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Journal articles on the topic 'Bioinspired Confined Catalysis'

Author: Grafiati

Published: 25 May 2024

Last updated: 31 July 2025

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1

Zhu, Congcong, Yunfei Teng, Ganhua Xie, et al. "Correction: Bioinspired hydrogel-based nanofluidic ionic diodes: nano-confined network tuning and ion transport regulation." Chemical Communications 56, no. 73 (2020): 10767. http://dx.doi.org/10.1039/d0cc90381g.

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Correction for ‘Bioinspired hydrogel-based nanofluidic ionic diodes: nano-confined network tuning and ion transport regulation’ by Congcong Zhu et al., Chem. Commun., 2020, 56, 8123–8126, DOI: 10.1039/D0CC01313G.

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2

Bauer, Christina A, David B. Robinson, and Blake A Simmons. "Silica Particle Formation in Confined Environments via Bioinspired Polyamine Catalysis at Near-Neutral pH." Small 3, no. 1 (2007): 58–62. http://dx.doi.org/10.1002/smll.200600352.

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3

Zhu, Congcong, Yunfei Teng, Ganhua Xie, et al. "Bioinspired hydrogel-based nanofluidic ionic diodes: nano-confined network tuning and ion transport regulation." Chemical Communications 56, no. 58 (2020): 8123–26. http://dx.doi.org/10.1039/d0cc01313g.

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The biological ion channel-based mass transport and signal transduction play a crucial role in physiological activities, and the biomimetic nanochannels with nanoconfined hydrogel network for ion transport have been extensively studied.

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4

Tan, Mei‐Ling, M. Ángeles Gutiérrez López, Naomi Sakai та Stefan Matile. "Anion‐(π)_n‐π Catalytic Micelles". Angewandte Chemie, 25 серпня 2023. http://dx.doi.org/10.1002/ange.202310393.

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AbstractAnion‐π catalysis operates by stabilizing anionic transition states on π‐acidic aromatic surfaces. In anion‐(π)n‐π catalysis, π stacks add polarizability to strengthen interactions. In search of synthetic methods to extend π stacks beyond the limits of foldamers, the self‐assembly of micelles from amphiphilic naphthalenediimides (NDIs) is introduced. To interface substrates and catalysts, charge‐transfer complexes with dialkoxynaphthalenes (DANs), a classic in supramolecular chemistry, are installed. In π‐stacked micelles, the rates of bioinspired ether cyclizations exceed rates on mon

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5

Tan, Mei‐Ling, M. Ángeles Gutiérrez López, Naomi Sakai та Stefan Matile. "Anion‐(π)_n‐π Catalytic Micelles". Angewandte Chemie International Edition, 25 серпня 2023. http://dx.doi.org/10.1002/anie.202310393.

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AbstractAnion‐π catalysis operates by stabilizing anionic transition states on π‐acidic aromatic surfaces. In anion‐(π)n‐π catalysis, π stacks add polarizability to strengthen interactions. In search of synthetic methods to extend π stacks beyond the limits of foldamers, the self‐assembly of micelles from amphiphilic naphthalenediimides (NDIs) is introduced. To interface substrates and catalysts, charge‐transfer complexes with dialkoxynaphthalenes (DANs), a classic in supramolecular chemistry, are installed. In π‐stacked micelles, the rates of bioinspired ether cyclizations exceed rates on mon

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6

Liu, Bi-Ying, Yu-Hui Zhang, Yongchao Qian, et al. "Single Idiosyncratic Ionic Generator Working in Iso‐Osmotic Solutions Via Ligand Confined Assembled in Gaps Between Nanosheets." Angewandte Chemie International Edition, December 20, 2023. http://dx.doi.org/10.1002/anie.202317361.

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Numerous reported bioinspired osmotic energy conversion systems employing cation‐/ anion‐selective membrane and solutions with different salinity are actually far from the biological counterpart. The iso‐osmotic power generator with the specific ionic permselective channels (e.g., K+ or Na+ channels) which just allow specific ions get across and iso‐osmotic solutions still remain challenges. Inspired by nature, we report a bioinspired K+‐channel by employing a K+ selective ligand, 1,1,1‐tris{[(2’‐benzylaminoformyl)phenoxy]methyl}ethane (BMP) and graphene oxide membrane. Specifically, the K+ an

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7

Tian, Jiaxin, Basudev Maity, Tadaomi Furuta, Tiezheng Pan, and Takafumi Ueno. "An Artificial Metal‐Free Peroxidase Designed Using a Ferritin Cage for Bioinspired Catalysis." Angewandte Chemie, April 24, 2025. https://doi.org/10.1002/ange.202504608.

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Developing artificial enzymes is challenging because it requires precise design of active sites with well‐arranged amino acid residues. Histidine‐rich oligopeptides have been recently shown to exhibit peroxidase‐mimetic activities, but their catalytic function relies on maintaining unique supramolecular structures. This work demonstrates the design of a specific array of histidine residues on the internal surface of the ferritin cage to function as an active center for catalysis. The crystal structures of the ferritin mutants revealed histidine‐histidine interactions, forming well‐defined hist

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8

Tian, Jiaxin, Basudev Maity, Tadaomi Furuta, Tiezheng Pan, and Takafumi Ueno. "An Artificial Metal‐Free Peroxidase Designed Using a Ferritin Cage for Bioinspired Catalysis." Angewandte Chemie International Edition, April 24, 2025. https://doi.org/10.1002/anie.202504608.

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Developing artificial enzymes is challenging because it requires precise design of active sites with well‐arranged amino acid residues. Histidine‐rich oligopeptides have been recently shown to exhibit peroxidase‐mimetic activities, but their catalytic function relies on maintaining unique supramolecular structures. This work demonstrates the design of a specific array of histidine residues on the internal surface of the ferritin cage to function as an active center for catalysis. The crystal structures of the ferritin mutants revealed histidine‐histidine interactions, forming well‐defined hist

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9

Noll, Niklas, and Frank Würthner. "Bioinspired Water Preorganization in Confined Space for Efficient Water Oxidation Catalysis in Metallosupramolecular Ruthenium Architectures." Accounts of Chemical Research, May 6, 2024. http://dx.doi.org/10.1021/acs.accounts.4c00148.

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10

Zhu, Ran, Zhenyang Zhao, Rui Yan, et al. "Sieve Tube‐Inspired Polysulfide Cathode with Long‐Range Ordered Channels and Localized Capture‐Catalysis Microenvironments for Efficient Li–S Batteries." Advanced Functional Materials, December 22, 2023. http://dx.doi.org/10.1002/adfm.202314593.

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AbstractAccelerating the conversion of soluble lithium polysulfides (LiPSs) to solid Li2S2/Li2S through single‐atom cathodes has emerged as a promising strategy for realizing high‐performance lithium–sulfur batteries. However, rationally optimizing the conversion effects and spatial capture abilities of LiPSs intermediates on the atomic catalytic sites is extremely required but still faces enormous challenges. Here, inspired by the delicate structure of sieve tubes in plants, Fe single‐atom cathode (channel‐FeSAC) equipped with long‐range ordered channels and localized capture‐catalysis microe

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11

Zhao, Wei, Zhouyue Lei, Baohu Wu, and peiyi Wu. "Hydrogels with Differentiated Hydrogen‐Bonding Networks for Bioinspired Stress Response." Angewandte Chemie International Edition, March 28, 2024. http://dx.doi.org/10.1002/anie.202400531.

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Stress response, an intricate and autonomously coordinated reaction in living organisms, holds a reversible, multi‐path, and multi‐state nature. However, existing stimuli‐responsive materials often exhibit single‐step and monotonous reactions due to the limited integration of structural components. Inspired by the cooperative interplay of extensor and flexor cells within Mimosa's pulvini, we present a hydrogel with differentiated hydrogen‐bonding (H‐bonding) networks designed to enable the biological stress response. Weak H‐bonding domains resemble flexor cells, confined within a hydrophobic n

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12

Xing, Fangshu, Jingwen Bai, Minghui Zhang, Yuyin Mao, and Jian Liu. "Recent Trends in Bioinspired Photocatalysis and Photoenzymatic Catalysis for CO2 Reduction to Formic Acid." ChemPhotoChem, January 23, 2025. https://doi.org/10.1002/cptc.202400351.

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The conversion of CO2 into fuels and chemical feedstocks represents a sustainable pathway to develop carbon‐neutral economy. Typically, among the accessible C1 commodities, formic acid has been a critical liquid product of CO2 reduction as an essential chemical intermediate or hydrogen storage medium. However, the activity and typical selectivity regulation of CO2‐to‐HCOOH are still far from the scale implementation requirement due to both thermodynamic and kinetic challenges. Billions of years of evolution have allowed natural CO2 reductases to achieve CO2 selective utilization by their uniqu

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13

Diao, Donglin, A. Jalila Simaan, Alexandre Martinez, and Cedric Colomban. "Bioinspired complexes confined in well-defined capsules: getting closer to metalloenzyme functionalities." Chemical Communications, 2023. http://dx.doi.org/10.1039/d2cc06990c.

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Reproducing the key features offers by metalloprotein binding cavities is an attractive approach to overcome the main bottlenecks of curent open artificial models (in terms of stability, efficiency and selectivity)....

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14

Magalhães, Flávia F., Ana F. Pereira, Mara G. Freire, and Ana P. M. Tavares. "New liquid supports in the development of integrated platforms for the reuse of oxidative enzymes and polydopamine production." Frontiers in Bioengineering and Biotechnology 10 (November 28, 2022). http://dx.doi.org/10.3389/fbioe.2022.1037322.

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Polydopamine (PDA), a bioinspired polymer from mussel adhesive proteins, has attracted impressive attention as a novel coating for (nano) materials with an adequate conformal layer and adjustable thickness. Currently, PDA is obtained from dopamine chemical oxidation under alkaline conditions, limiting its use in materials sensible to alkaline environments. Envisaging a widespread use of PDA, the polymerization of dopamine by enzymatic catalysis allows the dopamine polymerization in a large range of pHs, overcoming thus the limitations of conventional chemical oxidation. Moreover, the conventio

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15

Yu, Mingqing, Jiaqi Hu, Xinghao Li, et al. "Scalable Multifunctional Fabrics with Boosted Intrinsic Photothermal Efficiency for Salt‐Resistant Solar‐Driven Janus Evaporators." Advanced Science, May 29, 2025. https://doi.org/10.1002/advs.202504100.

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AbstractGlobal population growth and climate change are causing freshwater scarcity, which necessitates creative solutions like solar‐driven desalination. This technology's widespread adoption is hampered by cost and efficiency issues. Intrinsic photothermal conversion efficiency has gotten less attention than light trapping and thermal management, which have been the main focuses of efforts to increase photo‐to‐vapor efficiencies. Here, a commercial padding and vapor polymerization method are used to develop scalable nylon fabrics that act as solar absorbers. This is achieved by anchoring iro

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