Relevant bibliographies by topics / Binuclear complexes

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Academic literature on the topic 'Binuclear complexes'

Author: Grafiati
Published: 4 June 2021
Last updated: 26 July 2025

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Journal articles on the topic "Binuclear complexes"

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Nishida, Yuzo. "Synthesis and Reactivity of Copper(II) Complexes with New Binucleating Ligands Derived from 16-or 20-Membered N4-Macrocycles." Zeitschrift für Naturforschung B 45, no. 1 (1990): 39–44. http://dx.doi.org/10.1515/znb-1990-0109.

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Abstract New binucleating ligands, (L1) N ,N′,N″,N‴-tetrakis(2-benzimidazolylmethyl)-1,4,9,12-tetra-azacyclohexadecane, and (L2) N ,N′,N″,N‴-tetrakis(2-benzimidazolylmethyl)-1,4,11,14-tetra-azacycloeicosane were prepared. From the reaction mixture of copper(II) salt and the ligand, new binuclear copper(II) complexes, Cu2(L1) (NO3)4 (1), Cu2(L2)(NO3)4 (2), Cu2(L2)Br4 (3), and trinuclear complexes, Cu3(L1)Cl6 (4), and Cu3(L2)Cl6 (5) were obtained. Cyclic voltammograms revealed that the trinuclear complexes 4 and 5 are composed with the binuclear complex (1 or 2) and [CuCl4]2-. The interaction be
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Indira Priyadarshini and Dr. Rajesh Ranjan Pandey. "Synthesis, Characterization and Antimicrobial Activity of Homonuclear Cu(II) and Ni(II) Schiff Base Complexes." Journal of Advances in Science and Technology 20, no. 2 (2024): 96–100. http://dx.doi.org/10.29070/cp5vsm97.

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The current study aimed to synthesise, characterise, and investigate the antimicrobial activity of homonuclear Cu(II) and Ni(II) Schiff base complexes. Homonuclear Schiff Base Complexes chelates of Cu(II) and Ni(II) were synthesised. It appears that the complex is a potential metallo-ligand. It forms binuclear complexes when it reacts with two different metal salts, Ni and Cu. Using a Schiff base ligand made from 4-chloro-o-phenylenediamine and 3,5-dichloro-2-hydroxyacetophenone, the homo and hetero binuclear oxygen bridging Cu(II) and Ni(II) complexes were synthesized. Numerous common physico
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XU, XUAN, QIN-YU LI, LIANG FANG, and ZHONG-MIN SU. "QUANTUM CHEMISTRY STUDIES ON THE Fe-Hg INTERACTIONS AND 31P NMR IN [Fe(CO)3(RPhPpy)2 (HgCl2)] (R = Me, Et, Ph)." Journal of Theoretical and Computational Chemistry 10, no. 01 (2011): 53–63. http://dx.doi.org/10.1142/s0219633611006281.

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In order to study the effects of R group on Fe-Hg interactions and 31P NMR, the structures of mononuclear complexes [Fe(CO)3(RPhPpy)2] (1: R = Me; 2: R = Et; 3: R = Ph) and binuclear complexes [Fe(CO)3(RPhPpy)2(HgCl2)] (4: R = Me; 6: R = Et; 6: R = Ph) were calculated by density functional theory (DFT) PBE0 method. Moreover, the 31P NMR chemical shifts were calculated by PBE0-GIAO method. The replacement of Ph group in Ph2Ppy ligands with Me or Et group results in higher stabilities and stronger Fe-Hg interactions. The stabilities of binuclear complexes follow the order of 5 > 4 >6. Alth
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Nishida, Yuzo, and Miyuki Nasu. "Redox Interaction between Binuclear Mn2(III/IV) Complexes and Binuclear Mn2(II/II) Complexes." Zeitschrift für Naturforschung B 46, no. 2 (1991): 231–34. http://dx.doi.org/10.1515/znb-1991-0217.

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Spectroscopic and ESR studies have revealed that redox interaction occurs between binuclear Mn2(III/IV) complex, [Mn2O2(2,2′-bipyridine)4]3+ and binuclear Mn2(II/II) complexes, [Mn2(L-py)(CH3COO)2]+ and [Mn2(L-py)Cl2]+, in a dilute acetonitrile solution. Electrochemical data suggest that the chloride ion plays an additional important role in the above reaction.
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Kazin, Pavel E., V. I. Spitsyn, and V. V. Zelentsov. "Binuclear molybdenum(III) complexes." Russian Chemical Reviews 58, no. 12 (1989): 1157–68. http://dx.doi.org/10.1070/rc1989v058n12abeh003502.

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Mashuta, Mark S., Robert M. Buchanan, and William Pierce. "Binuclear schiff base complexes." Inorganica Chimica Acta 158, no. 2 (1989): 227–37. http://dx.doi.org/10.1016/s0020-1693(00)80838-5.

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García, M. Esther, Daniel García-Vivó, Alberto Ramos, and Miguel A. Ruiz. "Phosphinidene-bridged binuclear complexes." Coordination Chemistry Reviews 330 (January 2017): 1–36. http://dx.doi.org/10.1016/j.ccr.2016.09.008.

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Zhang, Zheng-Zhi, Hsu-Kun Wang, Hung-Gen Wang, and Ru-Ji Wang. "Studies on binuclear complexes." Journal of Organometallic Chemistry 314, no. 3 (1986): 357–67. http://dx.doi.org/10.1016/0022-328x(86)80398-9.

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Pabitra, K. Bhattacharya. "Electronic interaction between metal centres in binuclear complexes with long bridges." Journal of Indian Chemical Society Vol. 79, Feb 2002 (2002): 105–11. https://doi.org/10.5281/zenodo.5840381.

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Dick, Stefan, Armin Weiss, Ursel Wagner, Friedrich Wagner, and Gerhard Große. "Einkernige und oxoverbrückte zweikernige Fe(III)-Komplexe von N-Alkyl-N,N-bis(2-pyridylmethyl)aminen / Mononuclear and Oxo-Bridged Binuclear Fe(III) Complexes of N-Alkyl-N,N-bis(2-pyridylmethyl)amines." Zeitschrift für Naturforschung B 52, no. 3 (1997): 372–84. http://dx.doi.org/10.1515/znb-1997-0313.

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Abstract Tridentate amines of the type N-alkyl-N,N -bis(2-pyridylmethyl)amine with alkyl = methyl L1, benzyl L2 and adamantyl L3 form mononuclear Fe(III) complexes LFeCl3. In the presence of various carboxylates binuclear μ-oxo-bis(μ-carboxylato) Fe(III) complexes [L2Fe2O(RCO2)2]2+ are formed. These compounds can be synthesized from mono-, bi-, tri- and tetranuclear iron complexes as starting materials.The crystal structures of three mononuclear and four binuclear complexes show that the tridentate ligand is always facially coordinated to Fe. While in binuclear complexes of L1 and L2 the Namin
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Dissertations / Theses on the topic "Binuclear complexes"

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Easton, Thomas. "Ligand displacement reactions of binuclear ruthenium complexes." Thesis, University of Edinburgh, 1987. http://hdl.handle.net/1842/27970.

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CHAPTER.1 states the main objective of this work, the catalytic conversion of ethene to vinyl chloride using triple-halide-bridged binuclear ruthenium complexes, and emphasises the industrial significance of such a process. A brief account of relevant ruthenium chemistry is also given. CHAPTER.2 describes a new synthetic route to the complex RU2CI4 (PMe2Ph)5 involving photolysis of monomeric species. This and related complexes are used to prepare novel cationic triple-halide-bridged binuclear ruthenium complexes with the general formula [Ru2X3(L) (PR3)5 + where L = alkene, alkyne and dinitroge
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Metcalfe, Robert A. "Mononuclear and binuclear ruthenium complexes of quinonoid ligands." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp03/NQ33543.pdf.

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Wielstra, IJtsen. "Mono- and binuclear complexes of low-valent zirconium." [S.l. : [Groningen : s.n.] ; University Library Groningen] [Host], 1990. http://irs.ub.rug.nl/ppn/297968181.

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Holder, Grant Newton. "Redox reactivity of mononuclear and binuclear rhenium complexes." Diss., Georgia Institute of Technology, 1988. http://hdl.handle.net/1853/30392.

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Popham, Neil Andrew. "Studies on binuclear ansa-metallocene transition metal complexes." Thesis, University of Oxford, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.318628.

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Graham, A. "Binuclear and polynuclear metal complexes with bulky ligands." Thesis, University of Edinburgh, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.651687.

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This thesis presents routes to transition metal complexes of pyridonate and carboxylate ligands. Low nuclearity complexes with triphenyl acetate and 1<sup>st </sup>row transition metals of the formula [M<sub>4</sub>(OMe)<sub>4</sub>(O<sub>2</sub>CCPh<sub>3</sub>)<sub>4</sub>(MeOH)<sub>4</sub>] (M = Co, Ni or Zn) have been synthesised and mark a change from reactions with other carboxylates which produce linear trinuclear complexes. Molecular modelling studies investigate the close contacts that arise if triphenyl acetate is incorporated into a linear trinuclear compound to establish whether st
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Black, Daniel. "Studies on binuclear Schiff-base compartmental ligand complexes." Thesis, University of Nottingham, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.363560.

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Branscombe, Neil D. J. "Studies on binuclear compartmental Schiff-base thiolate complexes." Thesis, University of Nottingham, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299550.

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Jones, Guy Michael. "Reduction and functionalisation of binuclear uranium-oxo complexes." Thesis, University of Edinburgh, 2013. http://hdl.handle.net/1842/12230.

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Chapter one introduces uranium oxo chemistry with a focus on the structure, oxogroup reactivity and single electron reduction of the uranyl(VI) dication. In this context, the previous work in our group on the use of Schiff-base Pacman complexes for the reductive functionalisation of uranyl will be discussed. Chapter two details the synthesis of binuclear uranium(V) oxo complexes [(RMe2SiOUO)2(L)] (R = Me, Ph) by oxo group rearrangement and reductive silylation of uranyl(VI) silylamido precursors. The electronic structure and magnetic behaviour of the complexes are presented as well as insights
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Vance, Michael Alan. "Spectroscopic studies of structural and functional binuclear copper model complexes of coupled binuclear copper proteins /." May be available electronically:, 2007. http://proquest.umi.com/login?COPT=REJTPTU1MTUmSU5UPTAmVkVSPTI=&clientId=12498.

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Books on the topic "Binuclear complexes"

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Cox, Michael Gary. The preparation and reactivity of some ring-linked binuclear iron complexes. University College Dublin, 1991.

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Boss, Kevin F. Preparation and study of some linked and unlinked substituted binuclear iron complexes. University College Dublin, 1996.

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Launay, Jean-Pierre, and Michel Verdaguer. The localized electron: magnetic properties. Oxford University Press, 2018. http://dx.doi.org/10.1093/oso/9780198814597.003.0002.

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After preliminaries about electron properties, and definitions in magnetism, one treats the magnetism of mononuclear complexes, in particular spin cross-over, showing the role of cooperativity and the sensitivity to external perturbations. Orbital interactions and exchange interaction are explained in binuclear model systems, using orbital overlap and orthogonality concepts to explain antiferromagnetic or ferromagnetic coupling. The phenomenologically useful Spin Hamiltonian is defined. The concepts are then applied to extended molecular magnetic systems, leading to molecular magnetic material
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Book chapters on the topic "Binuclear complexes"

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Iglesias, Manuel, Eduardo Sola, and Luis A. Oro. "Binuclear Iridium Complexes in Catalysis." In Homo- and Heterobimetallic Complexes in Catalysis. Springer International Publishing, 2015. http://dx.doi.org/10.1007/3418_2015_145.

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Davies, R., Masayasu Mori, A. G. Sykes, et al. "Binuclear Complexes of Cobalt(III)." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132432.ch35.

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Harcourt, Richard D. "Some Cu(II) Binuclear Transition-Metal Complexes." In Lecture Notes in Chemistry. Springer International Publishing, 2015. http://dx.doi.org/10.1007/978-3-319-16676-6_8.

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Hodgson, Derek J. "Magneto-Structural Correlations in Binuclear Chromium(III) Complexes." In Magneto-Structural Correlations in Exchange Coupled Systems. Springer Netherlands, 1985. http://dx.doi.org/10.1007/978-94-009-6511-9_17.

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Balch, Alan L., Linda S. Benner, and John D. Basil. "11. Binuclear Transition Metal Complexes Bridged by Methylenebis(Diphenylphosphine)." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132524.ch11.

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Haim, Albert. "Redox Reactions of Binuclear Complexes of Ruthenium and Iron." In Advances in Chemistry. American Chemical Society, 1997. http://dx.doi.org/10.1021/ba-1997-0253.ch014.

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Basak, Arup K., and Arthur E. Martell. "Kinetics and Mechanisms of Degradation of Binuclear Cobalt Dioxygen Complexes." In Oxygen Complexes and Oxygen Activation by Transition Metals. Springer US, 1988. http://dx.doi.org/10.1007/978-1-4613-0955-0_22.

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Lawrance, Geoffrey A., Peter A. Lay, Alan M. Sargeson, Henry Taube, H. Englehardt, and M. Herberhold. "Pentaammineruthenium(III), Pentaammineruthenium(II), and Binuclear Decaamminediruthenium(III)/(II) Complexes." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132555.ch71.

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Sykes, A. G., and J. A. Weil. "The Formation, Structure, and Reactions of Binuclear Complexes of Cobalt." In Progress in Inorganic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470166147.ch1.

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Chiorboli, C., M. T. Indelli, and F. Scandola. "Photoinduced Electron/Energy Transfer Across Molecular Bridges in Binuclear Metal Complexes." In Molecular Wires and Electronics. Springer Berlin Heidelberg, 2005. http://dx.doi.org/10.1007/b136067.

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Conference papers on the topic "Binuclear complexes"

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Liu, Changlin, Rui Yan, Yan Xu, et al. "DNA binding and recognition by binuclear transition metal complexes." In International Conference on Sensing units and Sensor Technology, edited by Yikai Zhou and Shunqing Xu. SPIE, 2001. http://dx.doi.org/10.1117/12.440129.

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Guihéry, Nathalie, Renaud Ruamps, Rémi Maurice, and Coen de Graaf. "Synergy and destructive interferences between local magnetic anisotropies in binuclear complexes." In INTERNATIONAL CONFERENCE OF COMPUTATIONAL METHODS IN SCIENCES AND ENGINEERING 2015 (ICCMSE 2015). AIP Publishing LLC, 2015. http://dx.doi.org/10.1063/1.4938823.

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Dražić, Branka, Mirjana Antonijević Nikolić, Vojislav Stanić, Vesna Stojiljković, and Slađana Tanasković. "CYTOTOXIC ACTIVITY OF AMINOCARBOXYLATEMACROCYCLIC Cu(II) COMPLEXES." In 17th International Conference on Fundamental and Applied Aspects of Physical Chemistry. Society of Physical Chemists of Serbia, 2024. https://doi.org/10.46793/phys.chem24ii.577d.

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Five binuclear complexes with general formula [Cu2(L)tpmc](ClO4)4, L= valine (1), norvaline (2) leucine (3), norleucine (4) and isoleucine (5) were tested in vitro against human tumor cell lines: THP-1 (human acute monocytic leukemic cell line), Jurkat (human acute T cell leukemia) and Ramos (B cells, Burkitt’s lymphoma cell line). The values of IC50 were calculated. All tested complexes showed significant activity against the tested lines. Complex 2 has promoted significant decreases in the metabolic activity of all three cell lines, especially according to Ramos (IC50 value is 40.21 ± 1.45 µ
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Vlasenko, Valery G., Igor S. Vasilchenko, Irina V. Pirog, et al. "XAFS Study of the Ferro- and Antiferromagnetic Binuclear Copper(II) Complexes of Azomethine Based Tridentate Ligands." In X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference. AIP, 2007. http://dx.doi.org/10.1063/1.2644524.

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Jasim, Adyan Hameed, Mouayed Yousif Kadhum, and Sanaa Qasem Badr. "Spectral Properties and Biological Activities of Binuclear Mixed-Metal Bridged Thiocyanate Complexes Containing Schiff Bases Derived from Isatin." In RAiSE-2023. MDPI, 2024. http://dx.doi.org/10.3390/engproc2023059237.

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Abd, Suha Sahab, Hiyam Hadi Alkam, and Rehab Kadhim Raheem Al-Shemary. "Composition, depiction, antibacterial, antioxidant, and cytotoxicity activities studies of a new nano-sized binuclear metal (II) Schiff base complexes." In INTERNATIONAL CONFERENCE OF COMPUTATIONAL METHODS IN SCIENCES AND ENGINEERING ICCMSE 2021. AIP Publishing, 2023. http://dx.doi.org/10.1063/5.0121776.

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Peng, Tianyou, Ke Dai, Huabing Yi, Dingning Ke, and Ping Cai. "Photosensitization of Ruthenium(II) Complex on Titania for Photocatalytic H2 Evolution Under Visible-Light Irradiation." In ASME 2008 International Mechanical Engineering Congress and Exposition. ASMEDC, 2008. http://dx.doi.org/10.1115/imece2008-69172.

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Hydrogen production over dye-sensitized Pt/P25 under visible-light irradiation was investigated by using methanol or TEOA as an electron donor. The binuclear Ru(II) dye (Ru2(bpy)4L1-PF6) shows the best photosensitization in both sacrificial reagent solutions due to its larger conjugation system and “antenna effect”, which is loosely linked with TiO2 and exhibits more steady and higher increases in H2 evolution upon prolonging the irradiation time in comparison with the tightly linked N719. The dynamic equilibrium between the linkage of ground dye and divorce of oxidized dye from TiO2 can enhan
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Maeda, Kazuhiko. "Z-scheme reduction of carbon dioxide with visible light using a binuclear metal complex and a semiconductor." In SPIE Optics + Photonics for Sustainable Energy, edited by Chung-Li Dong. SPIE, 2016. http://dx.doi.org/10.1117/12.2237456.

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NIU, SHU YUN, JING JIN, GUANG DI YANG, and LING YE. "SYNTHESIS, STRUCTURE AND MAGNETISM OF A NEW IMIDAZOLATE-BRIDGED BINUCLEAR COMPLEX [Ni2(Im)(Phen)4]·(NO3)3·3H2O." In Proceedings of the International Symposium on Solid State Chemistry in China. WORLD SCIENTIFIC, 2002. http://dx.doi.org/10.1142/9789812776846_0040.

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Simplicio, Jad Lorena Feitosa, Jailton Romão Viana, João Gomes De Oliveira Neto, et al. "STUDY OF OPTICAL ABSORPTION SPECTRA AND BIOLOGICAL ASSESSMENT OF A BINUCLEAR COPPER (II) COORDINATION COMPLEX WITH MALEATE AND 1,10-PHENANTHROLINE LIGANDS." In Proceedings of the 4th ICAIC & 4th IMMSEM and 1st North and Northeast International Meeting on Materials Science and Engineering. Even3, 2023. http://dx.doi.org/10.29327/1342068.1-2.

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