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Journal articles on the topic 'Batteries Zn-ion'

Author: Grafiati

Published: 25 May 2024

Last updated: 31 July 2025

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1

Mackereth, Matthew, Rong Kou, and Sohail Anwar. "Zinc-Ion Battery Research and Development: A Brief Overview." European Journal of Engineering and Technology Research 8, no. 5 (2023): 70–73. http://dx.doi.org/10.24018/ejeng.2023.8.5.2983.

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With the advancement in the technology of lithium-ion batteries, the popularity and awareness of rechargeable, durable, long-lasting, and lightweight ion batteries have been in the public eye for a while now. Lithium-ion (Li-ion) is not the only type of ion battery out there. Zinc-ion (Zn-ion) batteries are a heavier, but safer, cheaper, and environmentally friendly form of this battery technology that has uses when portability is not the primary objective. One such use case is large format energy storage for intermittent renewable energy such as solar and wind fields for when the sun is no lo

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2

Ruan, Hulong, Zeyuan Li, Qixing Jia, Junjun Wang, and Lina Chen. "Nanomaterials for Zinc Batteries—Aerogels." Nanomaterials 15, no. 3 (2025): 194. https://doi.org/10.3390/nano15030194.

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Aqueous zinc batteries, mainly including Zn-ion batteries (ZIBs) and Zn–air batteries (ZABs), are promising energy storage systems, but challenges exist at their current stage. For instance, the zinc anode in aqueous electrolyte is impacted by anodic dendrites, hydrogen and oxygen precipitation, and some other harmful side reactions, which severely affect the battery’s lifespan. As for traditional cathode materials in ZIBs, low electrical conductivity, slow Zn2+ ion migration, and easy collapse of the crystal structure during ion embedding and migration bring challenges. Also, the slower criti

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3

Ma, Qianyi, and Aiping Yu. "2D Materials for Zn-Ion Batteries and Na-Ion Batteries." ECS Meeting Abstracts MA2025-01, no. 15 (2025): 1118. https://doi.org/10.1149/ma2025-01151118mtgabs.

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To tackle the environmental challenges, renewable energy storage, including batteries and supercapacitors, has garnered great attention over the past decade. My group has been focused on producing and modifying graphene, MXene, and other nanomaterials for Na-ion and Zn-ion batteries. Our strategy for nanomaterials control includes but is not limited to novel production methods, morphology control, chemical functionalization/doping, and composite structure. The new structured materials have been proven to dramatically enhance the relevant batteries' performance.

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4

Islam, Shakirul M., Ryan J. Malone, Wenlong Yang, et al. "Nanographene Cathode Materials for Nonaqueous Zn-Ion Batteries." Journal of The Electrochemical Society 169, no. 11 (2022): 110517. http://dx.doi.org/10.1149/1945-7111/ac9f72.

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Robust multivalent ion interaction in electrodes is a grand challenge of next-generation battery research. In this manuscript, we design molecularly-precise nanographene cathodes that are coupled with metallic Zn anodes to create a new class of Zn-ion batteries. Our results indicate that while electrodes with graphite or flat nanographenes do not support Zn-ion intercalation, the larger intermolecular spacing in a twisted peropyrene enables peropyrene electrodes to facilitate reversible Zn-ion intercalation in an acetonitrile electrolyte. While most previous Zn-ion batteries utilize aqueous el

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Wang, Xuyang, Alina V. Kirianova, Xieyu Xu, Yanguang Liu, Olesya O. Kapitanova, and Marat O. Gallyamov. "Novel electrolyte additive of graphene oxide for prolonging the lifespan of zinc-ion batteries." Nanotechnology 33, no. 12 (2021): 125401. http://dx.doi.org/10.1088/1361-6528/ac40bf.

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Abstract Aqueous zinc-ion batteries have attracted the attention of the industry due to their low cost, good environmental friendliness, and competitive gravimetric energy density. However, zinc anodes, similar to lithium, sodium and other alkali metal anodes, are also plagued by dendrite problems. Zinc dendrites can penetrate through polymer membranes, and even glass fiber membranes which seriously hinders the development and application of aqueous zinc-ion batteries. To resolve this issue, certain additives are required. Here we have synthesized an electrochemical graphene oxide with novel e

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Lim, Hana, Jiwoo Oh, and Myung Jun Kim. "Improving Zn Anode Stability in Zn Ion Battery by Controlling Electrochemical Zn Growth with Organic Additives." ECS Meeting Abstracts MA2024-02, no. 23 (2024): 1968. https://doi.org/10.1149/ma2024-02231968mtgabs.

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Lithium-ion batteries (LIBs) are indispensable for storing electrical energy in portable electronics and electric vehicles, thanks to their high energy density, light weight, and excellent reversibility and cyclability. Despite their successful integration into various electronic devices, their application in Energy Storage Systems (ESS) with substantial capacities is hindered by safety concerns. This is because increasing the energy storage capacity inevitably leads to a higher volume of flammable organic solvents. Therefore, significant research efforts have been directed towards aqueous bat

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7

Li, Hui, Changmiao Huang, Zixuan Teng, et al. "An Ionic Liquid Supramolecular Gel Electrolyte with Unique Wide Operating Temperature Range Properties for Zinc-Ion Batteries." Polymers 16, no. 12 (2024): 1680. http://dx.doi.org/10.3390/polym16121680.

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Zinc-ion batteries are promising candidates for large-scale energy storage. The side reactions of the hydrogen evolution reaction (HER) and zinc dendrite growth are major challenges for developing high-performance zinc-ion batteries. In this paper, a supramolecular gel electrolyte (BLO-ILZE) was self-assembled in an ionic liquid (EMIMBF4) with zinc tetrafluoroborate (Zn(BF4)2) on the separator in situ to obtain a gel electrolyte used in zinc-ion batteries. BLO-ILZE is demonstrated to significantly enhance conductivity over a broad temperature range between −70 and 100 °C. Interestingly, throug

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8

Song, Ming, Hua Tan, Dongliang Chao, and Hong Jin Fan. "Recent Advances in Zn-Ion Batteries." Advanced Functional Materials 28, no. 41 (2018): 1802564. http://dx.doi.org/10.1002/adfm.201802564.

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9

Al‐Abbasi, Malek, Yanrui Zhao, Honggang He, et al. "Challenges and protective strategies on zinc anode toward practical aqueous zinc‐ion batteries." Carbon Neutralization 3, no. 1 (2024): 108–41. http://dx.doi.org/10.1002/cnl2.109.

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AbstractOver the past decades, there has been a growing interest in rechargeable aqueous Zn‐ion batteries (AZIBs) as a viable substitute for lithium‐ion batteries. This is primarily due to their low cost, lower redox potential, and high safety. Nevertheless, the progress of Zn metal anodes has been impeded by various challenges, including the growth of dendrites, corrosion, and hydrogen evolution reaction during repeated cycles that result in low Coulombic efficiency and a short lifetime. Therefore, we represent recent advances in Zn metal anode protection for constructing high‐performance AZI

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10

Shelni Rofika, Rida Nurul, Mardiyati Mardiyati, and Rahmat Hidayat. "Characteristics of Ni-Zn Rechargeable Batteries with Zn Anode Prepared by Using Nano-Cellulose as its Binder Agent." Materials Science Forum 1028 (April 2021): 105–10. http://dx.doi.org/10.4028/www.scientific.net/msf.1028.105.

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While the operating voltages of Ni-Zn batteries are smaller than Li-ion batteries, Ni-Zn batteries offer some advantages, such as high specific energy and low cost. Ni-Zn batteries use green materials as they use aqueous electrolytes and do not need hazardous organic solvents. Both Ni and Zn are abundant and much less expensive in comparison to lithium. Therefore, Ni-Zn batteries are more suitable as secondary batteries for applications that do not need mobility, such as for storing electricity from solar panels at home or office building. At present, large scale usage of Ni-Zn batteries is hi

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11

Pang, Qiang, Xiangyu Yu, Shijing Zhang, et al. "High-Capacity and Long-Lifespan Aqueous LiV3O8/Zn Battery Using Zn/Li Hybrid Electrolyte." Nanomaterials 11, no. 6 (2021): 1429. http://dx.doi.org/10.3390/nano11061429.

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Aqueous zinc-ion batteries (AZIBs) are promising candidates for large-scale energy storage because of their low cost and high safety. However, their practical applications are impeded by low energy density and short service life. Here, an aqueous Zn2+/Li+ hybrid-ion battery is fabricated using the LiV3O8 nanorods as the cathode, metallic Zn as the anode, and 3 M Zn(OTf)2 + 0.5 M LiOTf aqueous solution as the electrolyte. Compared with the batteries using pure 3 M Zn(OTf)2 electrolyte, the cycle performance of the hybrid-ion battery is significantly improved. After 4000 cycles at 5 A g1, the re

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12

Hoang Huy, Vo Pham, Luong Trung Hieu, and Jaehyun Hur. "Zn Metal Anodes for Zn-Ion Batteries in Mild Aqueous Electrolytes: Challenges and Strategies." Nanomaterials 11, no. 10 (2021): 2746. http://dx.doi.org/10.3390/nano11102746.

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Over the past few years, rechargeable aqueous Zn-ion batteries have garnered significant interest as potential alternatives for lithium-ion batteries because of their low cost, high theoretical capacity, low redox potential, and environmentally friendliness. However, several constraints associated with Zn metal anodes, such as the growth of Zn dendrites, occurrence of side reactions, and hydrogen evolution during repeated stripping/plating processes result in poor cycling life and low Coulombic efficiency, which severely impede further advancements in this technology. Despite recent efforts an

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13

Cho, Beom-Keun, and Seung-Ho Yu. "Enhancing Electrochemical Performance through Anode Modification Strategies in Aqueous Zn Battery System." ECS Meeting Abstracts MA2024-02, no. 9 (2024): 1329. https://doi.org/10.1149/ma2024-0291329mtgabs.

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Commercial Li-ion batteries are widely applied in everyday life and industries, but there are some limitations in terms of low energy density/safety issues and unstable supply of resources. As an alternative to Li-ion batteries, aqueous Zn batteries have gained attention due to the abundance of Zn metal, low reduction potential (– 0.76 V vs. standard hydrogen electrode), and high theoretical capacity (820 mAh g–1) of multivalent Zn2+ ion. However, the growth of Zn dendrites on anode surface and the formation of irreversible surface reaction byproducts poses challenges for ensuring long battery

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14

Memon, Muzammil Hussain, Md Asraful Alam, Qiyuan Xie, et al. "Improved Performances of Zn//MnO2 Batteries with an Electrolyte Containing Co-Additives of Polyethylene Glycol and Lignin Derivatives." Polymers 17, no. 7 (2025): 888. https://doi.org/10.3390/polym17070888.

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Multi-component electrolyte additives may significantly contribute to improving the performance of rechargeable aqueous zinc-ion batteries. Herein, we propose a mixed electrolyte system employing polyethylene glycol 200 (PEG200) and quaternized kraft lignin (QKL) as co-additives in Zn//MnO2 batteries. Reduced corrosion and the suppression of the hydrogen evolution reaction on the zinc electrode were achieved when 0.5 wt.% of PEG200 and 0.2 wt.% of QKL were added to the reference aqueous electrolyte. This optimized electrolyte, 0.5% PEG200 + 0.2% QKL, was conducive to improving Zn reversibility

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15

Park, Sodam, Imanuel Kristanto, Gwan Yeong Jung, et al. "A single-ion conducting covalent organic framework for aqueous rechargeable Zn-ion batteries." Chemical Science 11, no. 43 (2020): 11692–98. http://dx.doi.org/10.1039/d0sc02785e.

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16

Kilic, Aysegul, Burcu Oral, Damla Eroglu, and Ramazan Yildirim. "Text Mining Analysis of Beyond Lithium-Ion Batteries." ECS Meeting Abstracts MA2024-01, no. 1 (2024): 175. http://dx.doi.org/10.1149/ma2024-011175mtgabs.

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Li-ion batteries (LIBs) are the most commonly used energy storage technology in various consumer goods, including electric vehicles. However, several alternatives, so-called beyond-LIBs, are greatly investigated to decrease battery costs using abundant and globally distributed materials with high theoretical capacities. Among the diverse beyond LIB systems, this paper includes the top 6 researched chemistries: univalent (Na- and K-) and multivalent (Zn-) metal-ion, metal-air (Li-air and Zn-air), and Li-S batteries. Naturally, all these six battery chemistries have problems that must be address

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17

Nam, Gyutae, and Meilin Liu. "(Invited) Wastewater Derived Cathode Materials for Aqueous Zn-Batteries." ECS Meeting Abstracts MA2022-02, no. 1 (2022): 32. http://dx.doi.org/10.1149/ma2022-02132mtgabs.

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While lithium-ion batteries (LIBs) have been widely used for portable devices and electric vehicles, it is highly desirable to develop safer and less expensive batteries as alternative to LIBs. In this regard, zinc (Zn) batteries have attracted much attention because of their excellent safety and low cost. However, one of the challenges is to develop cost-effective and highly efficient cathode materials for Zn-ion batteries (ZIBs) based on transition metal oxides. It would be more economical to recycle transition metals in order to reduce the fabrication cost. Co-precipitation method is widely

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18

Wu, Lisha, Ying Zhang, Ping Shang, Yanfeng Dong, and Zhong-Shuai Wu. "Redistributing Zn ion flux by bifunctional graphitic carbon nitride nanosheets for dendrite-free zinc metal anodes." Journal of Materials Chemistry A 9, no. 48 (2021): 27408–14. http://dx.doi.org/10.1039/d1ta08697a.

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19

Wei, Jing, and Aiping Yu. "Controlling Zn Ion Hydration by Interfacial H₂O Content Promotes Long-Life Aqueous Zn-Ion Batteries." ECS Meeting Abstracts MA2025-01, no. 6 (2025): 693. https://doi.org/10.1149/ma2025-016693mtgabs.

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Aqueous Zn-ion batteries (AZIBs) are promising for safe, cost-effective, and high-capacity energy storage but face challenges such as hydrogen evolution reaction (HER), metal corrosion, and dendrite growth during Zn plating/stripping. These issues shorten battery lifespan and limit practicality, especially in pouch cells where gas evolution causes short circuits. HER primarily arises from Zn-coordinated water instability and excess H₂O contact with Zn, so controlling interfacial water content is essential. To address these issues, we developed an H₂O buffer layer containing an anion-rich addit

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20

Mo, Ziyu. "Mechanism and Optimizations of Aqueous Zinc-ion Battery." Highlights in Science, Engineering and Technology 41 (March 30, 2023): 111–16. http://dx.doi.org/10.54097/hset.v41i.6785.

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Nowadays, more and more problems of environmental deterioration make the development of environmentally friendly energy imminent. For the requirements of low cost, high security, and high efficiency, aqueous Zn-ion batteries are a promising trend for research. In this paper, the mechanism of aqueous Zn-ion batteries will be illustrated in three aspects: cathode materials, zinc anode, and electrolytes. Moreover, possible alternatives for each part of the batteries will be comprehensively illustrated in detail. In addition, the challenges such as short capacity, zinc dendrites, and corrosion and

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21

Chen, Qihao, Zhiqiang Luo, and Xudong Zhao. "K-Ion intercalated V₆O₁₃ with advanced high-rate long-cycle performance as cathode for Zn-ion batteries." Journal of Materials Chemistry C 10, no. 2 (2022): 590–97. http://dx.doi.org/10.1039/d1tc04822h.

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Sharma, Mamta, and Rahul Sharma. "Zn-ion batteries: ZnMn2O4 as cathode material." Materials Today: Proceedings 26 (2020): 3378–85. http://dx.doi.org/10.1016/j.matpr.2019.10.152.

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23

Wang, Peng, and Petru Andrei. "(Battery Student Slam 8 Award Winner) A Simple and Fast Method to Assemble Flexible and Stable Quasi-Solid-State Zn Ion Pouch Cell." ECS Meeting Abstracts MA2024-01, no. 5 (2024): 760. http://dx.doi.org/10.1149/ma2024-015760mtgabs.

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Aqueous zinc-ion batteries (AZIBs) have been investigated intensively as effective energy storage devices that are environmentally friendly, safe, and have a lower cost than current Li-ion batteries.[1-5] Being outstandingly safe due to usage of non-organic electrolyte, AZIBs could also be used as power supply for wearable electronics. This also put high standard requirements in terms of flexibility, stability and electrochemical performance to AZIBs. On the other hand, the general challenges, such as the formation of the dendrites on the Zn anodes, hydrogen evolution and side reactions, have

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Yu, Wei, Keiki Takahashi, Liubing Dong, and Hirotomo Nishihara. "Multifunctional Separator for Zn Metal Anode Protection." ECS Meeting Abstracts MA2025-01, no. 6 (2025): 683. https://doi.org/10.1149/ma2025-016683mtgabs.

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Lithium-ion batteries (LIBs) have issues such as the high cost of raw materials due to the use of rare metals such as Li and Co in the electrode and the risk of fire due to the use of organic electrolytes.[1] Zn-ion batteries (ZIBs) based on aqueous electrolytes are inexpensive (~US$2 kg-1) and safe for practical use.[2] In addition, the high theoretical volumetric capacity (5854 mAh cm-3) of Zn metal anodes makes ZIBs suitable for large-scale energy storage systems.[3] However, the use of Zn metal in secondary batteries is hindered by problems such as dendrite growth from the anode to the cat

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Liu, Yu-E., and Xin Wang. "Stabilizing a Zn Anode by an Ionic Amphiphilic Copolymer Electrolyte Additive for Long-Life Aqueous Zn-Ion Batteries." Batteries 9, no. 1 (2022): 25. http://dx.doi.org/10.3390/batteries9010025.

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The rampant growth of zinc dendrites and severe uncontrollable reactions have largely limited the industrialization of aqueous Zn-ion batteries. Electrolyte additive engineering was found to be a facile yet effective strategy in addressing these issues; however, traditional organic small molecule additives raise additional safety and health risks and thus compromise the intrinsic advantage of aqueous batteries. In this study, we report a polyacrylonitrile-co-poly(2-acrylamido-2-methylpropanesulfonic acid) (PAN-co-PAMPS) copolymer with ionic and hydrophilicity PAMPS and non-ionic PAN, which act

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Ma, Qianyi, Anna Chen, and Michael Fowler. "Dual‐Doped Graphene Quantum Dots to Promote Long‐Life Aqueous Zn‐Ion Batteries." ECS Meeting Abstracts MA2025-01, no. 15 (2025): 1119. https://doi.org/10.1149/ma2025-01151119mtgabs.

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As a promising next-generation energy storage device, aqueous Zn-ion batteries (AZIBs) face critical challenges, including Zn dendrite formation and side reactions at the Zn metal anode. While interface modification strategies have improved Zn anode stability, they still fall short of meeting practical application demands. A key limitation lies in the absence of a multifunctional solid electrolyte interphase (SEI) designed to effectively regulate the solvation and desolvation processes of Zn ions at the anode interface. In this study, we report the fabrication of an amphiphilic SEI incorporati

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Sobianowska-Turek, Agnieszka, Katarzyna Grudniewska, Paweł Maciejewski, and Małgorzata Gawlik-Kobylińska. "Removal of Zn(II) and Mn(II) by Ion Flotation from Aqueous Solutions Derived from Zn-C and Zn-Mn(II) Batteries Leaching." Energies 14, no. 5 (2021): 1335. http://dx.doi.org/10.3390/en14051335.

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The Zn(II) and Mn(II) removal by an ion flotation process from model and real dilute aqueous solutions derived from waste batteries was studied in this work. The research aimed to determine optimal conditions for the removal of Zn(II) and Mn(II) from aqueous solutions after acidic leaching of Zn-C and Zn-Mn waste batteries. The ion flotation process was carried out at ambient temperature and atmospheric pressure. Two organic compounds used as collectors were applied, i.e., m-dodecylphosphoric acid 32 and m-tetradecylphosphoric 33 acid in the presence of a non-ionic foaming agent (Triton X-100,

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Wang, Xiaolei. "(Invited) Recycling Zn for Rechargeable Zinc-Ion Batteries." ECS Meeting Abstracts MA2024-01, no. 55 (2024): 2959. http://dx.doi.org/10.1149/ma2024-01552959mtgabs.

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Aqueous energy storage devices require highly reversible Zn electrodes, but this has been impeded by challenges including dendrite growth, low efficiency, hydrogen evolution, and metal corrosion. Here, we have successfully fabricated a reversible Zn powder electrode via engineering the growth of zinc crystals in different solvents from spent Zn foils. Theoretical calculations demonstrate that the adsorption energy gap of different solvents on the (002) or (100) facet of Zn metal varies and that a larger energy gap favors a higher orientation of Zn (002) plane. Highly oriented Zn (002) powder e

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Ni, Gang, Zhao Hao, Guoyin Zou, et al. "Potassium manganese hexacyanoferrate with improved lifespan in Zn(CF₃SO₃)₂ electrolyte for aqueous zinc-ion batteries." Sustainable Energy & Fuels 6, no. 5 (2022): 1353–61. http://dx.doi.org/10.1039/d1se02003j.

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Lu, Jiahui, Tianyi Wang, Jian Yang, et al. "Multifunctional Self‐Assembled Bio‐Interfacial Layers for High‐Performance Zinc Metal Anodes." Angewandte Chemie, July 26, 2024. http://dx.doi.org/10.1002/ange.202409838.

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Rechargeable aqueous zinc‐ion (Zn‐ion) batteries are widely regarded as important candidates for next‐generation energy storage systems for low‐cost renewable energy storage. However, the development of Zn‐ion batteries is currently facing significant challenges due to uncontrollable Zn dendrite growth and severe parasitic reactions on Zn metal anodes. Herein, we report an innovative strategy to improve the performance of aqueous Zn‐ion batteries by leveraging the self‐assembly of bovine serum albumin (BSA) into a bilayer configuration on Zn metal anodes. BSA's hydrophilic and hydrophobic frag

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Lu, Jiahui, Tianyi Wang, Jian Yang, et al. "Multifunctional Self‐Assembled Bio‐Interfacial Layers for High‐Performance Zinc Metal Anodes." Angewandte Chemie International Edition, July 26, 2024. http://dx.doi.org/10.1002/anie.202409838.

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Rechargeable aqueous zinc‐ion (Zn‐ion) batteries are widely regarded as important candidates for next‐generation energy storage systems for low‐cost renewable energy storage. However, the development of Zn‐ion batteries is currently facing significant challenges due to uncontrollable Zn dendrite growth and severe parasitic reactions on Zn metal anodes. Herein, we report an innovative strategy to improve the performance of aqueous Zn‐ion batteries by leveraging the self‐assembly of bovine serum albumin (BSA) into a bilayer configuration on Zn metal anodes. BSA's hydrophilic and hydrophobic frag

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Xu, Huiting, Wenyue Yang, Meng Li, et al. "Advances in Aqueous Zinc Ion Batteries based on Conversion Mechanism: Challenges, Strategies, and Prospects." Small, January 28, 2024. http://dx.doi.org/10.1002/smll.202310972.

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AbstractRecently, aqueous zinc‐ion batteries with conversion mechanisms have received wide attention in energy storage systems on account of excellent specific capacity, high power density, and energy density. Unfortunately, some characteristics of cathode material, zinc anode, and electrolyte still limit the development of aqueous zinc‐ion batteries possessing conversion mechanism. Consequently, this paper provides a detailed summary of the development for numerous aqueous zinc‐based batteries: zinc‐sulfur (Zn‐S) batteries, zinc‐selenium (Zn‐Se) batteries, zinc‐tellurium (Zn‐Te) batteries, zi

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Wang, Gang, Quan Kuang, Pan Jiang, Qinghua Fan, Youzhong Dong, and Yanming Zhao. "Integrating molybdenum into zinc vanadate enable Zn3V2MoO8 as a high-capacity Zn-supplied cathode for Zn-metal free aqueous batteries." Nanoscale, 2023. http://dx.doi.org/10.1039/d3nr00136a.

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The commercialization of aqueous zinc-ion batteries (AZIBs) has been hindered by the obsession of Zn-metal anode, just like the early days of lithium-ion batteries. Developing Zn-metal free aqueous batteries (ZFABs)...

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Kiatwisarnkij, Napat, Zehao Song, Chanin Tangpongkijjaroen, et al. "Texturing (002)‐Oriented Zinc atop a Cotton Cloth for High‐Performance Zn‐ion Batteries." Batteries & Supercaps, January 26, 2025. https://doi.org/10.1002/batt.202400727.

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Zn‐ion batteries emerge as a promising alternative to conventional Li‐ion batteries, owing to their superior environmental friendliness and high safety for sustainable energy storage in various applications. However, there are still concerns about the limitations of Zn‐ion batteries, such as uncontrolled dendrite growth and side reactions. In this study, the electroplating method was employed to deposit (002) plane‐dominated textures on the modified cotton cloth substrate, which comprises a silver conductive layer atop the cotton supporting layer. The electroplating current density and time ar

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Wan, Jiajun, Hongjiang Song, Jiyang Tian, Shengkui Zhong, and Jie Liu. "Recent progress and challenges of high-loading cathodes for aqueous Zn-ion batteries." Energy Materials 5, no. 8 (2025). https://doi.org/10.20517/energymater.2024.301.

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Owing to the advantages of low cost, rich resources, and intrinsic safety, aqueous Zn-ion batteries have attracted broad attention as the promising energy storage technology for large-scale smart grids. The cathodes for aqueous Zn-ion batteries have developed rapidly, including Mn-based cathodes, V-based cathodes, and halogen cathodes. High specific capacity and long cycling lifespan have been achieved. However, when the mass loading for cathode materials is scaled up to the practical level, the cycling stability and rate property of aqueous Zn-ion batteries are very unsatisfactory. Therefore,

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Liang, Hanhao, Jian Wu, Jiaming Li, Jianglin Wang, Zhanhong Yang, and Yuping Wu. "Achieving Dendrite‐Free and By‐Product‐Free Aqueous Zn‐Ion Battery Anode via Nicotinic Acid Electrolyte Additive with Molecule‐Ion Conversion Mechanism." Small, May 19, 2024. http://dx.doi.org/10.1002/smll.202402595.

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AbstractThe widespread adoption of aqueous Zn ion batteries is hindered by the instability of the Zn anode. Herein, an elegant strategy is proposed to enhance the stability of Zn anode by incorporating nicotinic acid (NA), an additive with a unique molecule‐ion conversion mechanism, to optimize the anode/electrolyte interface and the typical ZnSO4 electrolyte system. Experimental characterization and theoretical calculations demonstrate that the NA additive preferentially replaces H2O in the original solvation shell and adsorbs onto the Zn anode surface upon conversion from molecule to ion in

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Zhu, Yunhai, Guojin Liang, Xun Cui, et al. "Engineering hosts for Zn anode in aqueous Zn-ion batteries." Energy & Environmental Science, 2023. http://dx.doi.org/10.1039/d3ee03584k.

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Aqueous zinc-ion batteries (ZIBs) distinguish themselves among the numerous viable alternatives to lithium-ion batteries on account of their potential advantages, which encompass enhanced safety, cost-effectiveness, and eco-friendliness. However, the metal...

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Meng, Linghui, Yanzhe Zhu, Yile Lu, et al. "Rechargeable Zn−MnO₂ Batteries: Progress, Challenges, Rational Design, and Perspectives." ChemElectroChem, December 22, 2023. http://dx.doi.org/10.1002/celc.202300495.

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AbstractAs a new type of secondary ion battery, aqueous zinc‐ion battery has a broad application prospect in the field of large‐scale energy storage due to its characteristics of low cost, high safety, environmental friendliness, and high‐power density. In recent years, manganese dioxide (MnO2)‐based materials have been extensively explored as cathodes for Zn‐ion batteries. Based on the research experiences of our group in the field of aqueous zinc ion batteries and combining with the latest literature of system, we systematically summarize the research progress of Zn−MnO2 batteries. This arti

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Wang, jinguo, fan-gong Kong, zi-rui wang, et al. "Dendrite-Free Zinc Deposition Induced by an Artificial Layer of Strontium Titanate for Stable Zinc Metal Anode." Journal of The Electrochemical Society, June 12, 2023. http://dx.doi.org/10.1149/1945-7111/acdd9e.

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Abstract Rechargeable aqueous zinc ion batteries, featuring high specific capacity, low cost, and high safety, are considered one of the most promising alternatives to lithium-ion batteries for next-generation energy storage systems. Nevertheless, the undesired dendrite formation and serious side reaction of Zn metal anode significantly hinder the usage of Zn-based metal batteries. Here, we propose a nanosized SrTiO3 film as a highly self-adapting protective coating to facilitate fast Zn2+ kinetics and guarantee even ion flux, leading to endow homogeneous Zn deposition under the SrTiO3 layer.

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40

Cui, Jiayao, Yimei Chen, Yan Dong, Hao Zhang, and Douglas G. Ivey. "Sodium Succinate as Functional Electrolyte Additive to Achieve Highly Reversible Zinc-Ion Batteries." Journal of Materials Chemistry A, 2024. http://dx.doi.org/10.1039/d4ta05352d.

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Zn-ion batteries (ZIBs) have gained great traction due to their cost-effectiveness and improved safety when compared with Li-ion batteries (LIBs). However, dendrite formation and side reactions involving Zn corrosion and...

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41

Zhang, Fan, Ting Liao, Dongchen Qi, et al. "Zn-ion ultrafluidity via bioinspired ion channel for ultralong lifespan Zn-ion battery." National Science Review, June 12, 2024. http://dx.doi.org/10.1093/nsr/nwae199.

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Abstract Rechargeable aqueous Zn-ion batteries have been deemed as a promising energy storage device. However, the dendrite growth and side reactions have hindered their practical application. Herein, inspired by the ultrafluidic and K+ ion-sieving flux through enzyme-gated potassium channels (KcsA) in biological plasma membranes, a metal-organic-framework (MOF-5) grafted with –ClO4 groups as functional enzymes is fabricated to mimic the ultrafluidic lipid-bilayer structure for gating Zn2+ ‘on’ and anions ‘off’ states. Resulting from the perfect Zn2+/SO42− selectivity (∼10), enhanced Zn2+ tran

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Lahiri, Abhishek, Pranay Hirani, and Sophia Haghani. "Effect of Protic and Aprotic Formamide‐Based Organic Electrolytes for Rechargeable Zinc/MnO2 Battery." Batteries & Supercaps, April 24, 2024. http://dx.doi.org/10.1002/batt.202400140.

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Zinc ion batteries (ZIBs) are emerging as a promising and cost‐effective alternative energy storage system compared to other metal‐ion batteries. Aqueous electrolytes have been extensively studied in Zn‐ion batteries which has shown issues related to cathode dissolution. In comparison, little has been looked into the use of organic electrolytes in ZIBs. Here, we have studied both protic and aprotic forms of formamide‐based organic electrolytes containing Zn trifluoromethanesulfonate and their influence on the Zn solvation chemistry, electrochemistry, and performance of Zn‐MnO2 battery. It was

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43

Hu, Xueying, Haobo Dong, Nan Gao, et al. "Self-assembled polyelectrolytes with ion-separation accelerating channels for highly stable Zn-ion batteries." Nature Communications 16, no. 1 (2025). https://doi.org/10.1038/s41467-025-57666-0.

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Abstract Aqueous zinc-ion batteries offer a sustainable alternative to lithium-ion batteries due to their abundance, safety, and eco-friendliness. However, challenges like hydrogen evolution and uncontrolled diffusion of H⁺, Zn²⁺, and SO₄²⁻ in the electrolyte lead to the dendrite formation, side reactions, and reduced Coulombic efficiency for Zn nucleation. Here, to simultaneously regulate the diffusion of cations and anions in the electrolyte, an ion-separation accelerating channel is constructed by introducing layer-by-layer self-assembly of a flocculant poly(allylamine hydrochloride) and it

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44

Ying, Hangjun, Pengfei Huang, Zhao Zhang, et al. "Freestanding and Flexible Interfacial Layer Enables Bottom-Up Zn Deposition Toward Dendrite-Free Aqueous Zn-Ion Batteries." Nano-Micro Letters 14, no. 1 (2022). http://dx.doi.org/10.1007/s40820-022-00921-6.

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AbstractAqueous rechargeable zinc ion batteries are regarded as a competitive alternative to lithium-ion batteries because of their distinct advantages of high security, high energy density, low cost, and environmental friendliness. However, deep-seated problems including Zn dendrite and adverse side reactions severely impede the practical application. In this work, we proposed a freestanding Zn-electrolyte interfacial layer composed of multicapsular carbon fibers (MCFs) to regulate the plating/stripping behavior of Zn anodes. The versatile MCFs protective layer can uniformize the electric fie

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Adedoja, Oluwaseye Samson, Emmanuel Rotimi Sadiku, and Yskandar Hamam. "Density functional theory investigation of the energy storage potential of graphene‐polypyrrole nanocomposites as high‐performance electrode for Zn‐ion batteries." Polymer Engineering & Science, August 10, 2023. http://dx.doi.org/10.1002/pen.26454.

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AbstractThe present research explores, through the density functional theory (DFT) calculations, the viability of graphene‐polypyrrole (G/PPy) nanocomposites as an effective material for energy storage in Zn‐ion batteries. To this end, the CASTEP calculator in the Materials Studio software was employed to examine the electronic and structural properties of the nanocomposites and their potential to enhance energy storage capabilities of Zn‐ion batteries. Specifically, the study investigates the interaction of the Zn‐adatom with the nanocomposites, electronic properties, specific capacity, Zn ad

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Ji, Yuyao, Qiang Hu, Jingxin Zhao, Cuiping Han, and Hui-Ming Cheng. "A Dynamically Ion‐Sieved Electrolyte towards Ultralong‐Lifespan Zn‐Ion Batteries." Angewandte Chemie, August 29, 2024. http://dx.doi.org/10.1002/ange.202412853.

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The practical deployment of Zn‐ion batteries faces challenges such as dendrite growth, side reactions and cathode dissolution in traditional electrolytes. Here, we develop a highly conductive and dynamically ion‐sieved electrolyte to simultaneously enhance the Zn metal reversibility and suppress the cathode dissolution. The dynamic ion screen at the electrode/electrolyte interface is achieved by numerous pyrane rings with a radius of 3.69 Å, which can selectively facilitate the plating/stripping and insertion/extraction process of [Zn(H2O)6]2+ and Zn2+ on the anode and cathode surfaces. As a p

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Ji, Yuyao, Qiang Hu, Jingxin Zhao, Cuiping Han, and Hui-Ming Cheng. "A Dynamically Ion‐Sieved Electrolyte towards Ultralong‐Lifespan Zn‐Ion Batteries." Angewandte Chemie International Edition, August 29, 2024. http://dx.doi.org/10.1002/anie.202412853.

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The practical deployment of Zn‐ion batteries faces challenges such as dendrite growth, side reactions and cathode dissolution in traditional electrolytes. Here, we develop a highly conductive and dynamically ion‐sieved electrolyte to simultaneously enhance the Zn metal reversibility and suppress the cathode dissolution. The dynamic ion screen at the electrode/electrolyte interface is achieved by numerous pyrane rings with a radius of 3.69 Å, which can selectively facilitate the plating/stripping and insertion/extraction process of [Zn(H2O)6]2+ and Zn2+ on the anode and cathode surfaces. As a p

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Ma, Guanzhong, Zhengyu Ju, Xin Xu, et al. "Enhancing Organic Cathodes of Aqueous Zinc-Ion Batteries via Utilizing Steric Hindrance and Electron Cloud Equalization." Chemical Science, 2023. http://dx.doi.org/10.1039/d3sc04766k.

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Polyaniline (PANI), with merits of high electronic conductivity and capacity, is a promising material for zinc (Zn)-ion batteries. However, its redox window in Zn batteries is often limited, mainly due...

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Ye, Zhengqing, Ying Jiang, Li Li, Feng Wu, and Renjie Chen. "Rational Design of MOF-Based Materials for Next-Generation Rechargeable Batteries." Nano-Micro Letters 13, no. 1 (2021). http://dx.doi.org/10.1007/s40820-021-00726-z.

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AbstractMetal–organic framework (MOF)-based materials with high porosity, tunable compositions, diverse structures, and versatile functionalities provide great scope for next-generation rechargeable battery applications. Herein, this review summarizes recent advances in pristine MOFs, MOF composites, MOF derivatives, and MOF composite derivatives for high-performance sodium-ion batteries, potassium-ion batteries, Zn-ion batteries, lithium–sulfur batteries, lithium–oxygen batteries, and Zn–air batteries in which the unique roles of MOFs as electrodes, separators, and even electrolyte are highli

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Teng, Xiaowei, Xiaoqiang Shan, SaeWon Kim, Milinda Abeykoon, Gihan Kwon, and Daniel Olds. "Local Structure and Ions Storage Properties of Vanadate Cathode Materials Regulated by the Pre-Alkalization." Journal of Materials Chemistry A, 2022. http://dx.doi.org/10.1039/d2ta04490k.

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Aqueous Zn-ion batteries using mild acidic electrolytes utilizing a Zn2+/H+ dual-ion storage mechanism have shown great potential in achieving high energy density comparable to non-aqueous lithium-ion batteries. This study revealed...

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