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Journal articles on the topic 'Bicyclo [5,2,1] décène'

Author: Grafiati

Published: 4 June 2021

Last updated: 17 February 2022

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1

Bonnaud, B., R. Leyssens, R. Viani, J. P. Aycard, and M. Monnier. "Dicarbonitrileméthylène-2 diméthyl-8,9 oxo-5 bicyclo[4.4.0]décène-8-cis." Acta Crystallographica Section C Crystal Structure Communications 43, no. 11 (1987): 2248–49. http://dx.doi.org/10.1107/s0108270187088206.

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2

Nielsen, P., and F. Tarding. "The Metabolic Fate of 5-(bicyclo-3, 2, 1-oct-2-en-2-yl)-5-ethyl Barbituric Acid, (Reposal ®)." Acta Pharmacologica et Toxicologica 26, no. 6 (2009): 521–30. http://dx.doi.org/10.1111/j.1600-0773.1968.tb00471.x.

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3

Pachuta-Stec, Anna, Urszula Kosikowska, Anna Chodkowska, Monika Pitucha, Anna Malm, and Ewa Jagiełło-Wójtowicz. "Biological Activity of Novel N-Substituted Amides of endo-3- (3-Methylthio-1,2,4-triazol-5-yl)bicyclo[2.2.1]hept-5-ene-2- carboxylic Acid and N-Substituted Amides of 1-(5-Methylthio- 1,2,4-triazol-3-yl)cyclohexane-2-carboxylic Acids." Zeitschrift für Naturforschung C 67, no. 3-4 (2012): 123–28. http://dx.doi.org/10.1515/znc-2012-3-403.

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N-Substituted amides of endo-3-(3-methylthio-1,2,4-triazol-5-yl)bicyclo[2.2.1]hept-5-ene- 2-carboxylic acid and 1-(5-methylthio-1,2,4-triazol-3-yl)cyclohexane-2-carboxylic acid were prepared by the condensation reaction of endo-S-methyl-N1-(bicyclo[2.2.1]hept-5-ene-2,3- dicarbonyl)isothiosemicarbazide and S-methyl-N1-(cyclohexane-2,3-dicarbonyl)isothiosemicarbazide with primary amines. The synthesized compounds were screened for their microbiological and pharmacological activities

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4

Liu, Qi Mei, та Wan Xi Peng. "80°С-Based TD-GC/MS Analysis of Chemical Components from Branches of Cinnamomum camphora". Key Engineering Materials 480-481 (червень 2011): 466–71. http://dx.doi.org/10.4028/www.scientific.net/kem.480-481.466.

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The analytical result by 80°С-based TD-GC/MS showed that 65 peaks were obtained from the helium volatiles from the fresh branches of Cinnamomum camphora and 60 chemical compounds were identified. The results showed that the main components were as: 1,3-Benzodioxole, 5-(2-propenyl)- (12.629%), Tricyclo[2.2.1.0(2,6)]heptane, 1,7-dimethyl-7-(4-methyl-3-pentenyl)-, (-)- (10.302%), 3-Cyclohexene-1-methanol, .alpha.,.alpha.4-trimethyl- (9.084%), Bicyclo[2.2.1] heptan-2-one, 1,7,7-trimethyl-, (1R)- (7.406%), Nerolidol (6.695%), Bicyclo[2.2.1]heptane, 2-methyl-3-methylene-2-(4-methyl-3-pentenyl)-, (1S

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5

Petrov, Viacheslav A. "Stereoselective synthesis of 3-[(perfluoroprop-1-en-2-yl)bicyclo[2.2.1]-hept-5-en-2-yl]sulfanes." Mendeleev Communications 16, no. 3 (2006): 155–57. http://dx.doi.org/10.1070/mc2006v016n03abeh002327.

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6

Bourhis, Mireille, René Golse, Michel Goursolle, and Philippe Picard. "Synthesis of new norbornenones with the aminoester group methyl bicyclo [2-2-1] hept 5-ene 7-one 1-amino 2-carboxylates." Tetrahedron Letters 26, no. 29 (1985): 3445–48. http://dx.doi.org/10.1016/s0040-4039(00)98660-x.

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7

Ahlenstiel, Eckart, Wolfgang Kliegel, Steven J. Rettig, and James Trotter. "Structural studies of organoboron compounds. LVII. Synthesis and structure of bicyclic boron-nitrogen betaines. 1-Methyl-5-(3-nitrophenyl)-4,6,9-trioxa-1-azonia-5-boratabicyclo[3.3.1]nonane and 3,3,4-trimethyl-1-(3-nitrophenyl)-2,6,7-trioxa-3-azonia-1-boratabicyclo[2.2.2]octane." Canadian Journal of Chemistry 71, no. 2 (1993): 263–71. http://dx.doi.org/10.1139/v93-038.

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The syntheses and structures of the bicyclic boron-nitrogen betaines 1-methyl-5-(3-nitrophenyl)-4,6,9-trioxa-1-azonia-5-boratabicyclo[3.3.1]nonane, 7a, and 3,3,4-trimethyl-1-(3-nitrophenyl)-2,6,7-trioxa-3-azonia-1-boratabicyclo[2.2.2]-octane, 14a, are reported. Crystals of 7a are orthorhombic, a = 20.256(2), b = 37.652(2), c = 6.642(1) Å, Z = 16, space group Fdd2, and those of 14a are orthorhombic, a = 21.402(2), b = 11.334(3), c = 11.248(2) Å, Z = 8, space group Pbca. The structures were solved by direct methods and were refined by full-matrix least-squares procedures to R = 0.038 and 0.045 (

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8

Werstiuk, Nick Henry, та Chandra Deo Roy. "Experimental and AM1 calculational studies of the deprotonation of bicyclo[2.2.2]octane-2,5-dione and bicyclo[2.2.2]octane-2,6-dione: a study of homoconjugation, inductive, and steric effects on the rates and diastereoselectivities of α enolization". Canadian Journal of Chemistry 73, № 3 (1995): 460–63. http://dx.doi.org/10.1139/v95-060.

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The kinetics of NaOD-catalyzed H/D exchange (enolization) at C3 α to the carbonyl group of bicyclo[2.2.2]octane-2,5-dione (1) and bicyclo[2.2.2]octane-2,6-dione (2) have been studied in 60:40 (v/v) dioxane–D2O at 25.0 °C. The second-order rate constants for exchange are (9.7 ± 1.5) × 10−1 and (3.4 ± 1.2) × 10−5 L mol−1 s−1 for 1 and 2, respectively. Thus, 1, exchanges 76 times faster than bicyclo[2.2.2]octan-2-one (3) (k = (1.27 ± 0.02) × 10−2 L mol−1 s−1), but the 2,6-dione 2 unexpectedly is much less reactive (2.7 × 10−3) than the monoketone. Unlike the large exo selectivity of 658 observed

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9

Werstiuk, N. H., S. Yeroushalmi, and Hong Guan-Lin. "Synthesis of bicyclic diones and thiones. Facile methylation of the enolates of bicyclo[2.2.1]heptane-2,5-dione and bicyclo[2.2.2]octane-2,5-dione. An AM1 computational study of bicyclic enolates." Canadian Journal of Chemistry 70, no. 3 (1992): 974–80. http://dx.doi.org/10.1139/v92-130.

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A group of bicyclic ketones and thiones have been synthesized for homenolization studies. Bicyclo[2.2.1]heptane-2,5-dione (6) undergoes unusually rapid tetramethylation giving 3,3,6,6-tetramethylbicyclo[2.2.1]heptane-2,5-dione (1) in good yield. Treatment of 1 with P2S5 in xylene gave 3,3,6,6-tetramethylbicyclo[2.2.1]heptane-2,5-dithione (2) and 3,3,6,6-tetramethyl 15-oxo-bicyclo[2.2.1]heptane-2-thione (3), which was converted into 4 with Raney nickel. Bicyclo[2,2,2]octane-2,5-dione (7), prepared via a Diels–Alder reaction between 2-trimethylsilyloxy-1,3-cyclohexadiene and and α-acetoxyacrylon

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10

Liu, Qi Mei, Dang Quan Zhang, Kuan Peng та Wan Xi Peng. "Deep Analysis on Bioindustry Prospects of 40°С Volatiles of Cinnamomum camphora Branches". Key Engineering Materials 480-481 (червень 2011): 266–71. http://dx.doi.org/10.4028/www.scientific.net/kem.480-481.266.

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Cinnamomum camphora has been used to heal some specific diseases in the Chinese Folk for a long time. In order to explore the wide utilization in biomedicine and spicery, the chemical components of helium volatiles from the fresh branches of C. camphora were studied by TD-GC/MS. The analytical result by TD-GC/MS showed that 50 peaks were obtained from the helium volatiles from the fresh branches of C. camphora and 46 chemical compounds representing 99.993% of the total areas were identified. The results showed that the main components were as: Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1R)

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11

Saito, Nozomi, Yuki Tanaka, and Yoshihiro Sato. "Ruthenium-Catalyzed [2 + 2] Cycloaddition of Allenynes Leading to a Bicyclo[4.2.0]octa-1(8),5-diene Skeleton." Organic Letters 11, no. 18 (2009): 4124–26. http://dx.doi.org/10.1021/ol901616b.

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12

Hřebabecký, Hubert, Milena Masojídková, Martin Dračínský, and Antonín Holý. "Synthesis of Novel Conformationally Locked Carbocyclic Nucleosides Derived from 3-(Hydroxymethyl)bicyclo[2.2.1]heptane-2,5-diol." Collection of Czechoslovak Chemical Communications 71, no. 6 (2006): 871–88. http://dx.doi.org/10.1135/cccc20060871.

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(1R*,2R*,3R*,4R*,5R*,6S*)-3-Amino-5-(benzyloxy)-6-(hydroxymethyl)bicyclo[2.2.1]heptan-2-ol (18) was prepared in seven easy steps from benzyl (1R*,2S*,3S*,4S*)-3-(benzyloxy)bicyclo[2.2.1]hept-5-ene-2-carboxylate (10). Reaction of amine18with ethylN-((2E)-3-ethoxymethacryloyl)carbamate afforded 1-[(1R*,2R*,3R*,4R*,5S*,6R*)-6-(benzyloxy)-3-hydroxy-5- (hydroxymethyl)bicyclo[2.2.1]heptan-2-yl]-5-methylpyrimidine-2,4(1H,3H)-dione (21) and after deprotection by transfer hydrogenation, free thymine analogue22. The thymine derivative21was converted to 2,3'-anhydronucleoside26. Treatment of the benzyl d

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13

Fun, Hoong-Kun, Ching Kheng Quah, Chengmei Huang, and Haitao Yu. "1-Benzyl-5-methoxy-2′,3-dimethyl-4,6-dioxa-2-azaspiro[bicyclo[3.2.0]hept-2-ene-7,4′-isoquinoline]-1′,3′(2′H,4′H)-dione." Acta Crystallographica Section E Structure Reports Online 67, no. 6 (2011): o1311—o1312. http://dx.doi.org/10.1107/s160053681101600x.

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14

Scognamiglio, J., C. S. Letizia, and A. M. Api. "Fragrance material review on 1-[5(or 6)-methyl-7(or 8)-1-(methylethyl)bicyclo[2.2.2]oct-5-en-2-yl]ethan-1-one." Food and Chemical Toxicology 62 (December 2013): S61—S66. http://dx.doi.org/10.1016/j.fct.2013.08.066.

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15

Kim, JH, MJ Gallagher, and RF Toia. "Methanolysis of 4-Methyl-2,6,7-trioxa-1-phospha-bicyclo[2.2.2]octane 1-Oxide and 1-Sulfide: Mechanistic and Stereochemical Considerations." Australian Journal of Chemistry 47, no. 4 (1994): 715. http://dx.doi.org/10.1071/ch9940715.

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Methanolysis of 4-methyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane 1-oxide and 4-methyl-2,6,7- trioxa-1-phosphabicyclo[2.2.2]octane 1-sulfide have been studied by 31P n.m.r. spectroscopy. The trans-2-methoxy-5-methyl-1,3,2-dioxaphosphorinane-r-5-methanol 2-oxide and trans-2-methoxy-5-methyl-1,3,2-dioxaphosphorinane-r-5-methanol 2-sulfide are the initially formed products, respectively, but with time a product mixture comprising the trans- and cis -isomers and the acyclic dimethyl phosphate is formed. Methanolysis of the isolated trans-isomer, and of the isolated acyclic dimethyl phosphate und

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16

Yang, Ying-Qun, Wei Li, Zhi-Min Chen, and Li-Xia Fu. "Crystal Structure and Properties of a New Copper(II) Complex Cu2(phen)2[C7H8(COO)2]2 (H2O)4:5." Zeitschrift für Naturforschung B 67, no. 9 (2012): 872–76. http://dx.doi.org/10.5560/znb.2012-0097.

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A new complex Cu2(phen)2[C7H8(COO)2]2 (H2O)4:5 (1) has been synthesized, with the dianion of bicyclo[2.2.1] hept-2-ene-5,6-dicarboxylic acid [C7H8(COOH)2] (LH2) and 1,10-phenanthroline (phen) as ligands. In 1, L2- anions link Cu(II) cations to form two binuclear structure units, in which each Cu(II) cation is coordinated by five donor atoms to give a distorted square-pyramidal geometry. The magnetic data of 1 show that it exhibits weak antiferromagnetic properties at low temperature. When the excitation wavelength is at 470 nm, it has an intense photoluminescence. In addition, the cyclovoltamm

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17

Kohl, Eva, Thomas Ströter, Christina Siedschlag, Kurt Polborn, and Günter Szeimies. "The Carbene/Bridgehead-Olefin Rearrangement: DFT Calculations on 1-Bicyclo[2.1.1]hexylcarbene and 1-Bicyclo[3.1.1]heptylcarbene; Rearrangement of (5-Bromobicyclo[3.1.1]heptyl)bromocarbene." European Journal of Organic Chemistry 1999, no. 11 (1999): 3057–66. http://dx.doi.org/10.1002/(sici)1099-0690(199911)1999:11<3057::aid-ejoc3057>3.0.co;2-m.

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18

MARUBAYASHI, Nobuhiro, Masami YAMASHITA, and Noriaki HIRAYAMA. "Crystal Structure of .ALPHA.-Bicyclo(2.2.1)hept-5-en-2-yl-.ALPHA.-phenyl-1-piperidinepropanol (Biperiden)." Analytical Sciences 15, no. 8 (1999): 815–16. http://dx.doi.org/10.2116/analsci.15.815.

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19

Goursolle, M., M. Bourhis, and A. H'Naïfi. "Structure du diéthylamino-1 éthyl-6 oxo-7 bicyclo[2.2.1]heptène-5 carboxylate-2 de méthyle." Acta Crystallographica Section C Crystal Structure Communications 42, no. 11 (1986): 1641–42. http://dx.doi.org/10.1107/s0108270186091175.

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20

Gavina, Francisco, Ana M. Costero, Ana M. Gonzalez, and Santiago V. Luis. "Existence and reactivity of bicyclic annulenones. 2. Bicyclo[3.3.0]octa-1(5),3,7-triene-2,6-dione." Journal of Organic Chemistry 52, no. 14 (1987): 2997–99. http://dx.doi.org/10.1021/jo00390a009.

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21

Tănase, Drăghici, Hanganu, et al. "New HSV-1 Anti-Viral 1′-Homocarbocyclic Nucleoside Analogs with an Optically Active Substituted Bicyclo[2.2.1]Heptane Fragment as a Glycoside Moiety." Molecules 24, no. 13 (2019): 2446. http://dx.doi.org/10.3390/molecules24132446.

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New 1′-homocarbanucleoside analogs with an optically active substituted bicyclo[2.2.1]heptane skeleton as sugar moiety were synthesized. The pyrimidine analogs with uracil, 5-fluorouracil, thymine and cytosine and key intermediate with 6-chloropurine (5) as nucleobases were synthesized by a selective Mitsunobu reaction on the primary hydroxymethyl group in the presence of 5-endo-hydroxyl group. Adenine and 6-substituted adenine homonucleosides were obtained by the substitution of the 6-chlorine atom of the key intermediate 5 with ammonia and selected amines, and 6-methoxy- and 6-ethoxy substit

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22

Dookhun, Veedeeta, and Andrew J. Bennet. "Synthesis and biological evaluation of a bicyclo[4.1.0]heptyl analogue of glucose-1-phosphate." Canadian Journal of Chemistry 82, no. 9 (2004): 1361–64. http://dx.doi.org/10.1139/v04-109.

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The synthesis of a bicyclo[4.1.0]heptyl analogue of glucose-1-phophate, (1R,2R,3S,4S,5S,6S)-3,4,5-trihydroxy-6-(hydroxymethyl)-bicyclo[4.1.0]heptan-2-yl dihydrogen phosphate (5) is reported. The synthetic route chosen started with methyl α-D-glucopyranoside and was accomplished in 11 steps with an overall yield of 3%. Compound 5 was tested as a potential substrate of UTP:α-D-glucose-1-phosphate uridylyltransferase, the enzyme that converts glucose-1-phosphate into UDP-glucose. However, the conformationally restricted glucose-1-phosphate analogue 5 was found to be a weakly binding inhibitor, ra

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23

Li, Qing, Dang Quan Zhang, Qi Mei Liu та Kuan Peng. "Determination of Bioactive Components of 60°С Volatiles from Cinnamomum camphora Branches by TD-GC/MS". Advanced Materials Research 230-232 (травень 2011): 852–56. http://dx.doi.org/10.4028/www.scientific.net/amr.230-232.852.

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The chemical components of helium volatiles from the fresh branches of Cinnamomum camphora were studied by TD-GC/MS. The analytical result by 60°С-based TD-GC/MS showed that 55 peaks were obtained from the helium volatiles from the fresh branches of Cinnamomum camphora and 53 chemical compounds were identified. The results showed that the main components were as: Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1R)- (15.4328%), 1,3-Benzodioxole, 5-(2-propenyl)- (14.881%), Tricyclo[2.2.1.0(2,6)]heptane, 1,7-dimethyl-7-(4-methyl-3-pentenyl)-, (-)- (12.694%), p-menth-1-en-8-ol (9.832%), Bicyclo[2.2

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24

Shea, K. J., and L. D. Burke. "Bridgehead dienes. Thermal generation of the bicyclo[3.3.1]nona-1(2),4(5)-diene (ZZ) ring system." Tetrahedron Letters 28, no. 7 (1987): 735–38. http://dx.doi.org/10.1016/s0040-4039(01)80975-8.

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25

Koch, Ernst-Christian, and Guido J. Reiss. "Photochemisch induzierte C–C-Verknüpfungen zwischen einem Mangan-koordinierten Pentadienylliganden und Acetylen." Zeitschrift für Naturforschung B 70, no. 2 (2015): 143–50. http://dx.doi.org/10.1515/znb-2014-0227.

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AbstractIrradiation of tricarbonyl(η5-2,4-dimethyl-2,4-pentadien-1-yl)manganese (1) in tetrahydrofuran (THF) at 208 K affords the carmine solvent complex dicarbonyl(η5-2,4-dimethyl-2,4-pentadien-1-yl)(THF)manganese (2). Complex 2 thermally reacts with acetylene (3) to give tricarbonyl(η3:2-1,3-dimethyl-bicyclo[3.3.1]-3,6-nonadien-2-yl)manganese (4) and dicarbonyl(5-7,10-13-η-6,8-dimethyl-1,3,5,8,10,12-tridecahexaen-5-yl)manganese (5). The crystal structure of complex 4 was determined at room temperature [triclinic space group $P\bar 1,$a=7.6891(9), b=8.3860(8), c=10.5252(13) Å, α=93.000(9)°, β

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26

Moriguchi, Tetsuji, Suvratha Krishnamurthy, Toru Arai, et al. "Synthesis and Molecular Structure of tert-Butyl 3-oxo-2-oxa-5-azabicyclo[2.2.2]octane-5-carboxylate." Journal of Crystallography 2014 (August 17, 2014): 1–6. http://dx.doi.org/10.1155/2014/645079.

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The compound tert-butyl 3-oxo-2-oxa-5-azabicyclo[2.2.2]octane-5-carboxylate was synthesized as a cyclic amino acid ester from the corresponding ethyl 2-amino-4-(2-oxiranyl)butanoate HCl salt via an intramolecular lactonization reaction and was characterized by using 1H NMR spectroscopy and high-resolution mass spectrometry. The product was then recrystallized from dichloromethane/diethyl ether and its structure was determined via single crystal X-ray diffraction analysis. The crystal was found to be of the monoclinic space group P21/c (no. 14) with a = 10.217(2) Å, b = 11.676(3) Å, c = 10.273(

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27

Ngamga, Dieudonne, Josephine Bipa, Pearl Lebatha, et al. "Isoquinoline Alkaloids and Homoisoflavonoids from Drimiopsis barteri Bak and D. burkei Bak." Natural Product Communications 3, no. 5 (2008): 1934578X0800300. http://dx.doi.org/10.1177/1934578x0800300518.

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The powdered bulbs and leaves of Drimiopsis barteri yielded two novel isoquinoline alkaloids: 5-hydroxy-7,2′,3′,4′-tetramethoxy{2H-1-}benzopyran [4,3-c]isoquinoline and 6-hydroxy-7,2′,3′,4′-tetramethoxy{2H-1-}benzopyran [4,3-c]isoquinoline, three new scillascillins: 5,7-dihydroxy-2′,3′,4′-trimethoxyspiro-{2H-1-benzopyran-7′-bicyclo [4.2.0]octa[1,3,5]-triene}-4-one, 5-hydroxy-7,2′,3′,4′-tetramethoxyspiro{2H-1-benzopyran-7′-bicyclo [4.2.0]octa[1,3,5]-triene}-4-one and 5,2′,4′-trihydroxy-7,3′-dimethoxyspiro{2H-1-benzopyran-7′-bicyclo [4.2.0]octa[1,3,5]-triene}-4-one, and a tetrahydroxyhomo-isofla

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28

Weber, Martin, Gábor Balázs, Alexander V. Virovets, Eugenia Peresypkina, and Manfred Scheer. "Insertion of Phosphenium Ions into a Bicyclo[1.1.0]Tetraphosphabutane Iron Complex." Molecules 26, no. 13 (2021): 3920. http://dx.doi.org/10.3390/molecules26133920.

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By reacting [{Cp‴Fe(CO)2}2(µ,η1:1-P4)] (1) with in situ generated phosphenium ions [Ph2P][A] ([A]− = [OTf]− = [O3SCF3]−, [PF6]−), a mixture of two main products of the composition [{Cp‴Fe(CO)2}2(µ,η1:1-P5(C6H5)2)][PF6] (2a and 3a) could be identified by extensive 31P NMR spectroscopic studies at 193 K. Compound 3a was also characterized by X-ray diffraction analysis, showing the rarely observed bicyclo[2.1.0]pentaphosphapentane unit. At room temperature, the novel compound [{Cp‴Fe}(µ,η4:1-P5Ph2){Cp‴(CO)2Fe}][PF6] (4) is formed by decarbonylation. Reacting 1 with in situ generated diphenyl arse

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29

Peng, Wan Xi, Qiu Xue, Feng Juan Wu, Xu Zhang, and Zhong Feng Zhang. "Analysis on Health Risk of Volatile Organic Compounds of Smoked Bamboo Biomaterial by TD-GC-MS." Key Engineering Materials 467-469 (February 2011): 1697–701. http://dx.doi.org/10.4028/www.scientific.net/kem.467-469.1697.

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Smoked bamboo, which was made by bamboo in high temperature smoke, is a new indoors materials. In order to evaluate its potential health risk to human settlements, the volatile organic compounds of smoked bamboo biomaterial were adsorbed and determined by TD-GC-MS. And the main constituents of volatiles at 60°С were cyclononasiloxane, octadecamethyl-(35.14%), acetic acid(23.27%), cyclotrisiloxane, hexamethyl- (9.53%), bicyclo[4.4.0]dec-1-ene,2-isoprop yl-5-methyl-9-methylene-(7.56%), silane, 1,4-phenylenebis[trimethyl(4.32%), 1,3-benzodioxole, 5-(2-propenyl)- (3.47%), cedrol(2.75%), etc. (2) T

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30

Fun, Hoong-Kun, Ching Kheng Quah, Chengmei Huang, and Haitao Yu. "5-Methoxy-1,2′,3-trimethyl-4,6-dioxa-2-azaspiro[bicyclo[3.2.0]hept-2-ene-7,4′-isoquinoline]-1′,3′(2′H,4′H)-dione." Acta Crystallographica Section E Structure Reports Online 67, no. 6 (2011): o1340—o1341. http://dx.doi.org/10.1107/s1600536811016266.

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31

Ma, Qing Zhi, Feng Juan Wu¨, Dang Quan Zhang, and Wan Xi Peng. "Analysis on Function Components and Biohealth Function of Phyllostachys heterocycla Biomass." Advanced Materials Research 129-131 (August 2010): 55–59. http://dx.doi.org/10.4028/www.scientific.net/amr.129-131.55.

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Phyllostachys heterocycla, who was considered to have biohealth function in folk, is becoming a major biomass in rooms. Therefore, the chemical components from Phyllostachys heterocycla were identified by TD-GC/MS at different temperature. The main function components of Phyllostachys heterocycla biomass at 40°С were 1,2-benzenedicarboxylic acid, mono(2-ethylhexyl) ester(21.32%), [1,1':3',1''-terphenyl]-2'-ol(9.16%), (2,3-diphenylcyclopropyl)methyl ph enyl sulfoxide, trans-(6.54%), cedrol(6.11%), bicyclo[2.2.1]heptan-2-one, 1,7,7- trimethyl-, (1r)- (6.04%), 1,6-cyclodecadiene, 1-methyl-5-met h

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32

KATAYAMA, Sadamu, Hajime HIRAMATSU, Keiichi AOE, and Masashige YAMAUCHI. "Synthesis of 1-Hydroxybicyclo(3.2.1)oct-3-en-2-ones by Acyloin Rearrangement of 1-Methoxy- or 1-tert-Butyldimethylsilyloxy-bicyclo(2.2.2)oct-5-en-2-ones." CHEMICAL & PHARMACEUTICAL BULLETIN 45, no. 9 (1997): 1419–27. http://dx.doi.org/10.1248/cpb.45.1419.

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33

Fun, Hoong-Kun, Ching Kheng Quah, Chengmei Huang, and Haitao Yu. "(1S*,4′S*,5R*)-1-Isopropyl-5-methoxy-2′,3-dimethyl-4,6-dioxa-2-azaspiro[bicyclo[3.2.0]hept-2-ene-7,4′-isoquinoline]-1′,3′(2′H,4′H)-dione." Acta Crystallographica Section E Structure Reports Online 67, no. 5 (2011): o1271—o1272. http://dx.doi.org/10.1107/s1600536811015315.

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34

Fun, Hoong-Kun, Ching Kheng Quah, Chengmei Huang, and Haitao Yu. "(1S*,4′S*,5R*)-1-Isobutyl-5-methoxy-2′,3-dimethyl-4,6-dioxa-2-azaspiro[bicyclo[3.2.0]hept-2-ene-7,4′-isoquinoline]-1′,3′(2′H,4′H)-dione." Acta Crystallographica Section E Structure Reports Online 67, no. 5 (2011): o1273—o1274. http://dx.doi.org/10.1107/s1600536811015327.

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35

Min, Long, Xin Liu, and Chuang-Chuang Li. "Total Synthesis of Natural Products with Bridged Bicyclo[m.n.1] Ring Systems via Type II [5 + 2] Cycloaddition." Accounts of Chemical Research 53, no. 3 (2020): 703–18. http://dx.doi.org/10.1021/acs.accounts.9b00640.

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36

Kurzer, Frederick, and Jane E. Hawkes. "Bicyclo[2.2.2]octane-2-spirocyclohexanes, Part 5 [1] The Action of Grignard Reagents on Spirodiisophora-3′,6-dione." Zeitschrift für Naturforschung B 47, no. 7 (1992): 1000–1006. http://dx.doi.org/10.1515/znb-1992-0718.

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Grignard reagents react with spirodiisophora-3′,6-dione exclusively at its 3′-keto-function, yielding 3′-eq-alkyl(or phenyl)-3′-ax-hydroxyspirodiisophor-6-ones. Successive dehydration and monobromination of the methyl homologue yields products, the structural details of which are settled by their 13C NMR spectra.

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37

KUZNETSOV, M. A., I. D. KUCHUK, and V. A. GINDIN. "ChemInform Abstract: Thermolysis and Photolysis of 4,4,6,6-Tetramethyl-1-phenyl-5-phenylethynyl-2,3-diaza-2-bicyclo [3.1.0]hexene." ChemInform 29, no. 32 (2010): no. http://dx.doi.org/10.1002/chin.199832059.

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38

Brown, RFC, KJ Coulston, FW Eastwood, ADE Pullin, and AC Staffa. "Argon Matrix Study of the Infrared Spectrum of Butatrienone." Australian Journal of Chemistry 43, no. 3 (1990): 561. http://dx.doi.org/10.1071/ch9900561.

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Butatrienone, H2C=C=C=C=O, was generated by pyrolysis of each of six different precursors in a stream of argon at temperatures in the range 710-880°C, and the pyrolysate-argon mixture was condensed on a Csl plate at c. 10 K. Infrared spectra were obtained between 4000 and 250 cm-1. Two precursors, buta-2,3-dienoic trifluoracetic anhydride (1) and buta-2,3-dienoyl chloride (2), gave pyrolysates showing a spectrum consisting of six strong bands and five weak bands. Four precursors, bicyclo [2.2.1]hept-5′-en-2′-ylideneacetic trifluoracetic anhydride (3), 5-( bicyclo [2.2.1]hept-5′-en-2′-ylidene)-

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39

Buzas, Andrea, and Fabien Gagosz. "Gold(I) Catalyzed Isomerization of 5-en-2-yn-1-yl Acetates: An Efficient Access to Acetoxy Bicyclo[3.1.0]hexenes and 2-Cycloalken-1-ones." Journal of the American Chemical Society 128, no. 39 (2006): 12614–15. http://dx.doi.org/10.1021/ja064223m.

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40

Freeman, Fillmore, Mark Y. Lee, Hengyao Lu, Xiaojing Wang, and Eloy Rodriguez. "1-Thia-Cope Rearrangements during the Thionation of 2-endo-3-endo-Bis(aroyl)bicyclo[2.2.1]hept-5-enes." Journal of Organic Chemistry 59, no. 13 (1994): 3695–98. http://dx.doi.org/10.1021/jo00092a034.

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41

KATAYAMA, S., H. HIRAMATSU, K. AOE, and M. YAMAUCHI. "ChemInform Abstract: Synthesis of 1-Hydroxybicyclo[3.2.1]oct-3-en-2-ones by Acyloin Rearrangement of 1-Methoxy- or 1-tert-Butyldimethylsilyloxy-bicyclo[2.2.2]oct-5-en-2-ones." ChemInform 29, no. 11 (2010): no. http://dx.doi.org/10.1002/chin.199811102.

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42

Werstiuk, Nick Henry, and Jiangong Ma. "Applications and evaluation of IGAIM 13C and 1H chemical shift calculations for unsaturated hydrocarbons and organolithium compounds." Canadian Journal of Chemistry 74, no. 6 (1996): 875–84. http://dx.doi.org/10.1139/v96-096.

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Wave functions obtained at the RHF/6-31+G(d) level of theory were used with the new method IGAIM (individual gauges for atoms in molecules) developed by Keith and Bader to calculate the isotropic 13C and 1H NMR chemical shifts of a group of neutral molecules (bicyclo[3.2.1]octa-2,6-diene (1), bicyclo[3.2.1]oct-6-ene (2), bicyclo[2.2.1]hepta-2,5-diene (3), benzene (4)), carbanions (prop-2-en-1-yl (allyl) (5), bicyclo[3.2.1]octa-3,6-dien-2-yl (8)), and lithium complexes (prop-2-en-1-yllithium (6) and its dimer 7, bicyclo[3.2.1]octa-3,6-dien-2-yllithium (9)). The theoretical isotropic 13C NMR che

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43

Chan, Isa Y. H., Mohan M. Bhadbhade, and Roger Bishop. "Threefold helical assembly via hydroxy hydrogen bonds: the 2:1 co-crystal of bicyclo[3.3.0]octane-endo-3,endo-7-diol and bicyclo[3.3.0]octane-endo-3,exo-7-diol." Acta Crystallographica Section E Crystallographic Communications 77, no. 3 (2021): 270–76. http://dx.doi.org/10.1107/s2056989021001730.

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Reduction of bicyclo[3.3.0]octane-3,7-dione yields a mixture of the endo-3,endo-7-diol and endo-3, exo-7-diol (C8H14O2) isomers (5 and 6). These form (5)2·(6) co-crystals in the monoclinic P21/n space group (with Z = 6, Z′ = 1.5) rather than undergoing separation by means of fractional recrystallization or column chromatography. The molecule of 5 occupies a general position, whereas the molecule of 6 is disordered over two orientations across a centre of symmetry with occupancies of 0.463 (2) and 0.037 (2). Individual diol hydroxy groups associate around a pseudo-threefold screw axis by means

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44

Reza Salari, Mohammad, Mohammad H. Mosslemin, and Alireza Hassanabadi. "Green synthesis of trans-(4-chlorophenyl)-7-aryl-6,7-dihydro[1,3]dioxolo[4,5-f][1]benzofuran-6-yl)methanones in an aqueous medium." Journal of Chemical Research 43, no. 3-4 (2019): 86–89. http://dx.doi.org/10.1177/1747519819836527.

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A three-component one-pot condensation of 2-[2-(4-chlorophenyl)-2-oxoethyl)]isoquinolinium bromide with benzo[1,3]dioxol-5-ol and an arylglyoxal in the presence of catalytic amounts of 1,4-diaza-bicyclo[2.2.2]octane in refluxing water gave a series of seven trans-(4-chlorophenyl)-7-aryl-6,7-dihydro[1,3]dioxolo[4,5- f][1]benzofuran-6-yl)methanones in excellent yield and in a short time.

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45

Maas, Gerhard, and Rainer Rahm. "A Proton-Catalyzed Dimerization of a 2-Amino-1,3-diene which Ultimately Yields a 3-Aminobicyclo[4.2.0]octa-2,4-diene." Zeitschrift für Naturforschung B 60, no. 6 (2005): 673–76. http://dx.doi.org/10.1515/znb-2005-0611.

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The 2-pyrrolidino-1,3-dienes (E)-5 and (Z)-5 are obtained by the reaction of lithium di(tertbutyl) cuprate with propyne iminium salt 3. Quantitative Z→E isomerization of 5 takes place within 4 hours at 20 °C. In benzene solution, (E)-5 slowly equilibrates with a [1,5]-H shift to form the 1-amino-1,3-diene derivative 6. In concentrated chloroform solution, however, (E)-5 is transformed into the 3-pyrrolidino-bicyclo[4.2.0]octa-2,4-diene 7 which is identified by X-ray crystal structure analysis. A mechanism for this transformation is proposed.

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46

Kreiter, Cornelius G., та Klaus Lehr. "Photochemische Reaktionen von Übergangsmetall-Organyl-Komplexen mit Olefnen, VI. Reaktionen von Tricarbonyl-η5-2,4-cyclohexadienyl-mangan mit konjugierten Dienen / Photochemical Reactions of Transition Metal Organyl Complexes with Olefins, VI. Reactions of Tricarbonyl (η5-2,4-cyclohexadienyl)manganese with Conjugated Dienes". Zeitschrift für Naturforschung B 46, № 10 (1991): 1377–83. http://dx.doi.org/10.1515/znb-1991-1016.

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Tricarbonyl-η5-2,4-cyclohexadien-1-yl-manganese (1) was reacted photochemically at 253 K with simple conjugated dienes. Four different types of products were obtained, depending upon the dienes. With 1,3-butadiene (A) dicarbonyl-η4:3-1-(3-buten-1,2-diyl)-2,4-cyclohexadiene-manganese (2A) is isolated. 2-Methyl-1,3-butadiene (B) yields the methyl-substituted diastereomeric dicarbonyls 2B, 2B′, the [4+5]-cycloadduct tricarbonyl-η3:2-3-methyl-bicyclo-[4.3.1]-3,8-decadien-7-yl-manganese (3B) and tetracarbonyl-η3-4-methylene-bicyclo[4.3.1]-8-decen-3-yl-manganese (4B) with an exocyclically coordinate

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47

Lin', Ji-Mao, Li Fang та Wen-Tao Huang. "Synthesis of γ-N-[(Arylideneaminoethyl)-Aminoethyl]Aminopropyl-2, 8, 9-Trioxa-5-aza-1-sila-bicyclo[3, 3, 3]undecanes". Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry 25, № 9 (1995): 1467–77. http://dx.doi.org/10.1080/15533179508218283.

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48

Pal’chikov, V. A., S. A. Prid’ma, and L. I. Kas’yan. "Synthesis and aminolysis of N-(bicyclo[2.2.1]hept-5-en-endo-2-ylmethyl)-N-(oxiran-2-ylmethyl)(7,7-dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonamide." Russian Journal of Organic Chemistry 50, no. 9 (2014): 1312–16. http://dx.doi.org/10.1134/s1070428014090139.

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49

Werstiuk, Nick Henry, and Jiangong Ma. "An ab initio study on the magnetic susceptibility and magnetically induced current density distribution of the bicyclo[3.2.1]octa-3,6-dien-2-yl anion." Canadian Journal of Chemistry 77, no. 5-6 (1999): 752–59. http://dx.doi.org/10.1139/v99-049.

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The molecular susceptibility and the atomic contributions including the basin and surface components calculated at the RHF/6-31+G(d)//6-31+G(d) level of theory along with vector current densities obtained at the 6-31++G(d,p)//6-31+G(d) and 6-31+G(d)//6-31+G(d) levels are reported for benzene (1) and correlated - the agreement is excellent - with the results obtained by Keith and Bader with the 6-311++G(2d,2p) basis. This validates our similar studies on the bicyclo[3.2.1]octa-3,6-dien-2-yl anion (2) - initially considered to be a bishomoaromatic species - its parent hydrocarbon bicyclo[3.2.1]o

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50

Klunder, A. J. H., F. J. C. Van Gastel, J. M. M. Smits, Paul T. Beurskens, and Gezina Beurskens. "Crystal and molecular structure of (2R,3R)-2-exo-((1R)-1-hydroxy-2-methyl-propyl)-3-exo-hydroxymethyl-bicyclo[2.2.1]-hept-5-ene, C12H20O2." Journal of Chemical Crystallography 25, no. 7 (1995): 389–92. http://dx.doi.org/10.1007/bf01665275.

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