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Dissertations / Theses on the topic 'Bromine Acid'

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1

Haine, H. D. "Mechanistic studies of electrophilic reactions involving nitrous acid and bromine." Thesis, Swansea University, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.637196.

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A fair amount of research has been carried out on the reactions of nitrous acid with aryl hydrazines, with marked differences in mechanism between the reaction of nitrous acid with 2,4-dinitrophenylhydrazine, and the reaction of nitrous acid with alkyl and halogen substituted aryl hydrazines. It was hoped that study of the electrophilic nitrosation of 2-nitrophenylhydrazine would serve as a link between the two sets of results. A large range of electrophilic nitrosating agents are known, and the spectra of two of these; dinitrogen trioxide (N<SUB>2</SUB>O<SUB>3</SUB>) and nitrosyl thiocyanate
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2

Cader, Mohamed Shah Roshan. "The intercalation of bromine- and iodine fluorosulfate derivatives in solutions of fluorosulfuric acid." Thesis, University of British Columbia, 1986. http://hdl.handle.net/2429/25853.

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The oxidative intercalation of halogen fluorosulfate derivatives such as I(SO₃F) ₃, Br(SO₃F)₃, BrSO₃F, K[I(SO₃F)₄] and K[Br(SO₃F)₄] from solutions in fluorosulfuric acid into graphite (SP-1 and to a lesser extent HOPG) is studied. In addition, the intercalation of solvated cations of the type I₂₊ and NO⁺ is included in this research as well. The results, supported by microanalysis, X-ray powder diffraction data, Raman frequency shifts, Solid state -¹⁹F-NMR spectroscopy and UV-visible optical spectra of the supernatant solutions support three different courses of the intercalation reactions:
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3

Dowdell, David Christian. "An investigation of the thermophysical properties of hydrofluoroalkanes, and the contribution of halocarbons to the chlorine/bromine loading of the atmosphere." Thesis, University of Plymouth, 1993. http://hdl.handle.net/10026.1/1756.

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A capillary flow gas viscometer has been used to measure the shear viscosities of the hydrofluoroalkanes HFC 134a, HCFC 123, HCFC 124 and the ternary blend MP 39, at pressures up to 0.1 MPa relative to a nitrogen standard. Having applied small correction factors to the measured flow time data, the resultant viscosities are compared to those obtained by other workers (where possible) using alternative techniques. We calculate self diffusion coefficients and hard sphere collision diameters for the molecules within the rigorous Chapman-Enskog kinetic theory of gases, and calculate optimum well de
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4

Al-Subai, Saud Ghunaim A. "Corrosion resistance of austenitic stainless steel in acetic acid solution containing bromide ions." Thesis, University of Manchester, 2011. https://www.research.manchester.ac.uk/portal/en/theses/corrosion-resistance-of-austenitic-stainless-steel-in-acetic-acid-solution-containing-bromide-ions(f14e147e-76ac-4162-a934-ffe7e3a00106).html.

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In this research, the corrosion performance of two austenitic stainless steels, namely 316L and 254SMO, in concentrated acetic acid solutions containing bromide ions has been investigated. In this research, the influence of two different electrochemical surface treatments (electropolishing and nitric acid passivation) on the corrosion behaviour of 316L stainless steel immersed in 15.3M HAc with 18.7mM bromide ions at 900°C was examined. Also, attemptswere made to study the performance of three organic inhibitors in the same conditions. Corrosion rates are assessed both by weight loss, and line
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5

Coupe, Paul J. "Mechanistic investigations of the S-nitrosothiol, peroxynitrous acid and thiol system." Thesis, Durham University, 2001. http://etheses.dur.ac.uk/4211/.

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S-Nitrosothiols have been found to undergo nucleophilic attack by the hydroperoxide anion to effect electrophilic nitrosation of the nucleophile. Peroxynitrite anion is formed in almost quantitative yields and the kinetics of the reaction examined, confirming attack through the deprotonated form of hydrogen peroxide. Conversely, under slightly acidic conditions peroxynitrous acid, the neutral form of peroxynitrite, has been shown to nitrosate an excess of thiol in an indirect pathway. Initially two moles of thiol are oxidised to the corresponding disulfide with the concomitant production of ni
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6

Venerová, Tereza. "Interakce hyaluronanu a amfifilních molekul." Doctoral thesis, Vysoké učení technické v Brně. Fakulta chemická, 2013. http://www.nusl.cz/ntk/nusl-233374.

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This work is focused on interaction between hyaluronan (Hya) and amphiphilic molecules. Using fluorescent probes method were carried out screening of the interaction of various surfactants with Hya. For further examination was chosen cetyltrimethylammonium bromide (CTAB). Interactions in this system have also been studied using fluorescence correlation spectroscopy (FCS), and additionally were performed initial tests of the cytotoxicity of the system. As an alternative CTAB were also used hydrophobically modified amino acids. Results showed their self-aggregation, but their interactions with h
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7

Hayta, Mehmet. "Thermal transitions in wheat gluten." Thesis, University of Reading, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299298.

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8

Ngono, Bernadette. "Organométalliques à carbonyle masqué : quelques propriétés du lithio-1 triméthylsiloxy-2 éthylène." Rouen, 1989. http://www.theses.fr/1989ROUES021.

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La condensation du lithio-1 triméthylsiloxy-2 éthylène avec les chlorotrialkylsilanes et le triflate de t-butyldiméthylsilyle conduit aux éthers d'énols silyles -silyles. L'hydrolyse acide de ces derniers permet d'isoler le t-butyldiméthylsilyl acétaldéhyde. D'autre part, la condensation du lithio-1 triméthylsiloxy-2 éthylène avec les chlorures d'acides non énolisables conduit a des esters d'énols de -cétoaldéhydes
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9

Huang, Jin. "An evaluation of NOM precursors and bromide ion in the formation of haloacetic acids (HAAs) in water treatment." Thesis, Imperial College London, 2010. http://hdl.handle.net/10044/1/5601.

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Haloacetic acids (HAAs) are a group of disinfection by-products (DBPs) found in drinking water which are regulated in the USA but not yet in the EU. Epidemiology tests have shown that they may have carcinogenic and mutagenic effects on human beings. HAAs are produced during the disinfection process from the use of chlorination and they may persist during water distribution and finally reach the customers’ tap at concentrations of concern. The formation of HAAs arises from the reaction between precursor material – principally natural organic matter (NOM) – and chlorine, and the species and amou
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10

Vignaud, Caroline. "Etude de systèmes d'oxydoréduction susceptibles de contribuer à la consommation de composés thiols au cours du pétrissage des pâtes de farine de blé." Paris 11, 2002. http://www.theses.fr/2002PA112238.

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Au cours du pétrissage, la consommation des thiols de bas poids moléculaire (BPM) affecte la structure du réseau de gluten, en raison de la participation de ces composés aux réactions d'échanges SH / SS avec les protéines. En panification, récemment, des enzymes fongiques ont été proposées comme alternative plus naturelle à l'emploi des améliorants chimiques (KBrO3, acide ascorbique) pour oxyder ces composés thiols BPM. Dans ce cadre, la sulfhydryle oxydase d'Aspergillus niger a été étudiée et son action a été comparée à celle du KBrO3 et de la glutathion (GSH) déshydrogénase de blé (GSH-DHase
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11

Croué, Jean-Philippe. "Contribution a l'etude de l'oxydation par le chlore et l'ozone d'acides fulviques naturels extraits d'eaux de surface." Poitiers, 1987. http://www.theses.fr/1987POIT2289.

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12

Velasquez, Alejandro Vargas. "Comparação dos métodos lignina detergente ácido (LDA), lignina permanganato de potássio (LPer), lignina Klason (LK) e lignina brometo de acetila (LBA) na determinação do teor de lignina em plantas forrageiras e correlação com digestibilidade in vitro da matéria seca (DIVMS)." Universidade de São Paulo, 2013. http://www.teses.usp.br/teses/disponiveis/10/10135/tde-10092014-113254/.

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O desempenho animal pode ser melhorado pelo incremento na digestibilidade dos alimentos. Um dos elementos neste processo é a acurada caracterização da composição química. Objetivando avaliar quatro métodos para determinar o teor de lignina, foram estudadas cinco gramíneas: Brachiaria brizantha cv. Marandú, Brachiaria brizantha cv. Xaraés (MG-5), Panicum maximum cv. Mombaça, Pennisetum purpureum cv. Cameroon e Pennisetum purpureum cv. Napier. As frações fibrosas da parede celular (PC), fibra em detergente neutro (FDN) e fibra em detergente ácido (FDA) aumentaram conforme as plantas amadureceram
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13

Saffré, Dimitri. "Radiolyse de l’eau dans des conditions extrêmes de température et de TEL. Capture de HO• par les ions Br-." Thesis, Paris 11, 2011. http://www.theses.fr/2011PA112246/document.

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L’objectif de cette thèse est de contribuer à la compréhension du mécanisme d’oxydation de Br- dans lequel le radical HO• intervient. Le rendement du radical HO• étant alors intimement lié au rendement d’oxydation de Br-, c’est sur lui que l'influence de différents paramètres physicochimiques a été étudiée : température, TEL, débit de dose, pH, nature du gaz saturant. Les solutions ont été irradiées avec 4 types de rayonnement : rayons X de 13 à 18 keV, électrons de 7 et 10 MeV, faisceaux d’ions C6+ de 975 MeV et He2+ de 70 MeV. Le développement d’un autoclave optique avec circulation de solut
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14

Chen, Xiaocheng. "Synthesis of 10-Carboxy-N-Decyol-N, N’- Dimethyldecyl-1-Ammonium Bromide as Organogelator & Room temperature Shape Memory Programming of Stearic Acid/ Natural Rubber Bilayer Blend." University of Akron / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=akron1500563824207268.

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15

Huang, Zishuai. "Studies Using Vibrational Sum Frequency Generation Spectroscopy:I. Salty Glycerol versus Salty Water Surface Organization: Bromide and Iodide Surface PropensitiesII. Influence of Salt Purity on Na+ and Palmitic Acid Interactions." The Ohio State University, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=osu1373899240.

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16

Santamaria, Marcos Felipe Zuñiga. "Otimização do método lignina brometo de acetila na determinação do teor de lignina em plantas forrageiras e comparação com os métodos lignina detergente ácido e lignina Klason." Universidade de São Paulo, 2016. http://www.teses.usp.br/teses/disponiveis/10/10135/tde-09052016-112358/.

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Técnicas analíticas empregadas para a quantificação do teor de lignina em plantas forrageiras, atualmente em uso, são questionáveis quanto às suas acurácias. O método lignina detergente ácido (LDA), que é um dos métodos mais utilizado em Ciência Animal e Agronomia, apresenta algumas falhas, particularmente devido à parcial solubilização da lignina durante a preparação da fibra em detergente ácido (FDA). A lignina Klason (LK), outro método muito usado, apresenta o inconveniente de mensurar a proteína da parede celular como sendo lignina. Em ambos os procedimentos recomenda-se também mensurar ci
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17

Newton, Elizabeth Lynn. "Sustainable Reaction and Separation Systems." Thesis, Georgia Institute of Technology, 2005. http://hdl.handle.net/1853/7463.

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With increasing environmental awareness and natural resource limitations, researchers must begin to incorporate sustainability into their process and product designs. One target for green engineering is in reaction and separation design. This is typically done in a wasteful and often toxic manner with organic solvents and lack of recycle. The following thesis discusses alternatives to these costly separations by means of ionic liquids, benign extraction, separation with carbon dioxide, and near critical water. Ionic liquids are combined with carbon dioxide to induce melting point depressio
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18

Repová, Romana. "Studium interakce záporně nabitých vezikulárních systémů s polykationty." Master's thesis, Vysoké učení technické v Brně. Fakulta chemická, 2020. http://www.nusl.cz/ntk/nusl-414178.

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This diploma thesis deals with the preparation and characterization of negatively charged catanionic vesicular systems and their combination with selected polycations. The catanionic vesicular system was prepared by mixing of two oppositely charged surfactants SDS and CTAB. The negative charge as well as the stability of the vesicular system was provided by the incorporation of phosphatidic acid. Polycations, DEAE and TMC, have been selected for use in a pharmaceutical applications. Characterization of the prepared systems was performed by measuring DLS and ELS. The results indicate that we we
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19

Boone, Edna Karen. "Radical cation propagation through bulged and mis-paired DNA : "A purine:purine staggered walk" (Part I). Part II, bulged DNA cleavage via a "Classic intercalator": a surprising role for siglet-excited ethidium bromide in the selective cleavage of a G-bulge containing duplex. Part III, synthesis and photochemical behavior of peptide nucleic acid trimers containning [sic] benzamidonaphthalimide." Diss., Georgia Institute of Technology, 2001. http://hdl.handle.net/1853/30733.

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20

Grison, Claude. "Généralisation de la réaction d'alpha halogénation-carbonyloléfination et nouvelles applications en synthèse des acides dialkylphosphono-2-alcanoiques et des acides voisins apparentés alpha brome, alpha chlore et alpha fluore." Nancy 1, 1987. http://www.theses.fr/1987NAN10340.

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La réaction d'α -halogénation-carbonyloléfination a été étendue à la préparation de vinylséléniures α -chlorés et généralisée à l'α -bromation -carbonyloléfination. Les dianions des acides dialkylphosphonofluoracétiques réagissent avec les dérivés carbonylés par réaction de wittig-horner et conduisent stéréosélectivement aux acides α, β -éthyléniques α -fluorés. La réaction est généralisable aux dérivés chrysanthémiques. Ces acides permettent également un accès très efficace aux β -cétophosphonates α -fluorés et cétones α, β -éthyléniques α -fluorées. La réaction d'organocuprates sur les chlor
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21

Mulay, Prajakatta. "Synthesis of Folate-Targeted Poly(Ethylene Glycol)-Based Conjugates And Their Precursors." University of Akron / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=akron1574442562023675.

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22

Favard, Cyril. "Microspectrofluorimétrie in situ : développement, mise au point et études intracellulaires d'interactions moléculaires." Paris 6, 1996. http://www.theses.fr/1996PA066550.

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Dans le domaine des spectroscopies optiques et magnétiques, différents dispositifs ont été développés afin d'obtenir un signal provenant de cellules vivantes isolées. Le microspectrofluorimètre laser confocal construit par la société DILOR S. A. , mis au point et développé conjointement avec le laboratoire est un de ces dispositifs. Ses caractéristiques permettent d'obtenir des images spectrales bidimensionnelles. Ce microspectrofluorimètre a été utilisé dans deux types d'études. L'une concerne la pénétration et la localisation du bromure d'éthidium (BET), un intercalant des acides nucléiques,
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23

Saffré, Dimitri. "Radiolyse de l'eau dans des conditions extrêmes de température et de TEL. Capture de HO* par les ions Br-." Phd thesis, Université Paris Sud - Paris XI, 2011. http://tel.archives-ouvertes.fr/tel-00904672.

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L'objectif de cette thèse est de contribuer à la compréhension du mécanisme d'oxydation de Br- dans lequel le radical HO* intervient. Le rendement du radical HO* étant alors intimement lié au rendement d'oxydation de Br-, c'est sur lui que l'influence de différents paramètres physicochimiques a été étudiée : température, TEL, débit de dose, pH, nature du gaz saturant. Les solutions ont été irradiées avec 4 types de rayonnement : rayons X de 13 à 18 keV, électrons de 7 et 10 MeV, faisceaux d'ions C6+ de 975 MeV et He2+ de 70 MeV. Le développement d'un autoclave optique avec circulation de solut
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24

Denys, Goument Colombe. "Dicétones-1,4 thiosubstituées." Rouen, 1988. http://www.theses.fr/1988ROUES023.

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25

Wen-Chieh, Wang, and 王文傑. "(I) The Synthesis and Acid-catalyzed De-bromine-coupling Reactions of 2-Aryl-3-bromocycloheptenes (II) A Novel Synthesis of Calixfurans and Calixthiophenes (III) Reactions of Tricyclic Cyclopropanes with Diiron Nonacarbonyl." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/69406205000060149497.

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博士<br>輔仁大學<br>化學系<br>98<br>(I)1-Arylcycloheptenes (26、29-32) were reacted with bromine at 0 oC followed by acid-catalyzed de-bromine coupling to yield 1,2-diaryltri- cyclo[8.3.1.03,9]tetradec-3(9)-enes (28、34-37). When 1-(o-tolyl)cyclo- heptene (23) was treated with bromine, 3-bromo-2-(o-tolyl)cycloheptene (24) was generated. Compound 24 underwent isomerization to form isomer 25 under acidic condition. When compound 33 was examined under identical conditions, isomerization adduct 38 was generated. 2-Cycloheptenylpyridine (41) was treated with bromine to afford dibromide 42, which was furth
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26

Chang, Tso-Sheng, and 張佐聖. "A multi-technique investigation on dispersion behaviors of dihexadecyldimethylammonium bromide/ascorbic acid derivative mixtures." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/b93kt4.

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碩士<br>國立雲林科技大學<br>化學工程與材料工程系<br>106<br>In this study, a multi-technique investigation on dispersion properties of cationic dihexadecyldimethylammonium bromide (DHDAB), and anionic sodium palmitate (SP), and compound B (B) mixtures.
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27

KO, NING-YIN, and 柯甯尹. "Development of catanionic vesicles composed of dialkyldimethylammonium bromides (DXDAB) and stearic acid (SA) as carriers for curcumin." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/yjfcj6.

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28

Harper, Brett. "Mitigation of Disinfection By-Product Formation through Development of a Multiple Regression Equation and a Bayesian Network." Thesis, 2012. http://hdl.handle.net/10214/3655.

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Issues of Disinfection By-Product (DBP) formation in response to chlorination in drinking water treatment systems is a common issue encountered by WTP operators. Efforts to minimize DBP formation are complicated by the presence of zebra mussels, which may inhabit the raw water intake of WTPs. While chlorination at the intake to control zebra mussel populations is effective, the formation of DBPs is exacerbated. Methods for reducing DBPs are explored, including adjusting the location for chlorine additions in the treatment sequence. Multivariate models for Total Trihalomethane (TTHM) and Haloa
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29

Hsiao, Ching-Hua, and 蕭靖樺. "Physicochemical characteristics of mixed kojic acid derivative/dialkyldimethylammonium bromides (DXDAB) dispersions and their behaviors at the air/water interface." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/b96e6d.

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碩士<br>嘉南藥理科技大學<br>化妝品科技研究所<br>100<br>We choose cationic lipid, dialkyldimethylammonium bromides (DXDAB) with differing in dialkyl chain length-dimyristyldimethylammonium bromide (DMDAB), dihexadecyldimethylammonium bromide (DHDAB), and dioctadecyldimethylammonium bromide (DODAB) to improve stability of compound A dispersions. The physical stability, particles morphology and bilayer fluidity of mixed A/DXDAB dispersions were investigated by size distribution, zeta-potential, transmission electron microscope (TEM), fluorescence polarization and differential scanning calormetry (DSC) analysis, re
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30

Tsai, Reay-Fun, and 蔡瑞芳. "Kinetic study of the reaction to the Ce(III),Mn(II),Ferriin- catalyzed Bromate-2-ketoglutaric Acid Oscillating Reaction." Thesis, 1996. http://ndltd.ncl.edu.tw/handle/17732684418279400981.

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碩士<br>國立成功大學<br>化學系<br>84<br>Abstract The Ce(III),Mn(II) or Fe( phen)3+3 -catalyzed redox reaction ofbromate ion with 2-ketoglutaric Acid (KGA) in 1M aqueous sulfuric acid exhibits oscillating behavior in the concentration of bromide ions.The induction period approaches zero and its oscillating behavior seems like the Belousov-Zhabotinsky(BZ) oscillating reaction with Pyruvic Acid (PyA). The kinetics of the Ce(IV),Mn(III), or Fe(phen)3+3 ion oxidation of 2-ketoglutaric Acid was studie
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31

Chen, Ying-Fen, and 陳瑩芬. "Kinetic Study of the Reactions Related to the Ce(Ⅲ)- Mn(Ⅱ)- or ferroin-Catalyzed Bromate- Butylmalonic Acid Oscillating Reaction." Thesis, 1993. http://ndltd.ncl.edu.tw/handle/72213922904488799990.

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32

Hsu, Chung-Wei, and 徐君偉. "Liquid-Solid Reaction Catalyzed by the Liquid Containing Rich Phase Transfer Catalyst-Synthesis of Acetic Acid Hexyl Ester from n-Hexyl Bromide and Sodium Acetate." Thesis, 2004. http://ndltd.ncl.edu.tw/handle/78f47h.

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碩士<br>國立成功大學<br>化學工程學系碩博士班<br>92<br>This research is a novel alternate phase transfer catalysis method , that is a catalyst-rich-phase adds to the solid sodium acetate and organic reactant (hexyl bromide) which forms solid-liquid phase transfer catalysis become to solid-liquid-liquid phase transfer catalysis. Use this system to catalyze hexyl bromide and sodium acetate to hexyl acetate. This method can improve the catalyst retrieved difficult in liquid-liquid, solid-liquid phase transfer catalysis and carboxyl ion reactive reduce by hydration effect in liquid-liquid phase transfer catalysis. T
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33

Ko, Chung-Han, and 柯中涵. "Evaluations of the Permeation of Protective Gloves for Sequential Exposures to Thioglycolic Acid and Sodium Bromate, and Exposure to 1-Bromopropane." Thesis, 2014. http://ndltd.ncl.edu.tw/handle/kgqj25.

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碩士<br>輔仁大學<br>公共衛生學系碩士班<br>102<br>Background: Hairdressers often have occupational dermatitis on hands due to contact with chemical agents. The highest rate of use in variety of chemicals is perming agents. The frequency, time, and type of glove wearing behavior on hairdressers are inconsistent and may cause that skin is exposed to irritants and allergens. Metal cleaning technology is an important part of industry. Workers in those indistries might contact with large amounts and are exposed to high level concentrations of metal cleaning agents, but they usually don’t wear protective gloves or
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34

Yu, Yueh-o., and 余月娥. "The Ce(III)、Mn(II) or Fe(II) ion as catalyzed redox reaction of bromate ion with allylmalonic acid and kinetics studied." Thesis, 1997. http://ndltd.ncl.edu.tw/handle/07783992704275887984.

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35

Genest, Nicolas. "Synthèse et analyse conformationelle de dipeptides contenant l’isostère hydroxyéthylène." Thèse, 2010. http://hdl.handle.net/1866/4664.

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Dans ce mémoire, je présente mes études sur une stratégie efficace développée pour la synthèse de cétones homoallyliques substituées à partir de l’addition en cascade de réactifs de Grignard vinyliques substitués sur des α-amino esters catalysée par des sels de cuivre. L’utilisation de ces cétones homoallyliques a permis d’obtenir des mimes peptidiques comprenant un isostère de type hydroxyéthylène du lien amide. L’étape clé de cette stratégie repose sur la synthèse de cétones homoallyliques substituées intermédiaires à partir de la réaction d’additions en cascade catalysée au cuivre, de bromu
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36

Lian, Ruei-Jeng, and 連瑞政. "1. The study in copper-catalyzed cross-coupling of aryl chlorides and bromides with aqueous ammonia using salicyclic acid as a ligand 2. The study in the synthesis of desmethylated arzoxifene (DMA)." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/02227693330695064464.

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碩士<br>國立中興大學<br>化學系所<br>98<br>We successfully use copper(I) oxide to catalyze cross-coupling of aryl chlorides and bromides with aqueous ammonia using salicyclic acid as a ligand. This system takes place without organic solvent which conformed to the demand of green chemistry. Desmethylated arzoxifene(DMA) has the capability to treat breast cancer. We tried to use copper-catalyzed cross-coupling reactions of C-C and C-O bonds to accomplish the total synthesis of Desmethylated arzoxifene which is different from the traditional synthesis method of Desmethylated arzoxifene. We hope to shorten the
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