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1

Fadouach, M., B. Benali, A. Kadiri, C. Cazeau-Dubroca, and G. Nouchi. "Etude comparative en luminescence UV-visible du 1,1′-binaphtyle et du 2,2′-binaphtyle." Spectrochimica Acta Part A: Molecular Spectroscopy 48, no. 10 (October 1992): 1491–500. http://dx.doi.org/10.1016/0584-8539(92)80156-q.

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2

Assongo, C. Kenfack, B. Kabouchi, and B. Benali. "Etude des spectres d’absorption UV du 1,1′-binaphtyle et 2,2′-binaphtyle et de leurs auto-associations par le modèle d’interaction monopôle–dipôle atomique (AMDI)." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 56, no. 5 (April 2000): 941–46. http://dx.doi.org/10.1016/s1386-1425(99)00184-5.

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3

Sumi, Kenzo, Takao Ikariya, and Ryoji Noyori. "Efficient synthesis of optically active 2-amino-2'-diphenylphosphino-1,1'-binaphthyl and its derivatives." Canadian Journal of Chemistry 78, no. 6 (June 1, 2000): 697–703. http://dx.doi.org/10.1139/v99-248.

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Optically active 2-amino-2'-diphenylphosphino-1,1'-binaphthyls having various functional groups, such as amino, alkoxycarbonylamino, acylamino, mono- and dialkylamino, and sulfonylamino at C2 position were prepared. The key intermediate of the above aminophosphines was 2-carbamoyl-2'-diphenylphosphinyl-1,1'-binaphthyl synthesized from optically active 2-cyano-2'-diphenylphosphinyl-1,1'-binaphthyl. The transformation of the carbamoyl group to an amino group was effected by the Hofmann reaction.Key words: aminophosphine ligand, Hofmann reaction, optically active phosphine ligand.
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4

Benali, B., M. Fadouach, B. Kabouchi, A. Kadiri, and G. Nouchi. "Effet de la polarité du solvant sur les propriétés des états électroniques excités du 1,1′-binaphtyle: étude par spectroscopie UV-visible." Spectrochimica Acta Part A: Molecular Spectroscopy 49, no. 8 (July 1993): 1163–69. http://dx.doi.org/10.1016/0584-8539(93)80075-l.

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5

Jackson, S. David, Geoffrey Webb, and Nicola C. Young. "Adsorption of Chiral 2,2‘-Substituted-1,1’-Binaphthalenes onto Silica-Supported Palladium and Nickel." Adsorption Science & Technology 24, no. 3 (April 2006): 257–68. http://dx.doi.org/10.1260/026361706778812853.

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The nature of the adsorption of a series of 2,2‘-substituted-1,1’-binaphthalenes over supported palladium and nickel catalysts has been studied. Adsorption has been shown to occur through the 2,2‘-substituted functional groups. Where this is not possible, no adsorption of the binaphthyl is observed. Adsorption of 2,2’-diamino-1,1’-binaphthalene occurred solely on the metal components of the catalysts. However, total coverage of the metal surface was not obtained, with only specific sites being available for adsorption. Adsorption of 2,2‘-dihydroxy-1,1’-binaphthalene occurred on the metal components but also spilled over onto the support. Adsorption was detected for 2-hydroxy-2‘-methoxy-1,1’-binaphthalene but no spill-over was observed, indicating that both hydroxy groups are involved in the spill-over process. Co-adsorption and sequential adsorption studies revealed that there are a variety of adsorption sites that favour different binaphthyls.
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6

Hoshi, Takashi, Hiroshi Shionoiri, Masayoshi Katano, Toshio Suzuki, Masayoshi Ando, and Hisahiro Hagiwara. "(R)-2,2′-Bis(stannyl)-1,1′-binaphthyls as a New Chiral Bis-Metallic Binaphthyl Catalyst." Chemistry Letters 31, no. 6 (June 2002): 600–601. http://dx.doi.org/10.1246/cl.2002.600.

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7

Hatano, Bunpei, Kazuyuki Hashimoto, Hiroshi Katagiri, Tatsuro Kijima, Satoshi Murakami, Shigeru Matsuba, and Miho Kusakari. "Enantioresolution of 2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl Oxide Using Inclusion Complex with Chiral 2,2′-Dihydroxy-1,1′-binaphtyl." Journal of Organic Chemistry 77, no. 7 (March 19, 2012): 3595–97. http://dx.doi.org/10.1021/jo202630p.

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8

Kitamura, Sayaka, Kazuki Nakabayashi, Takashi Wakabayashi, Nobuo Tajima, Michiya Fujiki, and Yoshitane Imai. "Photoexcited state chirality transfer. Hidden tunability of circularly polarized luminescent binaphthyl–anthracene tandem molecular systems." RSC Advances 5, no. 83 (2015): 67449–53. http://dx.doi.org/10.1039/c5ra10716d.

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Circularly polarized luminescent properties of binaphthyl with two achiral anthracenes were tuned by exploiting photoexcited-state chirality transfer from the binaphthyl to anthracenes when open- or closed-type binaphthyl structure was chosen.
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9

Ogunlaja, Adeniyi S., Eric Hosten, Richard Betz, and Zenixole R. Tshentu. "Selective removal of isoquinoline and quinoline from simulated fuel using 1,1′-binaphthyl-2,2′-diol (BINOL): crystal structure and evaluation of the adduct electronic properties." RSC Advances 6, no. 45 (2016): 39024–38. http://dx.doi.org/10.1039/c6ra03854a.

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1,1′-Binaphthyl-2,2′-diol/quinoline (BINOL/QUN) and 1,1′-binaphthyl-2,2′-diol/isoquinoline (BINOL/ISOQUN) adducts were successfully synthesized. Isothermal titration calorimetry (ITC) involving 1,1′-binaphthyl-2,2′-diol (BINOL) and isoquinoline confirming interaction.
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10

Hoshi, Takashi, Hiroshi Shionoiri, Masayoshi Katano, Toshio Suzuki, Masayoshi Ando, and Hisahiro Hagiwara. "ChemInform Abstract: (R)-2,2′-Bis(stannyl)-1,1′-binaphthyls as a New Chiral Bis-metallic Binaphthyl Catalyst." ChemInform 33, no. 43 (May 19, 2010): no. http://dx.doi.org/10.1002/chin.200243040.

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11

Guo, Hui, and Kuiling Ding. "Reduction of 1,1′-binaphthyls to octahydro-1,1′-binaphthyl derivatives with Raney Ni–Al alloy in aqueous solution." Tetrahedron Letters 41, no. 51 (December 2000): 10061–64. http://dx.doi.org/10.1016/s0040-4039(00)01799-8.

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12

Tsubaki, Kazunori, Dinh T. T. Hai, Valluru K. Reddy, Hiroshi Ohnishi, Kaoru Fuji, and Takeo Kawabata. "Synthesis of chiral 2,2′-dimethyl-1,1′-binaphthyl-8,8′-diamine and barriers of atropisomerization of the related binaphthyls." Tetrahedron: Asymmetry 18, no. 8 (May 2007): 1017–21. http://dx.doi.org/10.1016/j.tetasy.2007.04.011.

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13

Miyano, Sotaro, Shin-ichi Okada, Toshiyuki Suzuki, Shigeru Handa, and Harukichi Hashimoto. "Practical Synthesis of 1,1′-Binaphthyl-2-carboxylic Acids via Side Chain Oxidation of 2-Methyl-1,1′-binaphthyls." Bulletin of the Chemical Society of Japan 59, no. 6 (June 1986): 2044–46. http://dx.doi.org/10.1246/bcsj.59.2044.

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14

Brunner, Henri, Matthias Weber, and Manfred Zabel. "Asymmetric Catalysis, 154 [1]. New 1,1’-Binaphthyl Ligands for Enantioselective Catalysis." Zeitschrift für Naturforschung B 58, no. 9 (September 1, 2003): 821–26. http://dx.doi.org/10.1515/znb-2003-0902.

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Chiral binaphthyl compounds, especially those with different substituents in 2- and 2’-position of the binaphthyl system, have gained interest as constituents of successful ligands in various catalytic reactions. Here, we present the synthesis and characterization of new binaphthyl ligands containing oxazoline, cyano and amide substituents in 2’-position in addition to methoxy, hydroxy or amino groups in 2-position. Starting from these compounds new ligands for enantioselective catalysis will be accessible.
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15

Guo, Hui, and Kuiling Ding. "ChemInform Abstract: Reduction of 1,1′-Binaphthyls to Octahydro-1,1′-binaphthyl Derivatives with Raney Ni-Al Alloy in Aqueous Solution." ChemInform 32, no. 11 (March 13, 2001): no. http://dx.doi.org/10.1002/chin.200111094.

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16

Coluccini, Carmine, Giancarlo Terraneo, and Dario Pasini. "Synthesis of Binaphthyl-Based Push-Pull Chromophores with Supramolecularly Polarizable Acceptor Ends." Journal of Chemistry 2015 (2015): 1–7. http://dx.doi.org/10.1155/2015/827592.

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We report on the design and synthesis of new enantiopure binaphthyl derivatives in which electron-donating and electron-withdrawing substituents are placed in direct conjugation, to create push-pull dyes potentially active for NLO applications. The dyes, unprecedentedly, extend theirπ-bridge from the 3,3′ positions of the binaphthyl units and incorporate as acceptors 1,3-dicarbonyl and tetrafluorobenzene units, useful for further supramolecular polarization of the chiral dyes.
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17

Liu, Na, Xing Wang, Hui Cao, Chun Hai Chen, and Wan Jin Zhang. "Synthesis of a Novel Hollow Sphere Having Rigid Binaphthyl Macrocycle as Shell." Solid State Phenomena 121-123 (March 2007): 219–22. http://dx.doi.org/10.4028/www.scientific.net/ssp.121-123.219.

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A novel hollow sphere having rigid binaphthyl macrocycle as shell was prepared by means of sacrifice the silica core. The synthesis of hollow sphere from rigid colloidal silica particles occurs in three steps: a) modification of silica particles with vinyltriethoxysilane as coupling agent, b) immersion in the solution of monomer having rigid binaphthyl macrocycle and polymerization, and c) removal of silica particles. These macrocycles contained in the shell of hollow spheres belong to an important class of host-guest macrocyclic material in which the rigid backbone and C2 symmetry of the binaphthyl unit play an important role in complexing guest molecules. This will endow hollow sphere with new opportunities in molecular recognition and separation.The morphology of colloidal silica particles and hollow spheres was characterized by SEM and TEM.
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18

Chen, Yehui, Liwen Yang, Nianfa Yang, and Zhusheng Yang. "Optically active helical poly(α,β-unsaturated ketone) from anionic polymerization of (S)-3-acrylyl-2,2′- bis(methoxymethoxy)-1,1′-binaphthyl." Canadian Journal of Chemistry 92, no. 7 (July 2014): 647–52. http://dx.doi.org/10.1139/cjc-2014-0102.

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(S)-3-acrylyl-2,2′-bis(methoxymethoxy)-1,1′-binaphthyl (3a) was synthesized and anionically polymerized using n-BuLi as an initiator. The polymer derived from 3a had a tremendous specific optical rotation [Formula: see text] = −304.2, while that of the monomer 3a is −68.7. Poly-3a was confirmed to exist in the form of a one-handed helical structure in solution by means of comparing the specific optical rotation, the circular dichroism, and UV-vis spectra with that of 3a and the model compounds such as (S)-3-propionyl-2,2′-bis(methoxymethoxy)-1,1′-binaphthyl (3b) and (S)-3-heptanoyl-2,2′-bis(methoxymethoxy)-1,1′-binaphthyl (3c). This conclusion was also confirmed by the fact that the g value of poly-3a is about 15 times of that of the monomer 3a.
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19

Korostylev, Andrei, Vitali I. Tararov, Christine Fischer, Axel Monsees, and Armin Börner. "Convenient and Efficient Reduction of 1,1‘-Binaphthyls to H8-1,1‘-Binaphthyl Derivatives with Pd and Ru Catalysts on Solid Support." Journal of Organic Chemistry 69, no. 9 (April 2004): 3220–21. http://dx.doi.org/10.1021/jo0497609.

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20

Shaykhutdinova, Polina, and Martin Oestreich. "Further Structural Modification of Sulfur-Stabilized Silicon Cations with Binaphthyl Backbones." Synthesis 51, no. 10 (March 11, 2019): 2221–29. http://dx.doi.org/10.1055/s-0037-1610697.

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The synthesis and spectroscopic characterization of two novel cationic silicon–sulfur Lewis pairs with a chiral 4,4′-disubstituted binaphthyl silepine backbone are described. Both Lewis acids induce significant enantioselectivity in the model Diels–Alder reaction of cyclohexa-1,3-diene and chalcone but additional substitution of the binaphthyl backbone exerts a minimal effect on enantioinduction compared to previously reported Lewis acids. Another silicon cation with a chiral spirocyclic backbone induces enantioselectivity in the same range but its synthesis is laborious.
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21

Maeda, Chihiro, Kanae Ogawa, Kosuke Sadanaga, Kazuto Takaishi, and Tadashi Ema. "Chiroptical and catalytic properties of doubly binaphthyl-strapped chiral porphyrins." Chemical Communications 55, no. 8 (2019): 1064–67. http://dx.doi.org/10.1039/c8cc09114e.

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22

Zhao, Luyang, Kang Wang, Taniyuki Furuyama, Jianzhuang Jiang, and Nagao Kobayashi. "Synthesis and spectroscopic properties of chiral binaphthyl-linked subphthalocyanines." Chem. Commun. 50, no. 57 (2014): 7663–65. http://dx.doi.org/10.1039/c4cc03426k.

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23

Tsurusaki, Akihiro, Rikako Ura, and Ken Kamikawa. "1,1′-Binaphthyl-substituted diphosphene: synthesis, structures, and chiral optical properties." Dalton Transactions 47, no. 13 (2018): 4437–41. http://dx.doi.org/10.1039/c8dt00441b.

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24

Maeda, Chihiro, Keiji Nagahata, Kazuto Takaishi, and Tadashi Ema. "Synthesis of chiral carbazole-based BODIPYs showing circularly polarized luminescence." Chemical Communications 55, no. 21 (2019): 3136–39. http://dx.doi.org/10.1039/c9cc00894b.

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25

Li, Junfeng, Chenxi Hou, Chao Huang, Shanqi Xu, Xuelei Peng, Qi Qi, Wen-Yong Lai, and Wei Huang. "Boosting Circularly Polarized Luminescence of Organic Conjugated Systems via Twisted Intramolecular Charge Transfer." Research 2020 (April 22, 2020): 1–10. http://dx.doi.org/10.34133/2020/3839160.

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Realizing a high luminescence dissymmetry factor (glum) is a paramount yet challenging issue in the research field of circularly polarized luminescence (CPL). Here, we reported a novel set of organic conjugated systems with twisted intramolecular charge transfer (TICT) characteristics based on conjugated o-carborane-binaphthyl dyads composing of binaphthyl units as chiral electron donors and o-carborane units as achiral electron acceptors, demonstrating intense CPL with large glum values. Interestingly, single-crystalline o-1 exhibited a high-level brightness and a large glum factor as high as +0.13, whereas single-crystalline o-2 processed a relatively low brightness with a decreased glum value to -0.04. The significant diversity of CPL-active properties was triggered by the selective introduction of o-carborane units onto the binaphthyl units. Benefiting from the large magnetic dipole transition moments in TICT states, the CPL activity of TICT o-carborane-based materials exhibited amplified circular polarization. This study provides an efficient molecular engineering strategy for the rational design and development of highly efficient CPL-active materials.
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26

Biscarini, P., J. Drabowicz, J. Zuczak, and M. MikoZajczyk. "Enantiomeric 2,2'-Dihydroxy-1,1'-Binaphtyl and 0,0'-(1,1'-Binaphthyl-2,2'-Diyl)-Dithiophosphoric Acid as Chiral Auxiliaries in the Preparation of Optically Active Sulfinyl Derivatives." Phosphorus, Sulfur, and Silicon and the Related Elements 153, no. 1 (January 1999): 365–66. http://dx.doi.org/10.1080/10426509908546473.

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27

Wu, Yanping, Sisi Wang, Zhifang Li, Zhen Shen, and Hua Lu. "Chiral binaphthyl-linked BODIPY analogues: synthesis and spectroscopic properties." Journal of Materials Chemistry C 4, no. 21 (2016): 4668–74. http://dx.doi.org/10.1039/c6tc00975a.

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28

Narazaki, Yu, Hiroya Nishikawa, Hiroki Higuchi, Yasushi Okumura, and Hirotsugu Kikuchi. "Substituent effects of bridged binaphthyl-type chiral dopants on the helical twisting power in dopant-induced chiral liquid crystals." RSC Advances 8, no. 2 (2018): 971–79. http://dx.doi.org/10.1039/c7ra12465a.

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29

Liu, Yan, Longguang Jiang, Ling Song, Datao Tu, Wei Zheng, Ping Huang, Mingmao Chen, and Xueyuan Chen. "Deciphering molecular interaction of binaphthyl compounds with Penicillium expansum lipase: enantioselectivity and reactivity prediction for lipase." Molecular Systems Design & Engineering 3, no. 4 (2018): 658–67. http://dx.doi.org/10.1039/c7me00120g.

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30

Camargo Solórzano, Patricia, María T. Baumgartner, Marcelo Puiatti, and Liliana B. Jimenez. "Arenium cation or radical cation? An insight into the cyclodehydrogenation reaction of 2-substituted binaphthyls mediated by Lewis acids." RSC Advances 10, no. 37 (2020): 21974–85. http://dx.doi.org/10.1039/d0ra04213g.

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31

Gao, Xiaohui, Xujin Qin, Xuefeng Yang, Yuangang Li, and Pengfei Duan. "(R)-Binaphthyl derivatives as chiral dopants: substituent position controlled circularly polarized luminescence in liquid crystals." Chemical Communications 55, no. 42 (2019): 5914–17. http://dx.doi.org/10.1039/c9cc02253h.

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32

Coluccini, Carmine, Marco Caricato, Elena Cariati, Stefania Righetto, Alessandra Forni, and Dario Pasini. "Synthesis, chiroptical and SHG properties of polarizable push–pull dyes built on π-extended binaphthyls." RSC Advances 5, no. 28 (2015): 21495–503. http://dx.doi.org/10.1039/c4ra16876c.

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33

Nagy, Sándor, Gyula Dargó, Péter Kisszékelyi, Zsuzsanna Fehér, András Simon, Júlia Barabás, Tibor Höltzl, et al. "New enantiopure binaphthyl-cinchona thiosquaramides: synthesis and application for enantioselective organocatalysis." New Journal of Chemistry 43, no. 15 (2019): 5948–59. http://dx.doi.org/10.1039/c8nj06451b.

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34

Xia, Yun-Tao, Jing Ma, Xiao-Dong Wang, Lei Yang, and Lei Wu. "Enantioselective hydrogenation of N-heteroaromatics catalyzed by chiral diphosphine modified binaphthyl palladium nanoparticles." Catalysis Science & Technology 7, no. 23 (2017): 5515–20. http://dx.doi.org/10.1039/c7cy01672g.

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35

Nakanishi, Shoma, Nobuyuki Hara, Natsuki Kuroda, Nobuo Tajima, Michiya Fujiki, and Yoshitane Imai. "Solvent-sensitive signs and magnitudes of circularly polarised luminescence and circular dichroism spectra: probing two phenanthrenes as emitters endowed with BINOL derivatives." Organic & Biomolecular Chemistry 16, no. 7 (2018): 1093–100. http://dx.doi.org/10.1039/c7ob02308a.

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36

Roszak, Kinga, and Andrzej Katrusiak. "High-pressure and temperature dependence of the spontaneous resolution of 1,1′-binaphthyl enantiomers." Physical Chemistry Chemical Physics 20, no. 7 (2018): 5305–11. http://dx.doi.org/10.1039/c7cp07234a.

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37

Mikláš, R., N. Miklášová, M. Bukovský, and F. Devínsky. "Synthesis and antimicrobial properties of binaphthyl derived quaternary ammonium bromides." Acta Facultatis Pharmaceuticae Universitatis Comenianae 59, no. 1 (January 1, 2012): 39–47. http://dx.doi.org/10.2478/v10219-012-0017-5.

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Synthesis and antimicrobial properties of binaphthyl derived quaternary ammonium bromides(S)-N-(2-(4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepin-1-yl)ethyl)-N, N-dimethyl-N-dodecyl ammonium bromide (S)-1a and (S)-N-(2-(4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepin-1-yl)ethyl)-N, N-dimethyl-N-tetradecylammonium bromide (S)-1b have been synthesized as optically active quaternary ammonium salts starting from 1,1'-binaphthyl-2,2'-diol. Their antimicrobial activity expressed as minimal inhibition concentration (MIC) was tested against Gram-positive human pathogenic bacteria S. Aureus, Gram-negative bacteria E. coli and human fungal pathogen C. Albicans.
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38

Zheng, Chao, Zhongfu An, Yosuke Nakai, Taiju Tsuboi, Yang Wang, Huifang Shi, Runfeng Chen, et al. "Relationships between main-chain chirality and photophysical properties in chiral conjugated polymers." J. Mater. Chem. C 2, no. 35 (2014): 7336–47. http://dx.doi.org/10.1039/c4tc01160k.

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39

Bříza, Tomáš, Zdeněk Kejík, Petr Vašek, Jarmila Králová, Pavel Martásek, Ivana Císařová, and Vladimír Král. "Chromophoric Binaphthyl Derivatives." Organic Letters 7, no. 17 (August 2005): 3661–64. http://dx.doi.org/10.1021/ol051139n.

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40

Yao, Chao, Piao Wu, Yue Huang, Yaoqi Chen, Lin Li, and Yue-Ming Li. "Binaphthyl-based chiral ligands: design, synthesis and evaluation of their performance in enantioselective addition of diethylzinc to aromatic aldehydes." Organic & Biomolecular Chemistry 18, no. 47 (2020): 9712–25. http://dx.doi.org/10.1039/d0ob02127j.

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41

Heister, Philipp, Tobias Lünskens, Martin Thämer, Aras Kartouzian, Sabine Gerlach, Thierry Verbiest, and Ueli Heiz. "Orientational changes of supported chiral 2,2′-dihydroxy-1,1′binaphthyl molecules." Phys. Chem. Chem. Phys. 16, no. 16 (2014): 7299–306. http://dx.doi.org/10.1039/c4cp00106k.

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42

Biscarini, P., J. Drabowicz, J. Łŭzak, and M. Mikołajczyk. "Enantiomeric 2,2'-Dihydroxy-1,1'-Binaphtyl and O,O'-(1,1'-Binaphthyl-2,2'-Diyl)-Dithiophosphoric Acid as Chiral Auxiliaries in the Preparation of Optically Active Sulfinyl Derivatives." Phosphorus, Sulfur, and Silicon and the Related Elements 153, no. 1 (October 1, 1999): 365–66. http://dx.doi.org/10.1080/10426509908038449.

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43

Gao, Bo, Xiang Li, Ranlong Duan, Qian Duan, Yanhui Li, Xuan Pang, Hejing Zhuang, and Xuesi Chen. "Hemi-salen aluminum catalysts bearing N, N, O-tridentate type binaphthyl-Schiff-base ligands for the living ring-opening polymerisation of lactide." RSC Advances 5, no. 37 (2015): 29412–19. http://dx.doi.org/10.1039/c5ra00956a.

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44

Lemmerer, Abraham, Brutiu, Roller, and Widhalm. "Synthesis, Structure, and Reactivity of Binaphthyl Supported Dihydro[1,6]diazecines." Molecules 24, no. 17 (August 26, 2019): 3098. http://dx.doi.org/10.3390/molecules24173098.

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A short approach to chiral diaza-olefines from protected 2,2′-diamino-1,1′-binaphthyl is presented. Cis- and trans-olefines can be selectively obtained by twofold N-allylation followed by RCM or by bridging a 2,2′-diamino-1,1′-binaphthyl precursor with trans-1,4-dibromo-2-butene. Deprotection afforded cis- and trans-dihydro[1,6]diazecines 1 in 58 and 64% overall yield. The reactivity of the but-2-ene-1,4-diyl fragment was investigated yielding corresponding epoxides, diols, and mono- and dibromo products. In several cases rearrangements and participation of the proximate N-Boc group was observed. In no case could allylic substitution be accomplished. From 13 compounds X-ray structure analyses could be obtained.
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45

Amako, Tomoyuki, Kazuki Nakabayashi, Atsushi Sudo, Michiya Fujiki, and Yoshitane Imai. "Solid-state circularly polarised luminescence of atropisomeric fluorophores embedded in achiral myo-inositol-containing polyurethanes." Organic & Biomolecular Chemistry 13, no. 10 (2015): 2913–17. http://dx.doi.org/10.1039/c4ob02553a.

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Two chiral binaphthyl fluorophores in two myo-inositol based polyurethane matrices with high grass transition temperatures emitted circularly polarised luminescence with a high circular anisotropy factor.
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46

Jeong, Dong-Cheol, Bohyun Mun, Hyekyung Lee, Seung Jun Hwang, Sung Jong Yoo, EunAe Cho, Yunmi Lee, and Changsik Song. "Binaphthyl-based molecular barrier materials for phosphoric acid poisoning in high-temperature proton exchange membrane fuel cells." RSC Advances 6, no. 65 (2016): 60749–55. http://dx.doi.org/10.1039/c6ra13123a.

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47

Zhang, Wenmeng, Shaoyun Chen, Dongyang Chen, and Zhuoliang Ye. "Sulfonated Binaphthyl-Containing Poly(arylene ether ketone)s with Rigid Backbone and Excellent Film-Forming Capability for Proton Exchange Membranes." Polymers 10, no. 11 (November 19, 2018): 1287. http://dx.doi.org/10.3390/polym10111287.

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Abstract:
Sterically hindered (S)-1,1′-binaphthyl-2,2′-diol had been successfully copolymerized with 4,4′-sulfonyldiphenol and 4,4′-difluorobenzophenone to yield fibrous poly(arylene ether ketone)s (PAEKs) containing various amounts of binaphthyl unit, which was then selectively and efficiently sulfonated using ClSO3H to yield sulfonated poly(arylene ether ketone)s (SPAEKs) with ion exchange capacities (IECs) ranging from 1.40 to 1.89 mmol·g−1. The chemical structures of the polymers were confirmed by 2D 1H–1H COSY NMR and FT-IR. The thermal properties, water uptake, swelling ratio, proton conductivity, oxidative stability and mechanical properties of SPAEKs were investigated in detail. It was found that the conjugated but non-coplanar structure of binaphthyl unit endorsed excellent solubility and film-forming capability to SPAEKs. The SPAEK-50 with an IEC of 1.89 mmol·g−1 exhibited a proton conductivity of 102 mS·cm−1 at 30 °C, much higher than that of the state-of-the-art Nafion N212 membrane and those of many previously reported aromatic analogs, which may be attributed to the likely large intrinsic free volume of SPAEKs created by the highly twisted chain structures and the desirable microscopic morphology. Along with the remarkable water affinity, thermal stabilities and mechanical properties, the SPAEKs were demonstrated to be promising proton exchange membrane (PEM) candidates for potential membrane separations.
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48

Liu, Jiaqi, Saide Cui, Zhenjiang Li, Songquan Xu, Jiaxi Xu, Xianfu Pan, Yaya Liu, He Dong, Herui Sun, and Kai Guo. "Polymerization of trimethylene carbonates using organic phosphoric acids." Polymer Chemistry 7, no. 35 (2016): 5526–35. http://dx.doi.org/10.1039/c6py01210h.

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49

Song, Sun Gu, Seonggyun Ha, Kyeong-Bae Seo, Jookyeong Lee, Tae-Lim Choi, Thathan Premkumar, and Changsik Song. "Binaphthyl-incorporated π-conjugated polymer/gold nanoparticle hybrids: a facile size- and shape-tailored synthesis." RSC Advances 6, no. 109 (2016): 107994–99. http://dx.doi.org/10.1039/c6ra22234j.

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50

Song, Jintong, Man Wang, Xuemei Xu, Lang Qu, Xiangge Zhou, and Haifeng Xiang. "1D-helical platinum(ii) complexes bearing metal-induced chirality, aggregation-induced red phosphorescence, and circularly polarized luminescence." Dalton Transactions 48, no. 13 (2019): 4420–28. http://dx.doi.org/10.1039/c8dt03615b.

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