Relevant bibliographies by topics / Azido metal complexes

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  1. Journal articles
  2. Dissertations / Theses
  3. Book chapters
  4. Conference papers

Academic literature on the topic 'Azido metal complexes'

Author: Grafiati
Published: 5 June 2025
Last updated: 1 August 2025

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Journal articles on the topic "Azido metal complexes"

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Abu-Youssef, Morsy A. M., Vratislav Langer, Assem Barakat, Matti Haukka, and Saied M. Soliman. "Molecular, Supramolecular Structures Combined with Hirshfeld and DFT Studies of Centrosymmetric M(II)-azido {M=Ni(II), Fe(II) or Zn(II)} Complexes of 4-Benzoylpyridine." Symmetry 13, no. 11 (2021): 2026. http://dx.doi.org/10.3390/sym13112026.

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The supramolecular structures of the three metal (II) azido complexes [Fe(4bzpy)4(N3)2]; 1, [Ni(4bzpy)4(N3)2]; 2 and [Zn(4bzpy)2(N3)2]n; 3 with 4-benzoylpyridine (4bzpy) were presented. All complexes contain hexa-coordinated divalent metal ions with a slightly distorted octahedral MN6 coordination sphere. Complexes 1 and 2 are monomeric with terminal azido groups while 3 is one-dimensional coordination polymer containing azido groups with μ(1,1) and μ(1,3) bridging modes of bonding. Hirshfeld analysis was used to quantitatively determine the different contacts affecting the molecular packing i
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Buys, IE, LD Field, AV George, TW Hambley, and GR Purches. "Synthesis and Reactions of Azido Complexes of Ruthenium." Australian Journal of Chemistry 48, no. 1 (1995): 27. http://dx.doi.org/10.1071/ch9950027.

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Sodium azide reacts with RuH2 ( dmpe )2 (1a) ( dmpe = 1,2-bis( dimethylphosphino )ethane) in methanol solution to form RuH (N3)( dmpe )2 (2a), and reacts with RuCl2( depe )2 (3b) ( depe = 1,2-bis( diethylphosphino )ethane) to form the bis ( azide ) complex Ru (N3)2( depe )2 (4b). The crystal structures of Ru ( Cl )2( depe )2 (3b) and Ru (N3)2( depe )2 (4b) have been determined and indicate that the chloro groups in (3b) and the azido groups in (4b) are trans across the metal centre.
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Stamatatos, Theocharis C., and Eva Rentschler. "Organic chelate-free and azido-rich metal clusters and coordination polymers from the use of Me3SiN3: a new synthetic route to complexes with beautiful structures and diverse magnetic properties." Chemical Communications 55, no. 1 (2019): 11–26. http://dx.doi.org/10.1039/c8cc08854c.

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A new synthetic route to structurally novel and magnetically interesting 3d-metal azido clusters and coordination polymers is presented; the key reagent for the preparation of solely azido-bridged molecule-based species is the organic azide precursor Me<sub>3</sub>SiN<sub>3</sub>.
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Taher, Thuraya A., Waleed K. Mahdi, and Falih H. Musa. "Synthesis and Characterization of some Metal Complexes with (3Z ,5Z, 8Z)-2-azido-8-[azido(3Z,5Z)-2-azido-2,6bis(azidocarbonyl)-8,9-dihydro-2H-1,7-dioxa-3,4,5triazonine-9-yl]methyl]-9-[(1-azido-1-hydroxy)methyl]-2H1,7-dioxa-3,4,5-triazonine – 2,6 – dica." Ibn AL- Haitham Journal For Pure and Applied Science 30, no. 3 (2017): 77. http://dx.doi.org/10.30526/30.3.1604.

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The reaction of LAs-Cl8 : [ (2,2- (1-(3,4-bis(carboxylicdichloromethoxy)-5-oxo-2,5dihydrofuran-2-yl)ethane – 1,2-diyl)bis(2,2-dichloroacetic acid)]with sodium azide in ethanol with drops of distilled water has been investigated . The new product L-AZ :(3Z ,5Z,8Z)-2azido-8-[azido(3Z,5Z)-2-azido-2,6-bis(azidocarbonyl)-8,9-dihydro-2H-1,7-dioxa-3,4,5triazonine-9-yl]methyl]-9-[(1-azido-1-hydroxy)methyl]-2H-1,7-dioxa-3,4,5-triazonine – 2,6 – dicarbonylazide was isolated and characterized by elemental analysis (C.H.N) , 1H-NMR , Mass spectrum and Fourier transform infrared spectrophotometer (FT-IR) .
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Dadashi, Jaber, Mohammad Khaleghian, Younes Hanifehpour, Babak Mirtamizdoust, and Sang Woo Joo. "Lead(II)-Azido Metal–Organic Coordination Polymers: Synthesis, Structure and Application in PbO Nanomaterials Preparation." Nanomaterials 12, no. 13 (2022): 2257. http://dx.doi.org/10.3390/nano12132257.

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The current study aims to explain recent developments in the synthesis of Pb(II)-azido metal-organic coordination polymers. Coordination polymers are defined as hybrid materials encompassing metal-ion-based, organic linkers, vertices, and ligands, serving to link the vertices to 1D, 2D, or 3D periodic configurations. The coordination polymers have many applications and potential properties in many research fields, primarily dependent on particular host–guest interactions. Metal coordination polymers (CPs) and complexes have fascinating structural topologies. Therefore, they have found numerous
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Mautner, Franz A., Magdalena Traber, Patricia Jantscher, et al. "Thiocyanato-metal(II) and azido-cobalt(III) complexes with hydroxymethylpyridines." Polyhedron 161 (March 2019): 309–16. http://dx.doi.org/10.1016/j.poly.2019.01.030.

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Strähle, Joachim. "Reactions of Transition Metal Azido Complexes and their Reaction Products." Zeitschrift für anorganische und allgemeine Chemie 633, no. 11-12 (2007): 1757–61. http://dx.doi.org/10.1002/zaac.200700170.

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Geisenberger, Josef, Jürgen Erbe, Jürgen Heidrich, Ulrich Nagela, and Wolfgang Beck. "Pseudohalogenometallverbindungen, LXV [1] Synthese von Tetrazolen und Triazolen über die 1,3-dipolare Cycloaddition an die Azid-Liganden von polymeren Cobalt(III)-und Palladium(II)-Komplexen. Darstellung und Struktur von 5-TrichlormethyItetrazol / Pseudohalogeno Metal Compounds, LXV [1] Synthesis of Tetrazoles and Triazoles via 1,3-Dipolar Cycloaddition to the Azido Ligands of Polymerie Cobalt(III) and Palladium(II) Complexes. Synthesis and Structure of 5-Trichloromethyltetrazole." Zeitschrift für Naturforschung B 42, no. 1 (1987): 55–64. http://dx.doi.org/10.1515/znb-1987-0112.

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Abstract The cycloaddition of nitriles and of dimethylacetylenedicarboxylate to the azide ligand of polymeric Schiff Base cobalt(III) and phosphine palladium(II) complexes gives the corresponding tetrazolate and triazolate complexes from which the heterocycles could be cleaved by hydrogen chloride. Usually the yields are low; if the heterocycle is soluble in ether or sublimable, yields up to 30% have been obtained. Using this method the hitherto unknown 5-trichlormethyltetrazole could be prepared which was characterized by an X-ray structural analysis. Similarly, the cyclo-addition of azido(te
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Bröring, Martin, Silke Köhler, and Clemens Pietzonka. "Pseudohalogenido complexes of iron-2,2′-bidipyrrins." Journal of Porphyrins and Phthalocyanines 16, no. 05n06 (2012): 641–50. http://dx.doi.org/10.1142/s1088424612500538.

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The chlorido iron(III) complex of octaethyl-2,2′-bidipyrrin has been transformed to a series of pseudohalide complexes by ligand exchange reactions with azide, cyanate, thiocyanate and selenocyanate anions. All new complexes show the expected N-coordination of the axial ligand to the iron(III) center. In the solid state, all four species display an intermediate spin (S = 3/2) ground state, with a gradual increase of a high spin (S = 5/2) contribution at elevated temperatures for the members with the smallest ligand field strengths, i.e. the cyanato and the azido derivatives. In solution, proto
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Portius, Peter, Anthony J. H. M. Meijer, Michael Towrie, Benjamin F. Crozier, and Ingrid Schiager. "Picosecond time-resolved infrared spectroscopy of rhodium and iridium azides." Dalton Trans. 43, no. 47 (2014): 17694–702. http://dx.doi.org/10.1039/c4dt02097a.

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Ultrafast photochemical processes induced in the transition metal azido complexes Rh(Cp*)(N<sub>3</sub>)<sub>2</sub>(PPh<sub>3</sub>) and Ir(Cp*)(N<sub>3</sub>)<sub>2</sub>(PPh<sub>3</sub>) upon laser excitation at 266 nm and 400 nm were elucidated by picosecond time-resolved infrared spectroscopy and density functional theory.
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Dissertations / Theses on the topic "Azido metal complexes"

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Organtzis, Stefanos. "Polynuclear transition metal complexes containing azido and pyrazolinato bridging ligands." Thesis, University of Manchester, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.496513.

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Following the discovery that a single molecule can behave as a magnet, the field of research on magnetism has become of great interest to scientists. A large number of polynuclear compounds have been produced and studied worldwide over the past two decades, in an effort to obtain better single molecule magnets (SMMs). The synthesis of such compounds involves mainly first row transition metals and a wide range of bridging ligands.
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Boukhris, Abdallah. "Étude par diffraction des rayons X des porphyrines de gallium, germanium et indium, synthons potentiels de conducteurs électriques unidimensionnels." Nancy 1, 1986. http://www.theses.fr/1986NAN10038.

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Étude des composés GA(OEP)(SO::(3)CH::(3)), GA(OEP)N::(3), GE(TPMEPP)(N::(3))::(2), GE(OEP)F::(2) et (OEP) IN-MN(CO)::(5). Caractérisation des groupements azido dans les porphyrines de gallium et de germanium. Première liaison simple métat-métal dans la série des métalloporphyrines. Dopage de fluoro-octaethylporphyrines de gallium et d'octaméthylporphyrines de nickel par l'iode moléculaire. Incommensurabilité des réseaux iode et porphyrine, caractère polymérique des métalloporphyrines. Étude de la conductivité électrique
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Frantz, Eric Benjamin. "Synthesis, reactivity, and coordination chemistry relevant to the copolymerization of CO2 and epoxides by first row transition metal schiff base complexes." [College Station, Tex. : Texas A&M University, 2008. http://hdl.handle.net/1969.1/ETD-TAMU-2893.

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Fauché, Kévin. "NHC portant des azotures : intermédiaires dans la synthèse catalysée d‘hétérocycles polyazotés et auto-fonctionnalisation de complexes métal-NHC." Thesis, Université Clermont Auvergne‎ (2017-2020), 2018. http://www.theses.fr/2018CLFAC062/document.

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Les carbènes N-hétérocycliques (NHC) sont très utilisés pour complexer les métaux de transition. Ils quittent rarement ce rôle de ligand ancillaire et trouvent, depuis une vingtaine d’années, des applications en catalyse ou, plus récemment, en chimie médicinale. Dans ce travail, nous discuterons d’une méthode de synthèse douce conduisant à la formation de complexes AgI – NHC via une source d’argent soluble. Cette méthode nous a permis d’obtenir des complexes bien connus mais également d’accéder à une nouvelle série de complexes NHC-Ag-phosphine. Nous présenterons également
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Book chapters on the topic "Azido metal complexes"

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Pontes, Ana Cristina, D. L. Pontes, F. O. da Silva Nascimento, and A. L. Anjos. "SÍNTESE E CARACTERIZAÇÃO DE COMPLEXOS DE MOLIBDÊNIO(VI) COM LIGANTES NITROGENADOS." In Open Science Research XVII. Editora Científica Digital, 2024. https://doi.org/10.37885/241018053.

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O trabalho objetiva a síntese e caracterização de complexos de molibdênio(VI) em sua isomeria cis-dioxo com os ligantes 1,10-Fenantrolina (phen) e Azida (N3-). Assim sendo, os compostos cis-[Mo(phen)(O)2Cl2] e cis-[Mo(phen)(O)2(N3)2] foram obtidos a partir do precursor cis [Mo(DMSO)2(O)2Cl2]. Os complexos foram obtidos ajustando as condições de síntese como temperatura, tempo reacional e proporção do precursor com os ligantes, para substituição dos ligantes DMSO pela phen ou met e dos cloretos pelas azidas. A caracterização foi realizada por meio de técnicas espectroscópicas (Infravermelho, Ra
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Biswas, Apurba. "Synthesis and Magnetic Properties of Polynuclear Complexes of 1st Transition Metals: A Mini Review." In Lincoln Publication. Lincoln Publication, 2024. http://dx.doi.org/10.31674/book.2024ecc.011.

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The design and synthesis of multinuclear complexes has attracted considerable interest for their utility in small memory devices and quantum phenomena. The studies of magnetic studies of those complexes are very important to know their behavior in presence of magnetic fields. Now a days, ongoing interest is to synthesis single molecule-based magnets (SMMs) that can be derived from transition metals with different ligands. Majority of the metals that are used for the synthesis of such singlemolecule magnets are Co(II/III), Mn(II/III), Cu(II) and Ni(II). Different synthetic routes and ligands ha
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Mondal, Prantik, Nikhil K. Singha, and Richard Hoogenboom. "Miscellaneous Click and Click-like Reactions in Polymer Science." In Click Chemistry in Polymer Science. Royal Society of Chemistry, 2024. http://dx.doi.org/10.1039/9781839169885-00142.

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Click chemistry approaches have directed the materials research community to access a diverse range of complex polymeric systems. Click chemistry involves exploiting the easy-to-execute chemical reactions that can be performed at ambient conditions while being efficient and rapid. Macromolecular engineering with click chemistry requires the explicit installation of clickable reactive groups on polymer side chains or chain ends. The copper(i)-catalyzed azide–alkyne (CuAAC) cycloaddition is the most prominent click reaction in polymer science. However, the Cu catalyst needs to be removed for man
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Lambert, Tristan H. "Advances in Heterocyclic Aromatic Construction." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0068.

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Rubén Vicente and Luis A. López at the University of Oviedo in Spain reported (Angew. Chem. Int. Ed. 2012, 51, 8063) the synthesis of cyclopropyl furan 2 from alkylidene 1 and styrene by way of a zinc carbene intermediate. The same substrate 1 was also converted (Angew. Chem. Int. Ed. 2012, 51, 12128) to furan 3 via catalysis with tetrahydrothiophene in the presence of benzoic acid by J. Stephen Clark at the University of Glasgow. Xue-Long Hou at the Shanghai Institute of Organic Chemistry discovered (Org. Lett. 2012, 14, 5756) that palladacycle 6 catalyzes the conversion of bicyclic alkene 4
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Taber, Douglass F. "Reactions of Alkenes." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0030.

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Fung-E Hong of the National Chung Hsing University devised (Adv. Synth. Catal. 2011, 353, 1491) a protocol for the oxidative cleavage of an alkene 1 (or an alkyne) to the carboxylic acid 2. Patrick H. Dussault of the University of Nebraska found (Synthesis 2011, 3475) that Na triacetoxyborohydride reduced the methoxy hydroperoxide from the ozonolysis of 3 to the aldehyde 4. Reductive amination of 4 can be effected in the same pot with the same reagent. Philippe Renaud of the University of Bern used (J. Am. Chem. Soc. 2011, 133, 5913) air to promote the free radical reduction to 6 of the interm
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Conference papers on the topic "Azido metal complexes"

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Inoue, K., M. Yamashita, H. Miyama, T. Ohishi, T. Yosida, and T. Takeuchi. "Haldane gap system: structure and magnetic properties of azide-bridged nickel complexes." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835682.

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