Relevant bibliographies by topics / Benzodioxane

Contents

  1. Journal articles
  2. Dissertations / Theses
  3. Book chapters
  4. Conference papers

Academic literature on the topic 'Benzodioxane'

Author: Grafiati
Published: 4 June 2021
Last updated: 1 February 2022

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Journal articles on the topic "Benzodioxane"

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Aitmambetov, A., G. Berdimbetova, and V. P. Khilya. "Synthetic analogs of natural flavolignans VIII. Synthesis of 6-chloro-1,3-benzodioxane, 1,4-benzodioxane, 1,5-benzodioxepane, and 1,6-benzodioxocane analogs of 4-thioflavone." Chemistry of Natural Compounds 33, no. 3 (May 1997): 286–88. http://dx.doi.org/10.1007/bf02234875.

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Corsano, Stefano, Giovannella Strappaghetti, and Antonella Codagnone. "Synthesis and Antihypertensive Properties of Benzodioxane-pyridazinones and Benzodioxane-dihydropyridazinones Synthese und antihypertensive Eigenschaften von Benzodioxan-pyridazinonen und Benzodioxan-dihydropyridazinonen." Archiv der Pharmazie 322, no. 11 (1989): 833–35. http://dx.doi.org/10.1002/ardp.19893221113.

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Sokolovskii, A. V., Yu B. Zelechonok, V. V. Zorin, S. S. Zlotskii, and D. L. Rakhmankulov. "Homolytic alkylation of 2-methylquinoline by benzodioxolane and benzodioxane." Chemistry of Heterocyclic Compounds 22, no. 4 (April 1986): 467–68. http://dx.doi.org/10.1007/bf00542797.

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Varadaraju, Kavitha Raj, Jajur Ramanna Kumar, Lingappa Mallesha, Archana Muruli, Kikkeri Narasimha Shetty Mohana, Chethan Kumar Mukunda, and Umesha Sharanaiah. "Virtual Screening and Biological Evaluation of Piperazine Derivatives as Human Acetylcholinesterase Inhibitors." International Journal of Alzheimer's Disease 2013 (2013): 1–13. http://dx.doi.org/10.1155/2013/653962.

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The piperazine derivatives have been shown to inhibit human acetylcholinesterase. Virtual screening by molecular docking of piperazine derivatives 1-(1,4-benzodioxane-2-carbonyl) piperazine (K), 4-(4-methyl)-benzenesulfonyl-1-(1,4-benzodioxane-2-carbonyl) piperazine (S1), and 4-(4-chloro)-benzenesulfonyl-1-(1,4-benzodioxane-2-carbonyl) piperazine (S3) has been shown to bind at peripheral anionic site and catalytic sites, whereas 4-benzenesulfonyl-1-(1,4-benzodioxane-2-carbonyl) piperazine (S4) and 4-(2,5-dichloro)-benzenesulfonyl-1-(1,4-benzodioxane-2-carbonyl) piperazine (S7) do not bind either to peripheral anionic site or catalytic site with hydrogen bond. All the derivatives have differed in number of H-bonds and hydrophobic interactions. The peripheral anionic site interacting molecules have proven to be potential therapeutics in inhibiting amyloid peptides aggregation in Alzheimer’s disease. All the piperazine derivatives follow Lipinski’s rule of five. Among all the derivatives 1-(1,4-benzodioxane-2-carbonyl) piperazine (K) was found to have the lowest TPSA value.
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Daukshas, V. K., P. G. Gaidyalis, A. B. Brukshtus, Yu Yu Ramanauskas, L. K. Labanauskas, G. A. Gasperavichene, I. Yu Yautakene, V. V. Lapinskas, and N. A. Lauzhikene. "Synthesis and pharmacological activity of 1,3-benzodioxolane and 1,3-benzodioxane derivatives." Pharmaceutical Chemistry Journal 23, no. 8 (August 1989): 660–64. http://dx.doi.org/10.1007/bf00766383.

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Mori, Sachio, and Shozo Takechi. "Synthesis of Benzodioxane Prostacyclin Analogue." HETEROCYCLES 31, no. 7 (1990): 1189. http://dx.doi.org/10.3987/com-90-5370.

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Hirata, Makoto, and Eiji Taniguchi. "Synthesis of (+)-(2S, 3S)-Benzodioxane." Journal of the Faculty of Agriculture, Kyushu University 42, no. 1/2 (December 1997): 101–12. http://dx.doi.org/10.5109/24197.

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Aitmambetov, A., and V. P. Khilya. "Synthetic and modified isoflavonoids. IX. Synthesis of benzodioxolane and benzodioxane analogs of 3-arylcoumarins." Chemistry of Natural Compounds 30, no. 2 (March 1994): 211–13. http://dx.doi.org/10.1007/bf00630008.

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Jeyamogan, Shareni, Naveed Ahmed Khan, Ayaz Anwar, Muhammad Raza Shah, and Ruqaiyyah Siddiqui. "Cytotoxic effects of Benzodioxane, Naphthalene diimide, Porphyrin and Acetamol derivatives on HeLa cells." SAGE Open Medicine 6 (January 1, 2018): 205031211878196. http://dx.doi.org/10.1177/2050312118781962.

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Objectives: To synthesize novel compounds belonging to Benzodioxane, Naphthalene diimide, Aminophenol derivatives and Porphyrin classes and test their potential anticancer properties. Methods: Several compounds were synthesized and their molecular identity was confirmed using nuclear magnetic resonance. Potential anticancer properties were determined using cytopathogenicity assays and growth inhibition assays using cervical cancer cells (HeLa). Cells were incubated with different concentrations of compounds belonging to Benzodioxane, Naphthalene diimide, Aminophenol derivatives and Porphyrins and effects were determined. HeLa cells cytopathogenicity was determined by measuring lactate dehydrogenase release using cytotoxicity detection assay. Growth inhibition assays were performed by incubating 50% semi-confluent HeLa cells with Benzodioxane, Naphthalene diimide, Aminophenol derivatives and Porphyrin compounds and HeLa cell proliferation was observed. Growth inhibition and host cell death were compared in the presence and absence of drugs. Results: Cytopathogenicity assays showed that the selected compounds were cytotoxic against HeLa cells, killing up to 90% of cells. Growth inhibition assays exhibited 100% growth inhibition. These effects are likely via oxidative stress, production of reactive oxygen species, changes in cytosolic and intracellular calcium/adenine nucleotide homeostasis, inhibition of ribonucleotide reductase/cyclooxygenase and/or glutathione depletion. Conclusions: Benzodioxane, Naphthalene diimide, Aminophenol derivatives and Porphyrins exhibited potent anticancer properties. These findings are promising and should pave the way in the rationale development of anticancer drugs. Using different cancer cell lines, future studies will determine their potential as anti-tumour agents as well as their precise molecular mode of action.
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Ferenczi, Renáta Kertiné, Tünde-Zita Illyés, Sándor Balázs Király, Gyula Hoffka, László Szilágyi, Attila Mándi, Sándor Antus, and Tibor Kurtán. "Evaluation of Different Synthetic Routes to (2R,3R)-3-Hydroxymethyl-2-(4-hydroxy- 3-methoxyphenyl)-1,4-Benzodioxane-6-Carbaldehyde." Current Organic Chemistry 23, no. 26 (January 1, 2020): 2960–68. http://dx.doi.org/10.2174/1385272823666191212113407.

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The reported enantioselective synthesis for the preparation of (+)-(2R,3R)-2-(4- hydroxy-3-methoxyphenyl)-3-hydroxymethyl-1,4-benzodioxane-6-carbaldehyde, precursor for the stereoselective synthesis of bioactive flavanolignans, could not be reproduced. Thus, the target molecule was prepared via the synthesis and separation of diastereomeric O-glucosides. TDDFT-ECD calculations and the 1,4-benzodioxane helicity rule were utilized to determine the absolute configuration. ECD calculations also confirmed that the 1Lb Cotton effect is governed by the helicity of the heteroring, while the higher-energy ECD transitions reflect mainly the orientation of the equatorial C-2 aryl group.
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Dissertations / Theses on the topic "Benzodioxane"

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Li, Kaichang. "Synthesis of lignin-carbohydrate model compounds and neolignans." Diss., This resource online, 1996. http://scholar.lib.vt.edu/theses/available/etd-06062008-152716/.

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Alliot, Julien. "Synthèse de composés anorexigènes, antidépresseurs et anticancéreux." Thesis, Paris 11, 2013. http://www.theses.fr/2013PA112218/document.

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Au cours de ce travail, nous nous sommes intéressés à la synthèse de composés biologiquement actifs. Dans un premier temps, nous avons étudié la déshydratation des macrocarpals A et B en vue d’obtenir un accès semi-synthétique rapide au macrocarpal G qui possède des propriétés anorexigèniques.Dans un second temps, nous avons développé une nouvelle synthèse énantiosélective du Lévomilnacipran qui est un antidépresseur qui vient de recevoir son autorisation de mise sur le marché aux Etats-Unis et au Canada. Cette synthèse de novo nous a permis d’obtenir le produit actif en neuf étapes avec un rendement global de 32 % et un excès énantiomérique conservé de 88 %. Nous avons ensuite mis au point une synthèse énantiosélective du 1,4-benzodioxane F17807. Cette synthèse en quatre étapes repose sur une étape clé de SNAr du (S)-isopropylidèneglycerol sur un fluorophénol. Cette étape permet d’introduire l’information chirale qui sera maintenue tout au long de la synthèse puisque le produit final est isolé avec un excès énantiomérique de 98 %.Nous avons également synthétisé des analogues du dérivé d’épipodophyllotoxine, F14512. Ces stéréoisomères sont des impuretés qui peuvent apparaitre dans la formulation finale du principe actif. Pour finir, nous avons imaginé de nouvelles formulations nanométriques du composé F14512 afin que celui-ci s’auto-assemble en micelle. Pour cela, quatre amphiphiles ont été synthétisés et les premiers tests montrent une internalisation préférentielle au niveau des tumeurs ou des cellules surexprimant le STP en fonction de leur fonctionnalisation
This thesis deals with the synthesis of biologically active compounds. In the first chapter, we developed a semi-synthetic process for the exo-dehydration of macrocarpals A and B to get access to macrocarpal G which is a drug known for its anorexigenic activity. The second chapter is dealing with the enantioselective synthesis of the anti-depressive drug Levomilnacipran which has recently been approved by the FDA. This de novo synthesis was performed in 9 steps with an overall yield of 32 % and with an enantiomeric excess of 88 % which was maintained throughout our synthesis. In the third chapter we worked on a novel route for the enantioselective synthesis of the antipsychotic drug F17807. Our four-step synthesis of the 1,4-benzodioxan unit relied, as the key step, on the SNAr reaction of optically active (S)-isopropylidenglycerol on a properly functionalized fluorophenol and subsequent transformations. F17807 was produced with an ee of 98%.The fourth chapter reports our investigations for the synthesis of three stereoisomers of F14512 which is a targeted epipodophyllotoxin-based anticancer drug.Finally, new nanometric formulations of F14512 were designed in the fifth chapter. Four different drug-containing amphiphilic compounds were synthesized, assembled into the corresponding micelles, and evaluated as delivery systems. Preliminary in vitro and in vivo results indicate that the nanomicelles are highly promising for the targeting of tumors as visualized by fluorescence imaging
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Leigh, Alistair J. "Synthetic studies on 1,4-benzodioxin." Thesis, University of Bristol, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.281803.

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Thiéry, Valérie. "Fonctionnalisation de 1,4-benzodioxines et de 2,3-dihydro-1,4-benzodioxines : application a la synthese de composes antioxydants." Orléans, 1995. http://www.theses.fr/1995ORLE2028.

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Les maladies cardio-vasculaires representent la premiere cause de mortalite dans les pays industrialises. De nombreuses enquetes epidemiologiques ont mis en evidence le lien existant entre un taux eleve de cholesterol dans le sang et le risque d'accidents ischemiques. Cependant, un autre facteur, tout aussi consequent, la peroxydation ou auto-oxydation des lipides, doit etre pris en consideration. Pour inhiber un tel phenomene l'usage d'antioxydants se revele necessaire. Dans le cadre de la mise en uvre d'une nouvelle therapeutique concernant certaines maladies cardio-vasculaires, la preparation de molecules 1,4-benzodioxiniques et 1,4-benzodioxaniques a activite mixte, hydroxylees ou aminees en position 6 ou 7 sur l'homocycle et substituees en position 2 par une fonction amide ou amine, a ete envisagee. Pour acceder a ces composes, nous avons consacre, une grande part de notre travail a la fonctionnalisation regioselective en position 6 et 7 des heterocycles 1,4-benzodioxiniques et 2,3-dihydro-1,4-benzodioxiniques substitues en position 2, en etudiant plus en detail les reactions de substitutions electrophiles de type de friedel et crafts. Plusieurs voies de synthese distinctes ont ainsi ete mises au point afin d'acceder aux acides benzodioxaniques et benzodioxiniques d'une part regioselectivement hydroxyles en c#6 ou c#7 et d'autre part regioselectivement amines en c#6. A partir de ces differents substrats, divers carboxamides et derives aminomethyles ont ete prepares. Les etudes pharmacologiques realisees sur ces composes ont fait apparaitre d'interessantes proprietes antioxydantes vis a vis de la protection de la peroxydation lipidique ainsi que de notables proprietes anticalciques et hypolipemiantes. Par ailleurs, en vue de preparer ulterieurement, les analogues benzodioxaniques du trolox et de ses analogues, nous avons developpe la synthese generale de composes benzodioxaniques doublement substitues en position 2, au depart des hemiacetals correspondants
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Dahlstedt, Emma. "Synthesis of Electroactive Molecules Based on Benzodioxins and Tetrathiafulvalenes." Doctoral thesis, KTH, Chemistry, 2003. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3601.

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This thesis deals with the synthesis of electroactiveorganic compounds. The synthesis of ethylenedioxy-benzodioxinstri-dioxin and tetra-dioxin are described. These molecules wereprepared with the aim of creating donor molecules for cationicradical salts. The symmetric analogs of tri-dioxin,methylenedioxy-derivative and ethylenedioxy-naphthalene werealso synthesized. Three different cation radical salts with 2:1stoichiometries were obtained from tri-dioxin, whiletetra-dioxin merely provided polycrystalline materials.Tri-dioxin and tetra-dioxin were also successful as operationalmatrixes in PALDI-TOF.

Tetrathiafulvalenes with the2-dialkyl-amino-1,3-dithiolium-4-thiolate mesoion asbuilding-block was also synthesized. A series of doublyalkylthiol-substituted TTFs were prepared with the aim offorming self-assembly monolayers on gold surfaces in theapplication of organic thin film field-effect transistors.Film-formation for two TTFs were studied and they providedrelatively dense packed monolayers with a discrete distance ofthe TTF moiety from the gold surface.

The mesoionic compound was also for the first time used inanumpolungreaction. The electrophile obtained in situ bytreatment of mesoion with sulfuryl chloride was reacted with avariety of electron-rich aromatic compounds. From the receivedproducts three new arylthio-substituted TTFs weresynthesized.

Keywords:Synthesis, Benzodioxin, Tetrathiafulvalene,Mesoion, Organic Conductor, Cation Radical Salt, CyclicVoltammetry, Electrocrystallization, Self-Assembly Monolayer,SAM, Organic Field-Effect Transistor, OFET

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Rhim, Abdelhak. "Synthese de spirobenzofuranes et de spirobenzodioxines a visee adrenergique et/ou antioxydante." Paris 11, 1996. http://www.theses.fr/1996PA114841.

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Meuche-Albeny, Jacobine. "Pharmacochimie antiparasitaire et réactions de transfert monoélectronique en séries benzodioxole et benzothiadiazole." Aix-Marseille 3, 1998. http://www.theses.fr/1998AIX30067.

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Notre memoire comporte cinq chapitres regroupes en deux grandes parties : l'une relative a la preparation et la reactivite dans des reactions de transfert monoelectronique de substrats nitro-heterocycliques, l'autre a la valorisation biologique des intermediaires precedemment synthetises. La premiere partie de ce travail decrit l'extension du mecanisme de substitution radicalaire nucleophile unimoleculaire (s#r#n1) en series 6-nitrobenzo1,3dioxole et 7-nitro-2,1,3-benzothiadiazole par une etude mecanistique complete et une generalisation a divers anions nitronates ou malonates. Dans la seconde partie, environ 50 molecules ont ete synthetisees par des reactions classiques de synthese organique (formation d'aldimines, d'hydrazones, reaction de knoevenagel) a partir des intermediaires necessaires a la synthese des molecules cibles decrites precedemment et ont ete soumises a des tests antiparasitaires. Ainsi par exemple, la fonctionnalisation du 5-benzo1,3dioxol-5-yl-1-methyl-1h-imidazole-2-carboxaldehyde conduit a de nouveaux composes possedant une activite leishmanicide superieure a celle de la pentamidine, produit de reference.
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Massacret, Magali. "Nouvelle méthodologie d'accès à des benzodioxanes et analogues structuraux énantiomériquement enrichis via les complexes du palladium(0) chiraux." Lyon 1, 1997. http://www.theses.fr/1997LYO10342.

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L'utilisation des complexes organometalliques, en particulier, ceux du palladium(o) connait un essor considerable depuis les annees 1970 ; elle permet en effet la realisation d'un grand nombre de reactions, notamment des reactions d'heterocyclisation, dans des conditions souvent douces avec des chimio-, des regio- et des diastereoselectivites remarquables. Il apparait donc clairement que le defi a l'heure actuelle est de realiser ces reactions de facon enantioselective. C'est donc dans cette optique que ce sont inscrits mes travaux de these. Des resultats anterieurs avaient montre que la synthese d'ethers allyliques, par reaction de o-alkylation intermoleculaire de carbonates allyliques par des phenols, s'effectuait avec de bons rendements. Nous avons donc mis a profit ces resultats en developpant cette reaction en serie intramoleculaire. Dans un premier temps, nous avons mis au point la reaction tandem mettant en jeu un dicarbonate allylique et des nucleophiles ambidents. Nous avons montre que l'acces a des heterocycles azotes et oxygenes etait possible, en presence d'une quantite catalytique de palladium(o) associe a une phosphine bidente, le 1,4-diphenylphosphinobutane (dppb). Nous avons ensuite etendu cette reaction de cyclisation en serie chirale et des benzodioxanes, des benzomorpholines et des benzopiperazines enantiomeriquement enrichis ont ete obtenus. L'influence de la geometrie du ligand chiral, de la temperature, du solvant et de la nature du nucleophile sur l'enantioselectivite de la reaction a ete largement mis en avant. Nous avons alors montre qu'un choix judicieux de ces differents parametres, nous a permis de synthetiser des benzomorpholines avec des exces enantiomeriques de 79%. Nous avons ensuite aborde l'aspect mecanistique de cette cyclisation et nous avons etabli que l'attaque nucleophile intramoleculaire n'etait vraisemblablement pas l'etape enantioselective, infirmant ainsi les resultats decrits dans la litterature.
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Ferri, Pedro Henrique. "Fitoquimica das folhas de Virola oleifera e sintese de compostos (1,4)-benzodioxanos e analogos nitrogenados." [s.n.], 1993. http://repositorio.unicamp.br/jspui/handle/REPOSIP/248372.

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Orientador : Lauro Euclides Soares Barata
Tese (doutorado) - Universidade Estadual de Campinas, Instituto de Quimica
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Bhandare, Richie R. "Thesis-Final-supplementary." Diss., Temple University Libraries, 2013. http://cdm16002.contentdm.oclc.org/cdm/ref/collection/p245801coll10/id/215231.

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Pharmaceutical Sciences
Ph.D.
The acetylcholine (ACh) receptor system belongs to rhodopsin GPCR family and is an integral membrane protein divided into two types: muscarinic and nicotinic. The naturally occurring neurotransmitter acetylcholine binds to these two receptor systems non- selectively. The regulatory effects of the neurotransmitter acetylcholine are diverse ranging from autonomic nervous system and the central nervous system through different types of neurons innervated by cholinergic inputs. Muscarinic acetylcholine receptors (mAChRs) are divided into five receptor subtypes (M1-M5). In general, M1, M3 and M5 receptor subtypes are coupled via Gq like proteins; while M2 and M4 subtypes are coupled to Gi-proteins. Muscarinic receptors are widely distributed in the body where they mediate a variety of important physiological effects. mAChRs have been the target of drug development efforts for the treatment of various disorders including overactive bladder, Alzheimer's disease, pain, cognitive impairment, dr
Temple University--Theses
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Book chapters on the topic "Benzodioxane"

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Vogt, J. "651 C7H6O2 1,3-Benzodioxole." In Asymmetric Top Molecules. Part 3, 138. Berlin, Heidelberg: Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-14145-4_73.

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Melchiorre, C., P. Angeli, M. L. Bolognesi, A. Chiarini, D. Giardinà, U. Gulini, A. Leonardi, et al. "α1-Adrenoreceptor antagonists bearing a quinazoline or a benzodioxane moiety." In Receptor Chemistry towards the Third Millennium, Proceedings of the 12th Camerino-Noordwijkerhout Symposium, 181–90. Elsevier, 2000. http://dx.doi.org/10.1016/s0165-7208(00)80016-1.

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"1,3-Benzodioxole." In Substance Index, edited by Backes, Fröhlich, and Padeken. Stuttgart: Georg Thieme Verlag, 2000. http://dx.doi.org/10.1055/b-0035-114031.

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Matsumoto, M. "2-Substituted 1,4-Benzodioxins from 2-Lithio-1,4-benzodioxins." In Six-Membered Hetarenes with Two Identical Heteroatoms, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-016-00030.

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Kollenz, G., and S. Ebner. "Of 2,3-Benzodioxin-1,4-dione." In Three Carbon-Heteroatom Bonds: Thio-, Seleno-, and Tellurocarboxylic Acids and Derivatives; Imidic Acids and Derivatives; Ortho Acid Derivatives, 1. Georg Thieme Verlag KG, 2006. http://dx.doi.org/10.1055/sos-sd-023-00254.

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Matsumoto, M. "1,4-Benzodioxins by Elimination of Water from 2-Hydroxy-2,3-dihydro-1,4-benzodioxins." In Six-Membered Hetarenes with Two Identical Heteroatoms, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-016-00019.

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Matsumoto, M. "5-Substituted 1,4-Benzodioxins via Lithiation of η-Chromium(0) Complexes of 1,4-Benzodioxins." In Six-Membered Hetarenes with Two Identical Heteroatoms, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-016-00032.

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Perst, H. "Ionization of 2,2-Dichloro-1,3-benzodioxole." In Five-Membered Hetarenes with One Chalcogen and One Additional Heteroatom, 1. Georg Thieme Verlag KG, 2002. http://dx.doi.org/10.1055/sos-sd-011-00029.

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Sakya, S. M., and J. Yang. "Alkylation of 1,4-Benzodioxin-6,7-dicarbaldehyde." In Six-Membered Hetarenes with Two Identical Heteroatoms, 1. Georg Thieme Verlag KG, 2012. http://dx.doi.org/10.1055/sos-sd-116-00528.

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Matsumoto, M. "1,4-Benzodioxins by Elimination of Bromine or Hydrogen Bromide from 2,3-Dibromo-2,3-dihydro-1,4-benzodioxins." In Six-Membered Hetarenes with Two Identical Heteroatoms, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-016-00018.

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Conference papers on the topic "Benzodioxane"

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Soubhye, Jalal. "Design, Synthesis and Activity Evaluation of New Irreversible Myeloperoxidase Inhibitors Derived From Benzodioxole ." In 1st International Electronic Conference on Medicinal Chemistry. Basel, Switzerland: MDPI, 2015. http://dx.doi.org/10.3390/ecmc-1-a008.

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