Academic literature on the topic 'Batch reactive distillation'

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Journal articles on the topic "Batch reactive distillation"

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Kalakuntala, Raju, R. Navya, T. Sisira, V. V. Basava Rao, and Srinath Surnani. "Experimental studies on reactive distillation of propionic acid using n-butanol as entrained." International Journal of Engineering & Technology 7, no. 3.29 (August 24, 2018): 46. http://dx.doi.org/10.14419/ijet.v7i3.29.18459.

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Reactive distillation is a cost effective chemical engineering process intensification method which involves the reaction and separation simultaneously in a single unit. In the present work the system selected was Propionic acid and n-butanol which undergoes esterification reaction to form butyl propionate. Propionic acid is an important raw material from a biodegradable polymer. The experiments were done in both conventional batch distillation and reactive distillation. In conventional batch distillation no catalyst were used were as in reactive distillation amberlite catalyst used with various weight percentage. several experiments performed by varying the initial concentration(i.e. 0.1,0.2,0.4,0.6,0.8,0.99) of Propionic acid, mole ratios of Propionic acid & n-butanol(that is 1:1 ,1:1.5 ,1:2 And amberlite catalyst weight percent (i.e. 1,2 and 3).the conventional batch distillation and reactive distillation were compared. it is found that maximum conversion obtained in conventional distillation process is 81% and in reactive distillation is 95.1% at the optimum conditions are at initial concentration 0.6 ,mole ratio 1:2 And amberlite catalyst weight percentage 3 .And the recovery of water is more in reactive distillation as compared with the conventional batch distillation .So reactive distillation process is better than conventional distillation.
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GIESSLER, SABINE, SHINJI HASEBE, and IORI HASHIMOTO. "Optimization Aspects for Reactive Batch Distillation." JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 34, no. 3 (2001): 312–18. http://dx.doi.org/10.1252/jcej.34.312.

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Gadewar, Sagar B., Michael F. Malone, and Michael F. Doherty. "Selectivity Targets for Batch Reactive Distillation†." Industrial & Engineering Chemistry Research 39, no. 6 (June 2000): 1565–75. http://dx.doi.org/10.1021/ie990497p.

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Guo, Zhe, Mudassir Ghufran, and Jae W. Lee. "Feasible products in batch reactive distillation." AIChE Journal 49, no. 12 (December 2003): 3161–72. http://dx.doi.org/10.1002/aic.690491216.

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Sørensen, Eva, and Sigurd Skogestad. "Control strategies for reactive batch distillation." Journal of Process Control 4, no. 4 (January 1994): 205–17. http://dx.doi.org/10.1016/0959-1524(94)80042-1.

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Huerta-Garrido, Maria E., Vicente Rico-Ramirez, and Salvador Hernandez-Castro. "Simplified Design of Batch Reactive Distillation Columns." Industrial & Engineering Chemistry Research 43, no. 14 (July 2004): 4000–4011. http://dx.doi.org/10.1021/ie030658w.

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Kao, Yu-Lung, and Jeffrey D. Ward. "Batch Reactive Distillation with Off-Cut Recycling." Industrial & Engineering Chemistry Research 54, no. 7 (February 12, 2015): 2188–200. http://dx.doi.org/10.1021/ie5042929.

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Maiti, Debadrita, Amiya K. Jana, and Amar Nath Samanta. "Intensified thermal integration in batch reactive distillation." Applied Energy 103 (March 2013): 290–97. http://dx.doi.org/10.1016/j.apenergy.2012.09.048.

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Guo, Zhe, and Jae W. Lee. "Feasible products in batch reactive extractive distillation." AIChE Journal 50, no. 7 (2004): 1484–92. http://dx.doi.org/10.1002/aic.10140.

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Chin, James, Jae W. Lee, and Jaehoon Choe. "Feasible products in complex batch reactive distillation." AIChE Journal 52, no. 5 (2006): 1790–805. http://dx.doi.org/10.1002/aic.10795.

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Dissertations / Theses on the topic "Batch reactive distillation"

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Todd, Heather Elizabeth. "Investigating catalyst performance in batch reactive distillation." Thesis, University of Newcastle Upon Tyne, 2011. http://hdl.handle.net/10443/1244.

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Reactive distillation (RD) combines chemical synthesis with separation by distillation, but this leads to a non-trivial system: the hardware selection, the system components, the mode of operation and the operating conditions all affect the performance of the RD process. A key process development issue is the identification of suitable catalysts that perform well under reactive distillation conditions, as catalysts are crucial for increasing reaction rate when operating temperature range is limited by evaporation. The main goal of this research is to develop a method, utilizing high throughput technology, which can be used to assess many candidate catalysts for batch RD systems. The identification of potentially suitable catalysts should be made as early as possible, but before experimental work begins the only information available is the catalyst composition and structure. The approach taken in this research is to correlate catalyst properties to the performance in RD tests and the outputs from the dynamic simulations. The case study used is a batch reactive distillation for the esterification of a long-chain fatty acid. Potential catalysts are studied at small scale in a high throughput platform, and further investigation if performaed in an experimental batch RD unit. The most active of the screened catalysts, sulfuric acid and MSA also have the highest initial activity under RD. Heteropoly acids appear to have a good activity level, while ferric sulfate gives intermediate but apparently increasing activity. Some outcomes of the RD experiments were unexpected: the strong homogeneous acid catalysts entail low distillate water yield, and some metal acetates had higher activity than anticipated in the RD tests. This demonstrates that pilot scale experiments currently remain necessary for the evaluation of catalyst performance for RD processes. The insights gained from this study lead to key recommendations for future studies: an increased scope of study with a larger number of candidates which preferable have similar structure; evaluation of additional catalyst performance indicators, performed over the full operating temperature range; use of the smallest suitable experimental column; and more focus on physical factors such as solubility. Use of a simulator with an established physical property calculation tool is essential for successful simulations of batch RD.
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Bahar, Almila. "Modeling And Control Studies For A Reactive Batch Distillation Column." Phd thesis, METU, 2007. http://etd.lib.metu.edu.tr/upload/12608344/index.pdf.

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Modeling and inferential control studies are carried out on a reactive batch distillation system for the esterification reaction of ethanol with acetic acid to produce ethyl acetate. A dynamic model is developed based on a previous study done on a batch distillation column. The column is modified for a reactive system where Artificial Neural Network Estimator is used instead of Extended Kalman Filter for the estimation of compositions of polar compounds for control purposes. The results of the developed dynamic model of the column is verified theoretically with the results of a similar study. Also, in order to check the model experimentally, a lab scale column (40 cm height, 5 cm inner diameter with 8 trays) is used and it is found that experimental data is not in good agreement with the models&rsquo
. Therefore, the model developed is improved by using different rate expressions and thermodynamic models (fi-fi, combination of equations of state (EOS) and excess Gibbs free energy (EOS-Gex), gama-fi) with different equations of states (Peng Robinson (PR) / Peng Robinson - Stryjek-Vera (PRSV)), mixing rules (van der Waals / Huron Vidal (HV) / Huron Vidal Original (HVO) / Orbey Sandler Modification of HVO (HVOS)) and activity coefficient models (NRTL / Wilson / UNIQUAC). The gama-fi method with PR-EOS together with van der Waals mixing rule and NRTL activity coefficient model is selected as the best relationships which fits the experimental data. The thermodynamic models
EOS, mixing rules and activity coefficient models, all are found to have very crucial roles in modeling studies. A nonlinear optimization problem is also carried out to find the optimal operation of the distillation column for an optimal reflux ratio profile where the maximization of the capacity factor is selected as the objective function. In control studies, to operate the distillation system with the optimal reflux ratio profile, a control system is designed with an Artificial Neural Network (ANN) Estimator which is used to predict the product composition values of the system from temperature measurements. The network used is an Elman network with two hidden layers. The performance of the designed network is tested first in open-loop and then in closed-loop in a feedback inferential control algorithm. It is found that, the control of the product compositions with the help of an ANN estimator with error refinement can be done considering optimal reflux ratio profile.
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Edreder, E. A. "Modelling and optimisation of batch distillation involving esterification and hydrolysis reaction systems. Modelling and optimisation of conventional and unconventional batch distillation process: Application to esterification of methanol and ethanol using acetic acid and hydrolysis of methyl lactate system." Thesis, University of Bradford, 2010. http://hdl.handle.net/10454/4296.

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Batch distillation with chemical reaction when takes place in the same unit is referred to as batch reactive distillation process. The combination reduces the capital and operating costs considerably. Among many different types of batch reactive distillation column configurations, (a) conventional (b) inverted (c) semi-batch columns are considered here. Three reaction schemes such as (a) esterification of methanol (b) esterification of ethanol (c) hydrolysis of methyl lactate are studied here. Four different types of dynamic optimisation problems such as (a) maximum conversion (b) maximum productivity (c) maximum profit and (d) minimum time are formulated in this work. Optimal design and or operation policies are obtained for all the reaction schemes. A detailed rigorous dynamic model consisting of mass, energy balances, chemical reaction and thermodynamic properties is considered for the process. The model was incorporated within the dynamic optimisation problems. Control Vector Parameterisation (CVP) technique was used to convert the dynamic optimisation problem into a nonlinear programming problem which was solved using efficient SQP (Successive Quadratic Programming) method available within the gPROMS (general PROcess Modelling System) software. It is observed that multi-reflux ratio or linear reflux operation always led to better performance in terms of conversion, productivity for all reaction schemes compared to that obtained using single reflux operation. Feed dilution (in the case of ethanol esterification) led to more profit even though productivity was found to be lower. This was due to reduction in feed price because of feed dilution. Semi-batch reactive distillation opertation (for ethanol esterification) led to better conversion compared to conventional batch distillation, however, the total amount of acetic acid (reactant) was greater in semi-batch operation. Optimisation of design and operation (for ethanol esterification) clearly showed that a single cloumn will not lead to profitable operation for all possible product demand profile. Also change in feed and /or product price may lead to adjust the production target to maximise the profitability. In batch distillation, total reflux operation is recommended or observed at the begining of the operation (as is the case for methnaol or ethanol esterification). However, in the case of hydrolysis, total reflux operation was obseved at the end of the operation. This was due to lactic acid (being the heaviest) was withrawn as the final bottom product.
Libyan Petroleum Institute
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Edreder, Elmahboub A. "Modelling and optimisation of batch distillation involving esterification and hydrolysis reaction systems : modelling and optimisation of conventional and unconventional batch distillation process : application to esterification of methanol and ethanol using acetic acid and hydrolysis of methyl lactate system." Thesis, University of Bradford, 2010. http://hdl.handle.net/10454/4296.

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Batch distillation with chemical reaction when takes place in the same unit is referred to as batch reactive distillation process. The combination reduces the capital and operating costs considerably. Among many different types of batch reactive distillation column configurations, (a) conventional (b) inverted (c) semi-batch columns are considered here. Three reaction schemes such as (a) esterification of methanol (b) esterification of ethanol (c) hydrolysis of methyl lactate are studied here. Four different types of dynamic optimisation problems such as (a) maximum conversion (b) maximum productivity (c) maximum profit and (d) minimum time are formulated in this work. Optimal design and or operation policies are obtained for all the reaction schemes. A detailed rigorous dynamic model consisting of mass, energy balances, chemical reaction and thermodynamic properties is considered for the process. The model was incorporated within the dynamic optimisation problems. Control Vector Parameterisation (CVP) technique was used to convert the dynamic optimisation problem into a nonlinear programming problem which was solved using efficient SQP (Successive Quadratic Programming) method available within the gPROMS (general PROcess Modelling System) software. It is observed that multi-reflux ratio or linear reflux operation always led to better performance in terms of conversion, productivity for all reaction schemes compared to that obtained using single reflux operation. Feed dilution (in the case of ethanol esterification) led to more profit even though productivity was found to be lower. This was due to reduction in feed price because of feed dilution. Semi-batch reactive distillation opertation (for ethanol esterification) led to better conversion compared to conventional batch distillation, however, the total amount of acetic acid (reactant) was greater in semi-batch operation. Optimisation of design and operation (for ethanol esterification) clearly showed that a single cloumn will not lead to profitable operation for all possible product demand profile. Also change in feed and /or product price may lead to adjust the production target to maximise the profitability. In batch distillation, total reflux operation is recommended or observed at the begining of the operation (as is the case for methnaol or ethanol esterification). However, in the case of hydrolysis, total reflux operation was obseved at the end of the operation. This was due to lactic acid (being the heaviest) was withrawn as the final bottom product.
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Aqar, Dhia Y. "Modelling and Optimization of Conventional and Unconventional Batch Reactive Distillation Processes. Investigation of Different Types Batch Reactive Distillation Columns for the Production of a Number of Esters such as Methyl Lactate, Methyl Decanoate, Ethyl Benzoate, and Benzyl Acetate using gPROMS." Thesis, University of Bradford, 2018. http://hdl.handle.net/10454/17139.

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The synthesis of a number of alkyl esters such as methyl lactate, methyl decanoate, and ethyl benzoate via esterification in a reactive distillation is quite challenging. It is due to the complexity in the thermodynamic behaviour of the chemical species in the reaction mixture in addition to the difficulty of keeping the reactants together in the reaction section. One of the reactants (in these esterification reactions) having the lowest boiling point can separate from the other reactant as the distillation continues. This can result in a significant drop in the reaction conversion in a conventional reactive distillation whether it is a batch or a continuous column. To overcome this challenge, new different types of batch reactive distillation column configurations: (1) integrated conventional (2) semi-batch (3) integrated semi-batch (4) integrated dividing-wall batch distillation columns have been proposed here. Four esterification reaction schemes such as (a) esterification of lactic acid (b) esterification of decanoic acid (c) esterification of benzoic acid (d) esterification of acetic acid are investigated here. A detailed dynamic model based on mass, energy balances, chemical reaction, and rigorous thermodynamic (chemical and physical) properties is considered and incorporated in the optimisation framework within gPROMS (general PROcess Modelling System) software. It is found that for the methyl lactate system, the i-SBD operation outperforms the classical batch operations (CBD or SBD columns) to satisfy the product constraints. While, for the methyl decanoate system, the i-DWCBD operation outperforms all CBD, DWBD and sr-DWBD configurations by achieving the higher reaction conversion and the maximum product purity. For the ethyl benzoate system, the performance of i-CBD column is superior to the CBD process in terms of product quality, and conversion rate of acid. The CBD process is found to be a more attractive in terms of operating time saving, and annual profit improvement compared to the IBD, and MVD processes for the benzyl acetate system.
The Higher Committee for Education Development in Iraq (HCED)
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Martinez, Claudio de Lima Miguel. "State estimation for improved control in batch reaction and distillation processes." Thesis, University of Nottingham, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.339553.

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Demicoli, Daniel. "Novel batch distillation processes for the separation of systems with and without chemical reaction." [S.l.] : [s.n.], 2005. http://deposit.ddb.de/cgi-bin/dokserv?idn=978975030.

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Masoud, Aboubaker Z. "Dynamic optimisation of batch distillation with and without chemical reaction with emphasis on product demand and operating cost : modelling conventional and unconventional batch distillation in gPROMS and operation parameters to maximise profitability whi." Thesis, University of Bradford, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.511386.

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Edreder, E. A., Iqbal M. Mujtaba, and M. Emtir. "Optimal Operation of Batch Reactive Distillation Process Involving Esterification Reaction System." 2015. http://hdl.handle.net/10454/9141.

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The performance of batch reactive distillation process involving the esterification of acetic acid with methanol to produce methyl acetate and water is considered in this work. Two cases studies with varying amount of the reactants are considered. The reflux ratio (single time interval) is selected as the control variable to be optimised (treated as piecewise constant) for different but fixed batch time ranging from 5 to 15 h, so as to maximise the conversion of methanol subject to product purity of methyl acetate. The dynamic optimisation problem is converted to a nonlinear programming problem by Control Vector Parameterization (CVP) technique and is solved by using efficient SQP method. The optimisation results show that as the methanol and methyl acetate are wide boiling, the separation of methyl acetate is easier without losing much of methanol reactant. The conversion improves by 6.4 % due to sufficient amount of acetic acid being reacted with methanol. Moreover an excess of acetic acid leads to high operation temperature and therefore high reflux operation (to reduce loss of methanol from the top of the column) to maximise the conversion.
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Qi, Wei. "Synthesis, design and operating strategies for batch reactive distillation." 2010. https://scholarworks.umass.edu/dissertations/AAI3427600.

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Batch reactive distillation (BRD), combines the flexibility of batch processing with the advantages of reactive distillation and can offer advantages over conventional batch processing for small to medium volume production. BRD is also important in process development for reactive distillation. The essence of reactive distillation is the integration between reaction and distillation. There are two limiting cases for integration between reaction and distillation, (1) no integration and (2) full integration. In this thesis, we have shown that by analyzing these two limiting cases, and combining the information obtained from two limiting cases in a novel way, we can develop a partial integrated design with an appropriate amount of integration and an appropriate operation mode, which can provide advantages over both conventional design without integration and a fully integrated design. We apply this approach in two realistic examples, i.e. (1) isopropyl acetate synthesis and (2) 1, 1-dimethoxyethane production. For the isopropyl acetate synthesis, we compare the vapor-liquid and liquid-liquid features of the phase equilibrium to nbutyl acetate and amyl acetate systems, and show the similarities and differences among them. In particular, we show why the isopropyl system is more difficult than the others and how to use the known information in two limiting cases to develop a semi-batch reactive distillation (SBRD) with partial integration, which overcomes the reactive azeotrope brought by full integration and results in a more efficient process for the production of isopropyl acetate than has been previously known. In SBRD, the loss of isopropanol can be substantially decreased, the purity of water can be improved, and the total refluxing or recycling of organic distillate can be avoided. The resulting SBRD can provide 20% higher production efficiency than BRD. For the example of 1, 1-dimethoxyethane (DMA) synthesis, following the approach, we develop a partially integrated BRD, which can take advantage of integration to overcome the reaction equilibrium limitation, meanwhile avoid a distillation boundary brought by over-integration. This leads to a high-purity product, which is unattainable in a fully integrated reactive distillation process without special and expensive treatment of the methanol/DMA azeotrope. In this thesis, we also address selectivity issues in BRD, and provide new results describing the impact of key operating parameters: the reflux or reboil ratio and the Damköhler number (Da). We show that selectivity improvements in BRD are limited for high values of Da or for high values of the reflux or reboil ratio and that selectivity is enhanced as Da or reflux or reboil ratio is decreased. However, decreasing Da will cause conversion loss, which can be mitigated by increasing reflux ratio (or reboil ratio) at expense of selectivity. Consequently, there is an optimum value of reflux or reboil ratio that gives a maximum yield for systems operated at low or moderate Da. We show sample results for a system of serial isomerization reactions and for the synthesis of ethylene glycol. For the isomerization, we show that for BRD with a constant heating rate, the additional heat released by reaction can improve selectivity at expense of conversion. For ethylene glycol synthesis, we show that at a low reboil ratio, integration between reaction and distillation has a negative impact on both conversion and selectivity by causing separation of the reactants. We also show that decreasing the reboil ratio near the end of the BRD can increase the removal rate of ethylene glycol and thereby improve selectivity. This operating strategy is different from the common practice in distillation of increasing the reboil ratio near the end of a batch or cut.
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Book chapters on the topic "Batch reactive distillation"

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"BATCH REACTIVE DISTILLATION (BREAD)." In Batch Distillation, 270–301. PUBLISHED BY IMPERIAL COLLEGE PRESS AND DISTRIBUTED BY WORLD SCIENTIFIC PUBLISHING CO., 2004. http://dx.doi.org/10.1142/9781860945465_0009.

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Biller, Nicholas C. T., and Eva Sørensen. "Controllability of Reactive Batch Distillation Columns." In European Symposium on Computer Aided Process Engineering-12, 35th European Symposium of the Working Party on Computer Aided Process Engineering, 445–50. Elsevier, 2002. http://dx.doi.org/10.1016/s1570-7946(02)80102-x.

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Steger, Csaba, Endre Rev, Zsolt Fonyo, Michel Meyer, and Zoltan Lelkes. "Feasibility study of batch reactive distillation in hybrid columns." In 16th European Symposium on Computer Aided Process Engineering and 9th International Symposium on Process Systems Engineering, 1063–68. Elsevier, 2006. http://dx.doi.org/10.1016/s1570-7946(06)80187-2.

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Rodriguez-Robles, C. F., S. Hernandez-Castro, H. Hernandez-Escoto, J. Cabrera-Ruiz, F. O. Barroso-Muñoz, and J. E. Terrazas-Rodriguez. "Control analysis of batch reactive distillation column with intermittent fed." In Computer Aided Chemical Engineering, 1357–62. Elsevier, 2019. http://dx.doi.org/10.1016/b978-0-12-818634-3.50227-7.

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Elgue, S., L. Prat, M. Cabassud, J. M. Le Lann, and J. Cézerac. "Optimisation of a Methyl Acetate Production Process by Reactive Batch Distillation." In European Symposium on Computer Aided Process Engineering-12, 35th European Symposium of the Working Party on Computer Aided Process Engineering, 475–80. Elsevier, 2002. http://dx.doi.org/10.1016/s1570-7946(02)80107-9.

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Modla, Gabor. "Feasibility of reactive pressure swing batch distillation in a double column configuration." In Computer Aided Chemical Engineering, 251–55. Elsevier, 2011. http://dx.doi.org/10.1016/b978-0-444-53711-9.50051-1.

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Säynätjoki, P., and L. Hammarström. "IDENTIFICATION OF A PILOT PLANT REACTIVE DISTILLATION PROCESS USING RBF NETWORKS." In Dynamics and Control of Chemical Reactors, Distillation Columns and Batch Processes (Dycord'95), 105–10. Elsevier, 1995. http://dx.doi.org/10.1016/b978-0-08-042368-5.50022-8.

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Kumar, Aditya, and Prodromos Daoutidis. "A DAE FRAMEWORK FOR MODELING AND CONTROL OF REACTIVE DISTILLATION COLUMNS." In Dynamics and Control of Chemical Reactors, Distillation Columns and Batch Processes (Dycord'95), 99–104. Elsevier, 1995. http://dx.doi.org/10.1016/b978-0-08-042368-5.50021-6.

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Mujtabaa, I. M., M. A. Greaves, and M. A. Hussain. "A quick efficient neural network based business decision making tool in batch reactive distillation." In Computer Aided Chemical Engineering, 286–91. Elsevier, 2003. http://dx.doi.org/10.1016/s1570-7946(03)80558-8.

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Marquez-Ruiz, Alejandro, J. H. A. Ludlage, and Leyla Özkan. "Optimization and Low-Level Control Design for Reactive Batch Distillation Columns including the Start-up." In 13th International Symposium on Process Systems Engineering (PSE 2018), 577–82. Elsevier, 2018. http://dx.doi.org/10.1016/b978-0-444-64241-7.50091-4.

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Conference papers on the topic "Batch reactive distillation"

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Konakom, Kwantip, Aritsara Saengchan, Paisan Kittisupakorn, Iqbal M. Mujtaba, and Sio-Iong Ao. "USE OF A BATCH REACTIVE DISTILLATION WITH DYNAMIC OPTIMIZATION STRATEGY TO ACHIEVE INDUSTRIAL GRADE ETHYL ACETATE." In IAENG TRANSACTIONS ON ENGINEERING TECHNOLOGIES VOLUME 6 - SPECIAL EDITION OF THE WORLD CONGRESS ON ENGINEERING AND COMPUTER SCIENCE 2010. AIP, 2011. http://dx.doi.org/10.1063/1.3627211.

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SILVA, G. A., J. C. TEIXEIRA, L. STRAGEVITCH, and J. M. F. SILVA. "MOVING BOUNDARY IN NON-EQUILIBRIUM SIMPLE BATCH REACTIVE DISTILLATION IN A NON-IDEAL MIXTURE ISOBUTENE/METHANOL/MTBE." In XXII Congresso Brasileiro de Engenharia Química. São Paulo: Editora Blucher, 2018. http://dx.doi.org/10.5151/cobeq2018-pt.0693.

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