Academic literature on the topic 'Benzothiazolo'

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Journal articles on the topic "Benzothiazolo"

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Arafat, Mahmoud, Ehab Abdel-Latif, Fathy M. El-Taweel, Seif-Eldin N. Ayyad, and Khaled S. Mohamed. "Synthesis and biological assessment of new benzothiazolopyridine and benzothiazolyl- triazole derivatives as antioxidant and antibacterial agents." Bulletin of the Chemical Society of Ethiopia 36, no. 2 (2022): 451–63. http://dx.doi.org/10.4314/bcse.v36i2.17.

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ABSTRACT. A novel series of benzothiazolopyridine derivatives was synthesized via interaction of -2-(benzothiazol-2-yl)-3-(4-chlorophenyl)acrylonitrile (2) with a diverse of commercially available reagents (indandione, thiobarbituric acid, and malononitrile). Moreover, a novel group of benzothiazole linked substituted 1,2,3-triazole derivatives were synthesized by exploring the chemical behavior of 5-benzothiazolyl-2-(4-chlorophenyl)-triazol-4-amine through refluxing in glacial acetic acid, condensation with phthalic anhydride, and cyanoacetylation reactions. All newly synthetized compounds ha
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Sridevi, CH, K. Balaji, A. Naidu, and R. Sudhakaran. "Antimicrobial Evaluation and Synthesis of Some Phenylpyrazolo benzothiazolo quinoxaline Derivatives." E-Journal of Chemistry 6, no. 3 (2009): 866–70. http://dx.doi.org/10.1155/2009/324358.

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2,3-Diphenyl quinoxaline(SI)was fused with 2-amino benzothiazoles(SII)by a methylene bridge, which was then allowed for acetylation. The acetylated product (SIV) was made to react with different aromatic aldehydes to give chalcones(SV1-SV5). Chalcones refluxed with substituted acid hydrazides to afford different phenyl pyrazolo benzothiazolo quinoxaline derivatives(SVI1-SVI15). The structure of chalcones and phenyl pyrazolo benzothiazolo quinoxaline derivatives were confirmed by M.P, TLC and spectral data. All the synthesized compounds were screened for their antimicrobial activities.
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Refat, Hala M., and Khaled S. Mohamed. "Efficient and convenient synthesis of pyrido [2,1-b]benzothiazole, pyrimidopyrido[2,1-b]benzothiazole and benzothiazolo[3,2-a][1,8]naphthyridine derivatives." Heterocyclic Communications 21, no. 4 (2015): 219–24. http://dx.doi.org/10.1515/hc-2015-0018.

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AbstractNew 3-aryl-pyrido[2,1-b][1,3]benzothiazole derivatives 2a–e were synthesized in excellent yields via the reaction of benzothiazoleacetonitrile (1) with different aromatic aldehydes. The treatment of 2-(benzo[d]thiazol-2-yl)-3-(pyridin-4-yl)acrylonitrile (6) with malononitrile afforded 1-amino-3-(pyridin-4-yl)-3H-pyrido[2,1-b][1,3]benzothiazole-2,4-dicarbonitrile (7), which was allowed to react with a variety of reagents to provide pyrimido[5′,4′:5,6]pyrido[2,1-b][1,3]benzothiazole 8, 9 and [1,3]benzothiazolo[3,2-a][1,8]naphthyridine 10, 15 derivatives. All synthesized products were con
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Sathe, B. S., E. Jaychandran, G. M. Sreenivasa, and V. A. Jagtap. "Antimycobacterial Activity of Some Synthesized Fluorinated Benzothiazolo Imidazole Compounds." E-Journal of Chemistry 8, no. 2 (2011): 830–34. http://dx.doi.org/10.1155/2011/581429.

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4-Fluoro-3-chloroanilline treated with potassium thiocyanate in presence of glacial acetic acid and bromine was converted into 2-amino-6-fluoro-7-chlorobenzothiazole, resulting into 2-amino benzothiazole. The synthesized compound in presence of 2-phenyl-4-benzylidine-5-oxazolinone refluxed in pyridine to obtain 2-(2-phenyl-4-benzylidenyl-5-oxo-imidazolin-1-yl amino)-6-fluoro-7-substituted(1,3)benzothiazoles. The above said compound was treated withortho, metaandpara nitroanillines, ortho, meta, parachloroanillines, morpholino, piperazine, diphenylamine in the presence of DMF to obtain differen
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K., S. Panpaliya* D. T. Tayade R. S. Shaikh. "SYNTHESIS OF 1-O-TOLYL-3-SUBSTITUTED-2,6-DITHIO-4-AMINO -[(2-O-TOLYLTHIOCARBAMIDO)-1,3-BENZOTHIAZOLO] -1,3,5-TRIAZINE." Indo American Journal of Pharmaceutical Sciences 04, no. 12 (2018): 4822–25. https://doi.org/10.5281/zenodo.1134392.

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We reported synthesis of 1-o-tolyl-3-substituted-2,6-dithio-4-amino-[(2-o-tolylthiocarbamido)-1,3-benzothiazolo] -1,3,5-triazines by isomerisation of 2-substituted-imino-6-o-tolylimino-4-[(2-o-tolylthiocarbamido)-1,3 -benzothiazolo]-1,3,5-dithiazines in 10 % aqueous ethanolic sodium bicarbonate mixture in ethanol solvent. The structure determination and justification of the synthesized compounds were done on the basis of elemental analysis, chemical characteristics and spectral studies. Keywords:2-substituted-imino-6-o-tolylimino-4-[(2-o-tolylthiocarbamido)-1,3-benzothiazolo]-1,3,5-dithiazines
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Ushakova, A. A., V. V. Fedotov, I. I. Butorin, E. N. Ulomsky, and V. L. Rusinov. "Benzothiazolo[3,2-a]pyrimidines and benzothiazolo[3,2-a]purines: synthesis and bioactivity prediction." Russian Chemical Bulletin 73, no. 8 (2024): 2316–25. http://dx.doi.org/10.1007/s11172-024-4355-y.

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Abdullah, Ahmad H., Jalal A. Zahra, Salim S. Sabri, et al. "Thiophene Ring-opening Reactions III: One-Pot Synthesis and Antitumor Activity of 1,3,4-Thiadiazoline–Benzothiazolo[3,2-b]pyridazine Hybrids†." Current Organic Synthesis 19, no. 2 (2022): 279–90. http://dx.doi.org/10.2174/1570179418666211109112148.

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Introduction: The preparation of model 6-chloro-5-nitrothieno[2,3-c]pyridazines incorporating (2'-halo-5'-nitrophenyl) entity is described. Interaction of these substrates with N'-(aryl)benzothiohydrazides, in the presence of triethylamine, followed a formal [4+1] annulation, furnishing the respective 1,3,4-thiadiazoline–benzothiazolo [3,2-b]pyridazine hybrids directly. This one-pot synthesis implies thiophene ring-opening and two consecutive intramolecular cyclizations. The structures of the synthesized new hybrids are supported by MS, NMR, and IR spectral data and further confirmed by single
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Kriplani, Prashant, Pawan Swarnkar, Rinku Maheshwari, and K. G. Ojha. "Microwave Assisted Synthesis of Some Biologically Active Benzothiazolotriazine Derivatives." E-Journal of Chemistry 3, no. 4 (2006): 307–12. http://dx.doi.org/10.1155/2006/486723.

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Synthesis of some biologically active benzothiazolotriazine derivatives by microwave irradiation is reported. 2-Amino-6-substituted benzothiazoles1on treatment with benzaldehyde in anhydrous ethanol afforded 2-benzylidenoimino-6-substitutedbenzothiazoles2which underwent cyclisation with ammoniumthiocyanate in dioxane to give 2-phenyl benzothiazolo [3,2-α]-s-triazine-4-[3H] thiones3.These both steps were carried out in microwave. Compound3with benzoyl chloride in anhydrous pyridine gave 2-phenyl-3-(benzoyl) benzothiazolo [3,2-α]-s-triazine-4-thiones4in good yields. The structure of all these co
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Liu, Kang-Chien, and Ling-Yih Hsu. "Zur Darstellung eines 12H-Benzothiazolo[2,3-b]chinazolin-Derivats. Synthesis of a 12H-Benzothiazolo[2,3-b]quinazoline Derivative." Archiv der Pharmazie 320, no. 6 (1987): 569–71. http://dx.doi.org/10.1002/ardp.19873200617.

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Khoobi, M., A. Ramazani, A. R. Foroumadi, H. Hamadi, Z. Hojjati, and A. Shafiee. "Efficient microwave-assisted synthesis of 3-benzothiazolo and 3-benzothiazolino coumarin derivatives catalyzed by heteropoly acids." Journal of the Iranian Chemical Society 8, no. 4 (2011): 1036–42. http://dx.doi.org/10.1007/bf03246560.

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Dissertations / Theses on the topic "Benzothiazolo"

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Fowler, Anne Michelle. "Metabolism of benzothiazole." Thesis, University of Hertfordshire, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.314573.

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Blunt, Christoper Edward. "The synthesis of benzisothiazole and benzothiazole natural products." Thesis, University of Nottingham, 2018. http://eprints.nottingham.ac.uk/49541/.

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Chapter 1 gives an introduction to benzisothiazole and benzothiazole natural products. It explores the scope of natural products that are known within these families and discusses what they are used for, how they have been made and how they may have been biosynthesised. Chapter 1 provides a review of each family of natural products in turn. Chapter 2 describes the total synthesis of the benzisothiazole natural products aulosirazole and pronqodine A, and a series of unnatural analogues. The Chapter begins with a short discussion on the use of the Diels-Alder reaction for the formation of naphth
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Billeau, Sébastien. "Synthèse de molécules dérivées du benzothiazole et de la tétrahydroacridine." Aix-Marseille 3, 2004. http://www.theses.fr/2004AIX30033.

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Au cours de ce travail, nous avons développé la synthèse d’une nouvelle famille de composés : les thiazolo-tétrahydroacridines. Une stratégie de synthèse a été élaborée puis optimisée et nous avons ainsi obtenu huit molécules originales. De nombreux composés benzothiazoliques préparés au cours de ce travail en tant qu’intermédiaires de synthèse, présentent, eux aussi, un intérêt certain. Ceci nous a permis de valoriser ces produits. Tous les composés synthétisés sont en cours d’évaluation dans différents domaines d’activité et notamment dans le domaine thérapeutique. Certains résultats au nive
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Potter, Charles Alan Stuart. "Excited state proton transfer in 2-substituted benzothiazoles." Thesis, University of Central Lancashire, 1993. http://clok.uclan.ac.uk/19742/.

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The photophysics of 2-(2'-hydroxyphenyl)benzothiazole (HBT) and related compounds has been studied as a function of solvent, pH or H 0 and temperature. Measurements of absorption and fluorescence spectra and fluorescence decay profiles under these various conditions have been combined with theoretical calculations to arrive at an understanding of the excited state behaviour of HBT and derivatives. An investigation has been made into the protonation and deprotonation of 2-phenylbenzothiazole, 2-(2'-methoxyphenyl)benzothiazole), HBT and derivatives of HBT with bromine, chlorine, hydroxy, methoxy
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Bunescu, Andrei. "Photo-et biodégradation de dérivés du benzothiazole : étude en système combiné." Phd thesis, Université Blaise Pascal - Clermont-Ferrand II, 2006. http://tel.archives-ouvertes.fr/tel-00713567.

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La dégradation en solution aqueuse du 2-aminobenzothiazole (ABT) et du benzothiazole (BT) a été étudiée par voies photochimique, microbiologique et en combinant les deux approches. La voie photochimique impliquait des complexes aqueux de fer ou le complexe entre le fer et l'acide nitrilotriacétique (FeNTA). La voie microbiologique utilisait une souche bactérienne de Rhodococcus rhodochrous. Les schémas de dégradation ont été établis pour les différentes voies. Nous avons montré qu'il existait une grande similitude entre la dégradation photochimique et microbiologique. De plus, deux nouveaux pr
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Paranjpe, Shirish. "Synthesis of Novel Fluorescent Benzothiazole Cyanine Dyes as Potential Imaging Agents." Digital Archive @ GSU, 2012. http://digitalarchive.gsu.edu/chemistry_theses/55.

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Near-infrared (NIR) fluorescence imaging has emerged as an attractive non-invasive approach for direct visualization of diseases which depends on the development of stable, highly specific and sensitive optical probes. The NIR region of the electronic spectrum offers a reduction in the background autofluorescence and an increase in the tissue penetration depth. Cyanine dyes have often been considered promising contrast optic agents owing to their photophysical properties. Herein the synthesis of various penta- and heptamethine benzothiazole cyanine dyes has been described and their in vivo ima
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Willis, Kimberlee Susan. "Developing benzothiazole functionalised ruthenium(II) polypyridyl complexes as tuneable DNA binders." Thesis, Queen's University Belfast, 2014. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.675442.

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The aim of this research is to develop a range of new ruthenium(II) polypyridyl complexes to be analysed spectroscopically in the presence of calf thymus-DNA to determine their relative binding affinities to the polynucleotide, thus determining the best criteria for a detection tool for DNA. Reactions of selected functional groups on one ligand of ruthenium(II) precursor complexes lead to the synthesis of six benzothiazole containing complexes; [Ru(bpY)2(B16)]2+,, [Ru(bpy)2(P5)]2+, [Ru(phen)2(B16)]2+, [Ru (phenh(P5)]2+, [Ru(Me2bpY)2(B16)]2+ and [Ru(Me2bpy)2(P5)]2+ and four "control" complexes;
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Leong, Chee-Onn. "Antitumour benzothiazoles : analysis of DNA damage induced by Phortress." Thesis, University of Nottingham, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.396792.

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Shi, Dong-Fang. "The medicinal chemistry of antitumour benzazoles." Thesis, University of Nottingham, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.283645.

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Vieira, Gabriella Cunha. "AvaliaÃÃo in vitro do potencial citotÃxico de quatro anÃlogos de benzotiazÃis." Universidade Federal do CearÃ, 2011. http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=6948.

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Conselho Nacional de Desenvolvimento CientÃfico e TecnolÃgico<br>BenzotiazÃis sÃo compostos com anel benzeno ligados ao anel tiazol, que apresentam atividade antitumoral significante. Devido à alteraÃÃo de ligaÃÃes quÃmicas de molÃculas ser um mÃtodo comum para desenho de fÃrmacos em quÃmica medicinal e uma tÃcnica Ãtil para o desenvolvimento de novos medicamentos, a sÃntese de BenzotiazÃis substituÃdos apresentou muita vantagem para o tratamento de tipos especÃficos de cÃncer. No presente estudo foi avaliado o potencial citotÃxico de quatro anÃlogos de benzotiazÃis substituÃdos frente a linha
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Books on the topic "Benzothiazolo"

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Heijstek, Atakan. Benzothiazole: Preparation, Structure and Uses. Nova Science Publishers, Incorporated, 2020.

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Heijstek, Atakan. Benzothiazole: Preparation, Structure and Uses. Nova Science Publishers, Incorporated, 2020.

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Shaikh, Faiyazalam, and Navin Patel. Benzothiazole. Biologically Useful and Important Scaffold. GRIN Verlag GmbH, 2018.

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Fernandez, Jose Miguel Aurrecoechea. Pyridine and benzothiazole derivatives in carbanionic reactions. 1985.

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Drewniak-Deyrup, Malgorzata. Some applications of benzotriazole as a synthetic auxiliary. 1988.

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Bhat, Mahesh, and S. L. Belagali, eds. In-Silico and In-Vitro Approaches to Screen the Antituberculosis Activity of Benzothiazole Analogs. BENTHAM SCIENCE PUBLISHERS, 2021. http://dx.doi.org/10.2174/97898114946351210101.

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Singh, Rajesh Kumar, ed. Key Heterocyclic Cores for Smart Anticancer Drug–Design Part I. BENTHAM SCIENCE PUBLISHERS, 2022. http://dx.doi.org/10.2174/97898150400741220101.

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This book provides an update on heterocyclic compounds that serve as key components of anti-cancer agents administered in pre-clinical settings. Many of the compounds highlighted in the book are being actively investigated for the bioactive properties against a range of cancer cell lines. There is potential for heterocyclic compounds to design agents that can target specific molecules to treat different types of cancers. Chapters are contributed by experts in pharmaceutical chemistry and are written to give a general overview of the topic to readers involved in all levels of research and decis
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Kreher, Mareta. 2,3-Dihydro-pyrrolo[2,1-b]oxazole, 2,3-Dihydro-pyrrolo[2,1-b]thiazole, 2-Aryl-pyrrolo[2,1-b]benzothiazole und 2,3-Dihydro-1H-pyrrolizine: Synthese, Analytik und Testung der antiinflammatorischen Wirksamkeit sowie der modifizierte HET-CAM-Test als Modell zur Bestimmung der antiphlogistichen und antirheumatischen Wirksamkeit von Arzneistoffen. 1995.

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Book chapters on the topic "Benzothiazolo"

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Wu, Yong-Jin. "Thiazoles and Benzothiazoles." In Topics in Heterocyclic Chemistry. Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/7081_2012_78.

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Rauf, Abdul, and Nida Nayyar Farshori. "Benzimidazoles, Benzothiazoles and Benzoxazoles." In SpringerBriefs in Molecular Science. Springer Netherlands, 2011. http://dx.doi.org/10.1007/978-94-007-1485-4_10.

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Klunk, William E., Yanming Wang, and Chester A. Mathis. "Development of Benzothiazole Amyloid-Imaging Agents." In The Living Brain and Alzheimer’s Disease. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-642-59300-0_9.

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Bhatia, Rohan, Preeti Ashokkumar Chaudhran, and Abha Sharma. "Benzothiazole-Based Fluorescent Probes for Various Applications." In Small Organic Molecules-Based Fluorescent Biosensors and their Applications. CRC Press, 2025. https://doi.org/10.1201/9781032706245-11.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of 1,3,2-benzothiazolyl radical." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-642-23675-4_4709.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of tetracyanonotrosylchromate(I) complex with benzothiazole." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49202-4_461.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of copper(II) complex with benzothiazole-2-carboxyhydrazide." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_272.

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Desai, Kishor R., Vedant Patel, Misha Patel, Bhavin R. Patel, and Anand J. Patel. "Synthesis and Biological Evaluation of Benzothiazepine, Benzothiazole, and Benzothiophene Derivatives." In S-Heterocycles. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-4308-7_6.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of nickel(II) complex with 2-(1-indazolyl)-benzothiazole." In Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 3. Springer Berlin Heidelberg, 2021. http://dx.doi.org/10.1007/978-3-662-62470-8_154.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of copper(II) complex with 2-(1-indazolyl)benzothiazole." In Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 4. Springer Berlin Heidelberg, 2021. http://dx.doi.org/10.1007/978-3-662-62474-6_424.

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Conference papers on the topic "Benzothiazolo"

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Lukovits, I., T. Kosztolányi, E. Kálmán, and G. Pálinkás. "Corrosion Inhibitors: Correlation between Chemical Structure and Efficiency." In CORROSION 1999. NACE International, 1999. https://doi.org/10.5006/c1999-99242.

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Abstract Corrosion inhibition efficiencies of heterocyclic, aromatic or partially saturated aromatic compounds (pyrimidines, benzothiazole derivatives, amino-acids containing an aromatic part, pyridines and quinolines) were correlated with quantum chemical indices of the respective molecules. Inhibition efficiencies measured in acidic solutions containing 0.001 and 0.01 mol/L of the inhibitor, respectively, were collected. The quantum chemical calculations were done by using the simple Hückel method. Comparison of inhibition efficiencies and the differences between energies of the highest occu
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Dandia, Anshu, Sarita Khaturia, Anuj Jain, and Kapil Arya. "Statement of a methodology for the microwave-induced preparation of biologically important benzothiazolo [2, 3-b] quinazolines and its comparison with ultrasonic and classical heating." In The 12th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2008. http://dx.doi.org/10.3390/ecsoc-12-01262.

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Cabrera, José, Mateo Alajarín, and Aurelia Pastor. "Dimeric Anhydro Bases from Benzothiazole Derivatives." In The 10th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2006. http://dx.doi.org/10.3390/ecsoc-10-01402.

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Ha, Sie-Tiong, Guan-Yeow Yeap, Teck-Leong Lee, and Teck-Ming Koh. "New Heterocyclic Liquid Crystals with Benzothiazole Core." In The 14th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2010. http://dx.doi.org/10.3390/ecsoc-14-00373.

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Bhagdev, Khyati, and Sibaji Sarkar. "Benzothiazole Moiety and Its Derivatives as Antiviral Agents." In ECMS 2021. MDPI, 2021. http://dx.doi.org/10.3390/ecms2021-10839.

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Blaja, Svetlana, Aculina Aricu, Kaleria Kuchkova, and Alic Barba. "Synthesis of some new homodrimane derivatives of benzothiazole from norambreinolide." In New frontiers in natural product chemistry, scientific seminar with international participation. Institute of Chemistry, 2021. http://dx.doi.org/10.19261/nfnpc.2021.ab26.

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Uma, Pathki, Firasath Unnisa, Pallati Naresh, Sai Prakash, P. R. Sushma, and Kamatala Chinna Rajanna. "Synthesis, characterization and biological activity of benzothiazoles derivatives." In PROCEEDINGS OF THE INTERNATIONAL CONFERENCE ON PHYSICS OF MATERIALS AND NANOTECHNOLOGY ICPN 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0009036.

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Alasadi, Rahman Tama Haiwal, Noralhuda M. A. Alhussein, and Zeid Hassan Abood. "Synthesis and preliminary antibacterial activities of novel benzothiazoles." In INTERNATIONAL CONFERENCE OF NUMERICAL ANALYSIS AND APPLIED MATHEMATICS ICNAAM 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0027666.

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Ha, Sie-Tiong, Hong-Cheu Lin, Guan-Yeow Yeap, Siew-Teng Ong, and Teck-Ming Koh. "Synthesis and Mesogenic Properties of New Schiff Bases Comprising Benzothiazole Moiety." In The 13th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2009. http://dx.doi.org/10.3390/ecsoc-13-00168.

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Smolicek, Maros, Dusan Chorvat, Beata Cunderlikova, Peter Hrobarik, and Alzbeta Marček Chorvátová. "Nonlinear optical imaging of benzothiazole analogues of BODIPY dyes (Conference Presentation)." In Multiphoton Microscopy in the Biomedical Sciences XXIII, edited by Ammasi Periasamy, Peter T. So, and Karsten König. SPIE, 2023. http://dx.doi.org/10.1117/12.2644815.

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Reports on the topic "Benzothiazolo"

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Steele, W. V., R. D. Chirico, S. E. Knipmeyer, and A. Nguyen. The thermodynamic properties of benzothiazole and benzoxazole. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/5364366.

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Tsai, Tsu-Tzu, and Fred E. Arnold. Synthesis and Properties of Rigid-Rod Benzobisazole Polymers Containing Benzothiazole Pendent Groups. Defense Technical Information Center, 1990. http://dx.doi.org/10.21236/ada234742.

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