Journal articles: 'Bimetallic complexes'

1

Schenk, Wolfdieter A., and Thomas Gutmann. "Bimetallic complexes." Journal of Organometallic Chemistry 552, no. 1-2 (1998): 83–89. http://dx.doi.org/10.1016/s0022-328x(97)00582-2.

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2

Gutmann, Thomas, Eberhard Dombrowski, Nicolai Burzlaff, and Wolfdieter A. Schenk. "Bimetallic complexes." Journal of Organometallic Chemistry 552, no. 1-2 (1998): 91–98. http://dx.doi.org/10.1016/s0022-328x(97)00583-4.

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3

Platts, James A., Benson M. Kariuki, and Paul D. Newman. "Welcoming Neighbour or Inhospitable Host? Selective Second Metal Binding in 5- and 6-Phospha-Substituted Bpy Ligands." Molecules 29, no. 5 (2024): 1150. http://dx.doi.org/10.3390/molecules29051150.

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The controlled formation of mixed-metal bimetallics was realised through use of a fac-[Re(CO)3(N,N′-bpy-P)Cl] complex bearing an exogenous 2,4,6-trioxa-1,3,5,7-tetramethyl-8-phosphaadamantane donor at the 5-position of the bpy. The introduction of gold, silver, and rhodium with appropriate secondary ligands was readily achieved from established starting materials. Restricted rotation about the C(bpy)-P bond was observed in several of the bimetallic complexes and correlated with the relative steric bulk of the second metal moiety. Related chemistry with the 6-substituted derivative proved more limited in scope with only the bimetallic Re/Au complex being isolated.

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Maslennikova, Vera I., Svetlana E. Goryukhina, Olga S. Serkova, and Edvard E. Nifantiev. "Bimetallic Complexes of Phosphocavitands." Phosphorus, Sulfur, and Silicon and the Related Elements 177, no. 8-9 (2002): 2219. http://dx.doi.org/10.1080/10426500213435.

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Le Gac, Stéphane, and Bernard Boitrel. "Structurally characterized bimetallic porphyrin complexes of Pb, Bi, Hg and Tl based on unusual coordination modes." Journal of Porphyrins and Phthalocyanines 20, no. 01n04 (2016): 117–33. http://dx.doi.org/10.1142/s1088424616300068.

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This minireview highlights the unusual coordination geometries observed in bimetallic complexes of mercury, thallium, lead and bismuth. These bimetallic complexes remain scarce and through an analysis of their X-ray structures, the various structural features that favorise them will be underlined.

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6

G., S. SODHI. "Fluorescence Studies on some Bimetallic Tetradithiocarbamate Complexes." Journal of Indian Chemical Society Vol. 68, Apr 1991 (1991): 236–37. https://doi.org/10.5281/zenodo.6135762.

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Department of Chemistry. S.G.T.B. Khalsa College, University of Delhi, Delhi-110 007 Manuscript received 16 August 1989, revised 1 February 1991,  accepted 8 April 1991 FLUORESCENCE studies on some bimetallic tetradithiocarbamate complexes1 of the type MCuL4 (M=ZnII, CdII, HgII ; L=N-ethyl cyclohexyldithio-carbamate) have been carried out. A number of photochemical parameters have been elucidated.

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7

Qin, C. Jin, Anna Gavrilova, and and B. Bosnich. "Cooperative bimetallic oxidative addition reactions." Pure and Applied Chemistry 73, no. 2 (2001): 221–26. http://dx.doi.org/10.1351/pac200173020221.

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The factors that control the oxidation of metals in bimetallic complexes are investigated in relation to the possibility of developing one-site addition two-metal oxidation reactions such as those that occur in the respiratory protein,hemerythrin. It is shown that the behavior of bimetallic complexes is not represented by the sum of the analogous monometallic parts because of metal and ligand interactions.

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8

P., P. SINGH, and SRIVASTAVA BEENA. "Bimetallic Complexes involving Schiff Base." Journal of Indian Chemical Society Vol. 63, Sep 1986 (1986): 797–800. https://doi.org/10.5281/zenodo.6298761.

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Chemistry Department, M L. K. (P. G.) College, Balrampur-271 201 Manuscript received 6 May 1985, revised 19 May 1986, accepted 18 June 1986 Phenylmercury derivative (phHgSA) of Schiff base SAH derived from salicylaldehyde and aniline have been prepared. Reaction of this derivative with M(NCS)2, where M - CoII, NiII, Cull and ZnII, gave complexes of general formulae (phHgSA)2M(NCS)2. These complexes on further reaction with pyridine or bipyridine (L) furnished adducts of general formula (phHgSA)2 M(NCS)2\(Lx\), where x -1 or 2. All the complexes have been characterised by elemental analysis, molecular weight, molar conductance, infrared and electronic spectral data. On the basis of these studies, probable structure of the complexes and quantitative softness parameters have been evaluated.

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9

Hu, Quan Yuan, та Guochen Jia. "Synthesis and electrochemical properties of bimetallic η5-indenyl ruthenium complexes". Canadian Journal of Chemistry 87, № 1 (2009): 134–38. http://dx.doi.org/10.1139/v08-106.

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Treatment of RuCl(dppm)(η5-C9H7) with alkynes HC≡C(C6H4)nC≡CH (n = 1, 2) in the presence of TlPF6 and t-BuONa affords the bimetallic ruthenium acetylide complexes [(η5-C9H7)(dppm)Ru]2(µ-C≡C(C6H4)nC≡C). Reactions of the hydride complex RuH(dppm)(η5-C9H7) with HC≡C(C6H4)nC≡CH (n = 1, 2) in refluxing toluene give the bimetallic ruthenium alkenyl complexes [(η5-C9H7)(dppm)Ru]2(µ-CH=CH(C6H4)nCH=CH). The electrochemical properties of the new complexes have been investigated by cyclic voltammetry, which reveals that the organic spacer –CH=CHC6H4CH=CH– is more effective than –C≡CC6H4C≡C– in mediating electronic communication between the two ruthenium moieties.Key words: ruthenium, bimetallic, acetylide, insertion, electrochemistry.

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10

Balakrishnan, Nithya, Jebiti Haribabu, Ananda Krishnan Dhanabalan, et al. "Thiosemicarbazone(s)-anchored water soluble mono- and bimetallic Cu(ii) complexes: enzyme-like activities, biomolecular interactions, anticancer property and real-time live cytotoxicity." Dalton Transactions 49, no. 27 (2020): 9411–24. http://dx.doi.org/10.1039/d0dt01309a.

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11

Uson, Rafael, Antonio Laguna, Mariano Laguna, Blanca R. Manzano, and Amado Tapia. "Bimetallic gold—silver pentachlorophenyl complexes." Inorganica Chimica Acta 101, no. 3 (1985): 151–53. http://dx.doi.org/10.1016/s0020-1693(00)87648-3.

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12

Kumbhar, Sadhana, Saibal Jana, Anakuthil Anoop, and Mark P. Waller. "Cooperativity in bimetallic glutathione complexes." Journal of Molecular Graphics and Modelling 62 (November 2015): 1–10. http://dx.doi.org/10.1016/j.jmgm.2015.05.003.

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13

Prosenc, Marc Heinrich, Gereon Niedner-Schatteburg, and Manfred Kappes. "4. Internationale Tagung „Bimetallic Complexes“." Nachrichten aus der Chemie 66, no. 12 (2018): 1199. http://dx.doi.org/10.1002/nadc.20184082725.

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14

Coste, Scott C., Tyler J. Pearson, Alison B. Altman, et al. "Orbital energy mismatch engenders high-spin ground states in heterobimetallic complexes." Chemical Science 11, no. 36 (2020): 9971–77. http://dx.doi.org/10.1039/d0sc03777j.

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We report a series of high spin bimetallic transition metal–tin complexes. The unusual high spin configuration in a bimetallic complex is enabled by an energetic mismatch in the orbital energies, leading to lanthanide-like nonbonding interactions.

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15

Chalmers, Brian A., David B. Cordes, Lauren Bertram, et al. "Heteronuclear Bimetallic Complexes with 3d and 4f Elements." Molbank 2023, no. 1 (2023): M1577. http://dx.doi.org/10.3390/m1577.

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Three heteronuclear bimetallic complexes [Cu(MeOH)(L)Ln(NO3)3] (1-Ce; Ln = Ce, 1-Pr; Ln = Pr, and 1-Nd; Ln = Nd) were prepared using H2L (1,3-bis[(3-methoxysalicylidene)amino]-2,2-dimethylpropane) in methanol, affording the complexes as green crystalline materials. These can be prepared in a one-pot synthesis from 2,2-dimethylpropan-1,3-diamine, o-vanillin, copper(II) nitrate, and Ln(III) nitrate (Ln = Ce, Pr, Nd). X-ray crystallography, high-resolution mass spectrometry, and UV-vis spectroscopy were used to characterize the bimetallic complexes. All three complexes showed the copper center adopting a five-coordinate square pyramidal geometry and the lanthanoid cation adopting a ten-coordinate geometry.

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Stafford, Verity S., Kogularamanan Suntharalingam, Arun Shivalingam, Andrew J. P. White, David J. Mann, and Ramon Vilar. "Syntheses of polypyridyl metal complexes and studies of their interaction with quadruplex DNA." Dalton Transactions 44, no. 8 (2015): 3686–700. http://dx.doi.org/10.1039/c4dt02910k.

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17

Lončarević, Andrea, Karla Ostojić, Inga Urlić, and Anamarija Rogina. "Preparation and Properties of Bimetallic Chitosan Spherical Microgels." Polymers 15, no. 6 (2023): 1480. http://dx.doi.org/10.3390/polym15061480.

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The aim of this work was to prepare bimetallic chitosan microgels with high sphericity and investigate the influences of metal-ion type and content on the size, morphology, swelling, degradation and biological properties of microgels. Amino and hydroxyl groups of chitosan (deacetylation degree, DD, of 83.2% and 96.9%) served as ligands in the Cu2+–Zn2+/chitosan complexes with various contents of cupric and zinc ions. The electrohydrodynamic atomization process was used to produce highly spherical microgels with a narrow size distribution and with surface morphology changing from wrinkled to smooth by increasing Cu2+ ions’ quantity in bimetallic systems for both used chitosans. The size of the bimetallic chitosan particles was estimated to be between 60 and 110 µm for both used chitosans, and FTIR spectroscopy indicated the formation of complexes through physical interactions between the chitosans’ functional groups and metal ions. The swelling capacity of bimetallic chitosan particles decreases as the DD and copper (II) ion content increase as a result of stronger complexation with respect to zinc (II) ions. Bimetallic chitosan microgels showed good stability during four weeks of enzymatic degradation, and bimetallic systems with smaller amounts of Cu2+ ions showed good cytocompatibility for both used chitosans.

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Pradhan, Alaka Nanda, Shivankan Mishra, Urminder Kaur, Bikram Keshari Rout, Jean-François Halet, and Sundargopal Ghosh. "Bimetallic Perthiocarbonate Complexes of Cobalt: Synthesis, Structure and Bonding." Molecules 29, no. 11 (2024): 2688. http://dx.doi.org/10.3390/molecules29112688.

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The syntheses and structural elucidation of bimetallic thiolate complexes of early and late transition metals are described. Thermolysis of the bimetallic hydridoborate species [{Cp*CoPh}{µ-TePh}{µ-TeBH3-ĸ2Te,H}{Cp*Co}] (Cp* = ɳ5-C5Me5) (1) in the presence of CS2 afforded the bimetallic perthiocarbonate complex [(Cp*Co)2(μ-CS4-κ1S:κ2S′)(μ-S2-κ2S″:κ1S‴)] (2) and the dithiolene complex [(Cp*Co)(μ-C3S5-κ1S,S′] (3). Complex 2 contains a four-membered metallaheterocycle (Co2S2) comprising a perthiocarbonate [CS4]2− unit and a disulfide [S2]2− unit, attached opposite to each other. Complex 2 was characterized by employing different multinuclear NMR, infrared spectroscopy, mass spectrometry, and single-crystal X-ray diffraction studies. Preliminary studies show that [Cp*VCl2]3 (4) with an intermediate generated from CS2 and [LiBH4·THF] yielded thiolate species, albeit different from the cobalt system. Furthermore, a computational analysis was performed to provide insight into the bonding of this bimetallic perthiocarbonate complex.

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19

Dharmveer, Singh, Verma Shalini, Shankar Vijay, and Krishna V. "Stability constants determination of homo and hetero bimetallic complexes of tmdta in aqueous solution." Journal of Indian Chemical Society 93, Jul 2016 (2016): 725–33. https://doi.org/10.5281/zenodo.5637771.

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Department of Chemistry, University of Allahabad, Allahabad-211 002, Uttar Pradesh, India E-mail : vkrishnaalld@rediffmail.com Department of Chemistry, B.S.N.V. Post Graduate College, Lucknow-226 001, Uttar Pradesh, India  Reaction of divalent metal ions, CuII, NiII, ZnII, CoII and CdII with ligand L (L = trimethylenediaminetetraacetic acid) for binary and ternary complexes were potentiometrically investigated in aqueous solution at 30 ± 0.1 ºC and I = 0.1 M (NaNO3). The binary (1 : 1, 2 : 1) and ternary (1 : 1 : 1) complexes of ligand were formed in a simultaneous manner. In homo bimetallic system the formation of M2L complexes occurred without formation of ML complexes while the formations of hetero bimetallic complexes follow the formation of binary ML complexes. The observed concentration of species formation of binary and ternary complexes obtained by SCOGS computer program and plotted using Origin 6.1. The stability constants of complexes were calculated by SCOGS computer programe using potentiometric pH-metric titration values. The relative stabilities of the ternary complexes were found higher compared to corresponding binary complexes in terms of log βpqrt values.

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20

Duan, Zhen Xiao, Tao Fang, Min Wang, and Guo Zhi Fan. "Chemical Fixation of Carbon Dioxide Catalyzed by Bimetallic Aluminum(Salen) Complex." Advanced Materials Research 549 (July 2012): 406–10. http://dx.doi.org/10.4028/www.scientific.net/amr.549.406.

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Bimetallic aluminum(salen) complexes were prepared and used as catalyst for the synthesis of DPC from CO2 and phenol in the presence of carbon tetrachloride. The bimetallic complex derived from 3,5-ditert salicylaldehyde and 1,2-cyclohexanediamine revealed more excellent activity than that obtained in the presence of other complexes and the simple Lewis acid ZnCl2. The influence of the amount of complex and the reaction conditions including the pressure of CO2 and the reaction temperature was also investigated.

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21

Sodhi, G. S., and J. Kaur. "Thermogravimetric Studies on Bimetallic Dithiocarbamate Complexes." Zeitschrift für Naturforschung B 47, no. 9 (1992): 1297–99. http://dx.doi.org/10.1515/znb-1992-0914.

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Thermogravimetric (TG) studies have been carried out for some bimetallic dithiocarbamate complexes of the type ZnML4 and NiM′L′4 [M = Co(II), Cu(II); M′ = Zn(II), Hg(II); L = N-methylcyclohexyldithiocarbamate; L′ = N-ethylcyclohexyldithiocarbamate]. From TG curves, the order, apparent activation energy and apparent activation entropy for the thermal decomposition reaction have been calculated. The thermal stabilities have been correlated with the structures of the complexes on the basis of hard and soft acid base (HSAB) theory.

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22

Himmelsbach, M., R. L. Lintvedt, J. K. Zehetmair, M. Nanny, and M. J. Heeg. "Neutral bimetallic macrocyclic complexes. 1. Investigation of mono- and bimetallic complexes of tetraiminato macrocyclic complexes derived from 1,3,5-triketones." Journal of the American Chemical Society 109, no. 26 (1987): 8003–11. http://dx.doi.org/10.1021/ja00260a010.

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23

Dowling, Carolyn, Danielle R. Dinsdale, and Martin T. Lemaire. "Preparation, electrochemical behavior, and variable-temperature magnetic properties of Co(3,5-DBSQ)2 complexes of imidazole- or pyrazole-substituted ligands." Canadian Journal of Chemistry 93, no. 7 (2015): 769–74. http://dx.doi.org/10.1139/cjc-2014-0583.

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Herein we describe the preparation of four new Co(3,5-DBSQ)2 containing known 2-(2-pyridyl)benzimidazole 1, 2,2′-bisbenzimidazole 2, or 2,2-(1H-pyrazole-3,5-diyl)dipyridine 3. We investigate the electronic and variable-temperature magnetic susceptibility properties of these complexes. Complexes containing 2 and 3 are bimetallic and variable-temperature magnetic susceptibility data suggest observation of a stable intermediate (high-spin and low-spin) state for the bimetallic complex with 3, which does undergo valence tautomerism. Complexes 4–6 containing imidazole-based ligands 1 and 2 feature high-spin ground states and no valence tautomerism is observed in these materials. This experimental finding is corroborated with density functional theory calculations, which support the existence of a stable high-spin ground state in these complexes.

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24

Huynh, Han Vinh, Hong Lee Ong, and Kausani Ghatak. "Mixed NHC–thiolato complexes of palladium: understanding the formation of di-versus mononuclear complexes." Dalton Transactions 50, no. 48 (2021): 18118–27. http://dx.doi.org/10.1039/d1dt03714e.

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Formations of mono- vs. dinuclear NHC/thiolato PdII complexes were rationalized. NHC cis to thiolato favors monopalladium complexes, while a trans position leads to bimetallic species with μ-thiolatos due to increased electron density at sulfur.

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25

Chadwick, F. Mark, Andrew E. Ashley, Robert T. Cooper, Luke A. Bennett, Jennifer C. Green, and Dermot M. O'Hare. "Group 9 bimetallic carbonyl permethylpentalene complexes." Dalton Transactions 44, no. 46 (2015): 20147–53. http://dx.doi.org/10.1039/c5dt03747f.

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26

Matsuura, Yukihito. "Spin transport in bimetallic pentalene complexes." Solid State Communications 151, no. 24 (2011): 1877–80. http://dx.doi.org/10.1016/j.ssc.2011.10.001.

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27

Skopenko, V. V., V. N. Kokozei, O. Yu Vasil'eva, and S. R. Petrusenko. "Direct Synthesis of Hetero Bimetallic Complexes." Theoretical and Experimental Chemistry 39, no. 5 (2003): 269–82. http://dx.doi.org/10.1023/b:thec.0000003487.65054.51.

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28

Gibson, Dorothy H., Jaime O. Franco, Michael T. Harris, and Tek Sing Ong. "Bimetallic iron complexes with carboxyethylene bridges." Organometallics 11, no. 6 (1992): 1993–94. http://dx.doi.org/10.1021/om00042a007.

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29

Uson, Rafael, Antonio Laguna, Mariano Laguna, Alfredo Uson, Peter G. Jones, and Cristina Freire Erdbruegger. "Bimetallic phosphorus ylide gold-silver complexes." Organometallics 6, no. 8 (1987): 1778–80. http://dx.doi.org/10.1021/om00151a026.

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30

Watton, Stephen P., Hua Cao, and Thomas V. O'Halloran. "Bimetallic complexes as DNA-protein crosslinkers." Journal of Inorganic Biochemistry 43, no. 2-3 (1991): 431. http://dx.doi.org/10.1016/0162-0134(91)84413-4.

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31

Lau, Nathanael, Yohei Sano, Joseph W. Ziller, and A. S. Borovik. "Modular bimetallic complexes with a sulfonamido-based ligand." Dalton Transactions 47, no. 35 (2018): 12362–72. http://dx.doi.org/10.1039/c8dt02455c.

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32

Kopotkov, Vyacheslav A., Valentina D. Sasnovskaya, Denis V. Korchagin, et al. "The first photochromic bimetallic assemblies based on Mn(iii) and Mn(ii) Schiff-base (salpn, dapsc) complexes and pentacyanonitrosylferrate." CrystEngComm 17, no. 20 (2015): 3866–76. http://dx.doi.org/10.1039/c5ce00354g.

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33

Lande, Sharad V., Nagesh Sharma, Ajay Kumar, and Raksh Vir Jasra. "Spectroscopic Characterization of Stability and Interaction of Pd-Ag Complexes." International Journal of Spectroscopy 2014 (May 8, 2014): 1–6. http://dx.doi.org/10.1155/2014/314070.

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Colloidal metal nanoparticles are of great interest because of their use as catalysts, photocatalysts, adsorbents, and sensors as well as their application in optical, electronic, and magnetic devices. Supported bimetallic systems represent a large part of heterogeneous catalysts which have been used in various reactions important in the chemical, petrochemical, and oil industry. Pd-Ag bimetallic nanocatalysts have become vitally important in some of the petrochemical industry’s processes like hydrogenation of C2–C5 olefins. A heat-treatment method for the preparation of well-stable Pd-Ag complexes is demonstrated using water, concentrated HCl and concentrated nitric acid as media. The stability and interaction of Pd-Ag complexes were characterized by UV-vis absorption spectroscopy. Pd-Ag bimetallic nanoparticles of spherical cubic and octahedral shape in the range of average particle size of 20–60 nm have been prepared and characterized by transmission electron microscopy (TEM).

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34

Priola, Emanuele, Nadia Curetti, Domenica Marabello, et al. "Crystal engineering of aurophilic supramolecular architectures and coordination polymers based on butterfly-like copper–dicyanoaurate complexes: vapochromism, P–T behaviour and multi-metallic cocrystal formation." CrystEngComm 24, no. 12 (2022): 2336–48. http://dx.doi.org/10.1039/d1ce00964h.

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A family of bimetallic complexes based on aurophilic interactions was synthesized, and tested for vapochromism and P–T variations. These complexes can originate cocrystals, opening the route to a new aurophilic-based crystal engineering.

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Xue, Songlin, Ningchao Liu, Peifeng Mei, et al. "Porphyrin(2.1.2.1) as a novel binucleating ligand: synthesis and molecular structures of mono- and di-rhodium(i) complexes." Chemical Communications 57, no. 95 (2021): 12808–11. http://dx.doi.org/10.1039/d1cc05641g.

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Wang, Kuiyuan, Timothy J. Prior, and Carl Redshaw. "Turning on ROP activity in a bimetallic Co/Zn complex supported by a [2+2] Schiff-base macrocycle." Chemical Communications 55, no. 75 (2019): 11279–82. http://dx.doi.org/10.1039/c9cc04494a.

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Homo-dinuclear Co or Zn complexes derived from a [2+2] Schiff-base macrocycle revealed near inactivity for the ring opening polymerization of δ-valerolactone and ε-caprolactone, whereas hetero-bimetallic complexes were efficient catalysts.

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Su, Bochao, Kei Ota, Yongxin Li, and Rei Kinjo. "Germylone-bridged bimetallic Ir and Rh complexes." Dalton Transactions 48, no. 11 (2019): 3555–59. http://dx.doi.org/10.1039/c9dt00145j.

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The reactions of germylone 1 with one equivalent of [M(COD)Cl]2 (M = Ir, Rh) afforded the germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and structurally characterized.

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38

Das, Deepankar, Rudrajit Mal, Nisha Mittal, Zhengbo Zhu, Thomas J. Emge, and Daniel Seidel. "Chiral bisoxazoline ligands designed to stabilize bimetallic complexes." Beilstein Journal of Organic Chemistry 14 (August 1, 2018): 2002–11. http://dx.doi.org/10.3762/bjoc.14.175.

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Chiral bisoxazoline ligands containing naphthyridine, pyridazine, pyrazole, and phenol bridging units were prepared and shown to form bimetallic complexes with various metal salts. X-ray crystal structures of bis-nickel naphthyridine-bridged, bis-zinc pyridazine-bridged, and bis-nickel as well as bis-palladium pyrazole-bridged complexes were obtained.

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39

Cloke, F. Geoffrey N. "Organometallic pentalene complexes." Pure and Applied Chemistry 73, no. 2 (2001): 233–38. http://dx.doi.org/10.1351/pac200173020233.

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There has been a recent renaissance in the organometallic chemistry of pentalene, following the discovery of the first complexes incorporating pentalene η8-ligated to a single metal center. This short review outlines recent work in the author's laboratory on the preparation of silylated pentalene ligands and the subsequent synthesis of novel, monometallic, and bimetallic pentalene sandwich and half-sandwich complexes of the f- and d-block elements.

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40

Delaney, Andie R., Li-Juan Yu, Michelle L. Coote, and Annie L. Colebatch. "Synthesis of an expanded pincer ligand and its bimetallic coinage metal complexes." Dalton Transactions 50, no. 34 (2021): 11909–17. http://dx.doi.org/10.1039/d1dt01741a.

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41

Walg, Simon P., Fabian Dietrich, Anneken Grün, et al. "Synthesis and photophysical properties of multimetallic gold/zinc complexes of (P,N,N,N,P) and (P,N,N) ligands." New Journal of Chemistry 46, no. 9 (2022): 4062–71. http://dx.doi.org/10.1039/d1nj05806a.

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42

Eleazer, Bennett J., Mark D. Smith, Alexey A. Popov, and Dmitry V. Peryshkov. "Expansion of the (BB)Ru metallacycle with coinage metal cations: formation of B–M–Ru–B (M = Cu, Ag, Au) dimetalacyclodiboryls." Chemical Science 9, no. 9 (2018): 2601–8. http://dx.doi.org/10.1039/c8sc00190a.

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43

Johnson, Alice, Isabel Marzo та M. Concepción Gimeno. "Heterobimetallic propargyl gold complexes with π-bound copper or silver with enhanced anticancer activity". Dalton Transactions 49, № 33 (2020): 11736–42. http://dx.doi.org/10.1039/d0dt02113j.

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Heterometallic propargyl gold species in which copper or silver is bound to the triple bond were prepared. The bimetallic complexes had improved activities compared to the mononuclear gold complexes, suggesting a possible synergy between the two metal centres within the cell.

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44

Kaps, Alexander, Sabine Foro, and Herbert Plenio. "Bi- and trimetallic complexes with macrocyclic xanthene-4,5-diNHC ligands." Dalton Transactions 51, no. 6 (2022): 2464–79. http://dx.doi.org/10.1039/d1dt03857e.

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45

Kariuki, Benson M., James A. Platts, and Paul D. Newman. "A hybrid bipy–NHC ligand for the construction of group 11 mixed-metal bimetallic complexes." RSC Advances 11, no. 54 (2021): 34170–73. http://dx.doi.org/10.1039/d1ra06581e.

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Ou, Ya-Ping, Jing Zhang, Yuxuan Hu, Jun Yin, Chunyan Chi, and Sheng Hua Liu. "Oxidized divinyl oligoacene-bridged diruthenium complexes: bridged localized radical characters and reduced aromaticity in bridge cores." Dalton Transactions 49, no. 46 (2020): 16877–86. http://dx.doi.org/10.1039/d0dt02883e.

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Schenck, Terry G., J. M. Downes, C. R. C. Milne, et al. "Bimetallic reactivity. Synthesis of bimetallic complexes containing a bis(phosphino)pyrazole ligand." Inorganic Chemistry 24, no. 15 (1985): 2334–37. http://dx.doi.org/10.1021/ic00209a003.

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Martínez, Javier, José A. Castro-Osma, Agustín Lara-Sánchez, et al. "Ring-opening copolymerisation of cyclohexene oxide and carbon dioxide catalysed by scorpionate zinc complexes." Polymer Chemistry 7, no. 42 (2016): 6475–84. http://dx.doi.org/10.1039/c6py01559j.

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Chu, Xiaoxiao, Jihao Jin, Bangrong Ming, et al. "Bimetallic nickel–cobalt hydrides in H2 activation and catalytic proton reduction." Chemical Science 10, no. 3 (2019): 761–67. http://dx.doi.org/10.1039/c8sc04346a.

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Wang, Junsi, Yue Lu, William McCarthy, et al. "Novel ruthenium and iridium complexes of N-substituted carbazole as triplet photosensitisers." Chemical Communications 54, no. 9 (2018): 1073–76. http://dx.doi.org/10.1039/c7cc08535d.

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Journal articles on the topic 'Bimetallic complexes'

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