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Dissertations / Theses on the topic 'Binuclear complexes'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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1

Easton, Thomas. "Ligand displacement reactions of binuclear ruthenium complexes." Thesis, University of Edinburgh, 1987. http://hdl.handle.net/1842/27970.

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CHAPTER.1 states the main objective of this work, the catalytic conversion of ethene to vinyl chloride using triple-halide-bridged binuclear ruthenium complexes, and emphasises the industrial significance of such a process. A brief account of relevant ruthenium chemistry is also given. CHAPTER.2 describes a new synthetic route to the complex RU2CI4 (PMe2Ph)5 involving photolysis of monomeric species. This and related complexes are used to prepare novel cationic triple-halide-bridged binuclear ruthenium complexes with the general formula [Ru2X3(L) (PR3)5 + where L = alkene, alkyne and dinitroge

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2

Metcalfe, Robert A. "Mononuclear and binuclear ruthenium complexes of quinonoid ligands." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp03/NQ33543.pdf.

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3

Wielstra, IJtsen. "Mono- and binuclear complexes of low-valent zirconium." [S.l. : [Groningen : s.n.] ; University Library Groningen] [Host], 1990. http://irs.ub.rug.nl/ppn/297968181.

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4

Holder, Grant Newton. "Redox reactivity of mononuclear and binuclear rhenium complexes." Diss., Georgia Institute of Technology, 1988. http://hdl.handle.net/1853/30392.

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5

Popham, Neil Andrew. "Studies on binuclear ansa-metallocene transition metal complexes." Thesis, University of Oxford, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.318628.

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6

Graham, A. "Binuclear and polynuclear metal complexes with bulky ligands." Thesis, University of Edinburgh, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.651687.

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This thesis presents routes to transition metal complexes of pyridonate and carboxylate ligands. Low nuclearity complexes with triphenyl acetate and 1<sup>st </sup>row transition metals of the formula [M<sub>4</sub>(OMe)<sub>4</sub>(O<sub>2</sub>CCPh<sub>3</sub>)<sub>4</sub>(MeOH)<sub>4</sub>] (M = Co, Ni or Zn) have been synthesised and mark a change from reactions with other carboxylates which produce linear trinuclear complexes. Molecular modelling studies investigate the close contacts that arise if triphenyl acetate is incorporated into a linear trinuclear compound to establish whether st

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7

Black, Daniel. "Studies on binuclear Schiff-base compartmental ligand complexes." Thesis, University of Nottingham, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.363560.

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8

Branscombe, Neil D. J. "Studies on binuclear compartmental Schiff-base thiolate complexes." Thesis, University of Nottingham, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299550.

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9

Jones, Guy Michael. "Reduction and functionalisation of binuclear uranium-oxo complexes." Thesis, University of Edinburgh, 2013. http://hdl.handle.net/1842/12230.

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Chapter one introduces uranium oxo chemistry with a focus on the structure, oxogroup reactivity and single electron reduction of the uranyl(VI) dication. In this context, the previous work in our group on the use of Schiff-base Pacman complexes for the reductive functionalisation of uranyl will be discussed. Chapter two details the synthesis of binuclear uranium(V) oxo complexes [(RMe2SiOUO)2(L)] (R = Me, Ph) by oxo group rearrangement and reductive silylation of uranyl(VI) silylamido precursors. The electronic structure and magnetic behaviour of the complexes are presented as well as insights

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10

Vance, Michael Alan. "Spectroscopic studies of structural and functional binuclear copper model complexes of coupled binuclear copper proteins /." May be available electronically:, 2007. http://proquest.umi.com/login?COPT=REJTPTU1MTUmSU5UPTAmVkVSPTI=&clientId=12498.

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11

鄺海倫 and Hoi-lun Kwong. "Photochemistry of binuclear platinum (II) and gold (I) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1989. http://hub.hku.hk/bib/B31208678.

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12

Makinde, Zainab Olusola. "Spectroscopic and electrochemical characterization of thio binuclear phthalocyanine complexes." Thesis, Rhodes University, 2017. http://hdl.handle.net/10962/59287.

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13

Harvey, Erica Lyn Gray Harry B. "Photochemical hydrogen atom transfer reactions of binuclear platinum complexes /." Diss., Pasadena, Calif. : California Institute of Technology, 1990. http://resolver.caltech.edu/CaltechETD:etd-06112007-134908.

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14

Smith, David Charles Goddard William A. Gray Harry B. "Electronic structure and photochemical reactivity of binuclear metal complexes." Diss., Pasadena, Calif. : California Institute of Technology, 1989. http://resolver.caltech.edu/CaltechTHESIS:11052009-142520920.

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Thesis (Ph. D.)--California Institute of Technology, 1989. UM #89-15,396.<br>Advisor names found in the Acknowledgements pages of the thesis. Title from home page. Viewed 01/19/2010. Includes bibliographical references.

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15

Kwong, Hoi-lun. "Photochemistry of binuclear platinum (II) and gold (I) complexes /." [Hong Kong : University of Hong Kong], 1989. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12434000.

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16

Thom, James Andrew. "Self-assembly and anion recognition with binuclear lanthanide complexes." Thesis, University of Oxford, 2014. http://ora.ox.ac.uk/objects/uuid:20de876d-0a52-4f11-82b7-922fc3e2ee45.

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This work describes an investigation into the solution-phase binding of anionic guests by bimacrocyclic lanthanide complexes. It outlines the preparation of different classes of complexes bearing two metallic domains, and the effects of association on both the complex and the guest. Chapter one provides a cursory introduction to the fundamental properties of the lanthanides with a focus on luminescence. A brief literature review is given on the use of emissive lanthanide probes for the sensing of analytes. Chapter two concerns the preparation and properties of a series of binuclear complexes i

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17

Stevens, Charlotte Jane. "Investigating the chemistry of binuclear chromium and uranium Pacman complexes." Thesis, University of Edinburgh, 2015. http://hdl.handle.net/1842/10007.

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Drawing inspiration from nature where enzymes containing multi-metallic active sites are ubiquitous, chemists have designed various ligands to bind more than one metal in precise structural arrangements. In Chapter One, a class of binucleating Schiff base pyrrole (Pacman) macrocycles which are both straightforward to synthesise and can be varied systematically to alter the metal environment and intermetallic separation are introduced, along with the state-of-the-art in this area. Previously reported complexes of these ligands with late transition metals, lanthanides and actinides are also revi

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18

Elliot, Marie. "An electrochemical and spectroelectrochemical investigation of binuclear transition metal complexes." Thesis, University of Edinburgh, 2001. http://hdl.handle.net/1842/13786.

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Three different types of mixed-valence complexes are studied in this thesis, namely, homonuclear d<sup>4</sup>/d<sup>5</sup>, heteronuclear d<sup>5</sup>/d<sup>6</sup> and homonuclear d<sup>5</sup>/d<sup>6</sup> binuclear metallic species. The electrochemical syntheses of the mononuclear complexes [OsC1<sub>5</sub>(N-cypy)]<sup>-/2-</sup> (N = 2,3, 4; cypy = cyanopyridine), and the asymmetrical homonuclear complexes, [C1<sub>5</sub>Os(N-cypy)OsC1<sub>5</sub>]<sup>n-</sup> (N = 3, 4; n = 4, 5, 6) are reported. The mononuclear cyanopyridine complexes produce two isomeric forms, the cyanopyridine

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19

Zadykowicz, Jerzy. "Bis(pyrazolyl)pyridines and their mono- and binuclear Ru(II) complexes." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp02/NQ33555.pdf.

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20

Martin, Ditanya I. C. "Transient Raman spectroscopy of mono- and binuclear complexes of Ruthenium(II)." Thesis, Queen's University Belfast, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.359114.

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21

Waugh, Mark. "Binuclear allenyl complexes : synthesis and a systematic study of their reactivity." Thesis, University of Newcastle Upon Tyne, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.312047.

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22

Chau, Chung-Nin. "Studies on binuclear iron nitrosyl complexes containing bridging alkylsulfide or diphenylphosphide /." The Ohio State University, 1985. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487261553059339.

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23

Johnson, Sean M. "Toward the Synthesis of Naphthalene-Bridged Bis-Triazole Bimetallic Complexes." Scholar Commons, 2017. http://scholarcommons.usf.edu/etd/6872.

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Bimetallic complexes are known to have unique electronic properties and are used in a variety of organic transformations as catalysts. The use of naphthalene-bridged bis- triazoles (NBT) for bimetallic complexes is unknown. NBTs have the unique property of being fluorescent stemming from a twisted intramolecular charge transfer. With the non- coplanar geometry and the distance between the 1,2,3-triazole rings, we hypothesized that 1,8-bis(4-phenyl-2H-1,2,3-triazol-2-yl)naphthalene (12) would be a suitable ligand to synthesize a bimetallic complex. The synthesis of 12 was optimized for large sc

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24

Esteves, Lucas Fagundes. "Investigação teórica do mecanismo de ação de compostos binucleares de platina(II)." Universidade Federal de Juiz de Fora, 2012. https://repositorio.ufjf.br/jspui/handle/ufjf/2048.

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25

Sorbie, Ruth J. "Electrochemical and spectroelectrochemical studies of some binuclear complexes of ruthenium and osmium." Thesis, University of Edinburgh, 1989. http://hdl.handle.net/1842/14452.

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26

Mock, Michael T. "Synthesis and reactivity of thioether-supported organoiron and low-valent iron complexes and cyanide-bridged binuclear complexes." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file, 282 p, 2008. http://proquest.umi.com/pqdweb?did=1481668291&sid=19&Fmt=2&clientId=8331&RQT=309&VName=PQD.

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27

Reed-Mundell, Joseph Jerome. "Binuclear and tetranuclear copper(II) complexes containing ligands derived from phenol or hydroquinone." Case Western Reserve University School of Graduate Studies / OhioLINK, 1990. http://rave.ohiolink.edu/etdc/view?acc_num=case1058302716.

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28

羅政藩 and Chang-fan Lo. "Substitution and redox reactions of some binuclear platinum (II) and platinum (III) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1989. http://hub.hku.hk/bib/B31231901.

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29

Devoille, Aline M. J. "New cofacial binuclear complexes for the oxygen reduction reaction and selective anion binding." Thesis, University of Edinburgh, 2011. http://hdl.handle.net/1842/9963.

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This thesis describes the design, synthesis and reactivity of bimetallic complexes of doubly-pillared Schiff-base calixpyrrole ligands. Chapter One introduces the oxygen reduction reaction in light of the global energy scenario at present and in the future. Compounds and materials known to catalyse this reaction are discussed, with particular focus on transition metal complexes of pyrrole-containing macrocycles and the ability of these compounds to act as catalysts in redox reactions. Chapter Two describes the design and synthesis of several of the macrocyclic ligands developed during this pro

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30

Mapolie, Selwyn Frank. "The synthesis and reactivity of binuclear μ-hydrocarbyl complexes of some transition metals". Doctoral thesis, University of Cape Town, 1988. http://hdl.handle.net/11427/22208.

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The new μ-(l,n)-alkanediyl compounds [(ƞ⁵-C₅R₄Me)Fe(CO)₂ ]₂{μ-(CH₂)n}, (R = H, n = 3 -10 and R =Me, n =3 - 6), [Mn(CO)₅]₂{μ-(CH₂)n} (M = Mn, n = 4-6 and M = Re, n= 3 and 4) have been prepared using essentially two synthetic routes. Thus the iron compounds were synthesized by the reaction of Na[(ƞ⁵-C₅R₄Me)Fe(CO)₂ ] with the appropriate dibromoalkane. The manganese and rhenium compounds on the other hand, were prepared by the decarbonylation of the corresponding diacyl compounds of the type, [M(CO)₅]₂{μ-CO(CH₂)nCO} (M = Mn or Re). These diacyl species in turn were synthesized by the reaction of

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31

Lo, Chang-fan. "Substitution and redox reactions of some binuclear platinum (II) and platinum (III) complexes /." [Hong Kong : University of Hong Kong], 1989. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12505304.

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32

Goy, Aytunc. "Axial Ligand Substitution Reaction Kinetics Of Pyrimidine-2-thionato Bridged Binuclear Platinum(iii) Complexes." Master's thesis, METU, 2007. http://etd.lib.metu.edu.tr/upload/2/12608684/index.pdf.

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ABSTRACT AXIAL LIGAND SUBSTITUTION REACTION KINETICS OF PYRIMIDINE-2-THIONATO BRIDGED BINUCLEAR PLATINUM(III) COMPLEXES G&ouml<br>y, Aytun&ccedil<br>M. S. Department of Chemistry Supervisor: Prof. Dr. H&uuml<br>seyin iS&ccedil<br>i Co-supervisor: Assoc. Prof.Dr. Seniz &Ouml<br>zalp Yaman September 2007, 89 pages The kinetics of the ligand substitution reactions, which is represented by the equation, [Pt2(C4H3N2S)4X2] + 2Y- Pt2(C4H3N2S)4Y2 + 2X- where X- = Cl-, Br-, I- and Y- = Cl-, Br-, I- are studied in acetonitrile in the presence of excess Y-

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33

李慧敏 and Huai-min Li. "Photochemical studies of binuclear platinum and rhodium complexes withbridging isocyanide, phosphite and phosphine ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1989. http://hub.hku.hk/bib/B31231603.

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34

Ainooson, Michael Kojo. "Binuclear late transition metal complexes with pyrazole based compartmental ligands: Scaffolds for cooperative organometallic transformations." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2014. http://hdl.handle.net/11858/00-1735-0000-0023-98FC-E.

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35

Drennan, Dennis. "The chemistry of mono- and binuclear 1,2,3-triphenylguanidine and 1,2,3-triphenylguanidinate complexes with transition metals." Thesis, University of Bristol, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.409525.

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36

Harris, Lauren Michelle. "Photophysical Properties of Binuclear and Trinuclear Monovalent Coinage Metal Complexes for Applications in Molecular Devices." Thesis, University of North Texas, 2020. https://digital.library.unt.edu/ark:/67531/metadc1703352/.

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Monovalent coinage metal complexes have been of significant interest due to their rich photophysical properties. This dissertation focuses on the design, synthesis, and characterization of gold, silver, and copper phosphors. Chapter 2 investigates new physical and photophysical properties of a gold diphosphine dimer in the solid state. Thermally activated luminescence switching between two structural states is discussed. Chapter 3 includes the photochemistry of closed shell group 11 transition metals with dithiophosphonate and diphosphine ligands as heteroleptic, homoleptic and heterometalli

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37

Li, Huai-min. "Photochemical studies of binuclear platinum and rhodium complexes with bridging isocyanide, phosphite and phosphine ligands /." [Hong Kong] : University of Hong Kong, 1989. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12428541.

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38

Sibanyoni, Johannes Mlandu. "The preparation of binuclear and polynuclear methyl complexes of palladium as catalyst precursors in phenylacetylene polymerization." Thesis, University of the Western Cape, 2007. http://etd.uwc.ac.za/index.php?module=etd&action=viewtitle&id=gen8Srv25Nme4_8510_1257938412.

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<p>This study focused on the development of binuclear and multinuclear catalyst for use in vinylic monomer oligomerization and polymerization. The main objective was to develop new homogeneous catalysts systems with hopefully improved activity, selectivity and stability.</p>

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39

Ma, Guibin. "On Thallium (III) and binuclear platinum-thallium complexes with N-donor ligands in solution and in solid." Doctoral thesis, Stockholm, 2001. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3129.

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40

Tussupbayev, Samat. "Theoretical study of reactivity and dynamics of hybride-bridged diruthenium complexes and silylium." Doctoral thesis, Universitat de Girona, 2009. http://hdl.handle.net/10803/8052.

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Esta tesis presenta un estudio computacional de los sistemas con hidruros puente. En la primera parte se estudia la química de complejos de dirutenio con cuatro hidruros puente. Esto incluye las siguientes reacciones: el intercambio del hidruro con hidrógeno molecular; la activación del enlace C-H del etileno para formar el complejo de bis(vinilo)-etileno; el acoplamiento C-C entre el etileno coordinado y dos ligandos vinilo para producir el complejo rutenaciclopentadieno. Al final de esta parte, se discuten a detalle los mecanismos de estas reacciones. Además, se demostró la importancia de la

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41

Melo, Vitor Hugo Soares de. "Investigação por meio de efeito SERS e SERRS dos sistemas híbridos formados pela interação da 3,6-bi-2-piridil-1,2,4,5-tetrazina e complexos de rutênio com ouro macroscópico e nanoparticulado." Universidade de São Paulo, 2010. http://www.teses.usp.br/teses/disponiveis/46/46134/tde-21072010-083127/.

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A síntese e caracterização de sistemas hetero-híbridos gerados a partir da 3,6-bi-2-piridil-1,2,4,5-tetrazina (bptz) e interações com ouro nanoparticulado são abordados nesta tese. O bptz foi estudado por meio de métodos espectroscópicos e teóricos, focalizando principalmente o efeito SERS associado à adsorção em nanopartículas de ouro. O mecanismo de transferência de carga para metais macroscópicos foi transposto para a condição nanoparticulada, envolvendo ligações químicas entre bptz e as nanopartículas. Os complexos estudados possuem fórmula geral [LmRu(µ-bptz)RuLm]Xn, com “L&#8

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42

Beng, Timothy Kum. "Kinetics and mechanism of the catalysis of the decomposition of hydrogen peroxide by Schiff base complexes of copper(II)." [Johnson City, Tenn. : East Tennessee State University], 2004. http://etd-submit.etsu.edu/etd/theses/available/etd-1113104-182005/unrestricted/BengT120104f.pdf.

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Thesis (M.S.)--East Tennessee State University, 2004.<br>Title from electronic submission form. ETSU ETD database URN: etd-1113104-182005 Includes bibliographical references. Also available via Internet at the UMI web site.

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43

Ainooson, Michael Kojo [Verfasser], Franc [Akademischer Betreuer] Meyer, Philipp [Akademischer Betreuer] Vana, and Dietmar [Akademischer Betreuer] Stalke. "Binuclear late transition metal complexes with pyrazole based compartmental ligands: Scaffolds for cooperative organometallic transformations / Michael Kojo Ainooson. Gutachter: Philipp Vana ; Dietmar Stalke. Betreuer: Franc Meyer." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2014. http://d-nb.info/1074758447/34.

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44

Broch, Fernanda. "Síntese, cristalografia e propriedades de ligantes triazenos mono e biscatenados e derivados complexos de Cu(II), Ni(II) e Pd(II)." Universidade Federal de Santa Maria, 2013. http://repositorio.ufsm.br/handle/1/4248.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior<br>Triazenes are a class of compounds characterized by the presence of a diazoamino functional group (N=N N) showing remarkable ability to support the stereochemical requisites of a wide variety of metal transition complexes. They act as versatile ligands in coordination chemistry when deprotonated and have relevant biological and synthetic porperties. This work presents the synthesis and investigation of molecular and crystal structure of a new series of monotriazenes [3-(4-phenyldiazenyl)-1-(2-fluorophenyl)triazene (2b); 1-(2-chloro

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45

Calancea, Sergiu. "Synthèse et caractérisations de nouveaux complexes binucléaires à transfert d’électron de type {Fe(µ-CN)M} (M = Fe, Mn, Co)." Thesis, Bordeaux 1, 2013. http://www.theses.fr/2013BOR14802/document.

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L’une des grandes directions de recherche dans la chimie moderne est la synthèse et l’étude denouveaux composés « commutables » capables de modifier leurs propriétés sous l’effet de stimuli extérieurs (température, lumière, champ magnétique ou électrique…). Ces systèmes peuvent stocker une information à l’échelle moléculaire. Dans ce contexte, parmi les systèmes les plus étudiés en chimie de coordination figurent les réseaux et les analogues moléculaires du bleu de Prusse. Cette thèse est dédiée à la synthèse et aux caractérisations de nouveaux analogues moléculaires du bleu de Prusse à transf

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46

Righez, Rosane Claumann. "Síntese e caracterização de novos complexos binucleares como ligante H2BPBPMP nitro substituído." reponame:Repositório Institucional da UFSC, 2013. http://repositorio.ufsc.br/handle/123456789/103055.

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Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas. Programa de Pós-Graduação em Química.<br>Made available in DSpace on 2013-07-16T02:47:37Z (GMT). No. of bitstreams: 1 275447.pdf: 1306263 bytes, checksum: d84b6cd5ee3af7a9bcf499eeb82713dd (MD5)<br>Por exercerem papéis de fundamental importância na manutenção da vida, por seu alto poder catalítico, e por sua alta especificidade e seletividade, a obtenção de informações sobre as propriedades e o modo de ação das enzimas, tem sido de grande interesse para químicos e bioquímicos de todo o mun

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47

Wohnrath, Karen [UNESP]. "Aplicação do '[RuCl IND. 3(DPPB)H IND.2 O] na obtenção do complexos mono e binucleares." Universidade Estadual Paulista (UNESP), 1999. http://hdl.handle.net/11449/105809.

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Made available in DSpace on 2014-06-11T19:35:08Z (GMT). No. of bitstreams: 0 Previous issue date: 1999-06-23Bitstream added on 2014-06-13T20:06:35Z : No. of bitstreams: 1 wohnrath_k_dr_araiq.pdf: 2129110 bytes, checksum: 7f32f1de19507766ae5c9a4b7787daba (MD5)<br>O complexo inédito mer-[RuCl3(dppb)H2O], foi caracterizado como precursor de uma série de compostos fosfínicos. Foram testadas sínteses do complexo título com ligantes providos de diferentes modos de coordenação, tais como os monodentados (L= DMSO, MeOH, NO e CO, py, 4-Mepy), exodentado (L= 4-CNpy), bidentados (L-L= 2,2'-bipy, fen) e

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48

Aguiar, Natanna Azevedo de. "Symmetrical binuclear ruthenium compounds : synthesis , characterization and study of electronic communication." Universidade Federal do CearÃ, 2015. http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=16405.

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CoordenaÃÃo de AperfeÃoamento de Pessoal de NÃvel Superior<br>No trabalho descrito a seguir, serÃo apresentados e discutidos os resultados das sÃnteses e caracterizaÃÃes de quatro compostos inÃditos, a citar: trans-[Ru(NH3)4(4-Apy)(pyS)]Cl2 (1), trans-[Ru(NH3)4(pyS)(iTna)]Cl2 (2), trans-{[Ru(NH3)4(pyS)]2-Â-4-Apy}(PF6)4 (3) e trans-{[Ru(NH3)4(pyS)]2-Â-iTna}(PF6)4 (4), onde pyS = 4-mercaptopiridina, 4-Apy = 4-aminopiridina e iTna = isotionicotinamida. O grau de comunicaÃÃo eletrÃnica entre os centros metÃlicos nos complexos binucleares foi avaliado por eletroquÃmica e apresentaram valores de con

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Rossi, Liane Marcia. "Novos complexos binucleares de cobre de relevância bioinorgânica." Florianópolis, SC, 2001. http://repositorio.ufsc.br/xmlui/handle/123456789/81613.

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Tese (doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas.<br>Made available in DSpace on 2012-10-19T06:08:18Z (GMT). No. of bitstreams: 0Bitstream added on 2014-09-25T22:27:53Z : No. of bitstreams: 1 177328.pdf: 6148233 bytes, checksum: f0c15786d151a9bd7e1855ddec1e07c4 (MD5)<br>Novos complexos binucleares de cobre(II) foram sintetizados e caracterizados: [Cu2(H2bbppnol)(m-CH3COO)(H2O)2]Cl2.2H2O (1), [Cu2(H2bbppnol)(m-CH3COO)(m-ClO4)]ClO4·H2O·EtOAc (2), [Cu2(Hbbppnol)(H2O)4](ClO4)2×2CH3OH (3), [Cu2(Hbtppnol)(m-CH3COO)](ClO4)2 (4), [Cu2(tppnol)(m-CH3COO

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Wohnrath, Karen. "Aplicação do '[RuCl IND. 3(DPPB)H IND.2 O] na obtenção do complexos mono e binucleares /." Araraquara : [s.n.], 1999. http://hdl.handle.net/11449/105809.

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Orientador: Alzir Azevedo Batista<br>Banca: Luiz Antônio Andrade de Oliveira<br>Banca: Regina Frem<br>Banca: Wagner Ferraresi de Giovani<br>Banca: Benedito Lima Neto<br>Resumo: O complexo inédito mer-[RuCl3(dppb)H2O], foi caracterizado como precursor de uma série de compostos fosfínicos. Foram testadas sínteses do complexo título com ligantes providos de diferentes modos de coordenação, tais como os monodentados (L= DMSO, MeOH, NO e CO, py, 4-Mepy), exodentado (L= 4-CNpy), bidentados (L-L= 2,2'-bipy, fen) e ambidentado (L-L= 4,4'-bipy). Os produtos destas reações foram isolados como espécies b

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