Academic literature on the topic 'Bis(Chloromethyl) Ether'

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Journal articles on the topic "Bis(Chloromethyl) Ether"

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Liteplo, R. G., and M. E. Meek. "Chloroalkyl ethers [bis(2‐chloroethyl) Ether, Bis(chloromethyl) ether and chloromethyl methyl ether]: Evaluation of risks to health from environmental exposure in Canada." Journal of Environmental Science and Health, Part C 12, no. 2 (November 1994): 231–36. http://dx.doi.org/10.1080/10590509409373442.

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Culea, Monica, N. Palibroda, A. Hantz, I. Fenesan, and Simona Nicoara. "Determination of Bis(chloromethyl) Ether in Laboratory Air." Indoor Environment 3, no. 5 (September 1994): 299–303. http://dx.doi.org/10.1177/1420326x9400300509.

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Culea, Monica, N. Palibroda, A. Hantz, I. Fenesan, and Simona Nicoara. "Determination of Bis(chloromethyl) Ether in Laboratory Air." Indoor and Built Environment 3, no. 5 (1994): 299–303. http://dx.doi.org/10.1159/000463576.

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Langelaan, F. C. G. M., and M. W. F. Nielen. "Determination of Trace Levels of Chloromethyl-Methylether and Bis(Chloromethyl)ether in Air." International Journal of Environmental Analytical Chemistry 36, no. 1 (May 1989): 27–34. http://dx.doi.org/10.1080/03067318908026855.

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Pert, DJ, and DD Ridley. "An Alternative Route to 2-Bromo-Estradiols and 2-Iodo-Estradiols From Estradiol." Australian Journal of Chemistry 40, no. 2 (1987): 303. http://dx.doi.org/10.1071/ch9870303.

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Through careful choice of reaction conditions, alkylation of estradiol with chloromethyl methyl ether may yield either the 3,17β-bis(methoxymethy1) ether or the 3-methoxymethyl ether derivative. Treatment of either of these protected estradiols with s- butyllithium, then with trimethylsilyl chloride affords, regioselectively, the 2-trimethylsilyl derivatives which can conveniently be converted into 2-bromo-or 2-iodo-estradiol.
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Luong, J., R. Gras, and R. A. Shellie. "Differential ion mobility spectrometry with temperature programmable micromachined gas chromatography for the determination of bis(chloromethyl)ether." Analytical Methods 9, no. 34 (2017): 5003–8. http://dx.doi.org/10.1039/c7ay00653e.

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A parts-per-million level screening technique for bis(chloromethyl)ether using micromachined differential ion mobility spectrometry combined with portable temperature programmable low thermal mass silicon micromachined gas chromatography is described.
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Liška, František, Jiří Fikar, and Petr Kuzmič. "Radical Reduction of C-Cl Bonds in Chlorofluoro Ethers." Collection of Czechoslovak Chemical Communications 58, no. 3 (1993): 565–74. http://dx.doi.org/10.1135/cccc19930565.

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Reduction of C-Cl bonds in 2,2-dichloro-1,1,2-trifluoroethyl trichloromethyl ether (I), 2-chloro-1,1,2-trifluoroethyl trichloromethyl ether (II), and 2,2-dichloro-1,1,2-trifluoroethyl dichloromethyl ether (III) with 2-propanol, 2-butanol, cyclohexanol, tetrahydrofurane, diethyl ether, and 1,3-dioxolane initiated photochemically and by radiation has been investigated. Beside the main reduction products - 2-chloro-1,1,2-difluoroethyl trichloromethyl ether (IV) and 2-chloro-1,1,2-difluoroethyl chloromethyl ether (V) - it was also possible to prove the formation of 1,2-dichloro-1,2-bis(2-chloro-1,1,2-trifluoroethoxy)ethane (VI), 1-chloro-1,2-bis(2-chloro-1,1,2-trifluoroethoxy)ethane (VII), and 1,2-dichloro-1,2-bis(2-chloro-1,1,2-trifluoroethoxy)ethene (VIII). The structure of products was confirmed by elemental analysis, MS, IR, 1H NMR and 19F NMR spectra and by GLC comparison of the elution times with those of standards. The relative reduction ability of the solvents used in the reduction rate order of C-Cl bonds in the compounds (CCl3 > CFCl2 > CHCl2 and CFClH) are given.
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Van Duuren, Benjamin L. "Comparison of potency of human carcinogens: Vinyl chloride, chloromethylmethyl ether and bis(chloromethyl)ether." Environmental Research 49, no. 2 (August 1989): 143–51. http://dx.doi.org/10.1016/s0013-9351(89)80059-3.

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Bock, Charles W., William H. Brendley, Herman Hamann, and Krishna L. Bhat. "Formation of bis (chloromethyl) ether in the vapor phase: a computational investigation." Journal of Molecular Structure: THEOCHEM 619, no. 1-3 (December 2002): 207–28. http://dx.doi.org/10.1016/s0166-1280(02)00577-8.

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Kantlehner, Willi, Ernst Anders, Jochen Mezger, Edmont V. Stoyanov, Ralf Kreß, Kurt Wermann, Wolfgang Frey, and Helmar Görls. "Orthoamide, LXVII [1]. Bis(diformylamino)methan – ein neues leistungsfähiges Formylierungsmittel für aromatische Verbindungen / Orthoamides, LXVII [1]. Bis(diformylamino)methane – a New Efficient Formylating Reagent for Aromatic Compounds." Zeitschrift für Naturforschung B 63, no. 4 (April 1, 2008): 395–406. http://dx.doi.org/10.1515/znb-2008-0406.

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AbstractFormaldehyde reacts with diformamide (10) to give N-(hydroxymethyl)diformamide (11), which upon treatment with thionylchloride yields N-(chlormethyl)diformamide (12) together with small amounts of oxydimethylenebis(diformamide) (13). Various diformylamine derivatives, such as diformylaminomethyl formiate (14), diformylaminomethylisothiocyanate (15) and the N-diformylaminomethylated guanidinium salt 16, can be prepared from 12. Bis(diformylamino) methane (7) can be obtained by the reaction of sodium diformamide (8) with either 1-(chloromethyl)pyridinium chloride (9) or N-(chloromethyl)diformamide (12) in acetonitrile. The action of tris(chloromethyl) amine (18) on sodium diformamide (8) affords tris(diformylaminomethyl)amine (19). The constitution of the compounds 7, 11 and 19 was confirmed by crystal structure determination. The nature of the products from the reactions of aromatic compounds with 12 depends on the Lewis acid which is used as activator. Thus the N-benzylformamides 20a, b can be obtained from toluene and mesitylene and 12/BF3-ether, whereas 1,2,4-trimethoxybenzene is formylated by 12/AlCl3 to give the aldehyde 22. Interestingly enough, a novel and efficient formylating reagent resulted from these investigations: bis(diformylamino)methane (7), which can be activated by Lewis acids, e. g. AlCl3. The scope of this procedure is comparable with that of the Olah-formylation method (formylfluoride/BF3).
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Books on the topic "Bis(Chloromethyl) Ether"

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Delic, J. Bis(chloromethyl)ether. London: H.M.S.O., 1990.

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Bis(chloromethyl) ether and chloromethyl methylk ether. [Ottawa, Canada]: Govt. of Canada, 1993.

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Canada. Health and Welfare Canada. and Canada Environment Canada, eds. Bis(chloromethyl) ether and chloromethyl methyl ether. Ottawa: Environment Canada, 1993.

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Delic, J. I., and S. Fairhurst. Bis(chloromethyl)ether (TR) (Toxicity Review). Health and Safety Executive (HSE), 1990.

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Selected chloroalkyl ethers. Geneva: World Health Organization, 1998.

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Selected Chloroalkyl Ethers (Environmental Health Criteria). World Health Organization, 1998.

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Book chapters on the topic "Bis(Chloromethyl) Ether"

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Vaman Rao, C. "Chloromethyl Ether, Bis-." In Encyclopedia of Toxicology, 565–67. Elsevier, 2005. http://dx.doi.org/10.1016/b0-12-369400-0/00220-9.

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Rao, C. V. "Chloromethyl Ether, Bis-." In Encyclopedia of Toxicology, 894–95. Elsevier, 2014. http://dx.doi.org/10.1016/b978-0-12-386454-3.00280-3.

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"BIS(Chloromethyl) Ether." In Toxicology Desk Reference, edited by Robert P. Ryan, Claude E. Terry, and Sanford S. Leffingwell, 1323–25. Routledge, 2019. http://dx.doi.org/10.1201/9780203735398-170.

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"Bis(Chloromethyl) Ether." In Toxicology Desk Reference, edited by Robert P. Ryan, Claude E. Terry, and Sanford S. Leffingwell, 191–96. Routledge, 2019. http://dx.doi.org/10.1201/9780203735398-26.

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Pfeiffer, W. D. "Chloromethylation with Chloromethyl Methyl Ether or Bis(chloromethyl) Ether." In Chlorine, Bromine, and Iodine, 1. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-035-00169.

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Lodge, James P. "Determination of Chloromethyl Methyl Ether (CMME) and Bis-Chloromethyl Ether (Bis-CME) in Air." In Methods of Air Sampling and Analysis, 658–61. Routledge, 2017. http://dx.doi.org/10.1201/9780203747407-130.

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"Bis(chloromethyl)ether (BGI 505-6E)." In Analyses of Hazardous Substances in Air, 27–38. Weinheim, FRG: Wiley-VCH Verlag GmbH, 2003. http://dx.doi.org/10.1002/3527600191.ch3.

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"Toxicological Profile for Bis(Chloromethyl)Ether." In ATSDR's Toxicological Profiles. CRC Press, 2002. http://dx.doi.org/10.1201/9781420061888_ch43.

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Lodge, James P. "Determination of Bis-(Chloromethyl) Ether (Bis-CME) in Air." In Methods of Air Sampling and Analysis, 654–57. Routledge, 2017. http://dx.doi.org/10.1201/9780203747407-129.

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Olah, George A., David A. Beal, and Judith A. Olah. "Aromatic Substitution. XXXVIII: Chloromethylation of Benzene and Alkylbenzenes with Bis(chloromethyl) Ether, 1,4-Bis(chloromethoxy)butane, 1-Chloro-4-chloromethoxybutane, and Formaldehyde Derivatives." In World Scientific Series in 20th Century Chemistry, 73–77. World Scientific Publishing Company, 2003. http://dx.doi.org/10.1142/9789812791405_0019.

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