Academic literature on the topic 'Bidentate ligand'

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Journal articles on the topic "Bidentate ligand"

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Oszwałdowski, Sławomir, Katarzyna Zawistowska-Gibuła, and Kenneth Roberts. "Characterization of CdSe quantum dots with bidentate ligands by capillary electrophoresis." Open Chemistry 9, no. 4 (2011): 572–84. http://dx.doi.org/10.2478/s11532-011-0037-3.

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AbstractThe CdSe quantum dots (QDs) with bidentate ligands: a-diimine (NN) and dihydrolipoic acid (DHLA) were synthesized and characterized by UV-Vis, particle size and capillary electrophoretic techniques. Two systems were analyzed: CdSe with one ligand (CdSe/ligand) and CdSe with two different ligands (CdSe//ligand1/ligand2), where ligand = α-diimine or DHLA. Hydrodynamic features of functionalized QDs were characterized by zone capillary electrophoretic (CZE), and particle size techniques and these methods were consistent. It was established that CZE, micellar (MEKC) and microemulsion (MEEK
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Chan, Chung Ying, and Peter J. Barnard. "Rhenium complexes of bidentate, bis-bidentate and tridentate N-heterocyclic carbene ligands." Dalton Transactions 44, no. 44 (2015): 19126–40. http://dx.doi.org/10.1039/c5dt03295d.

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Rhenium(i) tricarbonyl complexes of a range of bidentate, bis-bidentate and tridentate NHC ligands have been prepared. These NHC ligands are of interest for possible applications in the development of Tc-99m or Re-186/188 radiopharmaceuticals and the stability of two complexes were evaluated in ligand challenge experiments using the metal binding amino acids l-histidine or l-cysteine.
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Gopal, Meera, and Sreesha Sasi. "Synthesis and Structural Characterization of Lanthanum(III) Complexes of 4-Nitrosoantipyrine." Asian Journal of Chemistry 33, no. 3 (2021): 617–21. http://dx.doi.org/10.14233/ajchem.2021.23047.

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A new series of La(III) complexes of the ligand with the general formula [La(L)2(a)3] and [La2(L)4(aa)3], (a = nitrate (1), thiocyanate (2), acetate (3) and propionate (4) ions, aa = sulphate (5), thiosulphate (6), oxalate (7) and malonate (8) ions with the ligand 4-nitrosoantipyrine (L) were synthesized and characterized using various physico-chemical studies. The primary ligand L acts as a bidentate ligand utilizing the carbonyl group and the nitroso group for bonding. The nitrate, thiocyanate, acetate and propionate ions are monovalent unidentate ligands, whereas sulphate, thiosulphate, oxa
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Zhou, Wen, and Jian Wang. "A one-dimensional zinc(II) coordination polymer incorporating [1,1′-biphenyl]-4,4′-dicarboxylate andN,N′-bis(pyridin-3-ylmethyl)-[1,1′-biphenyl]-4,4′-dicarboxamide ligands." Acta Crystallographica Section C Crystal Structure Communications 69, no. 5 (2013): 486–90. http://dx.doi.org/10.1107/s0108270113008111.

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In the title compound,catena-poly[[[N,N′-bis(pyridin-3-ylmethyl)-[1,1′-biphenyl]-4,4′-dicarboxamide]chloridozinc(II)]-μ-[1,1′-biphenyl]-4,4′-dicarboxylato-[[N,N′-bis(pyridin-3-ylmethyl)-[1,1′-biphenyl]-4,4′-dicarboxamide]chloridozinc(II)]-μ-[N,N′-bis(pyridin-3-ylmethyl)-[1,1′-biphenyl]-4,4′-dicarboxamide]], [Zn2(C14H8O4)Cl2(C26H22N4O2)3]n, the ZnIIcentre is four-coordinate and approximately tetrahedral, bonding to one carboxylate O atom from a bidentate bridging dianionic [1,1′-biphenyl]-4,4′-dicarboxylate ligand, to two pyridine N atoms from twoN,N′-bis(pyridin-3-ylmethyl)-[1,1′-biphenyl]-4,4
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Liu, Liang, Hui Chen, Zhenqiang Yang, Junnian Wei, and Zhenfeng Xi. "C,C- and C,N-Chelated Organocopper Compounds." Molecules 26, no. 19 (2021): 5806. http://dx.doi.org/10.3390/molecules26195806.

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Copper-catalyzed and organocopper-involved reactions are of great significance in organic synthesis. To have a deep understanding of the reaction mechanisms, the structural characterizations of organocopper intermediates become indispensable. Meanwhile, the structure-function relationship of organocopper compounds could advance the rational design and development of new Cu-based reactions and organocopper reagents. Compared to the mono-carbonic ligand, the C,N- and C,C-bidentate ligands better stabilize unstable organocopper compounds. Bidentate ligands can chelate to the same copper atom via
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Emad N. Al_Sabawi, Ahmed S. Al-Janabi, and Hayfa Muhammed Jerjes. "Synthesis and Spectroscopic study of Pd(II)- Salicylaldoxime complexes with amine ligands." Tikrit Journal of Pure Science 26, no. 3 (2022): 26–34. http://dx.doi.org/10.25130/tjps.v26i3.140.

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New Pd(II) complexes of Salicylaldoxime (HSaly) with amine ligands {amine = Bipy, Phen and en} were synthesized and characterized by using CHN analysis, FT-IR spectra, molar conductivity and 1H NMR spectra. The HSaly ligand was coordinated with the Pd(II) ion as bidentate chelating ligand in complex [Pd(Saly)2], through oxygen atom of hydroxylate group and nitrogen atom of oxime group, whereas, bonded as monodentate ligand in complexes [Pd(Saly)2(amine)] (2-4), via the oxygen atom of hydroxylate group, and the amines were coordinated as bidentate chelate via N atom to give a square planner aro
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Sárosi, Imola, Menyhárt B. Sárosi, Peter Lönnecke, Luminiţa Silaghi-Dumitrescu, and Evamarie Hey-Hawkins. "Heterotopic As,S,P and As,S,As Ligands: Synthesis and Theoretical Studies." Australian Journal of Chemistry 66, no. 10 (2013): 1246. http://dx.doi.org/10.1071/ch13262.

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The heterotopic As,S,P ligands 1-AsPh2-2-StBu-3-PPh2-C6H3 (2) and 1-AsPh2-2-SH-3-PPh2-C6H3 (4) and dinucleating As,S,As ligand 1,3-(AsPh2)2-2-StBu-C6H3 (3) have been synthesized and characterized. The structural motif of these compounds suggests great potential for their use as monodentate, bidentate chelating, bidentate bridging, and tridentate ligands.
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Muth, Andreas, Gunther Reinhard, Gottfried Huttner, Thomas Seitz, Thomas Klein, and Laszlo Zsolnai. "Tripod-Liganden mit zwei verschiedenen Donorgruppen: Synthese und Koordinationsverhalten von H3CCH(CH2PPh2)2(CH2OH) / Tripod Ligands with Two Different Donor Groups: Synthesis and Coordination of H3CC(CH2PPh2)2(CH2OH)." Zeitschrift für Naturforschung B 49, no. 7 (1994): 889–97. http://dx.doi.org/10.1515/znb-1994-0706.

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Abstract Starting from pentaglycerin, H3CC(CH2OH)3, a convenient three step synthesis of the tri­pod ligand H3CC(CH2PPh2)2(CH2OH) (3) (abbreviated as PPO(H)) is described and its struc­ture is established by the usual analytical methods as well as by X-ray analysis. The ligand behaves as a bidentate donor towards nickel(II) as shown by the formation and X-ray analysis of the complex {PPO(H)}NiBr2 (4). In the square planar complex 4 only the PPh2 groups are coordinated. In the tetrahedral complex [{PPO(H)}2Ni](BF4)2 (5) two PPO(H) ligands sur­round nickel as bidentate ligands.
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Alghamdi, Israa A., Mohamed Abdelbaset, and Ines El Mannoubi. "Mixed Ligand Complexes of Copper(II) and Cobalt(II) with Hydrazones Derivatives and ortho-Vanillin: Syntheses, Characterizations and Antimicrobial Activity." Oriental Journal of Chemistry 35, no. 6 (2019): 1722–30. http://dx.doi.org/10.13005/ojc/350614.

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The purpose of this paper was to synthesis new mixed-ligand Cu(II) and Co(II) metal complexes utilizing bidentate and tridentate donor hydrazones derivatives as primary ligands and o-vanillin as co-ligand. The obtained compounds were characterized by elemental analysis, Infrared, UV-Vis., 1H-NMR, Mass spectra, molar conductance, thermal analysis and atomic absorption spectroscopy (ASS). Spectroscopic analysis results indicated that the hydrazone ligand (L1) behave as tridentate (ONO) and forms metal complexes having distorted square planar geometry. While the ligands (L2, L3 AND L4) behave as
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Ahmed S. M. Al-Janabi. "Synthesis, characterization and study of mercury(II) complexes with phosphine and heterocyclic thiones." Tikrit Journal of Pure Science 20, no. 4 (2023): 67–72. http://dx.doi.org/10.25130/tjps.v20i4.1215.

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Many new mixed ligand complexes of mercury(II) have been synthesized with LH = 4,5-(diphenyl)-1,2,4-triazole-3-thione (diptSH) and tertiary phosphines as co-ligands. The compounds have been characterized by elemental analyses, IR, UV–Vis, molar conductivity, and NMR spectroscopy. In the binuclear complexes (2-5), both Hg atoms have tetrahedral geometry, the Hg atom bonded to three halide ions and one thione ligand (LH) through the sulfur atom. The complex (6) show that thiolate ligand(diptS-) is coordinated as monodentate through the sulfur atom. The dppm behave as bidentate bridging ligand to
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Dissertations / Theses on the topic "Bidentate ligand"

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Fuente, Molina Verònica de la. "Ligand design for palladium and iridium selective catalysts." Doctoral thesis, Universitat Rovira i Virgili, 2011. http://hdl.handle.net/10803/34766.

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This doctoral thesis focuses on the synthesis of new ligands and their application in two types of catalytic process: a) palladium catalysed carbonylation reactions and b) asymmetric reactions (hydrogenation of challenge substrates and C-C bond formation). In the first part of the thesis, the synthesis of a family of new diphosphine ligands and their application in Pd-catalysed carbonylation processes is described. These ligands were first used in the Pd-catalysed methoxycarbonylation of ethane, achieving high activity and selectivity. A mechanistic study on these catalytic systems reveale
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Bott, Robyn Kirsty Joy. "Synthesis, structure and catalytic activity of novel bidentate ligand complexes of the group 4 metals." Thesis, University of East Anglia, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.423394.

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Pennington, Dale Andrew. "Synthesis, structure and catalytic activity of novel bidentate ligand complexes of the group 4 metals." Thesis, University of East Anglia, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.439899.

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Bair, Joseph Spencer. "Synthesis and optical properties of four oligothiophene-ruthenium complexes and synthesis of a bidentate ligand for C-F bond activation /." Diss., CLICK HERE for online access, 2006. http://contentdm.lib.byu.edu/ETD/image/etd1636.pdf.

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Bair, Joseph S. "Synthesis and Optical Properties of Four Oligothiophene-Ruthenium Complexes and Synthesis of a Bidentate Ligand for C-F Bond Activation." BYU ScholarsArchive, 2006. https://scholarsarchive.byu.edu/etd/1031.

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Photovoltaic cells and fluorescence sensing are two important areas of research in chemistry. The combination of photon-activated electron donors with electron acceptors provides a strong platform for the study of optical devices. A series of four oligothiophene-ruthenium complexes has been synthesized. Variation in oligothiophene length and bipyridine substitution allowed comparison of these variables on electronic properties. The longer oligothiophenes display lower energy absorption and emission compared to the shorter ones. Aromatic conjugation appears more complete with para-, rather than
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Vignolle, J. "Approches de complexes carbéniques hétérosubstitués originaux." Phd thesis, Université Paul Sabatier - Toulouse III, 2006. http://tel.archives-ouvertes.fr/tel-00192093.

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Les complexes carbéniques ont connu un essor considérable ces dernières années. L'introduction générale présente les différentes facettes de ces complexes aux propriétés aussi diverses qu'uniques. D'abord utilisés comme réactifs stoechiométriques, les complexes carbéniques sont devenus des catalyseurs de choix dans de nombreuses réactions. Dans ce contexte, nous présenterons différentes approches pour la synthèse de complexes carbéniques hétérosubstitués.<br /><br />Le premier chapitre présente la synthèse et la chimie de coordination d'aminoarylcarbènes possédant un squelette biphényl ou bina
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Vignolle, Joan. "Approches de complexes carbéniques hétérosubstitués originaux." Toulouse 3, 2006. http://www.theses.fr/2006TOU30223.

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Gillespie, Jason A. "Design and synthesis of wide bite angle phosphacyclic ligands." Thesis, University of St Andrews, 2012. http://hdl.handle.net/10023/3100.

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By examining structure activity relationships for a given catalytic reaction it is possible to discover what ligand features and parameters lead to stable and highly active/selective catalyst systems. With this knowledge in hand it may be possible to rationally design next generation ligands and catalysts to affect improved substrate transformations, with higher selectivities and faster reaction times. The success of Burk's DuPhos ligands in asymmetric hydrogenation demonstrated that chiral phosphacycles can be a potent source of chiral induction, whilst in a similar vein the work of van Leeuw
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Woods, Rebecca J. "Bidentate nitrogen ligands for olefin polymerisation." Thesis, University of Manchester, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.488051.

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Giboreau, Pascale. "Bisdithiocarbamates : synthese, protection et marquage au technetium 99m." Université Joseph Fourier (Grenoble), 1996. http://www.theses.fr/1996GRE10170.

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Ce travail presente la synthese de differents ligands bisdithiocarbamates comportant deux fonctions dithiocarbamates sur un meme squelette, ainsi que l'evaluation de leur capacite a complexer le technetium 99m, element largement utilise en medecine nucleaire. Apres avoir rappele, dans les deux premiers chapitres, quelques generalites sur la chimie du technetium et sur les proprietes complexantes des dithiocarbamates, les resultats de nos travaux seront presentes. Trois familles ont ete selectionnees, appartenant a des series aliphatiques lineaire, benzenique ou ferrocenique. Ces choix ont ete
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Books on the topic "Bidentate ligand"

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Lappas, Christina. Synthesis of N/N bidentate ligands. Laurentian University, 1997.

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Cavallin, Anthony. Synthesis of N/N bidentate ligands. Laurentian University, 1995.

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Johansson, Fredrik. The synthesis of chiral bidentate (N,N), (N,P) and (N,O) ligands and their use in metal-mediated asymmetric carbon-carbon bond formation. Acta Universitatis Upsaliensis, 1998.

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Nemra, Ghinwa. Comportement électrochimique de nouveaux complexes à liaison Pd-Pd et Pt-Pd stabilisés par des ligands bidentates Ph₂PCH₂PPh₂. A.N.R.T. Université Pierre Mendès France Grenoble 2, 1986.

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Book chapters on the topic "Bidentate ligand"

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of chromium(II) complex with bulky bidentate ″trisyl″ ligand." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54228-6_208.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of four coordinate nickel(II) complex with bidentate NS ligand." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-662-45972-0_599.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of manganese(II) halide-bridged complex with bulky bidentate “trisyl” ligand." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54228-6_436.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of cobalt(II) halide-bridged complex with bulky bidentate “trisyl” ligand." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54231-6_674.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of praseodymium(III) complex with bidentate biheterocyclic 2-(2-pyridyl)benzimidazole ligand." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-53974-3_636.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of neodymium(III) complex with bidentate biheterocyclic 2-(2-pyridyl)benzimidazole ligand." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-53974-3_647.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of samarium(III) complex with bidentate biheterocyclic 2-(2-pyridyl)benzimidazole ligand." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-53974-3_662.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of nickel(II) complex with triethylenetetraamine and bidentate nitrogen donor co-ligand." In Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 6. Springer Berlin Heidelberg, 2022. http://dx.doi.org/10.1007/978-3-662-65056-1_250.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of nickel(II) complex with triethylenetetraamine and bidentate nitrogen donor co-ligand." In Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 6. Springer Berlin Heidelberg, 2022. http://dx.doi.org/10.1007/978-3-662-65056-1_249.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of nickel(II) complex with triethylenetetraamine and bidentate nitrogen donor co-ligand." In Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 6. Springer Berlin Heidelberg, 2022. http://dx.doi.org/10.1007/978-3-662-65056-1_251.

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Conference papers on the topic "Bidentate ligand"

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Kostić, Marijana S., Nikola D. Radnović, Ana Radović, et al. "Synthesis and physicochemical characterisation of the Ni(II) complex with 3- (4-chlorophenyl)-1H-pyrazole ligand." In 2nd International Conference on Chemo and Bioinformatics. Institute for Information Technologies, University of Kragujevac, 2023. http://dx.doi.org/10.46793/iccbi23.527k.

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The coordination properties of 3-(4-chlorophenyl)-1H-pyrazole (HL) was investigated and its complex with Ni(II) ion was synthesized. The structure of the ligand was proven using SC-XRD, while both the ligand and the complex were characterized by spectroscopic, and thermogravimetric measurements. The purity and composition of the complex were confirmed by PXRD, elemental analysis, and conductometric measurements. Besides, the search for CSD was made to establish the frequency of different coordination modes of similar compounds. It was found that monodentate coordination of the neutral ligand m
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CRACIUN, Nicoleta, Elena MELNIC, Marina FONARI, and Diana CHISCA. "Synthesis and crystal structure of a mononuclear compound of Cd(II) with 2,2'-dipyridine and 4,4'-diaminodiphenylmethane ligands." In "Instruire prin cercetare pentru o societate prosperă", conferinţă ştiinţifico-practică internaţională. Ion Creangă Pedagogical State University, 2024. https://doi.org/10.46727/c.v1.16-17-05-2024.p74-78.

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Starting from Cd(NO3)2•6H2O salt the ligand 4,4'-diaminodiphenylmethane (dadpm), in the presence of the bidentate-chelate ligand 2,2′-dipyridine (2,2′-dpi), a mononuclear coordination compound was obtained with composition [Cd(dadpm)2(2,2′-dpi)2](dadpm)(NO3)2, which was characterized by IR spectroscopy and single-crystal Xray diffraction.
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Khadka, Dhruba B., Yasuhiro Shirai, Masatoshi Yanagida, and Kenjiro Miyano. "Effect of Bidentate Ligand Additive in Tin Perovskite Solar Cells." In 2023 IEEE 50th Photovoltaic Specialists Conference (PVSC). IEEE, 2023. http://dx.doi.org/10.1109/pvsc48320.2023.10359837.

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Zainun, A. R., M. Rusop, and U. Z. Noor. "Photoluminescence characterization of nanostructured copper (I) iodide (CuI) incorporate with bidentate ligand." In 2010 International Conference on Electronic Devices, Systems and Applications (ICEDSA). IEEE, 2010. http://dx.doi.org/10.1109/icedsa.2010.5503024.

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Munín-Cruz, Paula, Marcos Rúa-Sueiro, Juan Ortigueira, and José Vila. "Synthesis of novel bisiminophosphorane palladacycles with miscellaneous bidentate chelating ligands." In The 24th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2020. http://dx.doi.org/10.3390/ecsoc-24-08321.

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Sheikhshoaie, Iran, and Walter Fabian. "A Quantum Chemical Study of Second Order Nonlinear Optical Properties of Assymetric Bidentate Schiff Base Ligands." In The 8th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2004. http://dx.doi.org/10.3390/ecsoc-8-01965.

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Ki-Whan Chi, Joo-Yeon Park, Ho Yun Hwang, Young Min Lee, and Peter J. Stang. "Self-selected formation of single discrete supramolecules with flexible, bidentate ligands in the coordination-driven self-assembly." In 2008 Third International Forum on Strategic Technologies (IFOST). IEEE, 2008. http://dx.doi.org/10.1109/ifost.2008.4602976.

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Bastos, Neidemar de M. S., Júlia T. de Macedo, Marcos C. de Souza, et al. "Synthesis and characterization of novel phosphinamide bidentate ligands with groups P=O, P=S and P=Se: Application in coordination chemistry with Zn++." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013819151125.

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