Academic literature on the topic 'Bimetallic complexes'

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Journal articles on the topic "Bimetallic complexes"

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Schenk, Wolfdieter A., and Thomas Gutmann. "Bimetallic complexes." Journal of Organometallic Chemistry 552, no. 1-2 (1998): 83–89. http://dx.doi.org/10.1016/s0022-328x(97)00582-2.

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Gutmann, Thomas, Eberhard Dombrowski, Nicolai Burzlaff, and Wolfdieter A. Schenk. "Bimetallic complexes." Journal of Organometallic Chemistry 552, no. 1-2 (1998): 91–98. http://dx.doi.org/10.1016/s0022-328x(97)00583-4.

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Platts, James A., Benson M. Kariuki, and Paul D. Newman. "Welcoming Neighbour or Inhospitable Host? Selective Second Metal Binding in 5- and 6-Phospha-Substituted Bpy Ligands." Molecules 29, no. 5 (2024): 1150. http://dx.doi.org/10.3390/molecules29051150.

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The controlled formation of mixed-metal bimetallics was realised through use of a fac-[Re(CO)3(N,N′-bpy-P)Cl] complex bearing an exogenous 2,4,6-trioxa-1,3,5,7-tetramethyl-8-phosphaadamantane donor at the 5-position of the bpy. The introduction of gold, silver, and rhodium with appropriate secondary ligands was readily achieved from established starting materials. Restricted rotation about the C(bpy)-P bond was observed in several of the bimetallic complexes and correlated with the relative steric bulk of the second metal moiety. Related chemistry with the 6-substituted derivative proved more
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Maslennikova, Vera I., Svetlana E. Goryukhina, Olga S. Serkova, and Edvard E. Nifantiev. "Bimetallic Complexes of Phosphocavitands." Phosphorus, Sulfur, and Silicon and the Related Elements 177, no. 8-9 (2002): 2219. http://dx.doi.org/10.1080/10426500213435.

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Le Gac, Stéphane, and Bernard Boitrel. "Structurally characterized bimetallic porphyrin complexes of Pb, Bi, Hg and Tl based on unusual coordination modes." Journal of Porphyrins and Phthalocyanines 20, no. 01n04 (2016): 117–33. http://dx.doi.org/10.1142/s1088424616300068.

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This minireview highlights the unusual coordination geometries observed in bimetallic complexes of mercury, thallium, lead and bismuth. These bimetallic complexes remain scarce and through an analysis of their X-ray structures, the various structural features that favorise them will be underlined.
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G., S. SODHI. "Fluorescence Studies on some Bimetallic Tetradithiocarbamate Complexes." Journal of Indian Chemical Society Vol. 68, Apr 1991 (1991): 236–37. https://doi.org/10.5281/zenodo.6135762.

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Department of Chemistry. S.G.T.B. Khalsa College, University of Delhi, Delhi-110 007 <em>Manuscript received 16 August 1989,&nbsp;revised 1 February 1991,&nbsp; accepted 8 April 1991</em> FLUORESCENCE<strong>&nbsp;</strong>studies on some bimetallic tetra&shy;dithiocarbamate complexes<sup>1</sup>&nbsp;of the type MCuL4 (M=Zn<sup>II</sup>, Cd<sup>II</sup>, Hg<sup>II</sup> ; L=N-ethyl cyclohexyldithio-carbamate) have been carried out. A number of photochemical parameters have been elucidated.
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Qin, C. Jin, Anna Gavrilova, and and B. Bosnich. "Cooperative bimetallic oxidative addition reactions." Pure and Applied Chemistry 73, no. 2 (2001): 221–26. http://dx.doi.org/10.1351/pac200173020221.

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The factors that control the oxidation of metals in bimetallic complexes are investigated in relation to the possibility of developing one-site addition two-metal oxidation reactions such as those that occur in the respiratory protein,hemerythrin. It is shown that the behavior of bimetallic complexes is not represented by the sum of the analogous monometallic parts because of metal and ligand interactions.
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P., P. SINGH, and SRIVASTAVA BEENA. "Bimetallic Complexes involving Schiff Base." Journal of Indian Chemical Society Vol. 63, Sep 1986 (1986): 797–800. https://doi.org/10.5281/zenodo.6298761.

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Chemistry Department, M L. K. (P. G.) College, Balrampur-271 201 <em>Manuscript received 6 May 1985, revised 19 May 1986, accepted 18 June 1986</em> Phenylmercury derivative (phHgSA) of Schiff base SAH derived from salicylaldehyde and aniline have been prepared. Reaction of this derivative with M(NCS)<sub>2</sub>, where M -&nbsp;Co<em><sup>II</sup></em>, Ni<em><sup>II</sup></em>, Cu<em><sup>ll</sup></em> and Zn<em><sup>II</sup></em>, gave complexes of general formulae (phHgSA)<sub>2</sub>M(NCS)<sub>2.</sub>&nbsp;These complexes on further reaction with pyridine or bipyridine (L) furnished addu
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Hu, Quan Yuan, та Guochen Jia. "Synthesis and electrochemical properties of bimetallic η5-indenyl ruthenium complexes". Canadian Journal of Chemistry 87, № 1 (2009): 134–38. http://dx.doi.org/10.1139/v08-106.

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Treatment of RuCl(dppm)(η5-C9H7) with alkynes HC≡C(C6H4)nC≡CH (n = 1, 2) in the presence of TlPF6 and t-BuONa affords the bimetallic ruthenium acetylide complexes [(η5-C9H7)(dppm)Ru]2(µ-C≡C(C6H4)nC≡C). Reactions of the hydride complex RuH(dppm)(η5-C9H7) with HC≡C(C6H4)nC≡CH (n = 1, 2) in refluxing toluene give the bimetallic ruthenium alkenyl complexes [(η5-C9H7)(dppm)Ru]2(µ-CH=CH(C6H4)nCH=CH). The electrochemical properties of the new complexes have been investigated by cyclic voltammetry, which reveals that the organic spacer –CH=CHC6H4CH=CH– is more effective than –C≡CC6H4C≡C– in mediating
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Balakrishnan, Nithya, Jebiti Haribabu, Ananda Krishnan Dhanabalan, et al. "Thiosemicarbazone(s)-anchored water soluble mono- and bimetallic Cu(ii) complexes: enzyme-like activities, biomolecular interactions, anticancer property and real-time live cytotoxicity." Dalton Transactions 49, no. 27 (2020): 9411–24. http://dx.doi.org/10.1039/d0dt01309a.

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Dissertations / Theses on the topic "Bimetallic complexes"

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Schütze, Mike. "Bimetallic Complexes for Cooperative Polymerization Catalysis." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://hdl.handle.net/11858/00-1735-0000-002E-E4A0-A.

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Judd, Lawrence. "Bimetallic complexes of meta-substituted phosphinobenzenes." Thesis, University of Warwick, 1988. http://wrap.warwick.ac.uk/110018/.

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The ligand m-bis(diphenylphosphino)benzene (m-BDPPB) has been prepared and has been found to form bimetallic complexes of various structural types. The most common of these is the trans.trans face-to-face structure as demonstrated by the complex [CI2Pt(u-m-BDPPB)2PtCL2. Other bimetallic complexes such as [X(Me)Pt(u-m-BDPPB)2Pt(Me)X] (X = Cl or I) and [Me(sol)Pt(u-m-BDPPB)2Pt(sol)Me]2+ (sol = acetone or acetonitrile) have been prepared and have been shown by 31P-{1H) and 1H n.m.r. spectroscopy to be fluxional at room temperature. The probable processes giving rise to this fluxionality are discu
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Wells, Jordann Ashley Logan Slovenne Denis. "Bimetallic actinide complexes for small molecule activation." Thesis, University of Edinburgh, 2018. http://hdl.handle.net/1842/31167.

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The work described in this thesis concerns the synthesis of actinide complexes and their reactivity towards small unsaturated molecules. Complexes bearing tetraphenoxide, borohydride and boroxide ligands have been evaluated. Additionally, work towards the synthesis of heterobimetallic uranium transition metal complexes and their applications in catalysis is discussed. Chapter one reviews important organoactinide complexes reported in the literature which effect chemical transformations on small unsaturated substrates. Actinide complexes supported by aryloxide or borohydride ligands are reviewe
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Beck, Victoria Holly. "Synthesis and characterisation of bimetallic organometallic complexes." Thesis, University of Oxford, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.403935.

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Sundavadra, Bharat Viram. "The organometallic chemistry of alkyne-bridged bimetallic complexes." Thesis, University of Cambridge, 1993. https://www.repository.cam.ac.uk/handle/1810/272569.

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Collins, Richard. "Bimetallic group 4 complexes as olefin polymerisation catalysts." Thesis, University of Oxford, 2016. https://ora.ox.ac.uk/objects/uuid:f6cad6bf-c925-4cda-9797-7b1916f98a0f.

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This Thesis describes the synthesis and characterisation of half-sandwich bimetallic complexes supported by &kappa;<sup>1</sup>-amidinate ligands with different bridging moieties. <b>Chapter 1</b> introduces homogeneous polyolefin catalysis with a focus on Group 4 metals. The mechanism, catalyst development and the activation chemistry of metallocene and post-metallocene catalysts are discussed. The beneficial properties generated by bimetallic catalysts through cooperative interactions are introduced. <b>Chapter 2</b> describes the synthesis, structures and copolymerisation capabilities of cy
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Wan, Susan Wai Yee. "Heterobimetallic complexes of the early transition metals." Thesis, University of Nottingham, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.284050.

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Fotheringham, John David. "Heterobimetallic complexes of the platinum group metals." Thesis, University of Edinburgh, 1987. http://hdl.handle.net/1842/10906.

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Metcalf, Clive. "Mono and bimetallic transtion metal complexes that bind DNA." Thesis, University of Sheffield, 2003. http://etheses.whiterose.ac.uk/3428/.

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This thesis reports the syntheses and DNA binding properties of a number of novel DNA binding complexes. A library of ruthenium(II) and rhenium(I) complexes incorporating extended terpyridine type ligands has been synthesised (1). The library consists of a series of structurally related complexes in which we have varied the number of hydrogen bonding sites, charge, chirality and steric demand on the complexes. Experimental data offers clear evidence that these complexes interact with DNA, possibly in an intercalative mode, and that varying the characteristics above has significant effects on t
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Vei, Ino C. "Studies on new diiminodiphosphine-type ligands and their metal complexes." Thesis, University of Oxford, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.269491.

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Books on the topic "Bimetallic complexes"

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Judd, Lawrence. Bimetallic complexes of meta-substituted phosphinobenzenes. typescript, 1988.

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Davies, Edward Stephen. The synthesis, structure and reactivity of bimetallic cycloheptatrienyl complexes. University of Manchester, 1994.

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Charsley, Stephen M. The synthesis and electrochemistry of bimetallic complexes of tris-3, 5 dimethylpyrazolylborato molybdenum. University of Birmingham, 1985.

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McWhinnie, Sean Lakshman William. A study of the interactions between metal centres in bimetallic complexes incorporating various bridging ligands. University of Birmingham, 1989.

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Striplin, Durwin R. Spectroscopic and magnetic investigations of Re(I)Cl(CO)₃(Ü,Üʹ-diimine) complexes and group (1B,8B) bimetallic complexes. 1994.

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Fraser, Cassandra. The development of open-closed bimetallic complexes for redox cooperative oxygen binding, activation, and oxygen transfer catalysis. 1993.

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Book chapters on the topic "Bimetallic complexes"

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Fernando, Ranelka G., Ciera D. Gasery, Marshall D. Moulis, and George G. Stanley. "Bimetallic Homogeneous Hydroformylation." In Homo- and Heterobimetallic Complexes in Catalysis. Springer International Publishing, 2016. http://dx.doi.org/10.1007/3418_2015_147.

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Page, Michael J., D. Barney Walker, and Barbara A. Messerle. "Alkyne Activation Using Bimetallic Catalysts." In Homo- and Heterobimetallic Complexes in Catalysis. Springer International Publishing, 2015. http://dx.doi.org/10.1007/3418_2015_148.

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Braunstein, Pierre, Michael Knorr, Thomas Stährfeldt, and Christine Stern. "The Unusual Chemistry of Bimetallic Silyl Complexes." In Selective Reactions of Metal-Activated Molecules. Springer Berlin Heidelberg, 1998. http://dx.doi.org/10.1007/978-3-662-00975-8_29.

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Astruc, D., C. Valério, J. L. Fillaut, J. Ruiz, J. R. Hamon, and F. Varret. "Electron-Reservoir Sandwich Complexes: From Mono- and Bimetallic Complexes to Molecular Trees." In Magnetism: A Supramolecular Function. Springer Netherlands, 1996. http://dx.doi.org/10.1007/978-94-015-8707-5_7.

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Forschner, T. C., A. R. Cutler, P. A. Goodson, C. P. Casey, W. Beck, and K. H. Sünkel. "Preparation of Some Bimetallic μ-(η1-C, O) Acetyl Complexes." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132579.ch41.

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Bitterwolf, Thomas E. "Polymer Bound Bimetallic Complexes as Surface Reactants on Semiconductor Electrodes." In Metal-Containing Polymeric Systems. Springer US, 1985. http://dx.doi.org/10.1007/978-1-4615-9415-4_7.

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Meskaldji, Samir, Abdellah Zaiter, Lotfi Belkhiri, and Abdou Boucekkine. "A relativistic DFT study of magnetic exchange coupling in ketimide bimetallic uranium(IV) complexes." In Vincenzo Barone. Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-642-34462-6_11.

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Geiger, William E., Christopher G. Atwood, and Teen T. Chin. "One- and Two-Electron Oxidations of Bimetallic Fulvalene Complexes Studied by Voltammetry and IR Spectroelectrochemistry." In Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1628-2_49.

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Weiss, Karin, Wilfried Guthmann, Michael Denzner, and Sergio Maisuls. "Syntheses of Heterogeneous, Bimetallic Metathesis Catalysts by Reactions of Fischer Type Carbene and Carbyne Complexes with Reduced Phillips Catalyst. Part XVIII (1)." In Olefin Metathesis and Polymerization Catalysts. Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-011-3328-9_20.

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Shafi, Kurikka V. P. M., Yuri Koltypin, Israel Felner, and Aharon Gedanken. "Sonochemical Synthesis of Amorphous Bimetallic Fe-Ni Alloys." In Properties of Complex Inorganic Solids. Springer US, 1997. http://dx.doi.org/10.1007/978-1-4615-5943-6_21.

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Conference papers on the topic "Bimetallic complexes"

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Dewilde, J. M., L. Bortels, C. Baeté, B. Van Den Bossche, and R. Steingass. "Galvanic Corrosion Prevention of Complex Assemblies through Modeling." In CORROSION 2012. NACE International, 2012. https://doi.org/10.5006/c2012-01660.

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Abstract Corrosion impacts the value, safety, and readiness of many assets in almost all industries. The cost of maintaining and repairing runs into astronomical numbers. The current approach to evaluate susceptibility to galvanic corrosion is by determining the relative position of metals in the galvanic series table valid for a given environment. However the potential difference between metals provides no information on the kinetics of galvanic or bimetallic corrosion. Additionally, there is a wide range of factors which affect the corrosion severity like surface area ratio, flow rate, tempe
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Goodwin, Fred. "Next Generation Galvanic Anodes." In CORROSION 2016. NACE International, 2016. https://doi.org/10.5006/c2016-07868.

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Abstract Discrete galvanic anodes are used to minimize the ring/incipient/halo anode effect in concrete repairs relying on sacrificial corrosion of a more active metal than conventional reinforcing steel to provide continued protection. The demand for this protection changes with time based on the corrosion activity of the steel requiring protection. When the concrete is repaired, the repair material creates a strongly cathodic area within the repair that accelerates corrosion in the reinforcing steel immediately adjacent to the repair area known as the ring or incipient anode or halo effect.
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Heck, Juergen, Hugo C. Brussard, Sven Dabek, Timo Meyer-Friedrichsen, and Hans Wong. "Bimetallic sandwichlike complexes as novel NLO chromophores." In Optical Science, Engineering and Instrumentation '97. SPIE, 1997. http://dx.doi.org/10.1117/12.284254.

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Wang, Qi, Satu Mikkola, Zoltan Jori, Mia Helkearo, and Harri Lönnberg. "Bimetallic Ca2+ and Zn2+ complexes of BISDIEN: Potential catalysts of RNA cleavage." In XIth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 1999. http://dx.doi.org/10.1135/css199902222.

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Fairooz, Fatema, Saniat Ahmed Choudhury, Nahid Ibn Ashraf, Washaka Mahdi, and Mustafa Habib Chowdhury. "Use of Bimetallic Plasmonic Nanoparticle Complexes for Enhancing Thin-Film Solar Cell Efficiency." In 2019 International Conference on Electrical, Computer and Communication Engineering (ECCE). IEEE, 2019. http://dx.doi.org/10.1109/ecace.2019.8679450.

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Delaney, Paul. "Performance of iron aluminium and copper iron bimetallic particles in removal of heavy metals and metalloids." In Proceedings of XVI International Mineral Processing and Recycling Conference, Belgrade, 28-30.05.2025. University of Belgrade, Technical Faculty, Bor, 2024. https://doi.org/10.5937/imprc25306d.

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Acid Mine drainage (AMD) often leads to the mobilisation of elements that can be toxic and/or valuable. This study compared the performance of iron-aluminium and copper-iron bimetallic particles in removal of heavy metals, cadmium, arsenic and chromium. These particles were synthesised by a cementation process with four different elemental ratios. Sulphuric acid solutions containing heavy metals were synthesised and treated with the bimetallic particles over 24 hours, with timed samples tested with inductively coupled plasma spectroscopy. Copper-Iron bimetallic (~8.76% Cu) had the best perform
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Kashuba, M., S. Agulnikov та M. Kulkova. "НОВОЕ О ПОГРЕБЕНИИ БЕЛОЗЕРСКОЙ КУЛЬТУРЫ ХАДЖИЛЛАР (МОЛДАВИЯ) В СВЕТЕ РАДИОУГЛЕРОДНОГО ДАТИРОВАНИЯ". У Радиоуглерод в археологии и палеоэкологии: прошлое, настоящее, будущее. Материалы международной конференции, посвященной 80-летию старшего научного сотрудника ИИМК РАН, кандидата химических наук Ганны Ивановны Зайцевой. Samara State University of Social Sciences and Education, 2020. http://dx.doi.org/10.31600/978-5-91867-213-6-40-41.

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The unique burial Hadjillar of the Belozerskaya culture was excavated in the Low Dniestr region (Moldova). Features of burial ritual and status items in the grave goods such as wooden cup decorated by bronze, bimetallic knife etc., distinguish this complex and this is evidences about high social rank of burial man. New AMS radiocarbon date on a wooden piece of cup discuses about early appearance of innovative technologies connected with iron metallurgy and manufacture of bimetallic (bronze/iron) items.
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Kleiser, Geremy, Michael Steinberg, and Lalit Chhabildas. "Feasibility of an Explosive End-Projector for Conducting Shock Loading Experiments." In ASME 2009 Pressure Vessels and Piping Conference. ASMEDC, 2009. http://dx.doi.org/10.1115/pvp2009-77202.

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This paper focuses on examining the feasibility of using an explosive end-projector device to conduct shock loading experiments. The concept employs an explosive end-projector to accelerate a bonded bimetallic impactor toward a stationary target material in order to conduct complex shock loading experiments. A high-impedance material, tantalum, was specifically selected to generate high stresses in targets. The driver plate materials were varied to create an impedance spectrum from 2 to 4 which would encompass materials from aluminum to zirconium. Techniques for launching single density metal
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Morovati Mamaghani, M. R., B. M. Dariani, and M. Haddadzade. "Blank Design by ANN in Bimetallic Deep Drawing." In ASME 2009 International Manufacturing Science and Engineering Conference. ASMEDC, 2009. http://dx.doi.org/10.1115/msec2009-84300.

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The present paper deals with the initial blank design of bimetallic parts obtained by deep drawing process. Normally in deep drawing, the initial blank has a simple shape and after drawing, its perimeter shape will become very complex and has considerable influences on the forming results. If the initial blank shape is designed in such a way that is formed into the desired shape after the drawing process, not only it reduces the time of trimming process, but also decreases the drawing force and the raw material needed substantially. The present paper proposes a novel approach to initial blank
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Aftandiliants, Yevhenii, Svyatoslav Gnyloskurenko, Helena Meniailo, and Valerii Khrychikov. "Influence of technological factors on formation process of bimetallic castings." In 22nd International Scientific Conference Engineering for Rural Development. Latvia University of Life Sciences and Technologies, Faculty of Engineering, 2023. http://dx.doi.org/10.22616/erdev.2023.22.tf080.

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The analysis of the modern state of wear-resistant metallic material production showed that one of the promising directions for improving their quality is the use of bimetallic steel-cast iron castings, which have a complex of properties differentiated over the volume and surface of the products. However, the problem of obtaining a high-quality joint of the steel base and the working cast iron layers is not completely solved at present. So, the research aims to determine the quality criterion of a good diffusion joint and to study the selected technological factor influence on the formation pr
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Reports on the topic "Bimetallic complexes"

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Brown, David Stephen. I. Redox chemistry of bimetallic fulvalene complexes II. Oligocyclopentadienyl complexes. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/10165274.

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McElwee-White, Lisa. Final technical report. Bimetallic complexes as methanol oxidation catalysts. Office of Scientific and Technical Information (OSTI), 2002. http://dx.doi.org/10.2172/771348.

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Schrock, R. R. Chemistry of bimetallic linked cyclopentadienyl complexes: Progress report, 1 December 1986--30 November 1989. Office of Scientific and Technical Information (OSTI), 1986. http://dx.doi.org/10.2172/5924493.

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Tso, Chung C., and Alan R. Cutler. Homo- and Hetero-Bimetallic Mu(Eta1-O:Eta1-O') Formate Complexes (M- OCHO-M')+PF6-(M,M'=(Eta5-C5H5)(CO)(NO)Re, (Eta5-C5H5)(CO)3W, and (Eta5-C5H5)(CO) 2Fe): Their Synthesis, Solution Lability, and Reactivity Towards Hydride Donors. Defense Technical Information Center, 1988. http://dx.doi.org/10.21236/ada203025.

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