Relevant bibliographies by topics / Benzene carboxylate

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Academic literature on the topic 'Benzene carboxylate'

Author: Grafiati
Published: 4 June 2025
Last updated: 1 August 2025

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Journal articles on the topic "Benzene carboxylate"

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Aşkın, Gülçin Şefiye, Fatih Çelik, Nefise Dilek, Hacali Necefoğlu та Tuncer Hökelek. "Crystal structure ofcatena-poly[[aquabis(4-formylbenzoato)-κ2O1,O1′;κO1-zinc]-μ-pyrazine-κ2N:N′]". Acta Crystallographica Section E Crystallographic Communications 71, № 4 (2015): 402–5. http://dx.doi.org/10.1107/s2056989015005472.

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The asymmetric unit of the title polymeric compound, [Zn(C8H5O3)2(C4H4N2)(H2O)]n, contains two molecular units. Each unit comprises two 4-formylbenzoate (FB) anions, one pyrazine molecule and one coordinating water molecule; the FB anions act either as bidentate or as monodentate ligands. The O atoms of the bidentately coordinating FB anions are disordered over two positions, and they were refined with fixed occupancy ratios of 0.75:0.25 and 0.70:0.30, respectively. In the ordered monodentately coordinating FB anions, the carboxylate groups are twisted away from the attached benzene rings (Ban
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2

Fazal, E., Manpreet Kaur, B. S. Sudha, S. Nagarajan, and Jerry P. Jasinski. "4-Chlorophenyl quinoline-2-carboxylate." Acta Crystallographica Section E Structure Reports Online 69, no. 12 (2013): o1841. http://dx.doi.org/10.1107/s1600536813032054.

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In the title compound, C16H10ClNO2, the dihedral angle between the quinoline ring system and the benzene ring is 14.7 (5)°. The carboxylate group is twisted from the mean planes of the quinoline ring system and the benzene ring by 17.7 (5) and 32.1 (4)°, respectively. In the crystal, inversion dimers are formed with the molecules linked by pairs of weak C—H...O interactions arising from an activated aromatic C atom adjacent to the C—Cl bond, generatingR22(14) loops.
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3

Wardell, James L., and Edward R. T. Tiekink. "Crystal structures of the 1:1 salts of 2-amino-4-nitrobenzoate with each of (2-hydroxyethyl)dimethylazanium, tert-butyl(2-hydroxyethyl)azanium and 1,3-dihydroxy-2-(hydroxymethyl)propan-2-aminium." Acta Crystallographica Section E Crystallographic Communications 74, no. 12 (2018): 1735–40. http://dx.doi.org/10.1107/s2056989018015578.

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The crystal and molecular structures of the title molecular salts, C4H12NO+·C7H5N2O4 −, (I), C6H16NO+·C7H5N2O4 −, (II), and C4H12NO3 +·C7H5N2O4 −, (III), are described. The common feature of these salts is the presence of the 2-amino-4-nitrobenzoate anion, which exhibit non-chemically significant variations in the conformational relationships between the carboxylate and nitro groups, and between these and the benzene rings they are connected to. The number of ammonium-N—H H atoms in the cations increases from one to three in (I) to (III), respectively, and this variation significantly influenc
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Zhou, Li-Juan, Chang-Bao Han, and Yu-Ling Wang. "Two-dimensional ZnIIand one-dimensional CoIIcoordination polymers based on benzene-1,4-dicarboxylate and pyridine ligands." Acta Crystallographica Section C Structural Chemistry 72, no. 2 (2016): 133–38. http://dx.doi.org/10.1107/s2053229616000814.

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Coordination polymers constructed from metal ions and organic ligands have attracted considerable attention owing to their diverse structural topologies and potential applications. Ligands containing carboxylate groups are among the most extensively studied because of their versatile coordination modes. Reactions of benzene-1,4-dicarboxylic acid (H2BDC) and pyridine (py) with ZnIIor CoIIyielded two new coordination polymers, namely, poly[(μ4-benzene-1,4-dicarboxylato-κ4O:O′:O′′:O′′′)(pyridine-κN)zinc(II)], [Zn(C8H4O2)(C5H5N)]n, (I), andcatena-poly[aqua(μ3-benzene-1,4-dicarboxylato-κ3O:O′:O′′)b
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Lundvall, Fredrik, Pascal D. C. Dietzel, and Helmer Fjellvåg. "Crystal structure of dimethyl 4,4′-dimethoxybiphenyl-3,3′-dicarboxylate." Acta Crystallographica Section E Crystallographic Communications 72, no. 3 (2016): 328–30. http://dx.doi.org/10.1107/s2056989016002449.

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In the title compound, C18H18O6, the benzene rings are coplanar due to the centrosymmetric nature of the molecule, with an inversion centre located at the midpoint of the C—C bond between the two rings. Consequently, the methyl carboxylate substituents are oriented in atransfashion with regards to the bond between the benzene rings. The methyl carboxylate and methoxy substituents are rotated slightly out of plane relative to their parent benzene rings, with dihedral and torsion angles of 18.52 (8) and −5.22 (15)°, respectively. The shortest O...H contact between neighbouring molecules is about
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Smith, Graham, and Urs D. Wermuth. "Bis(benzylaminium) 4,5-dichlorobenzene-1,2-dicarboxylate monohydrate." Acta Crystallographica Section E Structure Reports Online 68, no. 6 (2012): o1928. http://dx.doi.org/10.1107/s1600536812023458.

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In the structure of the title salt, 2C7H10N+·C8H2Cl2O4 2−·H2O, the two benzylaminium anions have different conformations, one being essentially planar and the other having the side chain rotated out of the benzene plane [minimum ring to side-chain C—C—C—N torsion angles = −3.6 (6) and 50.1 (5)°, respectively]. In the 4,5-dichlorophthalate dianion, the carboxylate groups make dihedral angles of 23.0 (2) and 76.5 (2)° with the benzene ring. In the crystal, aminium N—H...O and water O—H...O hydrogen-bonding associations with carboxylate O-atom acceptors give a two-dimensional duplex sheet structu
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Zhong, Kai-Long. "A novel three-dimensional ZnIIcoordination polymer with 1,3,5-tris(imidazol-1-ylmethyl)benzene and cyclohexane-1,3,5-tricarboxylate ligands." Acta Crystallographica Section C Structural Chemistry 70, no. 2 (2014): 189–93. http://dx.doi.org/10.1107/s2053229613034347.

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In the ZnIIcompound poly[[bis(μ3-cyclohexane-1,3,5-tricarboxylato)bis[μ3-1,3,5-tris(imidazol-1-ylmethyl)benzene]trizinc(II)] hexahydrate], {[Zn3(C18H18N6)2(C9H9O6)2]·6H2O}n, based on mixed 1,3,5-tris(imidazol-1-ylmethyl)benzene and cyclohexane-1,3,5-tricarboxylate ligands, there are two types of crystallographically independent ZnIIcentres, one in a general position and one on a crystallographic twofold axis. They have similar fourfold distorted tetrahedral coordination geometries, ligated by two monodentate carboxylate groups from two cyclohexane-1,3,5-tricarboxylate ligands and by two N atom
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Öncüoğlu, Serkan, Nefise Dilek, Nagihan Çaylak Delibaş, Yavuz Ergün, and Tuncer Hökelek. "Ethyl 4,9-dimethyl-9H-carbazole-3-carboxylate." Acta Crystallographica Section E Structure Reports Online 70, no. 3 (2014): o240. http://dx.doi.org/10.1107/s1600536814002098.

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In the title compound, C17H17NO2, the carbazole skeleton includes an ethoxycarbonyl group at the 3-position. The indole three-ring system is almost planar [maximum deviation = 0.065 (2) Å], and the ethyl ester group is inclined to its mean plane by 15.48 (2)°. In the crystal, there are π–π stacking interactions between parallel benzene rings and between parallel benzene and pyrrole rings of adjacent molecules [centroid–centroid distances = 3.9473 (8) and 3.7758 (8) Å, respectively]. Weak C—H...π interactions are also present.
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9

Yin, Dejing. "Synthesis and crystal structure of tert-butyl 1-(2-iodobenzoyl)cyclopent-3-ene-1-carboxylate." Acta Crystallographica Section E Crystallographic Communications 75, no. 9 (2019): 1383–85. http://dx.doi.org/10.1107/s2056989019011514.

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1-(2-Iodobenzoyl)-cyclopent-3-ene-1-carboxylates are novel substrates to construct bicyclo[3.2.1]octanes with antibacterial and antithrombotic activities. In this context, tert-butyl 1-(2-iodobenzoyl)-cyclopent-3-ene-1-carboxylate, C17H19IO3, was synthesized and structurally characterized. The 2-iodobenzoyl group is attached to the tertiary C atom of the cyclopent-3-ene ring. The dihedral angle between the benzene ring and the mean plane of the envelope-type cyclopent-3-ene ring is 26.0 (3)°. In the crystal, pairs of C-H...O hydrogen bonds link the molecules to form inversion dimers.
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Fun, Hoong-Kun, Safra Izuani Jama Asik, B. Garudachari, Arun M. Isloor, and M. N. Satyanarayan. "2-(4-Bromophenyl)-2-oxoethyl anthracene-9-carboxylate." Acta Crystallographica Section E Structure Reports Online 68, no. 6 (2012): o1876. http://dx.doi.org/10.1107/s1600536812022684.

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In the title compound, C23H15BrO3, the anthracene ring system is essentially planar [maximum deviation = 0.29 (2) Å] and makes a dihedral angle of 5.74 (8)° with the mean plane of the bromo-substituted benzene ring. An intramolecular C—H...O hydrogen bond generates an S(9) ring motif. In the crystal, molecules are linked by C—H...O interactions, forming a two-dimensional network parallel to the ac plane. π–π stacking interactions are observed between benzene rings [centroid–centroid distances = 3.5949 (14) and 3.5960 (13) Å].
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Dissertations / Theses on the topic "Benzene carboxylate"

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Crapatureanu, Sanda Melania. "Modification of human hemoglobin with dibromosalicyl esters of benzene di, tri, and tetra carboxylates." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape10/PQDD_0003/MQ40731.pdf.

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Kauffman, Erin. "Modification of human hemoglobin with dibromosalicyl esters of benzene di, tri, and tetra carboxylates." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1996. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/MQ51532.pdf.

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HADDAD-FAHED, OMAIMA. "Catalyse micellaire de reactions de substitution nucleophile aromatique comportant des reactifs electriquement charges." Paris 6, 1987. http://www.theses.fr/1987PA066419.

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Sen, Mustafa Yasin. "SYNTHESIS OF MIDDLE-CHAIN CARBOXYL- AND PRIMARY AMINE-FUNCTIONALIZED POLYSTYRENES USING ANIONIC POLYMERIZATION TECHNIQUES." University of Akron / OhioLINK, 2005. http://rave.ohiolink.edu/etdc/view?acc_num=akron1132533104.

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Mahata, Partha. "Synthesis, Structure, Magnetic, Luminescent and Photocatalytic Studies on Metal-Organic Framework (MOF) Compounds." Thesis, 2009. http://etd.iisc.ac.in/handle/2005/3894.

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The research in the area of metal-organic frameworks (MOFs) continues to be interesting for their unique structures and tunable properties. In this thesis, the various aspects of metal-organic frameworks (MOFs) compounds are presented. As part of this study, preparation of MOFs of transition metals (Mn, Co, Ni, Zn), rare-earth metals (Y, La, Pr, Nd, Gd, Dy) and mixed metals (3d-4f) using aromatic carboxylates as linker ligands were accomplished. Structures of the synthesized compounds have been determined by single crystal X-ray diffraction technique. Magnetic properties of the transition m
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Mahata, Partha. "Synthesis, Structure, Magnetic, Luminescent and Photocatalytic Studies on Metal-Organic Framework (MOF) Compounds." Thesis, 2009. http://etd.iisc.ernet.in/2005/3894.

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The research in the area of metal-organic frameworks (MOFs) continues to be interesting for their unique structures and tunable properties. In this thesis, the various aspects of metal-organic frameworks (MOFs) compounds are presented. As part of this study, preparation of MOFs of transition metals (Mn, Co, Ni, Zn), rare-earth metals (Y, La, Pr, Nd, Gd, Dy) and mixed metals (3d-4f) using aromatic carboxylates as linker ligands were accomplished. Structures of the synthesized compounds have been determined by single crystal X-ray diffraction technique. Magnetic properties of the transition m
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Books on the topic "Benzene carboxylate"

1

Kauffman, Erin. Modification of human hemoglobin with dibromosalicyl esters of benzene di, tri, and tetra carboxylates. National Library of Canada, 1996.

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Book chapters on the topic "Benzene carboxylate"

1

Keeler, James, and Peter Wothers. "Bonding in extended systems – conjugation." In Why chemical reactions happen. Oxford University Press, 2003. http://dx.doi.org/10.1093/hesc/9780199249732.003.0010.

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This chapter discusses bonding in extended systems and relates this to conjugation. It uses the reaction of benzene bonding with all of the carbons as a reference. The chapter also refers to the structure of butadiene and propenal as examples showing the case of four p orbitals in a row. Amides, allyl anion and carboxylate anion are used to show cases where three p orbitals are in a row. In addition, the chapter discusses the chemical consequences of carbonyl compound reactions. It concludes by examining the stabilization of negative charges following the conjugation of bonds.
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Taber, Douglass F. "Preparation of Substituted Benzenes: The Beaudry Synthesis of Arundamine." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0064.

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Stephen G. DiMagno of the University of Nebraska developed (Chem. Eur. J. 2015, 21, 6394) a protocol for the clean monoiodination of 1 to 2. The bromomethylation (or chloromethylation, with HCl) of a benzene derivative is straightforward with formal­dehyde and HBr. Naofumi Tsukada of Shizuoka University designed (Organometallics 2015, 34, 1191) a Cu catalyst that mediated the coupling of an alkyne with the benzyl bromide so produced, effecting net propargylation of 3 with 4 to give 5. Triazenes such as 7, versatile intermediates for organic synthesis, are usually prepared by diazotization of t
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Taber, Douglass F. "Substituted Benzenes: The Subba Reddy Synthesis of 7-Desmethoxyfusarentin." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0064.

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Andrey P. A ntonchick of the Max-Planck-Institut Dortmund devised (Org. Lett. 2012, 14, 5518) a protocol for the direct amination of an arene 1 to give the amide 3. Douglass A. Klumpp of Northern University showed (Tetrahedron Lett. 2012, 53, 4779) that under strong acid conditions, an arene 4 could be carboxylated to give the amide 6. Eiji Tayama of Niigata University coupled (Tetrahedron Lett. 2012, 53, 5159) an arene 7 with the α-diazo ester 8 to give 9. Guy C. Lloyd-Jones and Christopher A. Russell of the University of Bristol activated (Science 2012, 337, 1644) the aryl silane 11 to give
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Taber, Douglass. "Preparation of Benzene Derivatives: The Barrett Syntheses of Dehydroaltenuene B and 15G256β." In Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.003.0064.

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Several new methods for the direct functionalization of Ar-H have appeared. Hisao Yoshida of Nagoya University observed (Chem. Comm. 2008, 4634) that under irradiation, TiO2 in water effected meta hydroxylation of benzonitrile 1 to give the phenol 2. Anisole showed ortho selectivity, while halo and alkyl aromatics gave mixtures. Melanie S. Sanford of the University of Michigan reported (J. Am. Chem. Soc. 2008, 130, 13285) a complementary study of Pd-catalyzed ortho acetoxylation. Jin-Quan Yu of Scripps/La Jolla developed (Angew. Chem. Int. Ed. 2008, 47, 5215) a Pd-catalyzed protocol for ortho
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Taber, Douglass F. "Developments in Flow Chemistry." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0017.

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Klavs S. Jensen of MIT showed (Angew. Chem. Int. Ed. 2014, 53, 470) that “batch” kinetics could be developed in flow by online IR analysis and continuous control. Professor Jensen also demonstrated (Org. Process Res. Dev. 2014, 18, 402) the contin­uous flow production of an active pharmaceutical product, the direct renin inhibitor aliskiren, over two steps and two crystallizations, starting from two advanced interme­diates. Michael Werner and Rainer E. Martin of Hoffmann-La Roche AG Basel com­bined (Angew. Chem. Int. Ed. 2014, 53, 1704) flow synthesis with a flow-based bioassay to develop stru
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