ch/cgi-bin/showAbstract.pl?u20=3877189083.

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16

Silva, Mauro Vinícius Almeida da. "Modificação química do poli(cloreto de vinila) com nucleófilos nitrogenados assistida por micro-ondas." Universidade do Estado do Rio de Janeiro, 2013. http://www.bdtd.uerj.br/tde_busca/arquivo.php?codArquivo=4844.

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Conselho Nacional de Desenvolvimento Científico e Tecnológico<br>Nesse trabalho foram realizadas reações de substituição nucleofílica (SN2), utilizando aquecimento térmico convencional e por irradiação de micro-ondas (MO), de alguns átomos cloro em amostras comerciais de poli(cloreto de vinila) (PVC), por grupos nitrila e também por grupos azida. Os grupos nitrila e azida foram substituidos na matriz em diferentes teores (10% e 20%). As reações do PVC com azida foram eficazes, apresentado percentuais de derivatização muito próximos dos valores desejados. Já no estudo com a nitrila não foi obti

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17

Sofin, Mikhail. "Neue Alkalioxometallate über die Azid/Nitrat-Route." [S.l. : s.n.], 2003. http://www.bsz-bw.de/cgi-bin/xvms.cgi?SWB11051832.

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18

Davis, Edward A. "Studies of sodium azide with tetraphenylcyclopentadienones and various analogs." Thesis, Virginia Tech, 1985. http://hdl.handle.net/10919/45676.

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<p>The reaction of sodium azide with 2-p-chloro- and 2-pâ methoxyphenylâ 3,4,5-triphenylâ 2,4-cyclopentadienâ Iâ one was studied to determine if the substituent would have any appreciable effect on the product distribution of the corresponding l,5,7,8â tetraphenyl-2,3,4â triazabicyclo[3.3.0]octa-2,7-dien-6-ones and the 3,4,5,6â tetraphenylâ 2(lH)â pyridinones that were formed by an acid catalyzed rearrangement. It was found that the chloro substituent had no effect on the reaction. The methoxy substituent had a moderate effect in that the product arising from the stabilized in

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19

Adero, Philip O. "Heterocycle Synthesis via Rhodium (II)-Catalyzed Azido Carbenoid Cyclization." Youngstown State University / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1348595887.

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20

Young, Mary Jennifer T. "The photochemistry of pentafluorophenyl azide and its transient intermediates /." The Ohio State University, 1988. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487596307356436.

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21

Habimana, Jean de la Croix. "Fonctionnalisation directe en polymérisation cationique : synthèse d'oligoisobutène azido-téléchélique." Grenoble INPG, 1989. http://www.theses.fr/1989INPG0016.

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22

Maciej, Marissa Lucy. "Azido sugars for the modification of glycosaminoglycans in biology." Thesis, University of Manchester, 2015. https://www.research.manchester.ac.uk/portal/en/theses/azido-sugars-for-the-modification-of-glycosaminoglycans-in-biology(cf34d9aa-d20b-4225-b871-93a5983832b6).html.

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Heparan sulphate (HS) is critical for embryonic development with involvement in a myriad of biological processes, centrally mediating morphogenic movements and facilitating the specification and differentiation of tissues. Complicated by its structural micro-heterogeneity along with expression on numerous different proteoglycan cores, the plethora of roles for HS in biology and their underlying mechanisms have not yet been fully defined. The discovery and characterisation of new reagents and methods for modification of HS expression and/or structure will aid efforts in elucidating the structur

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23

Wells, Sheryl McGaha Walker Robert Harold. "Granular forms of sodium and potassium azide as a nematicide for established turfgrasses." Auburn, Ala, 2009. http://hdl.handle.net/10415/1712.

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24

Long, Brian D. "A mechanistic study of the solution thermolysis of 2-azidodiphenylmethanes." Thesis, Keele University, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.279920.

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25

Marzeion, Axel Michael. "Untersuchungen zur Kultur humaner isolierter Pankreas-Azini sowie zum Einfluss von Ceruletid und Octreotid auf Morphologie, Enzymsekretion und -synthese kultivierter humaner isolierter Pankreas-Azini." [S.l.] : [s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=963489399.

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26

Schütt, Thomas. "Halogen-, Azid- und Koordinationsverbindungen des Arsens und Antimons." [S.l.] : [s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=963037811.

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27

Schütt, Thomas. "Halogen-, Azid- und Koordinationsverbindungen des Arsens und Antimons." Diss., lmu, 2001. http://nbn-resolving.de/urn:nbn:de:bvb:19-3668.

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28

Aronson, Joshua Boyer. "The Synthesis and Characterization of Energetic Materials From Sodium Azide." Diss., Georgia Institute of Technology, 2004. http://hdl.handle.net/1853/7597.

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A tetrazole is a 5-membered ring containing 4 nitrogens and 1 carbon. Due to its energetic potential and structural similarity to carboxylic acids, this ring system has a wide number of applications. In this thesis, a new and safe sustainable process to produce tetrazoles was designed that acheived high yields under mild conditions. Also, a technique was developed to form a trityl-protected tetrazole in situ. The rest of this work involved the exploitation of the energetic potential of tetrazoles. This moiety was successfully applied in polymers, ionic liquids, foams, and gels. The overa

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29

Organtzis, Stefanos. "Polynuclear transition metal complexes containing azido and pyrazolinato bridging ligands." Thesis, University of Manchester, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.496513.

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Following the discovery that a single molecule can behave as a magnet, the field of research on magnetism has become of great interest to scientists. A large number of polynuclear compounds have been produced and studied worldwide over the past two decades, in an effort to obtain better single molecule magnets (SMMs). The synthesis of such compounds involves mainly first row transition metals and a wide range of bridging ligands.

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30

Link, Aaron James Tirrell David A. "Azide-bearing amino acids in protein engineering and proteomic profiling /." Diss., Pasadena, Calif. : Caltech, 2006. http://resolver.caltech.edu/CaltechETD:etd-09132005-120123.

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31

Zhang, Jianjun. "Library Synthesis of Anticancer and Antibacterial Agents via Azide Chemistry." DigitalCommons@USU, 2010. https://digitalcommons.usu.edu/etd/711.

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Various anticancer and antibacterial agents have been synthesized via azide chemistry by taking advantage of carbohydrate. Starting from the synthesis of 14 glycosyl azides, a library of carbohydrate-oxazolidinone conjugates and a library of carbohydrate-cyclopamine conjugates with biological interests were synthesized based on a highly efficient "click reaction" assisted by sonication. Some of the conjugates have improved solubility and enhanced anticancer activity. A library of neomycin B derivatives with various modifications at the 5" position has been synthesized. Two leads exhibit

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32

Azimi, Samaneh. "Energy efficiency adoption of low-income households in Australia." Thesis, Queensland University of Technology, 2022. https://eprints.qut.edu.au/236798/1/Samaneh%2BAzimi%2BThesis%281%29.pdf.

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Low-income housing constitutes an important but frequently overlooked, role in energy use reduction. Monetary and non-monetary barriers persist for low-income households to participate in energy efficiency programs and adopt energy-efficient lifestyles. This study examines the potential for increasing the adoption of energy efficiency measures by overcoming the energy efficiency barriers of low-income households in Australia. It developed a model to determine the relationship between barriers and energy efficiency adoption of low-income households and proposed various strategies to aid policym

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33

Scheubeck, Thomas Josef. "Beiträge zur strukturchemischen Untersuchung von Wasserstoffbrückenbindungen in ammoniakhaltigen Aziden, Amiden und Ammoniumsalzen." kostenfrei, 2009. http://www.opus-bayern.de/uni-regensburg/volltexte/2009/1308/.

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34

Beveridge, Jennifer Marie. "Copper(I)-catalyzed azide-alkyne cycloaddition with membrane bound lipid substrates." Thesis, Georgia Institute of Technology, 2015. http://hdl.handle.net/1853/53594.

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The bioorthogonal copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) reaction exhibits complex but well-defined kinetics in aqueous and organic solution for soluble azides, alkynes, and ligand-bound copper(I). The kinetic profile in two dimensions, however, for CuAAC systems within a lipid bilayer membrane, has yet to be defined. The effect of triazole formation with lipid membrane-bound components on membrane properties such as fluidity and permeability is also of interest. Azide- and alkyne-functionalized lysolipids were synthesized and incorporated into non-fluid vesicles, which were th

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35

Brittain, William David George. "Asymmetric synthesis 1,2,3-triazoles utilising the copper-catalysed azide-alkyne cycloaddition." Thesis, University of Birmingham, 2018. http://etheses.bham.ac.uk//id/eprint/8143/.

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The copper-catalysed azide-alkyne cycloaddition (CuAAC) is a highly efficient reaction and is the cornerstone of “click” chemistry. However, unlike many common metal-mediated transformations asymmetric CuAAC variants are relatively sparse. This thesis details asymmetric “click” reactions with Chapter 1 introducing the CuAAC and the asymmetric variants already present in the literature. Chapter 2 outlines research demonstrating the first example of kinetic resolution of an alkyne via a CuAAC reaction. Selectivity factors of up to 22.1 ± 0.5 were obtained and triazoles and alkynes were obtained

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36

Evangelista, Fernanda Cristina Gontijo. "Evaluation of in vitro antitumor activity of triazole / azide synthetic chalcones." Instituto Nacional de Pesquisas da Amazônia, 2018. http://bdtd.inpa.gov.br/handle/tede/2639.

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Submitted by Repositorio Tarefa (tarefarepositorio@gmail.com) on 2018-10-22T15:15:33Z No. of bitstreams: 2 Avaliação de atividade antitumoral in vitroELIDA.PDF: 334912 bytes, checksum: 7e3630670b1d8ca55012362260918128 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5)<br>Made available in DSpace on 2018-10-22T15:15:33Z (GMT). No. of bitstreams: 2 Avaliação de atividade antitumoral in vitroELIDA.PDF: 334912 bytes, checksum: 7e3630670b1d8ca55012362260918128 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) Previous issue date: 2018-10-01<br>

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37

Curry, Omadee S. "Reaction of o-Nitrobenzenesulfonyl Azide/n-Butyl Lithium with Hindered Alcohols." Youngstown State University / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1379945812.

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38

Jagerovic, Nadine. "Réactivité de complexes azido en série métalloporphyrinique : synthèses et études spectroscopiques." Dijon, 1990. http://www.theses.fr/1990DIJOS049.

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39

Gramlich, Philipp Mathias Edwin. "Selective DNA modification using the Cu(I)-catalyzed alkyne-azide cycloaddition." Göttingen Cuvillier, 2008. http://d-nb.info/990811395/04.

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40

Sirivolu, Venkata Ramana. "DNA containing side chains with terminal triple bonds: Synthesis, base pairing and functionalization of nucleosides and oligonucleotides by the azide-alkyne cycloaddition = DNA mit Terminalen Dreifachbindungen in Seitenketten: Synthese, Basenpaarung und Funktionalisierung von Nucleosiden und Oligonucleotiden durch die Azid-Alkin Cycloaddition /." Osnabrück, 2008. http://opac.nebis.ch/cgi-bin/showAbstract.pl?sys=000254558.

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41

Berndt, Christian. "Bildungstendenz und Reaktionen von α-Azidoalkoholen". Doctoral thesis, Universitätsbibliothek Chemnitz, 2013. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-112553.

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Gegenstand der vorliegenden Arbeit ist die Synthese von α-Azidoalkoholen durch die Reaktion von aliphatischen sowie aromatischen Aldehyden mit Stickstoffwasserstoffsäure. Dabei stellt sich ein Gleichgewicht ein, dessen Lage durch die Ermittlung der Gleichgewichtskonstanten quantitativ bestimmt wird. In jedem Fall besteht die Möglichkeit, den α-Azidoalkohol in der Gleichgewichtsmischung zu charakterisieren und teilweise gelingt die Isolierung der reinen α-Azidoalkohole bei tiefen Temperaturen sowie deren Charakterisierung mittels Tieftemperatur-NMR-Spektroskopie. Die Ausgangsaldehyde für die Sy

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42

Mannuthodikayil, Jamsad [Verfasser]. "Chemical tools for bioconjugation : Application of the thioacid-azide ligation / Jamsad Mannuthodikayil." Konstanz : Bibliothek der Universität Konstanz, 2015. http://d-nb.info/1100392319/34.

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43

Azimi, Mahdi [Verfasser]. "Banach space valued stochastic integral equations and their optimal control / Mahdi Azimi." Halle, 2018. http://d-nb.info/1153401991/34.

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44

Tolland, John Douglas. "Stopped-flow infrared spectroscopy of carbon monoxide and azide reduction by nitrogenase_â’¸." Thesis, University of East Anglia, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.405912.

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45

Kwarkoh, Angela. "Conversion of Alcohols to Alkyl Azides Using O-Nitrobenzenesulfonyl Azide." Youngstown State University / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1380022166.

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46

Moghaddam, Alan. "A STUDY OF THE BEHAVIOR AND LOCALIZATION OF PT(II) AZIDE AND ALKYNE-MODIFIED DERIVATIVES IN CELLS USING BIOORTHOGONAL CHEMISTRY AND FLUORESCENCE MICROSCOPY." Thesis, University of Oregon, 2016. http://hdl.handle.net/1794/20727.

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Despite their ubiquitous use, Pt(II) anti-cancer drugs still suffer from many issues such as off-drug target effects, renal and nephrotoxicity as well as acquired and intrinsic drug resistance. To obtain a better understanding of how to mitigate these deleterious effects can be mitigated we first must know all the targets of these drugs. Highlighted in this dissertation is previous work performed by groups exploring the localization of Pt in cells using fluorescence microscopy. While Pt drugs such as cisplatin contain no native fluorescence, a great deal of work has been done to covalently mod

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47

Feizy, Nilab [Verfasser], and Ulrich [Gutachter] Schatzschneider. "iClick-Reaktionen von Palladium(II)azid- und Platin(II)azid-Komplexen mit tridentaten N,N,N-Chelatliganden und elektronenarmen Alkinen / Nilab Feizy ; Gutachter: Ulrich Schatzschneider." Würzburg : Universität Würzburg, 2019. http://d-nb.info/1182902839/34.

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48

Giovedi, Claudia. "Comportamento eletroquímico dos metais Co(II), Ni(II), Mn(II), Fe(II) e Zn(II) na presença do ligante azoteto." Universidade de São Paulo, 1998. http://www.teses.usp.br/teses/disponiveis/46/46133/tde-02122009-152133/.

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O comportamento eletroquímico dos metais cobalto(II), níquel(II), manganês(II), ferro(II) e zinco(II) na presença do ligante azoteto foi estudado em duas condições: variando-se a concentração do ligante em solução de 0 a 2,0 mol/L e apenas tendo-o pré-adsorvido na superficie do eletrodo de mercúrio, buscando-se assim esclarecer os fenômenos determinantes na extensão da atuação do ligante como mediador facilitando a etapa de transferência de elétrons do eletrodo para o metal. Os resultados obtidos nas duas séries de experimentos mostraram ser a extensão da atuação do ligante como mediador depen

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49

Azizi, Hossein [Verfasser], and Thomas [Akademischer Betreuer] Skutella. "Identification and Pluripotency of Mouse Spermatogonial Stem Cells / Hossein Azizi ; Betreuer: Thomas Skutella." Heidelberg : Universitätsbibliothek Heidelberg, 2014. http://d-nb.info/1177148854/34.

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50

Conway, Louis Patrick. "The aqueous phosphorylation and ligation of nucleoside analogues and aqueous azide reduction methodology." Thesis, Durham University, 2014. http://etheses.dur.ac.uk/10735/.

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Abstract:

The research within this thesis is primarily concerned with the synthesis of modified nucleosides, their oxyphosphorylation and thiophosphorylation to form analogues of nucleoside monophosphates and phosphodiester linkages, and the chemistry of the thiophosphoryl group. These families of compounds may have potential in the areas of antisense oligonucleotide agents or nuclease inhibition. The work described here may also provide routes to new glycosyltransferase inhibitors. This work builds upon previous work in the Hodgson research group, principally the thiophosphorylation and subsequent alky

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