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Relevant bibliographies by topics / Biaryls

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Academic literature on the topic 'Biaryls'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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Journal articles on the topic "Biaryls"

1

Sengmany, Stéphane, Eric Léonel, Rima Rahil, and Erwan Le Gall. "Nickel-Catalyzed Electrochemical Reductive Homocouplings of Aryl and Heteroaryl Halides: A Useful Route to Symmetrical Biaryls." Synthesis 50, no. 01 (2017): 146–54. http://dx.doi.org/10.1055/s-0036-1589100.

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Due to their widespread presence in functional materials and pharmaceuticals, biaryls are of fundamental importance in organic chemistry. Methods for the synthesis of symmetrical biaryls generally involve both metallic reduction and transition-metal catalysis. In this work, we show that electroreduction can also constitute a very relevant way to achieve the nickel-catalyzed reductive synthesis of symmetrical biaryl compounds. Therefore, it is demonstrated that both aryl and heteroaryl halides undergo reductive coupling to furnish the corresponding symmetrical biaryls in fair to excellent yield

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2

Fujita, Takeshi, Ryo Kinoshita, Tsuyoshi Takanohashi, Naoto Suzuki, and Junji Ichikawa. "Ring-size-selective construction of fluorine-containing carbocycles via intramolecular iodoarylation of 1,1-difluoro-1-alkenes." Beilstein Journal of Organic Chemistry 13 (December 14, 2017): 2682–89. http://dx.doi.org/10.3762/bjoc.13.266.

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1,1-Difluoro-1-alkenes bearing a biaryl-2-yl group effectively underwent site-selective intramolecular iodoarylation by the appropriate cationic iodine species. Iodoarylation of 2-(2-aryl-3,3-difluoroallyl)biaryls proceeded via regioselective carbon–carbon bond formation at the carbon atoms in β-position to the fluorine substituents, thereby constructing dibenzo-fused six-membered carbocycles bearing a difluoroiodomethyl group. In contrast, 2-(3,3-difluoroallyl)biaryls underwent a similar cyclization at the α-carbon atoms to afford ring-difluorinated seven-membered carbocycles.

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3

Bringmann, Gerhard, Robert-Michael Pfeifer, Christian Rummey, Thomas Pabst, Dirk Leusser, and Dietmar Stalke. "Structural Investigation of a Configurationally Stable Seven-Membered Bridged Biaryl of Relevance for Atroposelective Biaryl Syntheses*." Zeitschrift für Naturforschung B 58, no. 2-3 (2003): 231–36. http://dx.doi.org/10.1515/znb-2003-2-305.

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The atroposelective ring opening of lactone-bridged biaryl systems is the key step in the total synthesis of a series of axially chiral biaryl natural products and useful reagents or catalysts for asymmetric synthesis. For a more in-depth understanding of the mechanism and stereochemical course of this remarkable cleavage reaction, a seven-membered ether analog of such useful biaryl lactones has been investigated structurally, both experimentally, by X-ray diffraction analysis, and by ab initio calculations (B3LYP/6-31G*). In a nearly perfect agreement, both methods show that these seven-membe

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4

Morimoto, Koji, Toshifumi Dohi, and Yasuyuki Kita. "Metal-free Oxidative Cross-Coupling Reaction of Aromatic Compounds Containing Heteroatoms." Synlett 28, no. 14 (2017): 1680–94. http://dx.doi.org/10.1055/s-0036-1588455.

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The biaryl unit containing a heteroatom is a key structure in a large number of natural products and π-conjugated organic systems. The cross-couplings can provide powerful methods for the construction of biaryls and heterobiaryls; thus the development of a new coupling method has been intensively studied by synthetic chemists. Therefore, the oxidative biaryl coupling reaction of arenes containing a heteroatom is a significantly attractive, convenient, and straightforward route to the synthesis of biaryls due to its operational simplicity avoiding the preparation of the corresponding halogenate

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5

Xiang, Kang, Shuo Zhang, Long Liu, et al. "Tunable C–H arylation and acylation of azoles with carboxylic acids by Pd/Cu cooperative catalysis." Organic Chemistry Frontiers 8, no. 11 (2021): 2543–50. http://dx.doi.org/10.1039/d1qo00380a.

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Direct C–H arylation and acylation of azoles with carboxylic acids are achieved selectively through Pd/Cu cooperative catalysis: biaryls are generated selectively with dppp as ligand, while biaryl ketones are obtained with high selectivity using dpph or Ph<sub>2</sub>PCy as ligand.

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Wu, Fengtian, Chenlong Nan, Jianwei Xie, and Mingyang Ma. "2,5-Dihydroxyterephthalic Acid Accelerated Cu(NO3)2.3H2O-Catalyzed Homocoupling Reaction of Arylboronic Acids." Letters in Organic Chemistry 17, no. 11 (2020): 877–83. http://dx.doi.org/10.2174/1570178617666200210110041.

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A catalyst system derived from commercially available Cu(NO3)2.3H2O and 2,5- dihydroxyterephthalic acid is applied to the homocoupling reaction of arylboronic acids. This transformation provides a convenient approach to symmetrical biaryls with good to excellent yields (39%- 95%), and exhibits good functional group compatibility. Furthermore, biaryl can be prepared in gram quantities in good yield.

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7

Rainier, Jon D., and Xuchen Zhao. "The Synthesis of Conjugated Bis-Aryl Vinyl Substrates and Their Photoelectrocyclization Reactions towards Phenanthrene Derivatives." Synthesis 53, no. 07 (2021): 1200–1212. http://dx.doi.org/10.1055/s-0040-1706001.

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AbstractThe photoelectrocyclization of conjugated vinyl biaryls has proven to be a valuable and efficient strategy for generating phenanthrene derivatives. Contained in this review is an overview of the mechanism for the transformation and a discussion of the reaction scope with a focus on the electrocyclization itself, rearomatization, and the application of the reaction in natural product synthesis.1 Introduction2 The Synthesis of Conjugated Vinyl Biaryls3 Mechanistic Studies4 Substrate Scope5 Applications6 Conclusions

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8

Edwards, David J., Robin G. Pritchard, and Timothy W. Wallace. "Fine-tuning of biaryl dihedral angles: structural characterization of five homologous three-atom bridged biphenyls by X-ray crystallography." Acta Crystallographica Section B Structural Science 61, no. 3 (2005): 335–45. http://dx.doi.org/10.1107/s0108768105006713.

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The homologous series of three-atom bridged biaryls comprising 5,7-dihydro-1,2,3,9,10,11-hexamethoxydibenzo[c,e]oxepine, 6,7-dihydro-1,2,3,9,10,11-hexamethoxy-6-methyl-5H-dibenzo[c,e]azepinium chloride, 5,7-dihydro-1,2,3,9,10,11-hexamethoxydibenzo[c,e]thiepine, and the 6-oxide and 6,6-dioxide derivatives of the latter have been characterized by X-ray crystal structure analysis. Within this series the endocyclic and exocyclic biaryl dihedral angles vary over 10° ranges, reflecting the changing balance of intramolecular (steric, geometric) and intermolecular (crystal packing) forces, the former

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9

Kapłon, Katarzyna, Sławomir Frynas, Barbara Mirosław, Janusz Lipkowski, and Oleg M. Demchuk. "An Efficient Asymmetric Cross-Coupling Reaction in Aqueous Media Mediated by Chiral Chelating Mono Phosphane Atropisomeric Biaryl Ligand." Catalysts 13, no. 2 (2023): 353. http://dx.doi.org/10.3390/catal13020353.

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The enantiomerically pure ligand BisNap-Phos was obtained in a straightforward sequence of reactions beginning with inexpensive starting materials under the readily affordable conditions in high overall yield. An asymmetric BisNap-Phos-palladium complex-catalyzed Suzuki–Miyaura coupling leading to axially chiral biaryl compounds was described. The reactions were carried out under mild conditions in aqueous and organic media. A series of atropisomeric biaryls were synthesized with excellent yields and high enantioselectivities (up to 86% ee). The methodology provides an efficient and practical

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10

Chotana, Ghayoor, Soneela Asghar, Tayyaba Shahzadi, et al. "Iridium-Catalyzed Regioselective Borylation of Substituted Biaryls." Synthesis 50, no. 11 (2018): 2211–20. http://dx.doi.org/10.1055/s-0036-1591968.

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Biarylboronic esters are generally prepared by directed ortho-metalation or by Miyaura borylation and hence rely on the presence of a directing group or pre-functionalization. In this paper, the preparation of biarylboronic esters by direct C–H borylation of biaryl substrates is reported. Sterically governed regioselectivities were observed in the borylation of appropriately substituted biaryls by using [Ir(OMe)(COD)]2 precatalyst and di-tert-butylbipyridyl ligand. The resulting biarylboronic esters were isolated in 38–98% yields. The synthesized biarylboronic esters were further successfully

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Dissertations / Theses on the topic "Biaryls"

1

Teeveerapanya, Sasithorn. "Novel approaches to flexible enantiomerically pure biaryls." Thesis, University of Oxford, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.442990.

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Sutton, Benjamin M. "Chiral biaryls as high-twist nematic dopants." Thesis, University of East Anglia, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.426413.

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Mochida, Kenji. "Synthetic and Photophysical Studies on Silicon-bridged Biaryls." 京都大学 (Kyoto University), 2010. http://hdl.handle.net/2433/120817.

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4

Diers, Emelyne. "Ruthenium-Catalyzed Synthesis of Biaryls through C–H Bond Functionalizations." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2013. http://hdl.handle.net/11858/00-1735-0000-0001-BC4E-F.

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Andert, William D. "Palladium Catalyzed Suzuki-Miyaura Cross-Coupling of Axially Chiral Biaryls." The Ohio State University, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=osu1367536419.

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6

Brehier, Anaïs. "Nouvelles approches vers le contrôle de la chiralité axiale de biaryles via des arynes et en l'absence de métaux de transition." Thesis, Strasbourg, 2013. http://www.theses.fr/2013STRAF025.

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Les biaryles à chiralité axiale sont des structures privilégiées qui ont un rôle important en chimie. On les trouve dans de nombreux produits naturels biologiquement actifs, en tant que ligands chiraux en catalyse asymétrique ou encore en science des matériaux. Le but est de développer une méthode permettant de contrôler la chiralité axiale de biaryles en l’absence de métaux de transition en utilisant le couplage ARYNE. Une première approche consiste en un dédoublement atropo-diastéréosélectif dans lequel l’agent de dédoublement chiral est un sulfoxyde qui est introduit en position ortho d’un

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Hobbs, Matthew David. "Synthesis of novel rare earth complexes: from prochiral biaryls to chiral oxazolylphenols." Thesis, University of Liverpool, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.490800.

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8

Xiangfei, Wu. "Efficient Asymmetric Synthesis of Axially Chiral Biaryls and Spirofuranones via Phase-Transfer-Catalyzed Reactions." 京都大学 (Kyoto University), 2016. http://hdl.handle.net/2433/215326.

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9

Bottino, Paola. "Studies on extensions of tert-amino effect: Ring-fusion to bridged biaryls and steroids." Doctoral thesis, Università di Catania, 2013. http://hdl.handle.net/10761/1349.

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Studies on extensions of tert-amino effect: Ring-fusion to bridged biaryls and steroids The term t (later tert)-amino effect was introduced by Meth-Cohn and Suschitzky to generalize the thermal isomerization of ortho-substituted tertiary anilines to benzo-fused heterocyclic systems. In type 2 reactions, an ortho-vinyl tert-aniline gives a tetrahydroquinoline via C-C bond formation between the beta-vinyl carbon and the alfa-methylene carbon of the amino group; the reaction could be extended to heterocyclic and bi- and tri-aryl analogues of anilines to obtain novel medium or larger ring syst

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10

Bonnafoux, Laurence. "Modular synthesis of new C1-biaryl ligands and application in catalyric hydrogenation and coupling reactions." Université Louis Pasteur (Strasbourg) (1971-2008), 2008. http://www.theses.fr/2008STR13237.

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Il existe un grand nombre de ligands très efficaces actuellement employés pour la catalyse d’hydrogénation (BINAP, MeO-BIPHEP) et de couplage (S-PHOS, ligands PAP). La plupart d’entre eux possède une symétrie C2. Au cours de la thèse, nous avons étudié l’influence de la symétrie C1 sur les performances catalytiques de mono- et de diphosphines possédant une structure biaryle ou hétéro aromatique/ aromatique. Nous avons également étudié l’influence de leurs propriétés stériques et électroniques. Ces structures ont, pour la plupart, été obtenues par couplage aryne suivi par des réactions d’échang

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Books on the topic "Biaryls"

1

Picard, Christine J. Synthesis of polyfluorinated biaryls. National Library of Canada, 2002.

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2

Biarnés, Joana. Joana Biarnés: Disparant amb el cor. Blume, 2017.

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3

Sanders, Christopher John. Biaryl chelate complexes for enantioselective epoxidation, aziridination and cyclopropanation of alkenes. typescript, 2000.

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4

C, Cummings E. Father Biard's relation of 1616 and Saint Sauveur. s.n., 1986.

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5

Synthesis of Biaryls. Elsevier, 2004. http://dx.doi.org/10.1016/b978-0-08-044412-3.x5000-3.

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6

Cepanec, Ivica. Synthesis of Biaryls. Elsevier Science, 2004.

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Cepanec, Ivica. Synthesis of Biaryls. Elsevier Science, 2004.

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Cepanec, Ivica. Synthesis of Biaryls. Elsevier Science & Technology Books, 2010.

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9

Maus, Michael. Photoinduced Intramolecular Charge Transfer in Donor-Acceptor Biaryls and Resulting Applicational Aspects Regarding Fluorescent Probes and Solar Energy Conversion. Dissertation.com, 1998.

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10

Florensa, Joana Biarnés. Joana Biarnés. Art Blume, S.L., 2018.

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Book chapters on the topic "Biaryls"

1

Shahzad, Sohail Anjum. "The Synthesis of Naphthalenes and Biaryls." In Springer Theses. Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-642-33173-2_3.

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2

Davies, A. G. "17.6.3 Radical cations of biphenyls and higher biaryls." In Phosphorus-Centered Radicals, Radicals Centered on Other Heteroatoms, Organic Radical Ions. Part 2. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-87641-0_32.

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3

Nag, Ahindra. "Asymmetric Synthesis of Biaryls and Axially Chiral Natural Products." In Asymmetric Synthesis of Drugs and Natural Products. CRC Press, 2018. http://dx.doi.org/10.9774/gleaf.9781315302317-9.

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4

Adachi, Yohei, and Joji Ohshita. "Si-, Ge-, and Sn-Bridged Biaryls as π-Conjugated Element Blocks." In New Polymeric Materials Based on Element-Blocks. Springer Singapore, 2018. http://dx.doi.org/10.1007/978-981-13-2889-3_2.

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5

Uemura, Motokazu. "Stereoselective Synthesis of Axially Chiral Biaryls Utilizing Planar Chiral (Arene)chromium Complexes." In Selective Reactions of Metal-Activated Molecules. Springer Berlin Heidelberg, 1998. http://dx.doi.org/10.1007/978-3-662-00975-8_18.

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6

Bringmann, Gerhard, and Stefan Tasler. "The Atropisomer-Selective Synthesis of Biologically Active and Synthetically Useful Chiral Biaryls." In Current Trends in Organic Synthesis. Springer US, 1999. http://dx.doi.org/10.1007/978-1-4615-4801-0_14.

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7

Bringmann, G., C. Günther, M. Ochse, O. Schupp, and S. Tasler. "Biaryls in Nature: A Multi-Facetted Class of Stereochemically, Biosynthetically, and Pharmacologically Intriguing Secondary Metabolites." In Fortschritte der Chemie organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products. Springer Vienna, 2001. http://dx.doi.org/10.1007/978-3-7091-6227-9_1.

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8

Yamamoto, Yoshihiko. "Copper-Mediated Aryl-Aryl Bond Formation Leading to Biaryls: A Century after the Ullmann Breakthrough." In Copper-Mediated Cross-Coupling Reactions. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118690659.ch10.

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9

Šunjić, Vitomir, and Michael J. Parnham. "Biaryl Units in Valsartan and Vancomycin." In Signposts to Chiral Drugs. Springer Basel, 2011. http://dx.doi.org/10.1007/978-3-0348-0125-6_5.

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10

Schmid, Dietmar G., Alexandra Höltzel, Graeme J. Nicholson, et al. "Biaryl-Bridged Lipopeptides from Streptomyces sp. TÜ 6075." In Peptides: The Wave of the Future. Springer Netherlands, 2001. http://dx.doi.org/10.1007/978-94-010-0464-0_359.

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Conference papers on the topic "Biaryls"

1

Fernández-Figueiras, Adolfo, Fátima Lucio, Francisco Reigosa, et al. "Synthesis of functionalized biaryls using iminophosphorane palladacycles as Suzuki catalysts." In The 21st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2017. http://dx.doi.org/10.3390/ecsoc-21-04773.

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2

Lahmani, F., E. Bréhéret, O. Benoist d’Azy, A. Zehnacker-Rentien, and J. F. Delouis. "Time dependent fluorescence properties of the excited state of donor-acceptor substituted biaryls in protic solvents." In The 54th international meeting of physical chemistry: Fast elementary processes in chemical and biological systems. AIP, 1996. http://dx.doi.org/10.1063/1.50151.

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3

Trujillo, Carlos A., and Q. J. Ge. "Geometric Construction of Piecewise Line-Symmetric Spherical Motions Using Quaternion Biarcs." In ASME 2006 International Design Engineering Technical Conferences and Computers and Information in Engineering Conference. ASMEDC, 2006. http://dx.doi.org/10.1115/detc2006-99647.

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This paper employs quaternion biarcs to interpolate a set of orientations with angular velocity constraints. The resulting quaternion curve represents a piecewise spherical line-symmetric rational motion with C1 continuity. Since a quaternion arc corresponds to the motion of the planet gear in a special spherical epicyclic gear train, each segment of the quaternion biarcs can be realized with such an epicyclic gear train. Quaternion biarcs may be used to approximate B-spline quaternion curves that represent rational spherical motions that have applications in robot path planning, CAD/CAM, mech

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4

Kao, Ju-Hsien, Han Tong Loh, and Fritz B. Prinz. "Least-Square Biarc Curve Fitting for CNC Machining." In ASME 1997 Design Engineering Technical Conferences. American Society of Mechanical Engineers, 1997. http://dx.doi.org/10.1115/detc97/cie-4286.

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Abstract For CNC cutter path generation of nonlinear curves or surfaces, curve fitting using circular arc segments can be more efficient than linear segments. This paper presents a new algorithm for approximating large sets of points using a spline of biarcs, each of which consists of two circular arcs connected in tangent-continuous manner. The approach proposed in this paper differs from the previous work in that it does not require to pre-determine the number of arc segments, and yet all the family of biarcs between two points can be used, not only the ones which minimize the curvature diff

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5

Wang, Wenping, and Barry Joe. "Classification and properties of space biarcs." In Applications in Optical Science and Engineering, edited by Joe D. Warren. SPIE, 1992. http://dx.doi.org/10.1117/12.131745.

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Rahman, Khondaker M., Kamrun Nahar, Laureen Sander, et al. "Abstract 2517: Hybrid benzofused-biaryl polyamides with selective telomeric G-quadruplex stabilization potential." In Proceedings: AACR 102nd Annual Meeting 2011‐‐ Apr 2‐6, 2011; Orlando, FL. American Association for Cancer Research, 2011. http://dx.doi.org/10.1158/1538-7445.am2011-2517.

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7

Riedl, Jan, and Michal Hocek. "Synthesis of biaryl-substituted fluorescent nucleosides and nucleoside triphosphates and their incorporation to DNA." In XVth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2011. http://dx.doi.org/10.1135/css201112233.

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Vechia, Luciana Dalla, Benedikt Reichart, Toma Glasnov, Leandro S. M. Miranda, C. Oliver Kappe, and Rodrigo O. M. A. de Souza. "A three step continuous flow synthesis of the biaryl unit of the HIV protease inhibitor Atazanavir." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013917165936.

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9

Negmeldin, Ahmed T., and Mary Kay H. Pflum. "Abstract 19: Design and synthesis of biaryl indolyl benzamides as HDAC1-selective inhibitors via a fragment-based lead generation approach." In Proceedings: AACR Annual Meeting 2019; March 29-April 3, 2019; Atlanta, GA. American Association for Cancer Research, 2019. http://dx.doi.org/10.1158/1538-7445.sabcs18-19.

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Negmeldin, Ahmed T., and Mary Kay H. Pflum. "Abstract 19: Design and synthesis of biaryl indolyl benzamides as HDAC1-selective inhibitors via a fragment-based lead generation approach." In Proceedings: AACR Annual Meeting 2019; March 29-April 3, 2019; Atlanta, GA. American Association for Cancer Research, 2019. http://dx.doi.org/10.1158/1538-7445.am2019-19.

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Reports on the topic "Biaryls"

1

Jayatissa, Kuruppu. A Metal-Free Approach to Biaryl Compounds: Carbon-Carbon Bond Formation from Diaryliodonium Salts and Aryl Triolborates. Portland State University Library, 2000. http://dx.doi.org/10.15760/etd.2226.

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