Academic literature on the topic 'Biogenetic intermediate'

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Journal articles on the topic "Biogenetic intermediate"

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Tietze, Lutz F., Stephan Henke, and Christoph Bärtels. "Biomimetic transformations of the biogenetic key intermediate secologanin." Tetrahedron 44, no. 23 (1988): 7145–53. http://dx.doi.org/10.1016/s0040-4020(01)86082-8.

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Gassner, Cemena, Ronny Hesse, Arndt W. Schmidt, and Hans-Joachim Knölker. "Total synthesis of the cyclic monoterpenoid pyrano[3,2-a]carbazole alkaloids derived from 2-hydroxy-6-methylcarbazole." Org. Biomol. Chem. 12, no. 33 (2014): 6490–99. http://dx.doi.org/10.1039/c4ob01151a.

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Fukuzawa, Akio, Yasunori Takasugi, and Akio Murai. "Prelaureatin, a new biogenetic key intermediate isolated from Laurencia nipponica." Tetrahedron Letters 32, no. 40 (1991): 5597–98. http://dx.doi.org/10.1016/0040-4039(91)80093-l.

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Guardia, Juan J., Antonio Fernández, José Justicia, et al. "Unprecedented Elimination Reactions of Cyclic Aldols: A New Biosynthetic Pathway toward the Taiwaniaquinoid Skeleton." Molecules 28, no. 4 (2023): 1524. http://dx.doi.org/10.3390/molecules28041524.

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The acid treatment of 6,7-seco-abietane dialdehydes gives, in high yield, the corresponding derivatives with the 4a-methyltetrahydrofluorene skeleton of taiwaniaquinoids. A mechanism involving the elimination of formic acid from the cyclic aldol intermediate is proposed here. This process can be postulated as a new biogenetic pathway from abietane diterpenes to taiwaniaquinoids. Using this novel reaction, the first enantiospecific synthesis of bioactive natural cupresol and taxodal has been obtained.
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Liu, Zhang-Bin, Yosuke Matsuo, Yoshinori Saito, Yong-Lin Huang, Dian-Peng Li, and Takashi Tanaka. "Identification of Unstable Ellagitannin Metabolites in the Leaves of Quercus dentata by Chemical Derivatization." Molecules 28, no. 3 (2023): 1246. http://dx.doi.org/10.3390/molecules28031246.

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The identification of unstable metabolites of ellagitannins having ortho-quinone structures or reactive carbonyl groups is important to clarify the biosynthesis and degradation of ellagitannins. Our previous studies on the degradation of vescalagin, a major ellagitannin of oak young leaves, suggested that the initial step of the degradation is regioselective oxidation to generate a putative quinone intermediate. However, this intermediate has not been identified yet. In this study, young leaves of Quercus dentata were extracted with 80% acetonitrile containing 1,2-phenylenediamine to trap unst
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Takayama, Hiromitsu, Tomotake Ichikawa, Mariko Kitajima, Norio Aimi, Dazy Lopez, and Maribel G. Nonato. "A new alkaloid, pandanamine; finding of an anticipated biogenetic intermediate in Pandanus amaryllifolius Roxb." Tetrahedron Letters 42, no. 16 (2001): 2995–96. http://dx.doi.org/10.1016/s0040-4039(01)00339-2.

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Takayama, Hiromitsu, Tomotake Ichikawa, Mariko Kitajima, Norio Aimi, Dazy Lopez, and Maribel G. Nonato. "ChemInform Abstract: A New Alkaloid, Pandanamine; Finding of an Anticipated Biogenetic Intermediate in Pandanus amaryllifolius Roxb." ChemInform 32, no. 29 (2010): no. http://dx.doi.org/10.1002/chin.200129184.

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Hu, Wei-Min, and Jun Wu. "Protoxylogranatin B, a Key Biosynthetic Intermediate from Xylocarpus granatum: Suggesting an Oxidative Cleavage Biogenetic Pathway to Limonoid." Open Natural Products Journal 3, no. 1 (2010): 1–5. http://dx.doi.org/10.2174/1874848101003010001.

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Morimoto, Yoshiki, and Chiho Yokoe. "Total synthesis of haliclamine A, a macrocyclic marine alkaloid related to the key biogenetic intermediate of manzamines." Tetrahedron Letters 38, no. 52 (1997): 8981–84. http://dx.doi.org/10.1016/s0040-4039(97)10368-9.

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Albrecht, Wolfgang, та Roland Tressl. "Studies on the Biosynthesis of γ–Decalactone in Sporobolomyces odorus". Zeitschrift für Naturforschung C 45, № 3-4 (1990): 207–16. http://dx.doi.org/10.1515/znc-1990-3-411.

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Abstract Incubation of racemic ethyl [2,2-2H2]-(E)-3,4-epoxydecanoate and the corresponding acid with intact cells of Sporobolomyces odorus led to the formation of deuterium labeled γ-decalaetone. The detection of labeled 2-decen-4-olide and 4-oxodecanoic acid made it possi­ble to propose the biogenetic sequence leading to γ-decalactone. The determination of the en­ antiomeric ratio of the lactone revealed an unspecific metabolism of the precursor. In contrast to the (E)-isomer, after administration of ethyl [5,6-2H2]-(Z)-3,4-epoxydeeanoate no transfor­mation could be detected. These results i
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Dissertations / Theses on the topic "Biogenetic intermediate"

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Raulfs, Estella Callie. "Isolation of in vivo intermediates in iron sulfur cluster biogenesis." Diss., Virginia Tech, 2009. http://hdl.handle.net/10919/26949.

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Iron-sulfur clusters are simple inorganic cofactors that are ubiquitous in living systems. The assembly of iron sulfur clusters is an essential process and must be carefully controlled in order to limit the release of toxic free iron or sulfide. Thus far there are three known protein systems for iron sulfur cluster assembly including the <i>nif, suf,</i> and <i>isc</i> systems. The <i>nif</i> system makes iron-sulfur clusters for nitrogenase production, while both the <i>suf</i> and <i>isc</i> systems provide iron-sulfur clusters for general cellular use. In <i>Azotobacter vinelandii</i> the i
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Padilla, Acevedo Angela Isabel. "Studies directed towards the synthesis of secu'amamine A." Thesis, 2009. http://hdl.handle.net/2152/23286.

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Herein is described our synthetic studies towards the synthesis of secu'amamine A, a member of the Securinega alkaloids. The first chapter describes the isolation, biological significance and previous synthesis of secu'amamine A. Chapter 2 discusses our proposed biogenetic origin of secu'amamine A from allosecurinine and the model studies to support the intermediacy of the putative aziridinium ion. Chapter 3 discusses our synthetic approach to the formation of rings A and C, as well as investigations on the regioselective functionalization of 1,2-dihydropyridines. Chapter 4 discusses the synth
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Book chapters on the topic "Biogenetic intermediate"

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Barreteau, Hélène, Didier Blanot, Dominique Mengin-Lecreulx, and Thierry Touzé. "Lipid Intermediates in Bacterial Peptidoglycan Biosynthesis." In Biogenesis of Fatty Acids, Lipids and Membranes. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-43676-0_11-1.

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Barreteau, Hélène, Didier Blanot, Dominique Mengin-Lecreulx, and Thierry Touzé. "Lipid Intermediates in Bacterial Peptidoglycan Biosynthesis." In Biogenesis of Fatty Acids, Lipids and Membranes. Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-319-50430-8_11.

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Dörnemann, D. "New Aspects of the Intermediates, Catalytic Components and the Regulation of the C5 -Pathway to Chlorophyll." In Regulation of Chloroplast Biogenesis. Springer US, 1992. http://dx.doi.org/10.1007/978-1-4615-3366-5_24.

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Burger, Koert N. J., Gerd Knoll, Peter M. Frederik, and Arie J. Verkleij. "Influenza Virus Mediated Membrane Fusion: The Identification of Fusion Intermediates Using Modern Cryotechniques." In Dynamics and Biogenesis of Membranes. Springer Berlin Heidelberg, 1990. http://dx.doi.org/10.1007/978-3-642-74194-4_14.

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Sommer, Amos, Emma Ne’eman, and Eitan Harel. "Processing of the Light-Harvesting Chlorophyll a/b Protein II Precursor — Possible Intermediate Steps Examined by Using Truncated Precursors." In Regulation of Chloroplast Biogenesis. Springer US, 1992. http://dx.doi.org/10.1007/978-1-4615-3366-5_21.

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Cline, Kenneth, Ralph Henry, Chang-Jiang Li, and Jianguo Yuan. "Pathways and Intermediates for the Biogenesis of Nuclear-Encoded Thylakoid Proteins." In Research in Photosynthesis. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-009-0383-8_32.

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Benjamin, Sailas, Kizhakepowathil Nair Unni, Prakasan Priji, and Andre-Denis Girard Wright. "Biogenesis of Conjugated Linoleic Acids." In Examining the Development, Regulation, and Consumption of Functional Foods. IGI Global, 2017. http://dx.doi.org/10.4018/978-1-5225-0607-2.ch001.

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One of the key areas in animal husbandry is to improve the quality (nutritional value) of dairy and meat products by enriching them with Conjugated Linoleic Acids (CLAs) like (cis-9, trans-11)- and (trans-10, cis-12)-octadecadienicacids; the former (rumenic acid) predominates all the CLAs. Though Vaccenic Acid (VA) is the immediate precursor of rumenic acid, dietary unsaturated fatty acids like Oleic Acid (OA), Linoleic Acid (LA) and a-Linolenic Acid (ALA) are the distant precursors of CLAs; and that CLA and VA are formed as intermediates during the biohydrogenation of the dietary OA, LA and A
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Gu, Feng, and Jean Gruenberg. "In vitro reconstitution of early to late endosome transport: biogenesis and subsequent fusion of transport intermediates." In Essential Cell Biology. Oxford University PressOxford, 2003. http://dx.doi.org/10.1093/oso/9780199638338.003.0008.

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Abstract Vesicles formed via invaginations of the plasma membrane are responsible for the internalization and turnover of cell surface proteins and lipids, and for the uptake of extracellular ligands and solutes. Although evidence is accumulating for the existence of more than one internalization pathway, most receptors are internalized via the well characterized clathrin-dependent pathway. The bulk of internalized molecules, including solutes, ligands, and membrane constituents, are then delivered to common early endosomes, at least in most animal cell types. From there, many receptors and li
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Bean, Daniel W., and Steven W. Matson. "Identification and characterization of DNA helicases." In Eukaryotic DNA Replication. Oxford University PressOxford, 1999. http://dx.doi.org/10.1093/oso/9780199636815.003.0004.

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Abstract DNA helicases catalyse disruption of the hydrogen bonds between the two strands of duplex DNA to generate single-stranded DNA (ssDNA) products (1, 2). This reaction is generally referred to as an unwinding reaction. The ssDNA product(s) of the unwinding reaction is then available for use as a template for DNA replication or repair, or as a substrate in recombination. Enzymes that catalyse the unwinding of duplex RNA, RNA secondary structure, and DNA:RNA hybrids have also been described (3-7). These enzymes have important roles in mRNA biogenesis, transcription, and translation. Thus,
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