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Relevant bibliographies by topics / Binary phase diagram

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Journal articles

Academic literature on the topic 'Binary phase diagram'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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Journal articles on the topic "Binary phase diagram"

1

Sangster, James Malcolm. "Calculation of phase diagrams and thermodynamic properties of 18 binary common-ion systems of Na,K,Ba//F,MoO4,WO4." Canadian Journal of Chemistry 74, no. 3 (1996): 402–18. http://dx.doi.org/10.1139/v96-045.

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Phase diagram and thermodynamic data of 18 binary common-ion molten salt systems in Na,K,Ba//F,MoO4,WO4 were optimized by computer algorithm. The phase diagram data as well as single-salt data were retrieved from an extensive critical literature search. Expressions for the excess properties of solution phases and thermodynamic properties of intermediate compounds were thereby obtained. These data were used to generate a "best" phase diagram for each binary system considered. Key words: molten salts, phase diagrams, thermodynamic properties.

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2

Tkachenko, Alexei V. "Generic phase diagram of binary superlattices." Proceedings of the National Academy of Sciences 113, no. 37 (2016): 10269–74. http://dx.doi.org/10.1073/pnas.1525358113.

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Emergence of a large variety of self-assembled superlattices is a dramatic recent trend in the fields of nanoparticle and colloidal sciences. Motivated by this development, we propose a model that combines simplicity with a remarkably rich phase behavior applicable to a wide range of such self-assembled systems. Those systems include nanoparticle and colloidal assemblies driven by DNA-mediated interactions, electrostatics, and possibly, controlled drying. In our model, a binary system of large and small hard spheres (L and S, respectively) interacts via selective short-range (“sticky”) attraction. In its simplest version, this binary sticky sphere model features attraction only between S and L particles. We show that, in the limit when this attraction is sufficiently strong compared with kT, the problem becomes purely geometrical: the thermodynamically preferred state should maximize the number of LS contacts. A general procedure for constructing the phase diagram as a function of system composition f and particle size ratio r is outlined. In this way, the global phase behavior can be calculated very efficiently for a given set of plausible candidate phases. Furthermore, the geometric nature of the problem enables us to generate those candidate phases through a well-defined and intuitive construction. We calculate the phase diagrams for both 2D and 3D systems and compare the results with existing experiments. Most of the 3D superlattices observed to date are featured in our phase diagram, whereas several more are predicted for future discovery.

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3

Wicaksono, Yudi, Dwi Setyawan, and S. Siswandono. "Diagram Fase dan Sifat Termodinamik Campuran Biner Ketoprofen-Asam Suksinat." Jurnal ILMU DASAR 19, no. 2 (2018): 99. http://dx.doi.org/10.19184/jid.v19i2.5521.

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The equilibrium phase diagram and thermodynamic properties of a mixture of drugs and additives are information related to various possible interaction processes between components. Therefore, we conducted a study of the phase diagrams and thermodynamic properties of binary mixtures of ketoprofen-succinic acid to estimate the types of interactions that may occur between these materials. The solid-liquid phase diagram of ketoprofen-succinic acid binary mixtures was determined by differential scanning calorimetry and composition of eutectic system was determined accurately using a Tamman diagram. The measurement of binary mixtures of ketoprofen-succinic acid with differential scanning calorimeter obtained the value of melting temperature and heat of fusion of ketoprofen- succinic acid system. The solid-liquid phase diagram of ketoprofen- succinic acid showed the formation of eutectic type phase diagram. The Tamman diagram showed accurately composition of the eutectic system of the Kp-SA binary mixtures at the mole fraction of Kp 0.87 and temperature 96.9oC.Keywords: ketoprofen, phase diagram, eutectic system, Tamman diagram

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4

Kim, Han Gyeol, Joonho Lee, and Guy Makov. "Phase Diagram of Binary Alloy Nanoparticles under High Pressure." Materials 14, no. 11 (2021): 2929. http://dx.doi.org/10.3390/ma14112929.

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CALPHAD (CALculation of PHAse Diagram) is a useful tool to construct phase diagrams of various materials under different thermodynamic conditions. Researchers have extended the use of the CALPHAD method to nanophase diagrams and pressure phase diagrams. In this study, the phase diagram of an arbitrary A–B nanoparticle system under pressure was investigated. The effects of the interaction parameter and excess volume were investigated with increasing pressure. The eutectic temperature was found to decrease in most cases, except when the interaction parameter in the liquid was zero and that in the solid was positive, while the excess volume parameter of the liquid was positive. Under these conditions, the eutectic temperature increased with increasing pressure.

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5

Travesset, Alex. "Binary nanoparticle superlattices of soft-particle systems." Proceedings of the National Academy of Sciences 112, no. 31 (2015): 9563–67. http://dx.doi.org/10.1073/pnas.1504677112.

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The solid-phase diagram of binary systems consisting of particles of diameter σA=σ and σB=γσ (γ≤1) interacting with an inverse p = 12 power law is investigated as a paradigm of a soft potential. In addition to the diameter ratio γ that characterizes hard-sphere models, the phase diagram is a function of an additional parameter that controls the relative interaction strength between the different particle types. Phase diagrams are determined from extremes of thermodynamic functions by considering 15 candidate lattices. In general, it is shown that the phase diagram of a soft repulsive potential leads to the morphological diversity observed in experiments with binary nanoparticles, thus providing a general framework to understand their phase diagrams. Particular emphasis is given to the two most successful crystallization strategies so far: evaporation of solvent from nanoparticles with grafted hydrocarbon ligands and DNA programmable self-assembly.

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6

Sanders, Philip C., James H. Reeves, and Michael Messina. "The Binary Temperature–Composition Phase Diagram." Journal of Chemical Education 83, no. 1 (2006): 150. http://dx.doi.org/10.1021/ed083p150.

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7

Mckenney, Robert, and Thomas Krawietz. "Binary Phase Diagram Series: HMX/RDX." Journal of Energetic Materials 21, no. 3 (2003): 141–66. http://dx.doi.org/10.1080/716100385.

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8

Okamoto, H., and T. B. Massalski. "guidelines for binary phase diagram assessment." Journal of Phase Equilibria 14, no. 3 (1993): 316–35. http://dx.doi.org/10.1007/bf02668229.

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9

Legendre, B., and F. Querniard. "Glossary for Binary Phase Diagram Reactions." Journal of Phase Equilibria and Diffusion 35, no. 1 (2013): 11–14. http://dx.doi.org/10.1007/s11669-013-0266-6.

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10

Ramirez, Antonio J., and Sérgio Duarte Brandi. "Weldability Approach to Duplex Stainless Steels Using Multicomponent Phase Diagrams." Materials Science Forum 475-479 (January 2005): 2765–68. http://dx.doi.org/10.4028/www.scientific.net/msf.475-479.2765.

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Welding is a non-equilibrium process. However, some weldability issues, as the extension of the heat-affected zone (HAZ) can be addressed using equilibrium phase diagrams. The 70 wt% Fe-Cr-Ni pseudo-binary phase diagram is commonly used to establish the phase transformations during welding of duplex stainless steels. The predicted results are assumed to be reasonably good for most of the duplex stainless steels. Thermodynamic calculations were used to determine multicomponent phase diagrams and volumetric fraction of phases present as a function of temperature several commercial duplex stainless steels. Results showed that simplified pseudobinary phase diagram approach is valid to estimate welded joint microstructures only for the low alloy duplex stainless steels as UNS S32304, but phase transformations and mainly solidification paths of high alloy duplex stainless steels should predicted only using a multi-component phase diagram.

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