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Journal articles on the topic 'Bifunctional nanoreactor'

Author: Grafiati

Published: 2 June 2025

Last updated: 19 July 2025

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1

Guo, Yingchun, Lei Feng, Xiaomei Wang, and Xu Zhang. "Integration of yolk–shell units into a robust and highly reactive nanoreactor: a platform for cascade reactions." Chemical Communications 55, no. 21 (2019): 3093–96. http://dx.doi.org/10.1039/c9cc00288j.

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2

Altshuler, Heinrich, and Olga Altshuler. "Nanoreactor Effect in Bifunctional Cation Exchangers Based on Cis-Metacyclophanoctol." JOURNAL OF ADVANCES IN CHEMISTRY 7, no. 2 (2011): 1331–37. http://dx.doi.org/10.24297/jac.v7i2.2362.

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The nanoreactor effect consisting in sufficiently high rate increase of a cation diffusion flux in bifunctional cation exchangers based on cis-metacyclophanoctol has been found. The solutions of the fundamental differential equation of cation diffusion in bifunctional cation exchangers containing sulfonic acid and phenol ionogenic groups by means of the spherical layer and plane sheet models are presented for a variety of initial and boundary conditions with constant diffu-sion coefficient.

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3

Zhang, Xiaoming, Lingyan Jing, Fangfang Chang, Shuai Chen, Hengquan Yang, and Qihua Yang. "Positional immobilization of Pd nanoparticles and enzymes in hierarchical yolk–shell@shell nanoreactors for tandem catalysis." Chemical Communications 53, no. 55 (2017): 7780–83. http://dx.doi.org/10.1039/c7cc03177g.

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A hierarchical yolk–shell@shell nanoreactor that spatially positioned Pd nanoparticles and the CALB enzyme in separated domains is constructed, and served as an efficient bifunctional catalyst for the one-pot dynamic kinetic resolution (DKR) reaction of 1-phenylethylamine with excellent activity and selectivity.

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4

Ai, Gang Gang, Chuan Min Ding, Ya Long Wen, et al. "Synthesis and Application of Ni-M@Silica Yolk-Shell Nanostructures as Versatile Catalytic Materials." Materials Science Forum 852 (April 2016): 323–28. http://dx.doi.org/10.4028/www.scientific.net/msf.852.323.

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Recent developments in nanochemistry offer precise morphology control of nanomaterials, which has significant impacts in the field of heterogeneous catalysis. Rational design of bifunctional catalysts can influence various aspects of catalytic properties. In the present work, a new type of Ni-M(Co, Zr, Ce)@SiO2 yolk-shell nanoreactor framework comprising Ni-M cores inside hollow silica shells has been prepared through direct silica coating. The Ni-M@SiO2 nanoreactor structure is employed as a model catalyst for the partial oxidation of methane reaction. The Ni/ZrO2@SiO2 catalyst proved to be m

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5

Lee, Li-Chen, Jie Lu, Marcus Weck, and Christopher W. Jones. "Acid–Base Bifunctional Shell Cross-Linked Micelle Nanoreactor for One-Pot Tandem Reaction." ACS Catalysis 6, no. 2 (2016): 784–87. http://dx.doi.org/10.1021/acscatal.5b02538.

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6

Wang, Jiao, Maiyong Zhu, Xiaojuan Shen, and Songjun Li. "A Cascade-Reaction Nanoreactor Composed of a Bifunctional Molecularly Imprinted Polymer that Contains Pt Nanoparticles." Chemistry - A European Journal 21, no. 20 (2015): 7532–39. http://dx.doi.org/10.1002/chem.201406285.

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7

Li, Ping, Yu Yu, Pei-Pei Huang, Hua Liu, Chang-Yan Cao, and Wei-Guo Song. "Core–shell structured MgAl-LDO@Al-MS hexagonal nanocomposite: an all inorganic acid–base bifunctional nanoreactor for one-pot cascade reactions." J. Mater. Chem. A 2, no. 2 (2014): 339–44. http://dx.doi.org/10.1039/c3ta13403b.

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8

Shao, Mengliu, Junqing Xu, Xinxin Wang, et al. "Plasmolysis-inspired constructure of ZIF-8/-SO3H acid-base bifunctional nanoreactor with open-mouthed yolk-shell structure for efficient cascade catalysis." Colloids and Surfaces A: Physicochemical and Engineering Aspects 725 (November 2025): 137485. https://doi.org/10.1016/j.colsurfa.2025.137485.

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9

Li, Ping, Chang-Yan Cao, Hua Liu, Yu Yu, and Wei-Guo Song. "Synthesis of a core–shell–shell structured acid–base bifunctional mesoporous silica nanoreactor (MS-SO3H@MS@MS-NH2) and its application in tandem catalysis." Journal of Materials Chemistry A 1, no. 41 (2013): 12804. http://dx.doi.org/10.1039/c3ta13185h.

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10

Yang, Ying, Wen Zhang, Feng Yang, et al. "Ru nanoparticles dispersed on magnetic yolk–shell nanoarchitectures with Fe3O4 core and sulfoacid-containing periodic mesoporous organosilica shell as bifunctional catalysts for direct conversion of cellulose to isosorbide." Nanoscale 10, no. 5 (2018): 2199–206. http://dx.doi.org/10.1039/c7nr07875g.

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11

Rutkowska, Iwona A., Beata Rytelewska, and Pawel Kulesza. "(Invited) Development of Multifunctional Nanoscale Reactors for Electrocatalytic Oxidation of Dimethyl Ether Fuel." ECS Meeting Abstracts MA2024-01, no. 47 (2024): 2640. http://dx.doi.org/10.1149/ma2024-01472640mtgabs.

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There has been growing interest in utilizing small (simple) organic molecules, as alternative fuels to hydrogen, for electrochemical energy conversion in fuel cells. Dimethyl ether (DME) is one of the possible choices in this respect. But electrooxidation of DME is rather slow at ambient conditions. Obviously, there is a need to develop novel electrocatalytic materials. Bimetallic PtSn catalysts were found to be almost as active as PtRu for methanol oxidation, and PtSn was even more efficient toward the electrooxidation of ethanol where breaking of C-C bond is required. While PtRu forms a sing

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12

Zhang, Binbin, Tingyu Lu, Yiping Ren, et al. "Encapsulation of Co/Co3O4 hetero-nanoparticles within the inner tips of N-doped carbon nanotubes: Engineering Mott-Schottky nanoreactors for efficient bifunctional oxygen electrocalysis toward flexible zinc-air batteries." Chemical Engineering Journal 448 (November 2022): 137709. http://dx.doi.org/10.1016/j.cej.2022.137709.

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13

Sui, Simi, Haonan Xie, Biao Chen, et al. "Highly Reversible Sodium‐ion Storage in A Bifunctional Nanoreactor Based on Single‐atom Mn Supported on N‐doped Carbon over MoS2 Nanosheets." Angewandte Chemie, July 9, 2024. http://dx.doi.org/10.1002/ange.202411255.

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Conversion‐type electrode materials have gained massive research attention in sodium‐ion batteries (SIBs), but their limited reversibility hampers practical use. Herein, we report a bifunctional nanoreactor to boost highly reversible sodium‐ion storage, wherein a record‐high reversible degree of 85.65% is achieved for MoS2 anodes. Composed of nitrogen‐doped carbon‐supported single atom Mn (NC‐SAMn), this bifunctional nanoreactor concurrently confines active materials spatially and catalyzes reaction kinetics. In‐situ/ex‐situ characterizations including spectroscopy, microscopy, and electrochem

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14

Sui, Simi, Haonan Xie, Biao Chen, et al. "Highly Reversible Sodium‐ion Storage in A Bifunctional Nanoreactor Based on Single‐atom Mn Supported on N‐doped Carbon over MoS2 Nanosheets." Angewandte Chemie International Edition, July 9, 2024. http://dx.doi.org/10.1002/anie.202411255.

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Conversion‐type electrode materials have gained massive research attention in sodium‐ion batteries (SIBs), but their limited reversibility hampers practical use. Herein, we report a bifunctional nanoreactor to boost highly reversible sodium‐ion storage, wherein a record‐high reversible degree of 85.65% is achieved for MoS2 anodes. Composed of nitrogen‐doped carbon‐supported single atom Mn (NC‐SAMn), this bifunctional nanoreactor concurrently confines active materials spatially and catalyzes reaction kinetics. In‐situ/ex‐situ characterizations including spectroscopy, microscopy, and electrochem

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15

Lu, Chunqiang, Yaolin Wang, Dong Tian, et al. "Shielded bifunctional nanoreactor enabled tandem catalysis for plasma methane coupling." Nature Communications 16, no. 1 (2025). https://doi.org/10.1038/s41467-025-59709-y.

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Abstract The direct conversion of methane into valuable unsaturated C2 hydrocarbons (C2H2 and C2H4) attracts growing attention. Non-thermal plasma offers a promising approach for this process under mild conditions. However, the competing formation of C2H6 and excessive dehydrogenation limit the selectivity toward C2H2 and C2H4. Herein, we develop a promising shielded bifunctional nanoreactor with a hollow structure and mesoporous channels (Na2WO4-Mn3O4/m-SiO2) that effectively limits CH4 overactivation and promotes selective coupling to form C2H2 and C2H4 under plasma activation, achieving 39%

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16

Lu, Chunqiang, Yaolin Wang, Ruidong Xu, et al. "Shielded bifunctional nanoreactor enabled tandem catalysis for plasma methane coupling." Nature Communications 16 (May 17, 2025). https://doi.org/10.1038/s41467-025-59709-y.

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The direct conversion of methane into valuable unsaturated C2 hydrocarbons  (C2H2 and C2H4) attracts growing attention. Non-thermal plasma offers a promising approach for this process under mild conditions. However, the  competing formation of C2H6 and excessive dehydrogenation limit the selectivity toward C2H2 and C2H4. Herein, we develop a promising shielded bifunctional nanoreactor with a hollow structure and mesoporous channels (Na2WO4-Mn3O4/m-SiO2) that effectively limits CH4 overactivation and pro motes selective coupling to form C2H2 and C2H4 under plasma activation, &nbs

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17

Gong, Feilong, Zhilin Chen, Chaoqun Chang, et al. "Hollow Mo/MoS_Vn Nanoreactors with Tunable Built‐in Electric Fields for Sustainable Hydrogen Production." Advanced Materials, December 8, 2024. https://doi.org/10.1002/adma.202415269.

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AbstractConstructing built‐in electric field (BIEF) in heterojunction catalyst is an effective way to optimize adsorption/desorption of reaction intermediates, while its precise tailor to achieve efficient bifunctional electrocatalysis remains great challenge. Herein, the hollow Mo/MoSVn nanoreactors with tunable BIEFs are elaborately prepared to simultaneously promote hydrogen evolution reaction (HER) and urea oxidation reaction (UOR) for sustainable hydrogen production. The BIEF induced by sulfur vacancies can be modulated from 0.79 to 0.57 to 0.42 mV nm−1, and exhibits a parabola‐shaped rel

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18

Xiong, Fei, Chao Ma, Yi-Ren Zhu, et al. "A Highly Stereoselectivity and Recyclable Microgel-Supported Bifunctional Sulfonamide Organocatalyst for Asymmetric Alcoholysis of meso-Cyclic Anhydrides: A Thermo-responsive “Organic Nanoreactor”." New Journal of Chemistry, 2022. http://dx.doi.org/10.1039/d2nj01914k.

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A novel thermosensitive bifunctional sulfonamide microgels catalyst was synthesized by immobilization on a highly cross-linked three-dimensional network structure through covalent interactions. The microgels-supported organocatalyst has been successfully applied to catalyze...

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19

Pan, Shunlong, Xinrui Guo, Xing Lu, et al. "Boosting peroxymonosulfate activation by a novel bifunctional core-shell nanoreactor MnFe2O4@HZO for nitrilotris-methylenephosphonic acid removal." Applied Catalysis B: Environmental, February 2023, 122508. http://dx.doi.org/10.1016/j.apcatb.2023.122508.

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20

Zhang, Han, You-Xue Zhao, Chun-Xiu Li, Jiang Pan, and Jian-He Xu. "Improving the Stability of Membrane-Binding Enzymes for the Sustainable Production of Monoterpenes in a MOF-on-aMOF Bifunctional Core–Shell Nanoreactor." ACS Sustainable Chemistry & Engineering, June 11, 2024. http://dx.doi.org/10.1021/acssuschemeng.4c01502.

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21

Janani, B., V. Vinotha Sre, Asad Syed, et al. "Constructing bifunctional interfacial electric field triggered NiCo2S4 loaded 3D nanoflower CuFe LDH as self-cascade nanoreactor photo-Fenton system to efficiently degrade ciprofloxacin." Surfaces and Interfaces, March 2025, 106289. https://doi.org/10.1016/j.surfin.2025.106289.

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22

Liu, Zhihang, Xiaoqing Mao, Xihao Liu, Yuanyan Luo, and Pei Kang Shen. "N-doped Fe2(MoO4)3-decorated MoO3 nanorods via metal-organic framework-involved synthesis as a bifunctional nanoreactor for capturing and catalyzing polysulfides in lithium-sulfur batteries." New Journal of Chemistry, 2022. http://dx.doi.org/10.1039/d2nj03894c.

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Shuttling behavior and sluggish redox kinetics of lithium polysulfides (LiPSs) are fundamental reasons hindering the application of lithium-sulfur batteries (LSBs). A functional interlayer, introduced between the electrode and separator, fabricated...

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23

Chae, Kyunghee, Heejun Lee, Wen‐Tse Huang, et al. "Spin‐polarized Acidic Water Electrolysis with Antenna‐Reactor Plasmonic Electrocatalysts." Advanced Materials, June 26, 2025. https://doi.org/10.1002/adma.202507658.

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Abstract Water electrolysis, driven by renewable electricity, offers a sustainable path for hydrogen production. However, efficient bifunctional electrocatalysts are needed to overcome the high overpotentials of both the oxygen evolution reaction and hydrogen evolution reaction. To address this, a novel catalyst system is developed integrating plasmonic nanoreactors with chirality‐induced spin selectivity. In this system, chiral Au nanoparticles act as antennae, while single‐atom iridium serves as the catalytic reactor, achieving a 3.5 fold increase in reaction kinetics (at 1.57 V vs RHE) comp

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24

Han, Yi‐Wen, Yu‐Xin Zhang, Lei Ye, et al. "Embedding Tandem Built‐in Electric Fields within Hollow Architectures for Enhanced Photothermal Effect in Alcohol Oxidation Coupled with H₂ Production." Advanced Functional Materials, April 2025. https://doi.org/10.1002/adfm.202425473.

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AbstractRationally designing nanostructures based on a comprehensive understanding of structure‐property relationships is instrumental in enhancing the photothermal effect. Here, a general two‐stage morphology‐structure‐control strategy is presented to construct tandem built‐in electric fields (BIEFs) embedded hollow bifunctional photocatalysts (Sv‐chalcogenide hollow nanocage/NiCo2S4 heterojunctions, Sv represents sulfur vacancies, chalcogenides include ZnIn2S4, CdS, CdIn2S4). This strategy involves fabricating polyhedral cages via constraint epitaxy and embedding tandem BIEFs (consisting of

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25

Yuan, Junjie, Jiayi Zou, Zhongqiu Wu, Zhaolong Wang, Zongli Yang, and Hui Xu. "Bifunctional electrocatalytic reduction performance of nitrogen containing biomass based nanoreactors loaded with Ni nanoparticles for oxygen and carbon dioxide." Nanotechnology, October 13, 2023. http://dx.doi.org/10.1088/1361-6528/ad0301.

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Abstract In the face of increasing energy demand, the transformation approach that combines energy restructuring and environmental governance has become a popular research direction. As an important part of electrocatalytic reactions for gas molecules, reduction reactions of oxygen (ORR) and carbon dioxide (CO2RR) are very indispensable in the field of energy conversion and storage. However, the irreversibility of electrode materials is a constant challenge in electrocatalysis. However, the non-interchangeability and irreversibility of electrode materials have always been a challenge in electr

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26

Yu, Hongbo, Fei Zhang, Shuibo Wang, Yang Cong, Shiwei Wang, and Lin Zhu. "Hollow and Mesoporous M@Aluminosilicate (M=Rh, Pd and Pt) Bifunctional Catalytic Nanoreactors for the Hydrodeoxygenation of Lignin-Derived Phenols." New Journal of Chemistry, 2023. http://dx.doi.org/10.1039/d3nj01590d.

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Hydrodeoxygenation of lignin-derived phenolic compounds to produce alkanes is a promising method used for mitigating fossil energy consumption, but they often require high temperature and high pressure, resulting in their...

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27

Cheng, Yujun, Jianping Guan, Zhipeng Zhang, et al. "In Situ SERS Monitoring and Heterogeneous Catalysis Verification of Pd-Catalyzed Suzuki–Miyaura Reaction via Bifunctional “Black Raspberry-like” Plasmonic Nanoreactors." Analytical Chemistry, March 3, 2025. https://doi.org/10.1021/acs.analchem.4c03670.

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28

Zhang, Binbin, Tingyu Lu, Yiping Ren, et al. "Encapsulation of Co/Co3o4 Hetero-Nanoparticles within the Inner Tips of N-Doped Carbon Nanotubes: Engineering Mott-Schottky Nanoreactors for Efficient Bifunctional Oxygen Electrocalysis Toward Flexible Zinc-Air Batteries." SSRN Electronic Journal, 2022. http://dx.doi.org/10.2139/ssrn.4110642.

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