Academic literature on the topic 'Benzyl chloride'

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Journal articles on the topic "Benzyl chloride"

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Krečmerová, Marcela, Hubert Hřebabecký, and Antonín Holý. "Preparation of 5-Benzyluracil and 5-Benzylcytosine Nucleosides as Potential Inhibitors of Uridine Phosphorylase." Collection of Czechoslovak Chemical Communications 61, no. 4 (1996): 627–44. http://dx.doi.org/10.1135/cccc19960627.

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Reaction of 3,4,6-tri-O-acetyl-2-deoxyglucopyranosyl bromide (1) with silylated 5-benzyluracil and subsequent ammonolysis afforded α- and β-anomers of 5-benzyl-1-(2-deoxy-D-glucopyranosyl)uracil (2 and 3). Under catalysis with tin tetrachloride, silylated 5-benzyluracil reacted with 1-O-acetyl-2,3,5-tri-O-benzoyl-D-ribofuranose to give 2',3',5'-tri-O-benzoyl-5-benzyluridine (10), which was converted into the 4-thio derivative 11 by reaction with Lawesson reagent. Debenzoylation of compound 11 afforded 5-benzyl-4-thiouridine (12), whereas its reaction with methyl iodide and deblocking gave 4-me
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Kurz, Thomas, Detlef Geffken, and Claudia Wackendorff. "Carboxylic Acid Analogues of Fosmidomycin." Zeitschrift für Naturforschung B 58, no. 5 (2003): 457–61. http://dx.doi.org/10.1515/znb-2003-0517.

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N-Alkylation of N-Boc-O-benzylhydroxylamine (1) with benzyl 4-bromobutyrate (2) in DMF gave N,O-bisprotected benzyl 4-hydroxyamino-butyrate (3), which was converted into 4-benzyloxyamino-butyric acid benzyl ester (4) with TFA in methylene chloride. Treatment of 4 with formic acid/acetic anhydride or various acid chlorides followed by catalytic hydrogenation led to 4-(N-acyl-N-hydroxyamino)-butyric acids 6.
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Journal, Baghdad Science. "Synthesis , characterization and biological activity study of N-substituted sulfonamido maleimides substituted with different heterocycles." Baghdad Science Journal 7, no. 1 (2010): 641–53. http://dx.doi.org/10.21123/bsj.7.1.641-653.

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Eighteen new cyclic imides (maleimides) conncted to benzothiazole moiety through sulfonamide group were synthesized via multistep synthesis.The first step involved preparation of two maleamic acids N-phenylmaleamic acid and N-benzylmaleamic acid via reaction of maleic anhydride with aniline or benzyl amine.Dehydration of the prepared amic acids by treatment with acetic anhydride and anhydrous sodium acetate in the second step afforded N-phenylmaleimide and N- benzyl maleimide which in turn were treated with chlorosulfonic acid in the third step to afford 4-(N-maleimidyl) phenyl sulfonyl chlori
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Dutkiewicz, Grzegorz, B. P. Siddaraju, H. S. Yathirajan, A. N. Mayekar, and Maciej Kubicki. "Valyl benzyl ester chloride." Acta Crystallographica Section E Structure Reports Online 66, no. 2 (2010): o324. http://dx.doi.org/10.1107/s1600536810000176.

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Kim, Sung Soo, Yu Zhu, In Seok Oh, and Chang Gyeong Lim. "Reactions of benzyl methyl substituted-benzyl phosphites with tert-butyl hypochlorite: "balanced TS" validating reactivity/selectivity principle." Canadian Journal of Chemistry 76, no. 6 (1998): 836–42. http://dx.doi.org/10.1139/v98-081.

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Reactions of a series of several benzyl methyl substituted-benzyl phosphites with tert-butyl hypochlorite were investigated. The reactions produced phosphates, isobutene, alkyl chlorides, and benzyl chlorides via phosphonium chlorides as intermediates. Furthermore, the phosphates bearing a tert-butyl group underwent fragmentation to yield isobutene and another phosphates. Relative rates of formations of substituted benzyl and benzyl chloride (kY/kH) were measured at the temperatures (-20, 0, 20, 40°C). Logarithms of the rates (log kY/kH) were plotted against sigma + and 1/T, respectively. The
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Bijudas, K., and P. Bashpa. "Selective Oxidation of Benzyl Halides to Benzaldehydes by Phase Transfer Catalyzed Monochromate Ions in Non-Polar Solvents." Asian Journal of Organic & Medicinal Chemistry 5, no. 3 (2020): 249–53. http://dx.doi.org/10.14233/ajomc.2020.ajomc-p287.

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Benzyl chloride, benzyl bromide and their para substituted derivatives were selectively oxidized to corresponding benzaldehydes by acidified monochromate in toluene and ethyl acetate with the help of phase transfer catalysts like tetrabutylphosphonium bromide (TBPB), tetrabutylammonium bromide (TBAB), tetrabutylammonium hydrogen sulphate (TBAHS), cetyltrimethylammonium bromide (CTMAB) and tricaprylmethylammonium chloride (TCMC). The reaction was carried out by simple magnetic stirring for about 2 h at 60 ºC. The products were recrystallized and analyzed by infrared and UV-visible spectral tech
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Sarzyński, Dariusz S., and Irena Majerz. "Chemical Transformations of Benzyl Alcohol Caused by Atomic Chlorine." Molecules 29, no. 13 (2024): 3124. http://dx.doi.org/10.3390/molecules29133124.

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Atomic chlorine present in the polluted troposphere can form potentially carcinogenic compounds as a result of a reaction with a natural product. This paper examines the stability of benzyl alcohol—a natural product commonly found in cosmetics—in interaction with atomic chlorine, which is becoming ever more present in the Earth’s atmosphere as a result of its pollution. Research shows that atomic chlorine generated in the gas phase easily penetrates the liquid phase of benzyl alcohol, resulting in the formation of hydrochloric acid. The resulting HCl initiates further transformations of benzyl
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Kurian, Manju, and S. Sugunan. "Single Pot Benzylation of O-Xylene with Benzyl Chloride and Benzyl Alcohol Over Pillared Montmorillonites." Polish Journal of Chemical Technology 16, no. 3 (2014): 69–73. http://dx.doi.org/10.2478/pjct-2014-0053.

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Abstract Improvement of product selectivity is a major concern of the day. Presence of a coreactant can alter the rate as well as product selectivity of many key reactions like Friedel-Crafts benzylation. Single pot benzylation of o-xylene with benzyl chloride and benzyl alcohol was studied over transition metal exchanged pillared clay catalysts. Complete conversion of benzyl alcohol occured within one hour with 100% monoalkylated product selectivity. The reaction of o-xylene with benzyl alcohol was found to proceed fast in presence of benzyl chloride in single pot, than when present alone as
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Magnier, Emmanuel, and Claude Wakselman. "A Mild and Practical Preparation of Trifluoromethaneselenenyl Chloride." Collection of Czechoslovak Chemical Communications 67, no. 9 (2002): 1262–66. http://dx.doi.org/10.1135/cccc20021262.

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Trifluoromethaneselenenyl chloride is prepared by a two-step procedure with an 85% overall yield. Benzyl trifluoromethyl selenide is formed from dibenzyl diselenide and trifluoromethyl iodide in the presence of sodium hydroxymethanesulfinate. The benzyl-selenium bond is then cleaved with sulfuryl chloride to give the corresponding selenenyl chloride.
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Bian, Yan-Jiang. "N-Benzyl-N-methylmorpholinium chloride." Acta Crystallographica Section E Structure Reports Online 65, no. 1 (2008): o38. http://dx.doi.org/10.1107/s1600536808040506.

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Dissertations / Theses on the topic "Benzyl chloride"

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Wilson, F. I. C. "Reactions of some dinuclear transition metal complexes." Thesis, Kingston University, 1988. http://eprints.kingston.ac.uk/20522/.

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The work in this thesis consists of three related studies. (i) Further investigations have been made into the mechanism of the photochemical reaction between (Mn[sub]2(CO)[sub]8{PBu[sub]3}[sub]2) and benzyl halides, equation 1. A previous study in these laboratories, which included an (Mn[sub]2(CO)[sub]8{PBu[sub]3}[sub]2) + PhCH[sub]2Cl -->(MnCl(CO)[sub]4PBu[sub]3) + (Mn(PhCH[sub]2)(CO)[sub]4PBu[sub]3) 1 examination of reaction kinetics, led to the suggestion that the mechanism involved CO dissociation from the manganese dimer, followed by metal-metal bond homolysis and subsequent reaction of
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Yang, Jeongwoo. "Fate and effect of alkyl benzyl dimethyl ammonium chloride in mixed aerobic and nitrifying cultures." Thesis, Atlanta, Ga. : Georgia Institute of Technology, 2007. http://hdl.handle.net/1853/19871.

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Thesis (M. S.)--Civil and Environmental Engineering, Georgia Institute of Technology, 2008.<br>Committee Chair: Spyros G. Pavlostathis; Committee Member: Ching-Hua Huang; Committee Member: John A. Pierson.
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Aricci, G. "ELECTROCHEMICAL TECHNOLOGIES: ADVANCED ELECTRODE MATERIALS FOR ENVIRONMENTAL APPLICATION." Doctoral thesis, Università degli Studi di Milano, 2010. http://hdl.handle.net/2434/150133.

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An investigation on a new class on electrocatalytic materials for the electroreduction of organic halides is presented and discussed. The electrocatalysts are based on silver nanoparticles (Ag_NP and Ag_NC), ad hoc synthesised by two different synthetic path (Polyol assisted and Wet chemical reduction). The obtained nanoparticles are then supported on carbon black (pre-treated or untreated) (20% or 10% loading) for further characterisation and use. The electrocatalytic properties of the Ag_NP/carbon and Ag_NC/carbon composites towards the dehalogenation of halocompounds are tested by cyclic
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Fruteau, de Laclos Anne-Marie F. (Anne-Marie François). "Cleavage of benzyl aryl ethers by chlorine." Thesis, McGill University, 1991. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=70291.

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In order to extend application of the gel-degradation mechanism of delignification, model compounds of the general structure (3,4-dimethoxyphenyl)-CH(OR)R$ sp prime$ were treated at room temperature with increasing charges of molecular Cl$ sb2$ in glacial HOAc.<br>Catalytic amounts of Cl$ sb2$ cleaved benzyl aryl ether bonds (OR=2-methoxy-4-methylphenoxy) before any ring chlorination occurred. Yields of cleavage decreased in the order: R$ sp prime$=H; R$ sp prime$=$-$CH$ sb2$-2-methoxyphenoxy; R$ sp prime$=$-$CH(CH$ sb2$OH)-2-methoxyphenoxy. These results support the concept that the delignifi
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Lima, Camila Diana. "S?ntese de ?steres met?licos de ?cidos graxos (biodiesel) e de ?steres benz?licos por rea??o qu?mica com catalisadores heterog?neos baseados em NbCl5 e SiO2-Nb." UFVJM, 2017. http://acervo.ufvjm.edu.br/jspui/handle/1/1370.

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Submitted by Jos? Henrique Henrique (jose.neves@ufvjm.edu.br) on 2017-06-02T20:34:08Z No. of bitstreams: 2 camila_diana_lima.pdf: 4383425 bytes, checksum: a00aa24c475acb8858df11e235a0c29c (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5)<br>Approved for entry into archive by Rodrigo Martins Cruz (rodrigo.cruz@ufvjm.edu.br) on 2017-06-14T19:40:25Z (GMT) No. of bitstreams: 2 camila_diana_lima.pdf: 4383425 bytes, checksum: a00aa24c475acb8858df11e235a0c29c (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5)<br>Made available in DSpace on 201
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Metzger, Albrecht. "Preparation and Applications of Benzylic Zinc Chlorides." Diss., lmu, 2010. http://nbn-resolving.de/urn:nbn:de:bvb:19-115740.

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Abubaker, Mohamed. "Heterogen katalysierte Gasphasen-Alkylierung von Benzol mit Styrol." Doctoral thesis, [S.l. : s.n.], 2002. http://deposit.ddb.de/cgi-bin/dokserv?idn=965608867.

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CHAOUI, ROQUAI M'HAMMED. "Extraction d'indium (iii) en milieu chlorure par le 3-phenyl-4-benzoyl-5-hydroxy-isoxazole. Synergies. Comparaisons avec les 4-acyl-5-hydroxy-pyrazoles." Université Louis Pasteur (Strasbourg) (1971-2008), 1995. http://www.theses.fr/1995STR13134.

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Ce travail traite de l'extraction d'indium (iii) a partir du milieu chlorure par le 3-phenyl-4-benzoyl-5-hydroxy-isoxazole (hpbi) associe a des agents de synergie tels l'oxyde de tri-n-octylphosphine (topo) ou le chlorure de tri-n-octylammonium (tomacl). Une interaction forte entre hpbi et topo a ete mise en evidence par differentes techniques spectroscopiques (rmn du #1h, #1#3c, #3#1p, ir et uv). Les formes tautomeres de hpbi dans les divers solvants d'extraction ont ete determinees. Dans les extractions synergiques, des especes mixtes ont ete mises en evidence: incl#x(pbi)#3#-#x(topo)#2 (x =
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Quinio, Pauline Alice [Verfasser], and Paul [Akademischer Betreuer] Knochel. "New preparation of polysubstituted allenes, benzylic manganese chlorides and protected aldol products : transition metal free benzylation of unsaturated cyanides / Pauline Alice Quinio. Betreuer: Paul Knochel." München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2015. http://d-nb.info/1106854659/34.

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MacMillar, Susanna. "Isotopes as Mechanism Spies : Nucleophilic Bimolecular Substitution and Monoamine Oxidase B Catalysed Amine Oxidation Probed with Heavy Atom Kinetic Isotope Effects." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis (AUU), 2006. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-7441.

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Books on the topic "Benzyl chloride"

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Kagaku Busshitsu Hyōka Kenkyū Kikō and Shin Enerugī Sangyō Gijutsu Sōgō Kaihatsu Kikō (Japan), eds. Benjiru kurorido (betsumei enka benjiru): Benzyl chloride. Seihin Hyōka Gijutsu Kiban Kikō Kagaku Busshitsu Hyōka Kenkyū Kikō, 2009.

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Bruce, Cook. The Feasibility of measuring the rate constant and secondary [alpha]-deuterium kinetic isotope effect for the Sn2 reaction between sodium phenoxide and benzyl chloride at low concentrations of phenoxide ion. Laurentian University, 1995.

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Koerner, Terry. Using kinetic isotope effects to model the transition states for the sn2 reactions between sodium borohydride and para-substituted benzyl chlorides. Laurentian University Press, 1996.

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Book chapters on the topic "Benzyl chloride"

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Lide, David R. "Benzyl chloride." In Handbook of Organic Solvents. CRC Press, 2024. http://dx.doi.org/10.1201/9781003575191-28.

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Patnaik, Pradyot. "Benzyl Chloride." In Handbook of Environmental Analysis. CRC Press, 2017. http://dx.doi.org/10.1201/9781315151946-74.

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Bährle-Rapp, Marina. "Benzyl Triethyl Ammonium Chloride." In Springer Lexikon Kosmetik und Körperpflege. Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-71095-0_1107.

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Wohlfarth, Ch. "Viscosity of benzyl chloride." In Supplement to IV/18. Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-75486-2_244.

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Wohlfarth, Christian. "Viscosity of benzyl chloride." In Viscosity of Pure Organic Liquids and Binary Liquid Mixtures. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49218-5_244.

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Bährle-Rapp, Marina. "Cocoyl Benzyl Hydroxyethyl Imidazolinium Chloride." In Springer Lexikon Kosmetik und Körperpflege. Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-71095-0_2290.

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Wohlfarth, Christian. "Refractive index of benzyl chloride." In Optical Constants. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49236-9_269.

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Wohlfarth, Christian. "Surface tension of benzyl chloride." In Surface Tension of Pure Liquids and Binary Liquid Mixtures. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-48336-7_140.

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Bährle-Rapp, Marina. "Tall Oil Benzyl Hydroxyethyl Imidazolinium Chloride." In Springer Lexikon Kosmetik und Körperpflege. Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-71095-0_10290.

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Wohlfarth, Ch. "Viscosity of the mixture (1) benzyl chloride; (2) methoxybenzene." In Supplement to IV/18. Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-75486-2_1689.

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Conference papers on the topic "Benzyl chloride"

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Dominguez Olivo, J. M., B. Brown, and S. Nesic. "Modeling of Corrosion Mechanisms in the Presence of Quaternary Ammonium Chloride and Imidazoline Corrosion Inhibitors." In CORROSION 2016. NACE International, 2016. https://doi.org/10.5006/c2016-07406.

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Abstract The mitigation of corrosion in carbon steel pipelines due to the addition of corrosion inhibitors has traditionally been described by using adsorption isotherms. Consequently, current models of corrosion mitigation by inhibitors are based on the use of adsorption isotherms to predict surface coverage, inhibitor efficiency and ultimately the corrosion rate as a function of inhibitor concentration. However, a coverage does not properly describe the underlying electrochemical mechanisms, nor can it predict the resulting change in corrosion potential. The goal of this research is to analy
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Gulbrandsen, Egil, Rolf Nyborg, Trine Løland, and Kemal Nisancioglu. "Effect of Steel Microstructure and Composition on Inhibition of CO2 Corrosion." In CORROSION 2000. NACE International, 2000. https://doi.org/10.5006/c2000-00023.

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Abstract The effects of steel microstructure and composition on the inhibition of CO2 corrosion were studied at 25 °C, pH 5, 1 bar CO2 in 3 % NaCl solutions. Generic inhibitor compounds cocoalkyl-dimethyl-benzyl ammonium chloride (QUAT) and sodium thiosulfate (THIO) were used. Sixteen different carbon steels were tested with a blend of 40 ppm QUAT and 0.5 ppm THIO. The test specimens were precorroded for six days in the corrosive medium prior to inhibitor addition. The effect of inhibitors was assessed by electrochemical polarization tests. The inhibitor efficiency ranged from 84 to 98 %. The
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Yang, Zhen, Yefei Wang, Fengtao Zhan, et al. "Investigation of High-efficient Acidizing Inhibitors: Structure and Anti-corrosion Performance of Novel Indolizine Derivatives." In CORROSION 2019. NACE International, 2019. https://doi.org/10.5006/c2019-12744.

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Abstract The novel indolizine derivative inhibitor for acidizing shows an effective corrosion inhibition without the synergism of propargyl alcohol. The inhibitive indolizine derivatives were generated from BQC (Benzyl Quinolinium Chloride, a commonly used key compound in acidizing inhibitor) via a moderate 1,3-dipolar cycloaddition mechanism. High Resolution Mass Spectrometry (HRMS) and NMR were used to confirm the detailed chemical structure. The inhibition of two indolizine derivatives in 15 wt.% HCl for N80 steel were studied by weight loss measurement and electrochemical analysis. Without
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Barker, Richard, Joshua Owen, Richard C. Woollam, et al. "Unravelling Surfactant Partitioning: Part 1 – Fundamental Theory and Modelling of Single and Multi-component Surfactant Distribution Responses." In CONFERENCE 2024. AMPP, 2024. https://doi.org/10.5006/c2024-20882.

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Abstract The application of corrosion inhibitors are fundamental to the safe and reliable operation of carbon steel infrastructure, presenting one of the most cost effective methods of internal pipeline corrosion control when deployed correctly. Despite decades of application in the oil and gas industry, a number of gaps remain in relation to our fundamental understanding of the performance of inhibitors. This is particularly true in the context of partitioning, and more so when the system under consideration comprises multiple surfactants. Part 1 of this two-part paper provides a detailed ins
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May, Roger C., Longchun Cheng, and Feng Shao. "Second Generation, Halogen Resistant Copper Corrosion Inhibitors." In CORROSION 2002. NACE International, 2002. https://doi.org/10.5006/c2002-02413.

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Abstract Copper alloys are utilized in industrial cooling systems because of their excellent heat transfer properties. However, a corrosion inhibitor is needed to prevent equipment failures and, very importantly, to reduce the discharge of toxic copper compounds into the environment. Azoles, such as benzotriazole (BZT) and tolyltriazole (TTA), have been used for this purpose but they do not protect copper in the presence of oxidizing halogens which are commonly added to cooling systems to control microbiological activity. The halogens react with BZT and TTA and destroy their corrosion inhibiti
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Mathew, Manjusha Elizabeth, Ishak Ahmad, Sabu Thomas, Rusli Daik, and Muhammad Kassim. "Synthesis and characterization of poly (benzyl trimethyl ammonium chloride) ionic polymer." In THE 2017 UKM FST POSTGRADUATE COLLOQUIUM: Proceedings of the University Kebangsaan Malaysia, Faculty of Science and Technology 2017 Postgraduate Colloquium. Author(s), 2018. http://dx.doi.org/10.1063/1.5028023.

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Tu, Changqing, and Xinrong Wen. "Study on Spectrophotometric Determination of Trace Copper after Flotation Separation using Sodium Chloride-Ammonium Thiocyanate-Dodecyl Dimethyl Benzyl Ammonium Chloride System." In 2015 3rd International Conference on Advances in Energy and Environmental Science. Atlantis Press, 2015. http://dx.doi.org/10.2991/icaees-15.2015.110.

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Souza, Ronny F. M., Madalena C. C. Areias, Marcelo Navarro, et al. "Electrochemical dimerization of benzyl chloride on a powder cathode of silver, graphite or silver-graphite mixture." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_20137119933.

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Armstrong, Charles D., Luiza Andrade, and Renato M. DePaula. "Effect of Monovalent and Divalent Cations on the Biocidal Efficacy of Quaternary Cationic Biocides – A Salty Situation." In SPE International Conference on Oilfield Chemistry. SPE, 2025. https://doi.org/10.2118/224261-ms.

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Abstract Quaternary Cationic Biocides (ammonium and phosphonium based) are broad spectrum and fast acting. Due to their compatibility, low cost, and high effectiveness, they are often used as biocides in oil and gas operations alone and also as formulation components for multi-biocide packages. They have also found use as additives in corrosion inhibitor formulations, emulsifiers, nonemulsifiers, and even as scale inhibitors. While they tend to work well in fresh water where there is little to no salt present, they are shown to provide decreasing performance as the salt concentration increases
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Ahuja, Suresh K. "Visco-Elastic Modulus and Intercalation of Polymer Chains in Epoxy Nano-Composites." In ASME 2007 International Mechanical Engineering Congress and Exposition. ASMEDC, 2007. http://dx.doi.org/10.1115/imece2007-42503.

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Polymer nano-composites (PNC) are polymers which are reinforced with less than 5% by volume of nano-sized particles with high aspect ratios (L/h &gt; 300). Compared to conventional composites, where the reinforcement is on the order of microns, the nano-composites are reinforced on the order of a few nanometers with advantages in processing and toughness. Nano-composites of epoxy clay have been studied where epoxy is mixed at high shear rates with clay. In our method of making nano-composites, an epoxy, Diglycidyl ether of bisphenol (DGEBA) A was mixed under high shear with organically modifie
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