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1

Schütze, Mike. "Bimetallic Complexes for Cooperative Polymerization Catalysis." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://hdl.handle.net/11858/00-1735-0000-002E-E4A0-A.

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2

Judd, Lawrence. "Bimetallic complexes of meta-substituted phosphinobenzenes." Thesis, University of Warwick, 1988. http://wrap.warwick.ac.uk/110018/.

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The ligand m-bis(diphenylphosphino)benzene (m-BDPPB) has been prepared and has been found to form bimetallic complexes of various structural types. The most common of these is the trans.trans face-to-face structure as demonstrated by the complex [CI2Pt(u-m-BDPPB)2PtCL2. Other bimetallic complexes such as [X(Me)Pt(u-m-BDPPB)2Pt(Me)X] (X = Cl or I) and [Me(sol)Pt(u-m-BDPPB)2Pt(sol)Me]2+ (sol = acetone or acetonitrile) have been prepared and have been shown by 31P-{1H) and 1H n.m.r. spectroscopy to be fluxional at room temperature. The probable processes giving rise to this fluxionality are discu
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3

Wells, Jordann Ashley Logan Slovenne Denis. "Bimetallic actinide complexes for small molecule activation." Thesis, University of Edinburgh, 2018. http://hdl.handle.net/1842/31167.

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The work described in this thesis concerns the synthesis of actinide complexes and their reactivity towards small unsaturated molecules. Complexes bearing tetraphenoxide, borohydride and boroxide ligands have been evaluated. Additionally, work towards the synthesis of heterobimetallic uranium transition metal complexes and their applications in catalysis is discussed. Chapter one reviews important organoactinide complexes reported in the literature which effect chemical transformations on small unsaturated substrates. Actinide complexes supported by aryloxide or borohydride ligands are reviewe
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4

Beck, Victoria Holly. "Synthesis and characterisation of bimetallic organometallic complexes." Thesis, University of Oxford, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.403935.

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5

Sundavadra, Bharat Viram. "The organometallic chemistry of alkyne-bridged bimetallic complexes." Thesis, University of Cambridge, 1993. https://www.repository.cam.ac.uk/handle/1810/272569.

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6

Collins, Richard. "Bimetallic group 4 complexes as olefin polymerisation catalysts." Thesis, University of Oxford, 2016. https://ora.ox.ac.uk/objects/uuid:f6cad6bf-c925-4cda-9797-7b1916f98a0f.

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This Thesis describes the synthesis and characterisation of half-sandwich bimetallic complexes supported by &kappa;<sup>1</sup>-amidinate ligands with different bridging moieties. <b>Chapter 1</b> introduces homogeneous polyolefin catalysis with a focus on Group 4 metals. The mechanism, catalyst development and the activation chemistry of metallocene and post-metallocene catalysts are discussed. The beneficial properties generated by bimetallic catalysts through cooperative interactions are introduced. <b>Chapter 2</b> describes the synthesis, structures and copolymerisation capabilities of cy
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7

Wan, Susan Wai Yee. "Heterobimetallic complexes of the early transition metals." Thesis, University of Nottingham, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.284050.

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8

Fotheringham, John David. "Heterobimetallic complexes of the platinum group metals." Thesis, University of Edinburgh, 1987. http://hdl.handle.net/1842/10906.

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9

Metcalf, Clive. "Mono and bimetallic transtion metal complexes that bind DNA." Thesis, University of Sheffield, 2003. http://etheses.whiterose.ac.uk/3428/.

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This thesis reports the syntheses and DNA binding properties of a number of novel DNA binding complexes. A library of ruthenium(II) and rhenium(I) complexes incorporating extended terpyridine type ligands has been synthesised (1). The library consists of a series of structurally related complexes in which we have varied the number of hydrogen bonding sites, charge, chirality and steric demand on the complexes. Experimental data offers clear evidence that these complexes interact with DNA, possibly in an intercalative mode, and that varying the characteristics above has significant effects on t
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10

Vei, Ino C. "Studies on new diiminodiphosphine-type ligands and their metal complexes." Thesis, University of Oxford, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.269491.

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11

Johnson, Sean M. "Toward the Synthesis of Naphthalene-Bridged Bis-Triazole Bimetallic Complexes." Scholar Commons, 2017. http://scholarcommons.usf.edu/etd/6872.

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Bimetallic complexes are known to have unique electronic properties and are used in a variety of organic transformations as catalysts. The use of naphthalene-bridged bis- triazoles (NBT) for bimetallic complexes is unknown. NBTs have the unique property of being fluorescent stemming from a twisted intramolecular charge transfer. With the non- coplanar geometry and the distance between the 1,2,3-triazole rings, we hypothesized that 1,8-bis(4-phenyl-2H-1,2,3-triazol-2-yl)naphthalene (12) would be a suitable ligand to synthesize a bimetallic complex. The synthesis of 12 was optimized for large sc
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12

Metcalfe, Clive. "Mono and bimetallic transition metal complexes that bind to DNA." Thesis, University of Sheffield, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.490900.

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13

Tsai, Yi-Ju. "Two approaches to the design and synthesis of bimetallic complexes." Scholarly Commons, 2014. https://scholarlycommons.pacific.edu/uop_etds/272.

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Dirhodium complexes have been known for their catalytic reactivities toward C-H bond activation for nearly two decades. However, both experimental and theoretical studies have not given a clear explanation on the roles of each metal in the reactivities, largely due to the limited number of available bimetallic species. To study the system systematically, we set our goal to synthesize bimetallic complexes from two independent approaches. In the first approach, five N, N’ -diarylformamidines with symmetric or asymmetric substituents on the phenyl groups were synthesized and fully characterized.
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14

Van, Wyk Shane Cedrick. "Some new bimetallic nickel and palladium complexes for catalysis applications." University of the Western Cape, 2015. http://hdl.handle.net/11394/4873.

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>Magister Scientiae - MSc<br>This thesis reports on the syntheses of new bimetallic iminopyridyl nickel(II) and palladium(II) complexes as catalyst precursors for ethylene ligomerization/polymerization. Tetrahydrophenyl-linked iminopyridyl ligands, pyridin-2-ylmethyl-{4-[(pyridin-2-ylmethylimino)-methyl]-benzylidene}-amine (L1) and (2-pyridin-2-yl-ethyl)-{4-[(2-pyridin-2-yl-ethylimino)-methyl]-benzylidene}-amine (L2) were prepared via condensation from terephthaldehyde and 2 molar equivalents of a primary pyridylamine. Alkyl-linked iminopyridyl ligands N,N'-bis-pyridin-2-ylmethylene-propane-1
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15

Matsinha, Leah Charlie. "Aqueous phase catalysis using mono- and bimetallic transition metal complexes." Doctoral thesis, University of Cape Town, 2015. http://hdl.handle.net/11427/16704.

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Includes bibliographical references<br>The synthesis and characterization of monomeric and dimeric salicylaldimine water-soluble ligands is discussed. The salicylaldimine ligands (2.3-2.10) were synthesised via Schiff base condensation reactions of various amines with water-soluble sulfonated salicylaldehydes (2.1 and 2.2). The ligands were characterized using various analytical and spectroscopic techniques. Complexation reactions of these water-soluble ligands (2.3-2.10) with [Rh(COD)Cl]2 gave the corresponding water-soluble mononuclear (2.11-2.14) and binuclear (2.15-2.18) Rh(I) complexes. A
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16

Xue, Congcong. "Electrocatalytic and Photocatalytic CO2 Reduction by Ru-Re Bimetallic Complexes." The Ohio State University, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=osu1462205030.

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17

Lock, Philippa Edlyne. "The structures and dynamics of organometallic-arene complexes and bimetallic clusters /." *McMaster only, 2001.

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18

Kilpatrick, Alexander F. R. "Bimetallic complexes of d- and f-block metals with pentalene ligands." Thesis, University of Sussex, 2015. http://sro.sussex.ac.uk/id/eprint/53914/.

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The focus of this thesis is the synthesis and characterisation of organometallic complexes incorporating the silylated pentalene ligand, [C8H4{SiiPr3-1,4}2]2- (= Pn†), bound to more than one metal centre. In general, metals in low oxidation states from the d- and f-block of the periodic table have been selected for these bimetallic complexes, as they are potentially reactive with small molecule substrates. Chapter One introduces the pentalene molecule and its derivatives, and discusses their use as ligands in organometallic chemistry. Particular emphasis is given to the application of organome
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19

Kember, Michael R. "Bimetallic complexes as catalysts for the copolymerisation of epoxides and CO₂." Thesis, Imperial College London, 2010. http://hdl.handle.net/10044/1/6140.

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A series of novel macrocyclic ligands bearing amine and phenol donor atoms was synthesised, with differing substituents on the aromatic ring. These ligands were designed to allow incorporation of two metal centres in proximity within a flexible macrocyclic cavity. From these ligands, three new bimetallic zinc acetate complexes were produced. These complexes were the most active catalysts for the copolymerisation of CO2 and cyclohexene oxide at 1 atm CO2 pressure, which could significantly reduce the energy cost of plastic production. The catalysts produced poly(cyclohexene carbonate) with near
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20

Poulton, Andrew Michael. "Investigation into the uses of bimetallic alkyne complexes in organic synthesis." Thesis, Loughborough University, 2005. https://dspace.lboro.ac.uk/2134/34566.

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This thesis describes the use of both heterobimetallic and novel desymmetrised homobimetallic metal alkyne complexes in organic chemistry. A range of novel desymmetrised Co2(CO)5IPr-alkyne complexes have been synthesised and their reactivity investigated. This resulted in a highly diastereoselective thermal Pauson–Khand reaction. Previous protocols in the literature have had to use N-oxide promoters to achieve diastereoselectivity on desymmetrised bis-cobalt cores. The use of substituted dihydrofurans as cyclopropane surrogates for the formation of novel homobimetallic 1,3-dipoles has been rea
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21

Brinkmeier, Alexander. "Bimetallic Copper Complexes for Bioinspired Dioxygen Activation and Catalytic Water Oxidation." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://hdl.handle.net/11858/00-1735-0000-002E-E335-6.

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22

Manz, Dennis-Helmut. "Preorganized Bimetallic Nickel Complexes of Pyrazolate-Bridged Ligands for Cooperative Substrate Transformation." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2016. http://hdl.handle.net/11858/00-1735-0000-0023-3E41-E.

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23

Pastor, Michael B. "Bimetallic Complexes| The Fundamental Aspects of Metalmetal Interactions, Ligand Sterics and Application." Thesis, University of the Pacific, 2018. http://pqdtopen.proquest.com/#viewpdf?dispub=10932512.

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<p> Metal containing complexes have been used to catalyze various organic transformations for the past few decades. The success of several mononuclear catalysts led to transition metal catalysts used in pharmaceuticals, environmental, and industrial processes. While mononuclear complexes have been used extensively, bimetallic systems have received far less attention. Bimetallic or polynuclear sites are commonly found in metalloenzymes that perform elegant transformation in biological systems, underlying their significance. Inorganic chemists take inspiration from nature and design model bimeta
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24

Mason, Laura. "Synthesis, anion binding studies and applications of mono- and bimetallic lanthanide complexes." Thesis, University of Oxford, 2017. http://ora.ox.ac.uk/objects/uuid:285c82eb-c3c7-4ce4-a1eb-c72151b2ce15.

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This work describes the preparation and study of lanthanide complexes derived from heptadentate DO3A and DO3AM ligands. The work described encompasses a range of synthetic studies using conventional Click chemistry, novel gold catalysed couplings to prepare mono- and bi- metallic complexes and synthesis of DO3AM derivatives. These complexes have been used in a variety of studies to explore proton and anion binding events, and to develop catalysts for fluorination in protic solvents. Chapter one describes the fundamental properties of the lanthanides with a focus on their luminescent behaviour,
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25

Pastor, Michael Bernard. "Bimetallic complexes: The fundamental aspects of metal-metal interactions, ligand sterics and application." Scholarly Commons, 2018. https://scholarlycommons.pacific.edu/uop_etds/3559.

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Metal containing complexes have been used to catalyze various organic transformations for the past few decades. The success of several mononuclear catalysts led to transition metal catalysts used in pharmaceuticals, environmental, and industrial processes. While mononuclear complexes have been used extensively, bimetallic systems have received far less attention. Bimetallic or polynuclear sites are commonly found in metalloenzymes that perform elegant transformation in biological systems, underlying their significance. Inorganic chemists take inspiration from nature and design model bimetallic
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26

Yakushev, I. A., N. Y. Kozitsyna, O. N. Kondratyeva, M. N. Vargaftik, and I. I. Moiseev. "Mixed-Metal Palladium(II) Complexes: a Way from Heterometallic Carboxylates to Bimetallic Nanoparticles." Thesis, Sumy State University, 2013. http://essuir.sumdu.edu.ua/handle/123456789/35239.

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The paper describes some chemical transformations of the mixed-metal palladium (II) complexes, including interactions of binuclear complexes with pyridine, 1,10-phenanthroline and bipyridine; also described thermal and reductive transformations of some binuclear and pentanuclear nitrogen-containing complexes, in particular red-ox transformations in reductive media to yield mixed-metal nanomaterials. For this nanomaterials and nanoalloys also provided HREM and TEM investigations. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35239
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27

Whitman, Rachel A. "DNA Interactions of Bimetallic Ruthenium Complexes Containing Tridentate Ligands with Extended p-Systems." The Ohio State University, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=osu1409061017.

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28

Tarhuni, Sarah. "Mixed valency in redox-active, all-carbon bridged bimetallic complexes of iron and molybdenum." Thesis, University of Manchester, 2016. https://www.research.manchester.ac.uk/portal/en/theses/mixed-valency-in-redoxactive-allcarbon-bridged-bimetallic-complexes-of-iron-and-molybdenum(8e081a41-817f-4e98-bc89-c2e1a44e10fe).html.

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This thesis describes the development of new procedures for the synthesis of homo- and hetero-bimetallic complexes [M-(C≡C-C≡C)-M*] linked by a butadiyndiyl (-C≡C-C≡C-) bridge (where M, M* = Mo(dppe)(η-C7H7) and Fe(dppe)Cp) and also of the diethynyl-anthracenyl bridged complex [{Mo(dppe)(-C7H7)}2(μ-C≡CC14H8C≡C)] in which an anthracenyl group is inserted into the butadiyndiyl bridge. The redox chemistry and mixed valence character of these systems are investigated by a range of synthetic, electrochemical and spectroscopic techniques. Chapter 1: (Introduction) presents a literature review relat
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29

Mattox, Tracy Marie. "Synthesis of Bimetallic Paddlewheel Complexes and Metal Organic Frameworks for Future Use in Catalysis." Miami University / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=miami1164726701.

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30

Chen, Loren. "Syntheses, characterization and reactivity studies of some phosphido-bridged cyclopentadienyl cobalt(II) bimetallic complexes /." The Ohio State University, 1985. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487261553059417.

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31

Netto, Caterina Gruenwaldt Cunha Marques. "Desenvolvimento de catalisadores e sistemas enzimáticos para a redução do CO2." Universidade de São Paulo, 2013. http://www.teses.usp.br/teses/disponiveis/46/46136/tde-08052013-084051/.

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O gás carbônico é a fonte primária de carbono ideal para se obter novos compostos, devido principalmente à sua abundância, atoxidade e ao fato de ser renovável. Desta forma, novos métodos de introduzir o CO2 em rotas sintéticas se fazem necessários. Dentre os possíveis métodos, nesta tese foram estudadas duas rotas diferentes de utilização do gás carbônico: uma, empregando complexos bimetálicos como catalisadores da inserção do CO2 em alcenos e alcanos e outra utilizando enzimas imobilizadas em partículas magnéticas, atuantes no ciclo de redução do CO2 ao metanol. Os complexos bimetálicos fora
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32

Li, Kaiyu. "Supramolecular Ruthenium(II) and Osmium(II) Complexes: Synthesis, Characterization, DNA Binding and DNA Photocleavage." University of Dayton / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1513235232385279.

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33

Fyfe, Andrew Alston. "d- and f-metal alkoxy-tethered N-heterocyclic carbene complexes." Thesis, University of Edinburgh, 2016. http://hdl.handle.net/1842/15862.

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Chapter one is an introduction, outlining the structure and bonding of N-heterocyclic carbenes (NHCs). It then goes on to give examples of f -metal NHC complexes and describes any reactivity or catalytic activity. Chapter two describes the synthesis of the transition metal NHC complexes [Fe (LMes)2] 3 and [Co(LMes)2] 4 (LMes = OCMe2 CH2(1-C{NCH2CH2NMes})). The heterobimetallic complexes [(LMes)Fe(μ-LMes)U(μ-{N(SiMe3)Si(Me)2CH2})(N(Si Me3)2)2] 5 and [(LMes)Co(μ-LMes)U(μ-{N(SiMe3)Si(Me)2CH2})(N(SiMe3)2)2] 6 were prepared from the reaction between [({Me3Si}2N)2U(NSiMe3SiMe2CH2)] and 3 or 4, respe
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34

Sayre, Hannah Joy. "Modification of Excited State Behavior with Ligand Substitution in Ru(II),Rh(III) Bimetallic Supramolecular Complexes." Thesis, Virginia Tech, 2015. http://hdl.handle.net/10919/75150.

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The terminal ligand in [(Ph₂phen)₂Ru(dpp)RhCl₂(TL)](PF₆)₃ (Ph2phen = 4,7-diphenyl1,10-phenanthroline; dpp = 2,3-bis(2-pyridyl)pyrazine; TL = terminal ligand – a 4,4′-disubstituted-2,2′-bipyridine where the substituent was carbomethoxy (dcmbpy), hydrogen (bpy) or methyl (Me₂bpy)). The electron-withdrawing ability of the substituent was shown to increase the rate of chloride loss upon electrochemical reduction, facilitating catalytic water reduction. The electronic properties of the terminal ligand also impact the photophysical properties of the molecule. The excited state lifetime of the comple
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35

Supplee, Carolyn. "Synthesis and characterization of bimetallic palladium and platinum complexes resulting from chelating tertiary/secondary diphosphine ligands /." The Ohio State University, 1989. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487599963591294.

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36

Zhang, Hongtu. "Activation of Small Molecule and Organic Substrates by Tris(Phosphinoamide) Zr/Co Heterobimetallic Complexes." The Ohio State University, 2020. http://rave.ohiolink.edu/etdc/view?acc_num=osu1594900050962052.

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37

Imler, Gregory H. "Reactivity, Characterization, Equilibrium Thermodynamics and Hetero-bimetallic Studies of Tridentate and Tetradentate Complexes Relevant to Syngas Catalysis." Diss., Temple University Libraries, 2014. http://cdm16002.contentdm.oclc.org/cdm/ref/collection/p245801coll10/id/302256.

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Chemistry<br>Ph.D.<br>The unifying objective of this work is the study of model systems that will assist in the development of new metal catalysts capable of converting carbon monoxide and hydrogen (syngas) into organic oxygenates at mild temperature and pressure. The selective catalytic transformation of carbon monoxide and hydrogen to liquid fuels and chemical feedstocks represents a major "Grand Challenge" of catalysis science. A core objective is the study of a macrocycle that is related to a porphyrin ligand in order to circumvent some of the disadvantages of utilizing porphyrins in catal
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38

Chambers, Matthew Burke. "Ligand field considerations for the reactivity of high valent metal-oxo complexes and of bimetallic HX splitting photocatalysts." Thesis, Massachusetts Institute of Technology, 2013. http://hdl.handle.net/1721.1/82312.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2013.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references.<br>Inorganic molecular complexes are used to probe mechanistic steps in two reaction reactions related to energy storage. The first reaction considered is the O-O bond formation step required for water oxidation to oxygen. The second reaction considered is the photocatalytic generation of hydrogen and halogen from hydrohalic acid. Regarding the O-O bond formation process, terminal metal oxo complexes of pseudotetrahedral geometry wer
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39

Sturgeon, Matthew Robert. "Cyanide Bridged Multimetallics Derived From Extended Arrays of Alkaline Earth, Rare Earth, and Transition Metals: A Study From Complexes To Catalysts." The Ohio State University, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=osu1250009077.

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40

White, Travis Azor. "Design and Modification of Polyazine-Bridged Ru(II),Rh(III) Bimetallic and Trimetallic Supramolecular Complexes Applicable in Solar Energy Harvesting for the Photocatalytic Reduction of Water to Hydrogen." Diss., Virginia Tech, 2012. http://hdl.handle.net/10919/77230.

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The goal of this research was to develop a series of mixed-metal supramolecular complexes through systematic component variation to better understand the role of structural modification on basic chemical and photochemical properties including photocatalysis of H₂O to H₂. Varying bidentate polypyridyl terminal ligands (TL), non-chromophoric halides (X), or number of Ru(II) light absorbers (LA) tunes the electrochemical, spectroscopic, photophysical, and photochemical properties within the supramolecular architecture. Ru(II),Rh(III),Ru(II) trimetallics of the design [{(TL)₂Ru(dpp)}₂RhX₂](PF₆)₅ (
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41

Wenzel, Margot. "Synthèse de complexes organobimétalliques à activité biologique." Thesis, Dijon, 2013. http://www.theses.fr/2013DIJOS089.

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Un axe de recherche particulièrement développé en chimie organométallique moderneconcerne la recherche d’agents chimiothérapeutiques alternatifs au cisplatine dans lestraitements contre le cancer. Dans ce domaine, plusieurs stratégies ont été développées depuisplusieurs dizaines d’années, parmi lesquelles nous pouvons citer la multinucléarité, consistanten la création d’édifices polymétalliques. L’objectif de la première partie de ce manuscrits’inscrit dans cette thématique, par la conception, l’obtention et l’étude des propriétésbiologiques de complexes hétérobimétalliques "early-late" (Ti-Ru
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42

Brinkmeier, Alexander [Verfasser], Franc [Akademischer Betreuer] Meyer, Franc [Gutachter] Meyer, and Sven [Gutachter] Schneider. "Bimetallic Copper Complexes for Bioinspired Dioxygen Activation and Catalytic Water Oxidation / Alexander Brinkmeier ; Gutachter: Franc Meyer, Sven Schneider ; Betreuer: Franc Meyer." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://d-nb.info/1175204781/34.

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43

Mayberry, Darrell D. "Synthesis, Characterization, and Reactivity of Prochiral Ruthenium Clusters and Bimetallic Rhenium Complexes with an Unsymmetrical Diphosphine and Hard-Soft Donor Ligands." Thesis, University of North Texas, 2019. https://digital.library.unt.edu/ark:/67531/metadc1538707/.

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The reaction of [BrRe(CO)₄]₂ with 2-(diphenylphosphino)pyridine (PN) and 6-(diphenylphosphino)-2-formylpyridine (PON) was investigated. The reactions were regiospecific and exclusively produced the phosphorus-coordinated products, BrRe(CO)₄(κᵖ-PN) and BrRe(CO)₄(κᴾ-PON). The kinetics for the chelate ring closure (κᴾ→ κᴾᴺ) in BrRe(CO)₄(κᴾ-PN) were confirmed to occur by dissociative CO loss. The reaction of [BrRe(CO)₄]₂ with 2-(diphenylphosphino)pyridine (PN) was modeled computationally by DFT calculations. The preferred reaction pathway for the substitution reaction was determined to occur by di
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44

Kositzki, Ramona [Verfasser]. "Metal Centers in Hydrogenases, Bimetallic Oxidases, and Model Complexes Studied by Advanced X-ray Spectroscopy Techniques and Quantum Chemistry / Ramona Kositzki." Berlin : Freie Universität Berlin, 2020. http://d-nb.info/1216503656/34.

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45

Bertrand, Benoit. "Gold-based complexes : synthesis and evaluation as anticancer agents." Thesis, Dijon, 2015. http://www.theses.fr/2015DIJOS013.

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Depuis sa mise sur le marché à la fin des années 70, le Cisplatin est devenu l’un des pricipaux agents de chimiothérapie anticancéreuse. Actuellement, les composés à base de platine sont présents dans la majorité des coktails de chimiothérapie. Cependant, malgré leur succès clinique, ces composés présentent de nombreux inconvenients comme par exemple de nombreux et graves effets secondaires. Une des stratégies envisagées pour parer à ces défauts a été de remplacer le platine par d’autres métaux de transition. Parmi les différents métaux possibles, l’or est apparu comme particulièrement promett
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46

Haas, Ruth Marlen [Verfasser], Corinna [Akademischer Betreuer] Hess, Corinna [Gutachter] Hess, and Klaus [Gutachter] Köhler. "Unsymmetric Redoxactive Ligands for Mono- and Bimetallic Complexes; Synthesis and Characterisation / Ruth Marlen Haas ; Gutachter: Corinna Hess, Klaus Köhler ; Betreuer: Corinna Hess." München : Universitätsbibliothek der TU München, 2018. http://d-nb.info/1177241390/34.

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47

Manz, Dennis-Helmut [Verfasser], Franc [Akademischer Betreuer] [Gutachter] Meyer, and Sven [Gutachter] Schneider. "Preorganized Bimetallic Nickel Complexes of Pyrazolate-Bridged Ligands for Cooperative Substrate Transformation / Dennis-Helmut Manz ; Gutachter: Franc Meyer, Sven Schneider ; Betreuer: Franc Meyer." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2017. http://d-nb.info/114200130X/34.

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48

Dandachi, Hiba. "Nouveaux Complexes Oligomères Cycliques de Salens Chiraux pour la Catalyse Asymétrique." Thesis, Université Paris-Saclay (ComUE), 2015. http://www.theses.fr/2015SACLS106/document.

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Abstract:
Les ligands de type salen constituent la pierre angulaire des travaux décrits dans cette thèse. L’attention particulière portée aux complexes chiraux correspondants est due à leur utilisation comme catalyseurs énantiosélectives versatiles pour promouvoir une large gamme de réactions d’intérêt. Dans le contexte de la catalyse asymétrique hétérogène, nous nous focalisons plus particulièrement sur l’élaboration de catalyseurs polymères cycliques de salens chiraux, appelés complexes calixsalens. Ainsi, nous avons mis au point une voie d’accès directe aux calixsalens de cobalt (III) par polycondens
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Schütze, Mike [Verfasser], Franc [Akademischer Betreuer] Meyer, Franc [Gutachter] Meyer, et al. "Bimetallic Complexes for Cooperative Polymerization Catalysis / Mike Schütze ; Gutachter: Franc Meyer, Philipp Vana, Marc Walter, Matthias Otte, Shoubhik Das, Selvan Demir ; Betreuer: Franc Meyer." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://d-nb.info/116695062X/34.

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50

Wertz, Ashlee Elizabeth. "Bimetallic Ruthenium(II) Polypyridyl Complexes Bridged by a Boron Dipyrromethene (BODIPY): Synthesis, Spectroscopic and Plasmid DNA Photoreactions and The Impact of the 515 nm Effect in Photosynthesis: Model System Using β-Carotene Acid Complexes". University of Dayton / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1556044670985672.

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