Academic literature on the topic 'Benzoyl group'

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Journal articles on the topic "Benzoyl group"

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Delogu, Giovanna Lucia, and Michela Begala. "Unexpected Migration of Benzoyl Group in the Synthesis of 3-Benzoyl-2-Phenylbenzofurans under Wittig Conditions." Proceedings 9, no. 1 (2018): 38. http://dx.doi.org/10.3390/ecsoc-22-05656.

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In the present work, we report the unexpected formation of isomeric 3-benzoyl-2-phenylbenzo[b]furans using triphenylphosphonium salt and benzoyl chlorides under Wittig conditions. In particular, we found that the o-[(benzoyloxy)benzyl]-triphenyl-phosphoranes constitute the key intermediate that reasonably undergoes benzoyl group migration.
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Logvinenko, Ivan G., Violetta G. Dolovanyuk та Ivan S. Kondratov. "The preparative synthetic approach to 4-(trifluoromethoxy)piperidine and 4-(trifluoromethoxymethyl)piperidine". Journal of Organic and Pharmaceutical Chemistry 19, № 1(73) (2021): 3–9. http://dx.doi.org/10.24959/ophcj.21.222669.

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Aim. To develop a convenient synthetic approach for the preparation of multigram amounts of 4-(trifluoromethoxy)-piperidine and 4-(trifluoromethoxymethyl)piperidine – promising building blocks for medicinal chemistry.Results and discussion. 4-(Trifluoromethoxy)piperidine (8.4 g) and 4-(trifluoromethoxymethyl)piperidine (12.9 g) were synthesized in 5 stages starting from 4-hydroxypiperidine (the overall yield 40 %) and 4-(hydroxymethyl)piperidine (the overall yield 13.5 %), respectively.Experimental part. The first stage of the synthetic strategy was acylation of 4-hydroxypiperidine with benzoyl ch
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Varsha, Tiwari, Nayak Badavath Vishnu, Kumar Singh Adesh, and Kandasamy Jeyakumar. "Synthesis of photolabile group protected anomeric acetals and its application in carbohydrate synthesis with the assistance of continuous flow photo-reactor." Journal of Indian Chemical Society Vol. 97, Feb 2020 (2020): 227–36. https://doi.org/10.5281/zenodo.5651714.

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Department of Chemistry, Indian Institute of Technology (BHU), Varanasi-221 005, Uttar Pradesh, India <em>E-mail</em>: jeyakumar.chy@iitbhu.ac.in <em>Manuscript received online 20 October 2019, revised and accepted 02 January 2020</em> Selective deprotection of photolabile anomeric 2-nitrobenzyl acetals was achieved using continuous flow photo-reactor (UV radiation at 355 nm) in methanol-water. Various protecting groups such as acetyl, benzyl, benzoyl, benzylidine, TBS, etc. were found to be highly stable during the photolysis.
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Wan, Miao, Hongxiang Lou, and Lei Liu. "C1-Benzyl and benzoyl isoquinoline synthesis through direct oxidative cross-dehydrogenative coupling with methyl arenes." Chemical Communications 51, no. 73 (2015): 13953–56. http://dx.doi.org/10.1039/c5cc04791a.

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An oxidative cross-dehydrogenative coupling of isoquinolines with methyl arenes has been developed, yielding structurally diverse C<sub>1</sub>-benzyl and -benzoyl isoquinolines selectively. The direct use of readily available methyl arenes as coupling partners avoids unproductive steps for preactivating functional group installation, and is thereby attractive.
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Yu, Lan, Weihua Xue, Teng Ma, Changwei Li, Zhan-xin Zhang та Zhaoyan Wang. "Indium(III) Iodide-Catalyzed Stereoselective Synthesis of β-Glucopyranosides by Using a Glucosyl Fluoride Donor with 2-O-Benzoyl-3,4,6-Tri-O-Benzyl Protection". Synlett 28, № 19 (2017): 2633–36. http://dx.doi.org/10.1055/s-0036-1589121.

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We have developed a novel protocol for glucosylation by adopting a glucosyl fluoride donor with 2-O-benzoyl-3,4,6-tri-O-benzyl protection. The protocol is useful for the ready assembly of β-linked functional glycoconjugates, and the reaction accommodates a broad range of substrates. Conveniently, water-tolerant and commercially available InI3 is used as a catalyst, and no other additional reagent is required. The method involves an interesting process for glucosyl fluoride activation and, in particular, permits the stereoselective construction of partially benzylated glucopyranosides carrying
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Aguilar, David, Ignacio Fernández, Luciano Cuesta, et al. "Synthesis, Structure, and Reactivity ofN-Benzoyl IminophosphoranesOrthoLithiated at the Benzoyl Group." Journal of Organic Chemistry 75, no. 19 (2010): 6452–62. http://dx.doi.org/10.1021/jo101151s.

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Ton, Quoc Cuong, Michael Bolte, and Ernst Egert. "Structural similarities among eight benzoylhydrazones." Acta Crystallographica Section C Structural Chemistry 70, no. 9 (2014): 912–19. http://dx.doi.org/10.1107/s2053229614018658.

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The crystal structures of eight benzoylhydrazones with different substituents have been investigated, namely 1-benzoyl-2-(propan-2-ylidene)hydrazone, C10H12N2O, (I), 1-benzoyl-2-(1-cyclohexylethylidene)hydrazone, C15H20N2O, (II), 1-benzoyl-2-[1-(naphthalen-2-yl)ethylidene]hydrazone, C19H16N2O, (III), 1-benzoyl-2-(1-cyclohexylbenzylidene)hydrazone, C20H22N2O, (IV), 1-benzoyl-2-(1-phenylbenzylidene)hydrazone, C20H16N2O, (V), 1-benzoyl-2-[1-(4-chlorophenyl)benzylidene]hydrazone, C20H15ClN2O, (VI), 1-benzoyl-2-(4-hydroxybenzylidene)hydrazone methanol monosolvate, C14H12N2O2·CH3OH, (VII), and 1-ben
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Huang, Zhe, Yinning Chen, Riming Huang, and Zhengang Zhao. "Identification and Structure–Activity Relationship of Recovered Phenolics with Antioxidant and Antihyperglycemic Potential from Sugarcane Molasses Vinasse." Foods 11, no. 19 (2022): 3131. http://dx.doi.org/10.3390/foods11193131.

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Sugarcane molasses vinasse is the residue of the fermentation of molasses and the water and soil environmental pollutants from distilleries. However, its recycling value has been neglected. The chemical analysis of the molasses vinasse led to the isolation of a new benzoyl chloride called 2,3,4-trihydroxy-5-methoxy benzoyl chloride, as well as thirteen known compounds, including six benzoic acids. The structure of the new benzoyl chloride was elucidated on the basis of extensive spectroscopic analysis. The antioxidant activity of all isolated compounds was measured using the ORAC assay. Moreov
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Tamboli, Majid I., Vir Bahadur, Rajesh G. Gonnade, and Mysore S. Shashidhar. "Correlation of the solid-state reactivities of racemic 2,4(6)-di-O-benzoyl-myo-inositol 1,3,5-orthoformate and its 4,4′-bipyridine cocrystal with their crystal structures." Acta Crystallographica Section C Structural Chemistry 70, no. 11 (2014): 1040–45. http://dx.doi.org/10.1107/s2053229614021834.

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Racemic 2,4(6)-di-O-benzoyl-myo-inositol 1,3,5-orthoformate, C21H18O8,(1), shows a very efficient intermolecular benzoyl-group migration reaction in its crystals. However, the presence of 4,4′-bipyridine molecules in its cocrystal, C21H18O8·C10H8N2,(1)·BP, inhibits the intermolecular benzoyl-group transfer reaction. In(1), molecules are assembled around the crystallographic twofold screw axis (baxis) to form a helical self-assembly through conventional O—H...O hydrogen-bonding interactions. This helical association places the reactive C6-O-benzoyl group (electrophile, El) and the C4-hydroxy gr
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Jin, Zong-ming, Weiqun Zhou, and Zheng Jin. "X-ray powder diffraction analysis of a nonlinear optical material 1-benzoyl-3-(4-benzyl)thiourea [N-benzoyl-N′-(4-benzyl)thiourea]." Powder Diffraction 13, no. 1 (1998): 41–43. http://dx.doi.org/10.1017/s088571560000974x.

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A nonlinear optical material, 1-benzoyl-3-(4-benzyl)thiourea (C15H14N2OS), has been characterized by X-ray powder diffraction. Experimental values of 2θ corrected for systematic errors, relative peak intensities, values of d, and the Miller indices of 82 observed reflections with 2θ up to 80° are reported. The powder diffraction data have been evaluated, and the figures-of-merit are reported. The least-squares refined unit cell parameters are a=22.0243(6)Å, b=10.9795(7)Å, c=13.0322(8)Å, β=116.88(2)°, V=2810.8(9)Å3, Z=8, Dx=1.278 g/cm3, space group Pn.
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Dissertations / Theses on the topic "Benzoyl group"

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Papageorgiou, Edward Andrew. "Selective hydrogenolysis of benzyl protective groups : novel methodology in the benzyl carbamate and benzyl amine series." Thesis, University of Cambridge, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.620936.

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Du, Guodong. "Group 4 Metalloporphyrin diolato Complexes and Catalytic Application of Metalloporphyrins and Related Transition Metal Complexes." Washington, D.C. : Oak Ridge, Tenn. : United States. Dept. of Energy. Office of Science ; distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 2004. http://www.osti.gov/servlets/purl/835301-irsXCw/webviewable/.

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Hlimi, Fouzia. "Cycloaddition de diarylnitrilimines sur des dérivés de la benzodioxine 1,4 et de la benzoxazine-1,4 : regiochimie de la réaction sur un alcene portant un groupe donneur et un groupe accepteur sur la même extrêmité." Besançon, 1987. http://www.theses.fr/1987BESA2018.

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La cycloaddition dipolaire 1,3 des diarylnitrilimines sur le benzodioxinne-1,4 carboxylate-2 d'ethyle conduit a des cycloadduits qui apres ouverture donnent des derives de l'aryloxy-4 diphenyl-1,3 pyrazole qui ne sont pas accessibles par une methode classique de synthese de pyrazoles
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Erlekam, Undine. "Sterically flexible molecules in the gas phase." Doctoral thesis, Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät I, 2008. http://dx.doi.org/10.18452/15833.

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Für die makroskopischen Eigenschaften und Funktionen biologisch relevanter Materie spielen schwache, intra- und intermolekulare Wechselwirkungen dispersiver und elektrostatischer Natur auf molekularem Niveau eine große Rolle. Um diese schwachen Wechselwirkungen zu untersuchen, können Modellsysteme, isoliert in der Gasphase, herangezogen werden. Benzoldimer, ein schwach gebundener Van der Waals Komplex, kann beispielsweise als Modellsystem für dispersive Wechselwirkungen dienen. In der vorliegenden Arbeit werden die strukturellen Eigenschaften und die (interne) Dynamik des Benzoldimers mit Hil
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Ferroud, Clotilde. "Étude de la réaction de Diels-Adler intra et intermoléculaire sous haute pression : application à la synthèse stéréosélective d'alcaloïdes de l'indole du groupe des yohimbanes." Paris 6, 1986. http://www.theses.fr/1986PA066023.

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Le schéma de synthèse repose sur une unité bicyclique, précurseur direct des unités (d,e) du squelette pentacyclique. Cet intermédiaire est basé sur une réaction de Diels-Alder sous haute pression, utilisant la cycloaddition de diènes de structure donneur-accepteur 1,4 avec une lactone insaturée comme diénophile. La synthèse du système pentacyclique est exposée à partir de cet intermédiaire clé.
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Lu, Zhi Hui, and 盧稚慧. "Catalytic Transfer Hydrogenation of Certain Benzoyl Group Compounds." Thesis, 1993. http://ndltd.ncl.edu.tw/handle/28715065463706973141.

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Sanderson, Cynthia T. "Characterization of benzoyl-substituted group 8 metallocenes as photochemical initiators for the anionic polymerization of vinylic monomers." 2004. http://purl.galileo.usg.edu/uga%5Fetd/sanderson%5Fcynthia%5Ft%5F200408%5Fphd.

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Joshi, Rajendra [Verfasser]. "Application of proteases for the total enzymatic synthesis of the cholecystokinin octapeptide (CCK-8) using benzoyl-arginine as an enzymatically cleavable N-terminal protecting group = Anwendung von Proteinen für die vollenzymatische Synthese des Cholecystokininoctapeptids (CCK-8) unter Verwendung von Benzoylarginin als enzymatisch spaltbare N-terminale Schutzgruppe / vorgelegt von Rajendra Joshi." 2007. http://d-nb.info/988688166/34.

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ZHANG, QIONG-FEN, and 張瓊芬. "Synthesis and characterization of side-chain liquid crystalline polymethacrylates and polyacrylates containing benzyl ether based mesogenic side group." Thesis, 1990. http://ndltd.ncl.edu.tw/handle/67575592479810954997.

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Truran, George Anthony. "Advantages of the highly base-sensitive benzo(B)thiophenesulfone-2-methoxycarbonyl amino-protecting group for the assembly of peptides subject to base-catalyzed side reactions." 1998. https://scholarworks.umass.edu/dissertations/AAI9841928.

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Two new, highly base-labile urethane-based $\alpha$-amino protecting groups were examined for their utility in peptide synthesis. The first such system examined, 3H-benz(e)indene)-1-methoxycarbonyl (eBimoc) 59, was synthesized from 1H-benz(e)indene 60 for which a practical large-scale synthesis was developed. Treatment of an eBimoc protected model amine shows that both deblocking and by-product scavenging are much faster than for the corresponding 9-fluorenemethoxycarbonyl derivative (Fmoc) 3. Unfortunately eBimoc protection proved to be too sensitive for general use in peptide synthesis as si
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Book chapters on the topic "Benzoyl group"

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Cabral, Joaquim M. S., Hernani L. S. Maia, Mário R. J. Rebelo, and L. M. Rodrigues. "The benzoyl group in racemization-free peptide synthesis." In Peptides 1992. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1470-7_83.

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Martin, Robert. "Phenols with one benzoyl group and one or several acetyl groups (Class of ETHANONES)." In Handbook of Hydroxybenzophenones. Springer Netherlands, 2000. http://dx.doi.org/10.1007/978-94-011-4347-9_6.

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Martin, Robert. "Phenols with One Benzoyl Group and One or Several Acetyl Groups (Class of ETHANONES)." In Aromatic Hydroxyketones: Preparation and Physical Properties. Springer Netherlands, 2011. http://dx.doi.org/10.1007/978-1-4020-9787-4_5.

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Martin, Robert. "Phenols with two or several benzoyl groups (Class of METHANONES)." In Handbook of Hydroxybenzophenones. Springer Netherlands, 2000. http://dx.doi.org/10.1007/978-94-011-4347-9_7.

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Martin, Robert. "Phenols with Two or Several Benzoyl Groups (Class of METHANONES)." In Aromatic Hydroxyketones: Preparation and Physical Properties. Springer Netherlands, 2011. http://dx.doi.org/10.1007/978-1-4020-9787-4_6.

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Rowlands, C. C., and R. D. Farley. "15.6.2 Benzo[c]cinnolines and azobenzene derivatives." In Landolt-Börnstein - Group II Molecules and Radicals. Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-45824-1_51.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of trinuclear nickel(II) complex bridged by α-benzyl-dioximato group." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54234-7_453.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of trinuclear nickel(II) complex bridged by α-benzyl-dioximato group." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54234-7_454.

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Kikelj, D., and U. Urleb. "Removal of the Benzoyl Group from 5-Benzoylthiazoles." In Five-Membered Hetarenes with One Chalcogen and One Additional Heteroatom. Georg Thieme Verlag KG, 2002. http://dx.doi.org/10.1055/sos-sd-011-00969.

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von Angerer, S. "Benzyl Group." In Science of Synthesis Knowledge Updates KU 2011/1. Georg Thieme Verlag KG, 2011. http://dx.doi.org/10.1055/sos-sd-116-00341.

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Conference papers on the topic "Benzoyl group"

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Brenna, Andrea, Marco Ormellese, and Silvia Beretta. "Efficiency of Organic Compounds as Vcis for the Packaging of Carbon Steel Engine Elements in Automotive." In CORROSION 2020. NACE International, 2020. https://doi.org/10.5006/c2020-15004.

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Abstract Carbon steel elements for motor engine assembly are produced in different companies typically settled far from the assembly plant. As corrosion must be avoided, condition of transportation are of paramount importance. VCIs are used in the packaging, applied of the polymer sheet used to envelop the metallic element of impregnated in the carbon box. In the present paper, the inhibition efficiency of several pure organic substances was studied by potentiodynamic measurements and linear polarization resistance (LPR) tests. Organic substances containing a carboxylic group and/or an aminic
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Domínguez Olivo, J. M., B. Brown, D. Young, and S. Nesic. "Electrochemical Model of CO2 Corrosion in the Presence of Quaternary Ammonium Corrosion Inhibitor Model Compounds." In CORROSION 2019. NACE International, 2019. https://doi.org/10.5006/c2019-13392.

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Abstract The oil and gas industry utilizes surfactant-type organic corrosion inhibitors to mitigate internal pipeline corrosion. Changes in corrosion rates due to inhibitor addition have been related to adsorption isotherms as a function of the inhibitor concentration. However, the question as to how a corrosion inhibitor affects the electrochemical reactions governing CO2 corrosion remains unclear. This research proposed to investigate the issue by using a systematic approach: four different corrosion inhibitor model compounds, synthesized in-house, were utilized to determine the effect of th
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Miyasaka, Hiroshi, and Noboru Mataga. "Femtosecond Laser Photolysis Studies on the Conformation Change of Benzil in Solutions." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 1990. http://dx.doi.org/10.1364/up.1990.mc23.

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It is well-known that benzil (diphenylethanedione) has near-skewed form in the ground state, while the structure in the excited singlet state has been attributed to trans-planar geometry. (The terms "skewed" and "planar" used here refer to the dihedral angle between the planes containing the benzoil groups.) This structural change of benzil in solution has been considered to be very fast at room temperature. In this study, we have directly measured the structural change process by means of transient absorption spectroscopy with femtosecond laser. On the basis of the experimental result, we wil
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Miller, Terry A. "Laser spectroscopy of aromatic and organometallic radicals." In OSA Annual Meeting. Optica Publishing Group, 1992. http://dx.doi.org/10.1364/oam.1992.thi1.

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Laser induced fluorescence techniques can be used to obtain rotationally resolved electronic spectra of moderately large aromatic and organometallic radicals cooled to &lt;2 K in a supersonic free jet expansion. Aromatic organic radicals studied include cyclopentadienyl, benzyl, triphenyl methyl, and substituted derivatives thereof. Organometallic radicals studied include Cd and Zn monomethyl as well as group IIA and IIB derivatives of cyclopentadienyl, methylcyclopentadienyl, and pyrrolyl radicals.
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Cai, Sui Xiong, Qingbing Xu, Lizhen Wu, et al. "Abstract 1643: Discovery of 1-benzylquinazoline-2,4(1H,3H)-diones as novel and potent PARP inhibitors. SAR of the benzyl group." In Proceedings: AACR 106th Annual Meeting 2015; April 18-22, 2015; Philadelphia, PA. American Association for Cancer Research, 2015. http://dx.doi.org/10.1158/1538-7445.am2015-1643.

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Blagojević, Zorica, Milan Milenković, Danica Aranđelović, Katarina Jovanović, and Margarita Dodevska. "Testing of phthalate content in polymer toys." In Proceedings of the International Congress Public Health - Achievements and Challenges. Institute of Public Health of Serbia "Dr Milan Jovanović Batut", 2024. http://dx.doi.org/10.5937/batutphco24185b.

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Background: Phthalates, a group of synthetic organic compounds, have been subject of numerous studies due to their harmful effects on health. The use of bis(2-ethylhexyl)-phthalate (DEHP), dibutyl-phthalate (DBP), benzyl-butyl-phthalate (BBP) and diisobutyl-phthalate (DIBP) in concentrations equal to or greater than 0.1% by weight in plasticized materials is prohibited due to their classification as reproductive toxicants. Before ban, phthalates were used as polymer softeners in production of flexible, soft toys. Phthalates do not chemically bind to polymer, but are only incorporated into poly
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Warsito, Warsito, Masruri Masruri, Sinta Murlistyarini, Dwika Putri Pangesti, and Asyfariatus Zulfa Azhar. "Screening Multitarget Anticancer Compounds from Salicylic Acid Derivatives: (Without and with Amino Acid Linkage) by <i>In Silico</i> Docking." In International Conference on Chemistry and Material Sciences 2023 (IC2MS). Trans Tech Publications Ltd, 2024. http://dx.doi.org/10.4028/p-svkm5p.

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This research aims to design anticancer molecules using the hybridization concept based on molecular derivatives of salicylic acid. The investigation explores structures with and without linked amino acid alanine through an in-silico docking approach. The research conducts screenings of the designed salicylic acid derivative molecules against receptors, including MMP9, MMP2, CDK2, P53, BAK EGFR, and ADP Ribose Polymerase. The most promising docking results for multitarget cancer compounds were observed in salicylic acid derivatives with amino acid linkages, specifically salicylic acid-curcumin
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Mardiguian, J. "IS PENTASACCHARIDE THE SMALLEST HEPARIN OLIGOSACCHARIDE WITH BINDING AFFINITY TO ANTITHROMBIN III ? AN OVERVIEW." In XIth International Congress on Thrombosis and Haemostasis. Schattauer GmbH, 1987. http://dx.doi.org/10.1055/s-0038-1644849.

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The binding of heparin to antithrombin III is ascribed to the presence in the heparin molecule of a specific binding site which contains a typical 3-0- sulfate group located on a glucosamine residue. It has been postulated that the smallest heparin oligosaccharide capable of high affinity binding to antithrombin III and eliciting anti-factor Xa activity is a pentasaccharide containing three glucosamine units and two uronic acid residues. Such a pentasaccharide has been recently isolated after chemical depolymerization of pig mucosal heparin and its structure found to be very close to that of a
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Osada, K., S. Okazaki, S. Kimura, et al. "Optical detection of mutagenic substances using ultraweak chemiluminescence from primary culture of rat hepatocytes." In OSA Annual Meeting. Optica Publishing Group, 1987. http://dx.doi.org/10.1364/oam.1987.thpo45.

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Very weak light emission observed in the Ames test system suggests that such chemiluminescence can be used for the detection and monitoring of mutagenic substances. To explore a new potentially practicable method of detection, we measured and examined ultraweak chemiluminescence as the response of a primary culture of rat hepatocytes to specific mutagenic and nonmutagenic substances employing a highly sensitive photon counting system that has been developed recently by our group. Hepatocytes were collected from rats (Wistar, male, 6 weeks of age) using the collagenase perfusion method and cult
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T. Gonçalves, M. Sameiro, B. Rama Raju, Joana Parente, Maria P. S. Leitão, and Paulo J. G. Coutinho. "New benzo[a]phenoxazines bearing the (4,6-dichloro-1,3,5-triazin-2-yl)amino group: synthesis and photophysical properties." In The 19th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2015. http://dx.doi.org/10.3390/ecsoc-19-a012.

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Reports on the topic "Benzoyl group"

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Dudareva, Natalia, Alexander Vainstein, Eran Pichersky, and David Weiss. Integrating biochemical and genomic approaches to elucidate C6-C2 volatile production: improvement of floral scent and fruit aroma. United States Department of Agriculture, 2007. http://dx.doi.org/10.32747/2007.7696514.bard.

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The specific objectives of approved proposal include to: 1. Elucidate the C6-C2 biochemical pathways leading to the biosynthesis of phenylacetaldehyde, phenylethyl alcohol and phenylethyl acetate in floral tissues of ornamentally important plants, pefunia and roses. 2. Isolate and characterrze genes responsible for the production of these C6-C2 compounds and those involved in the regulation of the pathway using genomic and transcriptomic tools. 3. Determine whether altering the expression of key genes of this pathway can result in changing the aroma characteristics of flowers. Aldehydes are in
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