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Dissertations / Theses on the topic 'Benzoyl'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Dias, Fernando Lino. "Desenvolvimento e validação de método indicador de estabilidade de formulações farmacêuticas de uso tópico contendo peróxido de benzoíla." Universidade de São Paulo, 2014. http://www.teses.usp.br/teses/disponiveis/9/9139/tde-24032014-112539/.

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O peróxido de benzoíla, produto de interação do peróxido de sódio com cloreto de benzoíla, é um poderoso agente antibacteriano de amplo espectro com ação queratolítica, comedolítica, descamativa, antipruriginosa e desengordurante, além de também ser um potente agente oxidante, que reage com materiais orgânicos rompendo as membranas celulares de inúmeros agentes patogênicos. Em virtude de suas características, o peróxido de benzoíla é utilizado como produto de eleição como adjuvante no tratamento de sarnas (dermodicidoses), desqueratinizações, complexo seborréico, piodermites, foliculites super

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2

Williamson, Brian Leslie. "Structural studies using chemical ionisation ion trap mass spectrometry." Thesis, Nottingham Trent University, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.294164.

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3

West, Sarah Kate. "Selective chemical ionization in an ion trap mass spectrometer." Thesis, Nottingham Trent University, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.310855.

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4

Ahmad, F. B. H. "Synthesis and reactions of benzoyl-1,4-benzoquinones : an approach to anthracyclinones." Thesis, University of Manchester, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376238.

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5

Wathen, Steven Patrick. "The effect of metal ions on the hydrolysis of acyl hydroxylamines and the effect of Cu(II) on the hydrolysis of N-benzoyl iminodiacetic acid and N-benzoyl sarcosine /." The Ohio State University, 1992. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487777170406684.

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6

Rather, Liv Juliane [Verfasser], and Georg [Akademischer Betreuer] Fuchs. "Structure and mechanism of benzoyl-CoA epoxidase BoxAB from Azoarcus evansii : : an elegant strategy to break the aromatic ring = Struktur und Mechanismus der Benzoyl-CoA Epoxidase BoxAB aus Azoarcus evansii." Freiburg : Universität, 2011. http://d-nb.info/1123459215/34.

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7

Creswick, Heather Alison. "The Oxidation of beta-Cyclodextrin Via the Photolysis of 6-beta-Cyclodextrin Benzoyl Formate." W&M ScholarWorks, 1993. https://scholarworks.wm.edu/etd/1539625808.

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8

Williams, Daniel MacDougall. "The Synthesis of 5-Benzoyl-1,3-benzendediacids for the Double-Capping of beta-Cyclodextrin." W&M ScholarWorks, 1994. https://scholarworks.wm.edu/etd/1539625881.

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9

Huwiler, Simona G. [Verfasser], and Matthias [Akademischer Betreuer] Boll. "Structure and function of the tungsten-containing active site of class II benzoyl-CoA reductases." Freiburg : Universität, 2015. http://d-nb.info/1140735284/34.

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10

Sahu, Bindia, Jaya Prakash Alla, Gladstone Christopher Jayakumar, Kalarical Janardhanan Sreeram, and Jonnalagadda Raghava Rao. "Optimization of chamois oxidation process of leather using benzoyl per oxide as oxidizing agent - 70." Verein für Gerberei-Chemie und -Technik e. V, 2019. https://slub.qucosa.de/id/qucosa%3A34255.

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Content: Chamois leathers are basically oil tanned leathers, usually requires 10 to 15 days to process from raw skins. In chamois making, air oxidation plays a major role, free radicals initiate the oxidation process in oil, which oxidizes the double bond of the fatty acid and then the oxidized oil interacts with collagen to stabilize the skin by coating the fibers (Fig 1). In the present study an attempt has been made to reduce the time for chamois leather processing. A common oxidizing agent (Benzoyl peroxide (BPO) was utilized to enhance the oxidation of oil and reduce the time duration. It

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11

MESSAOUDI, ABDELKADER. "Extraction liquide-liquide du strontium par le 3-phenyl-4-benzoyl-5-hydroxy-isoxazole. Synergies." Université Louis Pasteur (Strasbourg) (1971-2008), 1993. http://www.theses.fr/1993STR13112.

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La methode de preparation du 3-phenyl-4-benzoyl-5-hydroxy-isoxazole (hpbi) a ete optimisee. Les mesures de constante d'acidite en systeme liquide-liquide ont montre que hpbi est un acide relativement fort compare au 1-phenyl-3-methyl-4-benzoyl-5-hydroxy-pyrazole (hpmbp) ou aux -dicetones. L'etude de l'extraction synergique de sr#2#+, ba#2#+, mg#2#+ et de cs#+ par des melanges de hpbi et d'ethers-couronnes (e), de sels d'ammonium (b#+, x#), et d'oxyde de tri-n-octylphosphine (topo) dans le chloroforme et le toluene, montrent que l'echange proton-metal est operant des ph 2. Avec les ethers-couro

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12

Keller, Christopher. "Photolysis of 1-(4-azidomethyl-phenyl)-ethanone and matrix/LFP studies of 2-benzoyl-3-methyl-2H-azirine." University of Cincinnati / OhioLINK, 2005. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1121442210.

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13

Foloppe, Marie-Paule. "Synthèse et étude physico-chimique de N-(benzoyl) prolines et de pyrrolo (2,1-c) (1,4) benzodiazépines à visée thérapeutique." Caen, 1994. http://www.theses.fr/1994CAEN4057.

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14

AIT, MANSOUR HAMID. "Recherches dans la serie des acyl-6 benzoxazolinones : metabolites de la benzoyl-6 benzoxazolinone et pharmacomodulation des derives halogenoacyles." Lille 2, 1991. http://www.theses.fr/1991LIL2T007.

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15

Shelton, Thomas Earl. "Small Phosphomonoesters as Probes of Protein-Tyrosine Phosphatase Active Sites." Thesis, Virginia Tech, 1999. http://hdl.handle.net/10919/44898.

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I evaluated the potential of isomers of the low molecular weight phosphomonoester naphthyl phosphate as general diagnostic substrates for differentiating between two families of protein phosphatases: the protein-tyrosine phosphatases [PTPs] and the dual-specificity protein phosphatases [DSPs]. Three PTPs, PTP-1B, Tc-PTPa, and PTP-H1, and three DSPs, Cdc-14, VHR, and IphP, were challenged in vitro with alpha-naphthyl phosphate and beta-naphthyl phosphate. Both the DSPs and PTPs readily hydrolyzed beta-naphthyl phosphate. As expected, the DSPs also hydrolyzed alpha-naphthyl phosphate at rates

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16

Paisner, Kathryn A. 1983. "Crystal Engineering with Thioureas: A Structure-Based Inquiry." Thesis, University of Oregon, 2011. http://hdl.handle.net/1794/11583.

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xviii, 724 p. : ill. (some col.)<br>Structural trends applicable to crystal engineering were studied in three classes of thiourea-based compounds. The aim of the study was to identify, predict, and ultimately design reliable single-molecule structural features, which could then be used to engineer crystals with desirable properties. In one class of compounds, this goal was achieved: N-alkyl and N-aryl derivatives of N,N'-bis(3-thioureidopropyl)piperazine adopted an identical conformation in the solid state, which resulted in near-identical crystal packing. A second class of closely related com

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17

Bruce, Jocelyn Catherine. "Use of the N,N-dialkyl-N’-benzoyl(thio)selenoureas as single source precursors for the synthesis of semiconducting quantum dots." Thesis, Stellenbosch : Stellenbosch University, 2008. http://hdl.handle.net/10019.1/1205.

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Thesis (PhD (Chemistry and Polymer Science))--Stellenbosch University, 2008.<br>The successful preparation and structural characterization of a number of N,N-dialkyl-N’-benzoyl(thio)selenourea ligands is described; where the intermolecular interactions are characterized by the presence of Resonance Assisted Hydrogen Bonding (RAHB), π- π interactions between neighbouring benzene residues only being evident amongst the longer alkyl chain derivatives. The first structural characterization of an asymmetrically substituted N,N-dialkyl- N’-benzoylselenourea ligand reveals an increased stability

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18

Lespinasse, Anne-Dominique. "Voies d’accès à des dérives aminés du D-fructofuranose et du D-psicofuranose." Lyon, INSA, 1985. http://www.theses.fr/1985ISAL0057.

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Nos travaux s'inscrivent dans le domaine de la chimie des cétohexoses et en particulier de deux d'entre eux : le D-fructose et le D-psicose. En vue de l'évaluation des potentialités biologiques de ces oses, nous avons d'abord étudié les voies'd'accès à des nucléosides dérivés du D-fructofuranose puis la synthèse de composés aminés issus de cet ose et du D-psicofuranose. Cette approche nous a amené à mettre au point la préparation d'un dérivé du D-psicofuranose comportant une différenciation au niveau de ses deux hydroxyméthyles. Ce composé devrait permettre de résoudre certains problèmes synth

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19

Murthy, Rajesh S. "Effects of Chemical Environment on the Photochemical Behavior of Alkoxy Carbonyl Azides and 2-benzoyl-3-methyl-2H-Azirine." Cincinnati, Ohio University of Cincinnati, 2007. http://www.ohiolink.edu/etd/view.cgi?ucin1175296082.

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Thesis (Ph.D.)--University of Cincinnati, 2007.<br>Title from electronic thesis title page (viewed July 24, 2007). Includes abstract. Keywords: azide; nitrene; azirine; photolysis; argon matrix Includes bibliographical references.

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20

Shreepathi, Subrahmanya. "Dodecylbenzenesulfonic Acid: A Surfactant and Dopant for the Synthesis of Processable Polyaniline and its Copolymers." Doctoral thesis, Universitätsbibliothek Chemnitz, 2006. http://nbn-resolving.de/urn:nbn:de:swb:ch1-200602029.

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Das Ziel der vorliegenden Arbeit ist die bessere Verarbeitung von Polyanilin (PANI), da dies bisher ein großer Nachteil unter leitfähigen Polymeren war. Dazu wird ein sperriges Tensid und Dotand, Dodecylbenzensulfonsäure (DBSA) verwendet. Zur Synthese der PANI kommen zwei verschiedene Methoden zur Anwendung, die in dieser Dissertation in zwei Kapiteln beschrieben werden. Im ersten Teil wurden in einem kleinen Reaktionsvolumen (250 mL) PANI-DBSA-Suspensionen synthetisiert, wobei mit einem binären Gemisch aus 2-Propanol und Wasser als Lösungsmittel gearbeitet wird um die Löslichkeit zu unterstüt

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21

LUBENOVA, ANTOANETA. "Etude physico-chimique et structurale de la complexation des ions du zn(ii), ca(ii) et mg(ii) par l'agent chelateur salicylaldehyde benzoyl hydrazone." Paris 7, 1997. http://www.theses.fr/1997PA077248.

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La premiere partie de la these constitue une introduction a la chimie de coordination des hydrazones a partir d'une classification generale des hydrazones a partir des substituants de pont hydrazone ainsi qu'une mise au point bibliographique des donnees concernant les structures de thiosemicarbazones, thioaroylhydrazones et oxyaroylhydrazones ainsi que celles de leurs complexes avec des metaux de transition 3d. La seconde partie du memoire concerne l'etude physico-chimique de la complexation du salicylaldehyde benzoyl hydrazone (sbh) avec les ions zn(ii), ca(ii) et mg(ii) et l'etude structural

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22

CHAOUI, ROQUAI M'HAMMED. "Extraction d'indium (iii) en milieu chlorure par le 3-phenyl-4-benzoyl-5-hydroxy-isoxazole. Synergies. Comparaisons avec les 4-acyl-5-hydroxy-pyrazoles." Université Louis Pasteur (Strasbourg) (1971-2008), 1995. http://www.theses.fr/1995STR13134.

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Ce travail traite de l'extraction d'indium (iii) a partir du milieu chlorure par le 3-phenyl-4-benzoyl-5-hydroxy-isoxazole (hpbi) associe a des agents de synergie tels l'oxyde de tri-n-octylphosphine (topo) ou le chlorure de tri-n-octylammonium (tomacl). Une interaction forte entre hpbi et topo a ete mise en evidence par differentes techniques spectroscopiques (rmn du #1h, #1#3c, #3#1p, ir et uv). Les formes tautomeres de hpbi dans les divers solvants d'extraction ont ete determinees. Dans les extractions synergiques, des especes mixtes ont ete mises en evidence: incl#x(pbi)#3#-#x(topo)#2 (x =

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23

Sumoreeah, Ravi Leckman. "Studies towards the total synthesis of galanthamine and the total synthesis of 2-Benzoyl-9-azabicyclo[4.2.1]non-2-ene : phenyl analogue of (#+-#)Anatoxin-a." Thesis, University of Sussex, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.289225.

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This thesisd escribess yntheticw ork carriedo ut on two separatep rojects. (i) Synthetics tudiest owardst he total synthesiso f galanthamine (ii) The total synthesis of 2-Benzoyl-9-azabicyclo[4.2.1 ]non-2-ene Galanthamine is an amaryllidaceae alkaloid processing a rigid tetracyclic structure with a fused dihydrobenzofuran onto a cyclohexenol and a bridging tertiary amine. 2-Benzoyl-9-azabicyclo[4.2.1]non-2-ene is an analogue of anatoxin-a, whereby the acetyl side chain has been substituted with a benzoyl group. Anatoxin-a itself possesses a 9-azabicyclo[4.2.1]nonane framework. Although structu

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24

Yeung, Kai Tai. "Molecular simulations of the enantioseparating mechanism of polysaccharide-based chiral stationary phase and enzymatic acylation of N-benzoyl-L-arginine ethyl ester in binary aquo-organic solvent mixtures." HKBU Institutional Repository, 2007. http://repository.hkbu.edu.hk/etd_ra/819.

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25

Clément, Martin. "Identification des déterminants moléculaires de la liaison et de l'activation du récepteur AT[indice inférieur 1] de l'angiotensine II." Thèse, Université de Sherbrooke, 2009. http://savoirs.usherbrooke.ca/handle/11143/4312.

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Les récepteurs couplés aux protéines G (GPCR) sont formés de sept domaines transmembranaires. Cette famille de récepteur fait l'objet d'études qui visent à comprendre leurs fonctions, leurs interactions avec leurs ligands, les changements de conformations produits suite à cette liaison ainsi que leur mécanisme d'activation. Notre hypothèse est que le récepteur humain de l'angiotensine II de type 1 (hAT1 ) possède des déterminants moléculaires responsables de sa liaison à l'angiotensine II (AngII). Nos objectifs sont d'identifier des déterminants moléculaires responsables de sa liaison à AngII,

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26

TORKESTANI, KAMRAN. "Extraction liquide-liquide de cu(ii), zn(ii) et cd(ii) par le 3-phenyl-4-benzoyl-5-hydroxy-isoxazole en presence de nitrate de methyl tri-octylammonium ou d'oxyde de tri-octylphosphine." Université Louis Pasteur (Strasbourg) (1971-2008), 1995. http://www.theses.fr/1995STR13075.

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Les composes 3-phenyl-4-acyl-5-hydroxy-isoxazoles hpbi (acyl = benzyole) et hptbbi (acyl = para-tertbutylbenzoyle) ont ete prepares et leur comportement en systeme liquide-liquide a ete etudie: leur pk#a (1,2-1,5) plus bas que ceux de leurs homologues pyrazoles (4,0-4,5) en fait des agents d'extraction potentiels de cations metalliques (m#m#+) a partir de milieux plus acides. C'est ce que demontre l'etude de l'extraction synergique du cuivre, du zinc et du cadmium par des melanges de hpbi et de nitrate de methyl-tri-n-octylammonium (toma. No#3) ou d'oxyde de tri-n-octylphosphine (topo) dans le

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27

Büschel, Michael. "Photochemisch, elektrochemisch und konformativ schaltbare Fluoreszenzfarbstoffe Benzodithiophene, Squaraine und Polysulfanylbenzole /." [S.l.] : [s.n.], 2002. http://deposit.ddb.de/cgi-bin/dokserv?idn=965095401.

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28

Papageorgiou, Edward Andrew. "Selective hydrogenolysis of benzyl protective groups : novel methodology in the benzyl carbamate and benzyl amine series." Thesis, University of Cambridge, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.620936.

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29

Campbell, Matthew James Johnson Jeffrey Scott. "I. Mechanistic studies of a copper-catalyzed electrophilic amination of diorganozinc reagents reagents by O-benzoyl N,N-dialkylhydroxylamines II. Development of a 3-Exo-Dig cyclization for the preparation of vinylidene cyclopropanes III. Total synthesis of +-polyanthellin A." Chapel Hill, N.C. : University of North Carolina at Chapel Hill, 2009. http://dc.lib.unc.edu/u?/etd,2881.

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Thesis (Ph. D.)--University of North Carolina at Chapel Hill, 2010.<br>Title from electronic title page (viewed Jun. 23, 2010). "... in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry." Discipline: Chemistry; Department/School: Chemistry.

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30

Lin, Tai-Yuan David. "Laser-induced fluorescence spectroscopy of benzyl, methyl benzyl, and arylmethyl radicals /." The Ohio State University, 1991. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487694702784492.

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31

Adnani, Driss. "Réactivité en cycloaddition [4+2] et [3+2] du tétrafluoroborate de 2-benzoyl-1, 2-dihyfroisoquinoléine - 1 carbonitrile (composé de Reissert dérivé de l'isoquinoléine) avec quelques énones et ethers d'enol. : Étude de la régio- et de la stéréochimie des cycloadduits." Besançon, 1995. http://www.theses.fr/1995BESA2022.

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Les réactions étudiées ont mis en évidence la réactivité des cétones Alpha, Beta éthyléniques vis-à-vis du tétrafluoroborate de 2-benzoyl-1, 2-dihydroisoquinoléines-1 -carbonitrile : on observe généralement une réaction de cycloaddition [4+2] qui conduit à des dérivés substitués de pyrrole. Dans le cas de deux de ces cétones, nous avons pu mettre en évidence la réaction concurrente de cycloaddition dipolaire 1,3 qui conduit à un dérivé de la pyrrolo(2,1 -a)isoquiléine. Ceci indique que l'on a doncà faire à deux réactions concurrentes même dans le cas des alcènes alors que McEwen indiquait que

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32

Siglow, Klaus. "Hochauflösende UV-Spektroskopie von neutralen und ionischen Molekülen und Clustern Rydbergzustände und Starkeffekt /." [S.l. : s.n.], 2000. http://deposit.ddb.de/cgi-bin/dokserv?idn=962036382.

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33

Reis, Omer. "Development Of Acyl Anion Precursors And Their Applications." Phd thesis, METU, 2005. http://etd.lib.metu.edu.tr/upload/3/12605950/index.pdf.

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This thesis presents the development of new acyl anion precursors and their applications. The main concern of this thesis was to make use of acyl anion precursors in catalytic bond forming reactions. Toward this aim, previously known cyanide ion catalyzed cleavage of benzils was investigated in scope and efficiency in unsymmetrical benzoin condensation. Although benzils were proved to be useful entities as acyl anion precursors in benzoin condensation, they suffer some major drawbacks. Therefore acylphosphonates were proposed and investigated as a new generation of acyl anion precursor. They w

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34

Auberlet, Delle-Vedove Agnès. "Synthèse et étude structurale de n-benzoyl-n'-phenylurees, insecticides, en vue d'établir une relation entre la structure, la rétention dans des adsorbants modèles et le mode de dégradation. Suivi de recherches sur l'enseignement expérimental de la formulation : étude d'une famille de tensioactifs." Angers, 1995. http://www.theses.fr/1995ANGE0002.

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Dans une première partie, cinq n-benzoyl-n'-phenylurees sont synthétisées, en vue de modéliser leurs interactions avec l’environnement : rétention dans les sols, dégradation. Ces molécules sont des insecticides rémanents agissant par inhibition de la biosynthèse de la chitine. L'analyse d'extraits d'adsorbants modèles traites avec ces molécules est effectuée par chromatographie liquide haute pression en phase inverse. L'étude structurale de ces molécules est réalisée par la combinaison de diverses techniques spectroscopiques : spectrométrie de masse, spectroscopie de rayons X, RMN du proton, d

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35

Lieubray, Jean Pierre. "Toxicologie du péroxyde de benzoyle." Paris 5, 1988. http://www.theses.fr/1988PA05P013.

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36

Schepers, Claudia. "Molekulardynamische Simulationen von Sorptions- und Diffusionsvorgängen in Pervaporationsmembranen." [S.l.] : [s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=962852910.

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37

Orschel, Matthias. "Konventionelle und kombinatorische Suche nach neuen Katalysatoren für die selektive Oxidation von Benzol zu Phenol." [S.l. : s.n.], 2000. http://deposit.ddb.de/cgi-bin/dokserv?idn=962794902.

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38

Gillooly, David John. "Benzyl alcohol dehydrogenase from Acinetobacter calcoaceticus." Thesis, University of Glasgow, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.309385.

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39

Okruss, Michael. "Rotationsstruktur- und Starkeffektuntersuchungen an ausgewählten aromatischen Molekülen im Überschalldüsenstrahl mittels hochauflösender UV-Laserspektroskopie." [S.l.] : [s.n.], 2005. http://deposit.ddb.de/cgi-bin/dokserv?idn=975744690.

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40

Schäfer, Martina. "Untersuchungen zum Abbau chlorierter Benzole durch Mischkulturen in kontinuierlich betriebenen Reaktoren /." Berlin : TU, FG Siedlungswasserwirtschaft, Sekr. KF 7, 1994. http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=007288332&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA.

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41

Clara, Martin. "Relaxationsdynamik und Ladungstransfer in isolierten molekularen Systemen Experimente in der Zeit- und Frequenzdomäne /." [S.l. : s.n.], 2000. http://deposit.ddb.de/cgi-bin/dokserv?idn=962024287.

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42

Casajus, Hubert. "Étude de la polymérisation enzymatique de la malolactonates en présence de lipases." Thesis, Rennes 1, 2017. http://www.theses.fr/2017REN1S090/document.

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Les polyesters aliphatiques, comme le poly(acide malique) et ses dérivés, sont une famille de polymères aux propriétés de bio(comptabilité) et de bio(dégradabilité) remarquables, qui en font des candidats de choix pour l'élaboration de systèmes de vectorisation de principes actifs. Généralement, ces polymères sont synthétisés via des réactions de polymérisation utilisant des amorceurs, voir des catalyseurs, organiques, organométalliques ou métalliques. La présence de ces molécules, même à l'état de traces, peut être à l'origine d'une toxicité non souhaitée. Par conséquent, l'utilisation de bio

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43

Faven, Catherine. "Mise en évidence et dosage du peroxyde de benzoyle par chimiluminescence." Lille 1, 1992. http://www.theses.fr/1992LIL10053.

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Le travail présenté porte sur les réactions chimiluminescentes du peroxyde de benzoyle, en vue d'un dosage de ce dernier. Dans un premier temps, nous avons montré que la réaction de ce peroxyde avec la triéthylamine est chimiluminescente et que la luminescence est proportionnelle à la concentration des réactifs. Le spectre de chimiluminescence a été enregistré et les produits de la réaction identifiés par R. M. N. Par la suite, la réaction a été étendue à d'autres dérivés azotés. La comparaison des résultats obtenus a permis une optimisation des réactifs mis en jeu lors du dosage. Finalement,

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44

Fruteau, de Laclos Anne-Marie F. (Anne-Marie François). "Cleavage of benzyl aryl ethers by chlorine." Thesis, McGill University, 1991. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=70291.

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In order to extend application of the gel-degradation mechanism of delignification, model compounds of the general structure (3,4-dimethoxyphenyl)-CH(OR)R$ sp prime$ were treated at room temperature with increasing charges of molecular Cl$ sb2$ in glacial HOAc.<br>Catalytic amounts of Cl$ sb2$ cleaved benzyl aryl ether bonds (OR=2-methoxy-4-methylphenoxy) before any ring chlorination occurred. Yields of cleavage decreased in the order: R$ sp prime$=H; R$ sp prime$=$-$CH$ sb2$-2-methoxyphenoxy; R$ sp prime$=$-$CH(CH$ sb2$OH)-2-methoxyphenoxy. These results support the concept that the delignifi

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45

Arya, Nlin. "Modulation of carcinogen metabolism by benzyl isothiocyanate." Thesis, University of Surrey, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.494202.

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Precision-cut rat liver slices were incubated with various concentrations of benzyl isothiocyanate (BITC) (0-25 μM) for 24 hours. BITC decreased the dealkylation of ethoxy-(EROD) and methoxyresomfin (MROD) but increased CYP1A1/2 apoprotein levels; in vitro studies confirmed that it is mechanism-based inhibitor. BITC decreased both dealkylation of pentoxyresorufin (PROD) and CYP2B1 apoprotein levels but there was no effect on 7-benzyloxyquinoline (7-BQ) metabolism and CYP3A apoprotein levels. In the case of Phase II enzyme systems, BITC increased epoxide hydrolase and GST activity and a similar

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46

Ross, Jennifer Nicola. "Alkoxy- substituted aryl- and benzyl- organotin compounds." Thesis, University of Aberdeen, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.324880.

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New organotin compounds containing alkoxy- functionalities have been prepared. The methods of preparation of the tetraorganotin species have involved three routes. Hydrostannation reactions using triphenyltin hydride have resulted in the synthesis of triphenyltin derivatives of a series of alkoxy- substituted allyl ethers. The addition of tin IV chloride, diphenyltin dichloride and phenyltin trichloride to alkoxy- substituted aryl- and benzyl- Grignard reagents have also been successful. Alkoxy- substituted benzyltin compounds have been prepared by following an alternative preparation of benzy

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47

Greenhalgh, Richard P. "Diasteroselective Wittig rearrangements." Thesis, University of Kent, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.359407.

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Wilson, F. I. C. "Reactions of some dinuclear transition metal complexes." Thesis, Kingston University, 1988. http://eprints.kingston.ac.uk/20522/.

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The work in this thesis consists of three related studies. (i) Further investigations have been made into the mechanism of the photochemical reaction between (Mn[sub]2(CO)[sub]8{PBu[sub]3}[sub]2) and benzyl halides, equation 1. A previous study in these laboratories, which included an (Mn[sub]2(CO)[sub]8{PBu[sub]3}[sub]2) + PhCH[sub]2Cl -->(MnCl(CO)[sub]4PBu[sub]3) + (Mn(PhCH[sub]2)(CO)[sub]4PBu[sub]3) 1 examination of reaction kinetics, led to the suggestion that the mechanism involved CO dissociation from the manganese dimer, followed by metal-metal bond homolysis and subsequent reaction of

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49

Prochnow, Thaís. "Ciclização intramolecular do 1-benzil-2-alquinilbenzeno promovida por FeCl3 e dicalcogeneto de diorganoíla: síntese dos 9-(organocalcogênio)-5H-benzo[7]anulenos." Universidade Federal de Santa Maria, 2016. http://repositorio.ufsm.br/handle/1/10614.

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In the present work, a series of 1-benzyl-2-alkylbenzenes functionalized was subjected to intramolecular cyclization reaction promoted by iron(III) chloride with diorganyl dichalcogenide allowed the synthesis of 9-(organochalcogen)-5H-benzo[7]annulenes whereas the mutual action between diorganyl dichalcogenide and iron(III) chloride in a 0.5:1.0 mole ratio was essential in order to achieve the maximal yields of the products. The cyclization reaction tolerated a variety of functional groups, such as trifluoromethyl, chloro, fluorine and methoxyl, in both 1-benzyl-2-alkynylbenzenes and diorganyl

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Cerda, Cavieres Christopher David. "Síntesis de Derivados N-Benzoil-2-(2-Nitrofenil)-1-Hbenzimidazoles. Desarrollo de Metodologías Analíticas y Caracterización Fisicoquímica de N-(p-Flúor)-Benzoil-2-(2-Nitrofenil)-Benzimidazol y N-(p-Nitro)-Benzoil -2-(2 Nitrofenil)-Benzimidazol." Tesis, Universidad de Chile, 2008. http://repositorio.uchile.cl/handle/2250/105700.

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La presente Memoria se orientó al estudio y caracterización electro-analítica de una serie de derivados N-(4-R-benzoil)-2-(2-nitrofenil)-1-H-benzimidazoles como sustratos de interés biológico. Los compuestos estudiados fueron sintetizados a partir de 2-(o-nitrofenil)-benzimidazol, generado por condensación entre 1,2-diamino-benceno y 2-nitrobenzaldehído. Posterior reacción del benzimidazol con una serie de cloruros de aroílo, generó la serie de cuatro N-(4-R-benzoil)-2-(2-nitrofenil)-1-H-benzimidazoles en buen rendimiento (R = NO2, Cl, F), con la excepción del producto denominado PMNB (R =

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