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Dissertations / Theses on the topic 'Bimetalic'

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1

Sengupta, Debasish. "Preparation, characterization of bimetalic nanoparticles soaked on poly -ionic resins and their ctalalytic applications." Thesis, University of North Bengal, 2014. http://ir.nbu.ac.in/handle/123456789/1827.

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2

Rowe, S. J. "Adsorption studies of simple molecules on metalic, bimetalic and semiconductor interfaces." Thesis, University of Southampton, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.383911.

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3

Gallo, Irã Borges Coutinho. "Surface structure and electronic properties of carbon supported PdAu nanoparticles and their catalytic behavior toward the oxygen reduction reaction /." Araraquara, 2018. http://hdl.handle.net/11449/153370.

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Orientador: Hebe de las Mercedes Villullas<br>Banca: Rodrigo Fernando Costa Marques<br>Banca: Leandro Martins<br>Banca: Elisabete Inacio Santiago<br>Banca: Joelma Perez<br>Abstract: Carbon supported PdAu nanoparticles with different Au contents (20-50% in atoms) were synthesized using a procedure carried out in a liquid two-phase system. As-prepared materials presented similar average particle diameter (~3nm) with narrow distribution over the carbon support, as shown by Transmission Electronic Microscopy (TEM). The combined data from X-ray Diffraction (XRD) and X-ray Photoelectron Spectroscopy
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4

Pereira, Luis Gustavo da Silva. "Avaliação do mecanismo de oxidação de hidrogênio contaminado por monóxido de carbono em células PEMFC contendo catalisadores anódicos baseados em Pt-M/C (M=Ru, Mo, Fe e W)." Universidade de São Paulo, 2009. http://www.teses.usp.br/teses/disponiveis/75/75131/tde-11032010-110241/.

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A busca por fontes alternativas de energia é uma tendência mundial e, neste contexto, as células a combustível alimentadas com hidrogênio obtido pela reforma de biocombustíveis constitui uma das alternativas mais promissoras. Entretanto, o desempenho das células a combustível de membrana de troca protônica (PEMFC) com ânodos baseados em Pt é drasticamente reduzido quando se utiliza hidrogênio contaminado por CO, o qual é produzido no processo de reforma. Neste trabalho, a eletrocatálise da tolerância ao CO e a estabilidade de Pt/C, PtRu/C, PtFe/C, PtMo/C e PtW/C como eletrocatlisadores anódico
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5

Galhardo, Thalita Soares. "Oxidação de glicerol utilizando catalisadores mono e bimetálicos à base de nanopartículas de Pt, Cu ou Ni suportadas em carvão ativado." reponame:Repositório Institucional da UFABC, 2017.

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6

Atmatzakis, Evangelos. "Bimetallic photonic metamaterials." Thesis, University of Southampton, 2016. https://eprints.soton.ac.uk/399982/.

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In this thesis, I introduce bimetallic ring resonator arrays as a platform for enhancing and controlling magneto-optical and thermoelectric effects. By taking advantage of differences in the physical (optical, electronic, thermal, magnetic) properties of the two elements comprising the resonators, I have demonstrated tailoring of the optical absorption and the Faraday effect, and generation of THz magnetic pulses. In particular: I have theoretically predicted for the first time the light-driven generation of intense, highly-localised, THz magnetic pulses in thermoelectric metamaterials. Excita
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7

Morris, James Alan. "Palladium-ruthenium bimetallic cascades." Thesis, University of Leeds, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.405707.

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8

Migliaccio, Luca. "Bimetallic catalysts for CO2 electroreduction." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2017. http://amslaurea.unibo.it/14470/.

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Over the last decades, many steps have been taken in the search for an effective method to reduce carbon dioxide to small organic molecules that can be used as fuel or building blocks for the chemical industry. The object of this work is to prepare two bimetallic electrocatalysts utilizing Cu combined with Au or In for the efficient and selective reduction of CO2 to CO, HCOOH and small fuels molecules. The copper-gold electrode is prepared through the electrodeposition of Cu on the surface of Au, using the underpotential deposition (UPD) technique to obtain a copper monolayer. The prepared ele
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9

Merrifeild, Ruth Corrin. "Bimetallic Nanoclusters and Protein Interactions." Thesis, University of Birmingham, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.522011.

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10

Cooper, Ian Ronald. "Palladium-indium bimetallic cascade processes." Thesis, University of Leeds, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.401087.

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11

Davies, S. J. R. "The structure of bimetallic catalysts." Thesis, University of Cambridge, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.373245.

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12

Ence, Chloe Christine. "Organic Synthesis using Bimetallic Catalysis." BYU ScholarsArchive, 2020. https://scholarsarchive.byu.edu/etd/8397.

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Bimetallic Catalysis is an emerging field of study that uses two metals to cooperatively perform organic transformations. These metals can serve to activate or bind substrates in order to increase the rate and selectivity of reactions. This work first describes the synthesis and utilization of six new chiral, titanium-containing phosphinoamide ligands. These Lewis acidic ligands withdraw electron density from an active palladium center to induce chirality and increase the rate of allylic amination of hindered, secondary N-alkyl amines. X-ray quality crystals were grown for each ligand and comp
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13

Kühn, Laura. "Bimetallic aerogels for electrocatalytic applications." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2017. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-226469.

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Polymer electrolyte fuel cells (PEFCs) have emerged as a promising renewable emission-free technology to solve the worldwide increasing demand for clean and efficient energy conversion. Despite large efforts in academia and automotive industry, the commercialization of PEFC vehicles still remains a great challenge. Critical issues are high material costs, insufficient catalytic activity as well as longterm durability. Especially due to the sluggish kinetics of the oxygen reduction reaction (ORR), high Pt loadings on the cathode are still necessary which leads to elevated costs. Alloys of Pt w
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14

Zhu, Chengzhou, Dan Wen, Martin Oschatz, et al. "Kinetically controlled synthesis of PdNi bimetallic porous nanostructures with enhanced electrocatalytic activity." Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-208520.

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15

Berg, Katja E. "Bimetallic model compounds for artificial photosynthesis /." Stockholm, 1997. http://www.lib.kth.se/abs98/berg0109.pdf.

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16

Simpkins, Simon M. E. "Bimetallic organoiron dipoles as NLO materials." Thesis, University of East Anglia, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.365015.

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17

MacLeod, Norman. "Alloy formation in bimetallic reforming catalysts." Thesis, University of Glasgow, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.388553.

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18

McCaffrey, Shaun. "Enantioselective Pd/In bimetallic cascade processes." Thesis, University of Leeds, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.432336.

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19

Campbell, Steven Bruce. "Characterisation of bimetallic diesel oxidation catalysts." Thesis, University of Aberdeen, 2014. http://digitool.abdn.ac.uk:80/webclient/DeliveryManager?pid=211242.

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With mobile emission limits worldwide becoming more stringent, catalysts have increased in complexity to achieve improved activities and selectivities. This has required catalysts to be characterised under more severe conditions e.g. after extended thermal treatments to simulate catalyst lifetime. Detailed characterisation may allow a deeper understanding of the interactions within these catalysts and lead to improvements in catalyst design. The characterisation of these and other sophisticated catalysts may be improved by the development of an advanced characterisation technique using quantit
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20

Schütze, Mike. "Bimetallic Complexes for Cooperative Polymerization Catalysis." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://hdl.handle.net/11858/00-1735-0000-002E-E4A0-A.

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21

Judd, Lawrence. "Bimetallic complexes of meta-substituted phosphinobenzenes." Thesis, University of Warwick, 1988. http://wrap.warwick.ac.uk/110018/.

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The ligand m-bis(diphenylphosphino)benzene (m-BDPPB) has been prepared and has been found to form bimetallic complexes of various structural types. The most common of these is the trans.trans face-to-face structure as demonstrated by the complex [CI2Pt(u-m-BDPPB)2PtCL2. Other bimetallic complexes such as [X(Me)Pt(u-m-BDPPB)2Pt(Me)X] (X = Cl or I) and [Me(sol)Pt(u-m-BDPPB)2Pt(sol)Me]2+ (sol = acetone or acetonitrile) have been prepared and have been shown by 31P-{1H) and 1H n.m.r. spectroscopy to be fluxional at room temperature. The probable processes giving rise to this fluxionality are discu
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22

Eliáš, Lumír. "Zavedení a optimalizace linky pro výrobu bimetalických komor do vstřikovacích lisů." Master's thesis, Vysoké učení technické v Brně. Fakulta strojního inženýrství, 2008. http://www.nusl.cz/ntk/nusl-227962.

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The Diploma Thesis deals with the explanation and the effective solution of the initial problems during a production line implementation of different type in the existing process. In order to make the production economical effective and correspondent with decided standards and customer requirements, the thesis is based on the identification and elimination of abnormal phenomenon by new production line implementation for bimetallic barrels.
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23

Huang, Wei. "Selective hydrogenation on zeolite-supported bimetallic catalysts." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file 0.90 Mb., p. 76, 2005. http://proquest.umi.com/pqdlink?did=1037889271&Fmt=7&clientId=8331&RQT=309&VName=PQD.

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24

Zhou, Shenghu. "Architecturally controlled bimetallic nanoparticles for heterogeneous catalysis." College Park, Md. : University of Maryland, 2007. http://hdl.handle.net/1903/6722.

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Thesis (Ph. D.)--University of Maryland, College Park, 2007.<br>Thesis research directed by: Chemistry. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.
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25

Beck, Victoria Holly. "Synthesis and characterisation of bimetallic organometallic complexes." Thesis, University of Oxford, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.403935.

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26

Maggini, Simona. "Novel phosphinooxazolines as precursor of bimetallic systems." Thesis, University of Oxford, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.433366.

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27

Nanada, Swagata. "Bimetallic alkoxides as potential lewis acid catalysts." Thesis, University of Newcastle Upon Tyne, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.533694.

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28

Chiffey, Andrew Francis. "Bimetallic compounds of palladium, platinum and gold." Thesis, University of Southampton, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.294602.

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29

Cambanis, George. "Platinum bimetallic catalysts for fuel cell applications." Thesis, Imperial College London, 1986. http://hdl.handle.net/10044/1/37958.

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30

Hardeman, David. "Growth of carbon nanotubes using bimetallic catalysts." Thesis, University of Cambridge, 2016. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.709528.

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31

Wells, Jordann Ashley Logan Slovenne Denis. "Bimetallic actinide complexes for small molecule activation." Thesis, University of Edinburgh, 2018. http://hdl.handle.net/1842/31167.

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The work described in this thesis concerns the synthesis of actinide complexes and their reactivity towards small unsaturated molecules. Complexes bearing tetraphenoxide, borohydride and boroxide ligands have been evaluated. Additionally, work towards the synthesis of heterobimetallic uranium transition metal complexes and their applications in catalysis is discussed. Chapter one reviews important organoactinide complexes reported in the literature which effect chemical transformations on small unsaturated substrates. Actinide complexes supported by aryloxide or borohydride ligands are reviewe
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32

Luo, Kai. "Spectroscopic characterization of monometallic and bimetallic model catalysts." [College Station, Tex. : Texas A&M University, 2006. http://hdl.handle.net/1969.1/ETD-TAMU-1709.

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33

Roudgar, Ataollah. "Local reactivity of bimetallic overlayer and cluster systems." [S.l. : s.n.], 2004. http://deposit.ddb.de/cgi-bin/dokserv?idn=971640084.

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34

Scherlin, Freddy. "Synthesis and characterization of bimetallic platinum-thallium compounds." Thesis, Linköping University, The Department of Physics, Chemistry and Biology, 2008. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-15403.

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<p>The solid bimetallic compounds TtPt(CN)<sub>4</sub>(ClO<sub>4</sub>) and TtPt(CN)<sub>4</sub>(NO<sub>3</sub>) have been prepared by reactions between tetracyanoplatinate complex [Pt(CN)4]2- and aqueous solutions of Tl(ClO<sub>4</sub>)<sub>3</sub> and Tl(NO<sub>3</sub>)<sub>3</sub>, respectively. The elemental analysis (N, C, H, Tl) of the compound has been carried out. The results of the analysis are reasonably consistent with the above compositions of the compounds. The bimetallic compounds have been characterized by IR and Raman spectroscopy as well as X-ray diffraction. IR and Raman spec
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35

Gjervan, Torbjørn. "Studies of bimetallic particle formation in reforming catalysts." Doctoral thesis, Norwegian University of Science and Technology, Department of Chemical Engineering, 2000. http://urn.kb.se/resolve?urn=urn:nbn:no:ntnu:diva-1482.

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36

Rademacher, Carolin [Verfasser]. "Synthesis and analysis of bimetallic nanoparticles / Carolin Rademacher." Bielefeld : Universitätsbibliothek Bielefeld, 2014. http://d-nb.info/1052627609/34.

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37

Collins, Richard. "Bimetallic group 4 complexes as olefin polymerisation catalysts." Thesis, University of Oxford, 2016. https://ora.ox.ac.uk/objects/uuid:f6cad6bf-c925-4cda-9797-7b1916f98a0f.

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This Thesis describes the synthesis and characterisation of half-sandwich bimetallic complexes supported by &kappa;<sup>1</sup>-amidinate ligands with different bridging moieties. <b>Chapter 1</b> introduces homogeneous polyolefin catalysis with a focus on Group 4 metals. The mechanism, catalyst development and the activation chemistry of metallocene and post-metallocene catalysts are discussed. The beneficial properties generated by bimetallic catalysts through cooperative interactions are introduced. <b>Chapter 2</b> describes the synthesis, structures and copolymerisation capabilities of cy
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38

Persson, Katarina. "Bimetallic palladium catalysts for catalytic combustion of methane." Licentiate thesis, Stockholm, 2004. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-332.

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39

Snyder, Brian. "An investigation into bimetallic hollow nanoparticles in catalysis." Thesis, Georgia Institute of Technology, 2013. http://hdl.handle.net/1853/47614.

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Nanocatalysis, catalysis using particles on the nanoscale, is an emerging field that has tremendous potential. Nanoparticles have different properties than bulk material and can be used in different roles. Macro sized precious metals, for example, are inert, but nanoparticles of them are becoming more widely used as catalysts. Understanding the manner in which these particles work is vital to improving their efficacy. This thesis focuses on two aspects of nanocatalysis. Chapter 1 begins with a brief introduction into nanotechnology and some of the areas in which nanoparticles are different tha
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40

O'Brien, S. D. "The preparation and properties of bimetallic hydrogenation catalysts." Thesis, Queen's University Belfast, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.421011.

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41

Nuttall, Christopher John. "Bimetallic tris-oxalate magnets : synthesis structure and properties." Thesis, University College London (University of London), 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299144.

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42

Marshall, Robert. "Preparation of bimetallic catalysts by surface organometallic chemistry." Thesis, Open University, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.265345.

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43

Chantry, Ruth L. "Characterising the structure and properties of bimetallic nanoparticles." Thesis, University of Birmingham, 2013. http://etheses.bham.ac.uk//id/eprint/4500/.

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The work presented in this thesis explores the use of aberration corrected scanning transmission electron microscopy (ac-STEM) in characterising the structure and properties of bimetallic nanoparticles. STEM imaging and energy dispersive X-ray spectroscopy (EDX) are used to show the influence that reaction kinetics have over the formation of structure in AuRh and AuPd nanorods. Correlated imaging and electron energy loss spectroscopy (EELS) are used to characterise the localised surface plasmon resonance (LSPR) response of single AuPd and AuRh nanorods, showing how ac-STEM can be used to ident
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44

Khimyak, Tetyana. "New bimetallic clusters - precursors for heterogeneous nano-catalysts." Thesis, University of Cambridge, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.620698.

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45

Wise, Anna MacDonald. "Characterisation of bimetallic alloy and core-shell electrocatalysts." Thesis, University of Southampton, 2012. https://eprints.soton.ac.uk/341819/.

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Core-shell electrocatalysts are of interest for the oxygen reduction reaction in proton exchange membrane fuel cells as enhancements in activity have been reported compared to the traditionally-used Pt/C electrocatalysts. To fully understand the origin of the activity of these samples, and how the structure changes in the electrochemical environment, full in situ structural characterisation is required. The aim of this work was to develop and apply in situ synchrotron based X-ray characterisation techniques (EXAFS, WAXS, SAXS and ASAXS) to study a set of well-defined Pd-core, Pt-shell electroc
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46

Van, Aswegen Sivan. "Exploring heterogeneous bimetallic nanoparticle catalysts for sustainable oxidations." Thesis, University of Southampton, 2017. https://eprints.soton.ac.uk/415218/.

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Prior work in the group has focused on developing the synthesis and activation of supported monometallic noble metal nanoparticle (Au, Pt and Pd) copper chlorophosphate frameworks (CuClPs), and exploring their potential as oxidation catalysts. Herein, bimetallic variants (AuPt/CuClP, PtPd/CuClP and AuPd/CuClP) have been synthesised, characterised and employed in catalytic reactions. Characterisation by TEM and XPS revealed the presence of small, metallic nanoparticles in the bimetallic CuClP materials, with the AuPt/CuClP sample containing the smallest and most uniform particles. The bimetalli
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47

Sundavadra, Bharat Viram. "The organometallic chemistry of alkyne-bridged bimetallic complexes." Thesis, University of Cambridge, 1993. https://www.repository.cam.ac.uk/handle/1810/272569.

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48

Lee, Adam Fraser. "Structural and catalytic properties of bimetallic Pd systems." Thesis, University of Cambridge, 1995. https://www.repository.cam.ac.uk/handle/1810/273061.

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49

Dylla, Anthony Greg. "Synthesis, characterization and catalytic properties of bimetallic nanoparticles." College Park, Md.: University of Maryland, 2009. http://hdl.handle.net/1903/9609.

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Thesis (Ph. D.) -- University of Maryland, College Park, 2009.<br>Thesis research directed by: Dept. of Chemistry and Biochemistry. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.
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50

Moon, Il Kweon. "Optical performance of bimetallic mirrors in thermal environments." Diss., The University of Arizona, 2001. http://hdl.handle.net/10150/279805.

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Evaluation of the optical performances of bimetallic mirrors with various substrate shapes was conducted using the finite element analysis program, SDRC-IDEAS. In these analyses, two different plating materials, nickel and aluminum were considered for an aluminum and a beryllium mirror substrate. Thermal environments used in this study are: a unit thermal soak (temperature difference), an axial temperature distribution, and radial temperature distributions on the mirror substrate. The goal of this study is to optimize the optical surface quality for various plating thicknessess. Surface errors
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