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Journal articles on the topic 'Bromobutyl'

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1

Khakimullin, Yuri N., Larisa Yuryevna Zakirova, and Alfred D. Khusainov. "Determination of the Composition of Substances Migrating from Plugs Based on Bromo-Butyl Rubber into Infusion and Injection Preparations." Key Engineering Materials 869 (October 2020): 135–39. http://dx.doi.org/10.4028/www.scientific.net/kem.869.135.

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The results of experimental studies of the composition of individual substances migrating from medical rubber plugs produced both in and abroad based on technical bromobutyl rubber are presented. The quantitative content of volatile organic compounds related to species impurities of gasoline was determined by gas chromatography from a standard glass bottle sealed with a sterile stopper based on bromobutyl rubber. The method of atomic emission spectroscopy was used to determine (indirect) the presence of organometallic, organosulfur and metal-inorganic compounds that did not pass through chroma
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2

Wang, Qing-Peng, Juan-Juan Chang, Hui-Zhen Zhang, Jing-Song Lv, and Cheng-He Zhou. "9-(4-Bromobutyl)-9H-carbazole." Acta Crystallographica Section E Structure Reports Online 68, no. 4 (2012): o1112. http://dx.doi.org/10.1107/s1600536812010987.

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In the title compound, C16H16BrN, the bromobutyl group lies on one side of the carbazole ring plane and has a zigzag shape. The dihedral angle between the two benzene rings is 0.55°. In the crystal, molecules are connected by van der Waals interactions.
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3

Moreno-Fuquen, Rodolfo, Carlos Grande, Rigoberto C. Advincula, Juan C. Tenorio, and Javier Ellena. "9-(4-Bromobutyl)-9H-carbazole." Acta Crystallographica Section E Structure Reports Online 68, no. 6 (2012): o1853. http://dx.doi.org/10.1107/s1600536812022398.

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In the title compound, C16H16BrN, the tricyclic carbazole system is essentially planar (r.m.s. deviation of all non-H atoms = 0.010 Å). The dihedral angle between the two outer carbazole rings is 1.1 (3)°. There are no directional intermolecular contacts in the crystal packing.
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4

Galuska, A. A. "Surface chemistry of bromobutyl binary blends." Surface and Interface Analysis 27, no. 10 (1999): 889–96. http://dx.doi.org/10.1002/(sici)1096-9918(199910)27:10<889::aid-sia645>3.0.co;2-g.

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5

Chu, Chia Yeh, Kenneth Norman Watson, and Rastko Vukov. "Determination of the Structure of Chlorobutyl and Bromobutyl Rubber by NMR Spectroscopy." Rubber Chemistry and Technology 60, no. 4 (1987): 636–46. http://dx.doi.org/10.5254/1.3536147.

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Abstract An analysis of the 1H and 13C NMR spectra of the chlorobutyl and bromobutyl rubbers was performed. Peaks were assigned based on evidence from broad-band decoupled, off-resonance decoupled, selectively decoupled and J-modulated spectra, the known characterization of butyl rubber and halogenation studies on model compounds. The assignment of the minor peaks indicated that the exomethylene-type structure is predominant in both halogenated rubbers. They also contain some nonhalogenated isoprenyl units. Bromobutyl rubber also contains some α-bromomethyl-type structures resulting from rearr
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6

Liu, Yunkui, and Yongmin Zhang. "Tetrahydrofuran Ring Opening with Acyloxyphosphonium Bromide Catalysed by Allylsamarium Bromide: A Novel and Effective Method for the Preparation of 4-Bromobutyl Esters." Journal of Chemical Research 2002, no. 1 (2002): 15–16. http://dx.doi.org/10.3184/030823402103170493.

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A tetrahydrofuran ring can be opened with acyloxyphosphonium bromide generated in situ catalysed by allylsamarium bromide to afford 4-bromobutyl esters under mild conditions in good to excellent yields.
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7

Davis, Benjamin G., Steven D. Wood, and Michael AT Maughan. "Towards an unprotected self-activating glycosyl donor system: Bromobutyl glycosides." Canadian Journal of Chemistry 80, no. 6 (2002): 555–58. http://dx.doi.org/10.1139/v02-029.

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Bromobutyl mannopyranosides have been successfully used as both protected and unprotected glycosyl donors both with and without the use of an external activator.Key words: glycosylation, unprotected glycosyl donors, oligosaccharides.
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8

Xie, Pei, Kai Wang, Peijian Wang, Yang Xia, and Guangsheng Luo. "Synthesizing bromobutyl rubber by a microreactor system." AIChE Journal 63, no. 3 (2016): 1002–9. http://dx.doi.org/10.1002/aic.15431.

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9

Stein, Sebastian, Anton Mordvinkin, Brigitte Voit, Hartmut Komber, Kay Saalwächter, and Frank Böhme. "Self-healing and reprocessable bromo butylrubber based on combined ionic cluster formation and hydrogen bonding." Polymer Chemistry 11, no. 6 (2020): 1188–97. http://dx.doi.org/10.1039/c9py01630a.

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The properties of modified bromobutyl rubber are strongly influenced by competing interactions via hydrogen bridges and ionic cluster formation. Dynamic network formation enables self-healing and reprocessability of the material.
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10

Puskas, Judit E., and Gabor Kaszas. "Blends of Butyl and Bromobutyl Rubbers and Polystyrene—Polyisobutylene—Polystyrene (PS—PIB—PS) Block Copolymers with Improved Processability and Physical Properties." Rubber Chemistry and Technology 74, no. 4 (2001): 583–600. http://dx.doi.org/10.5254/1.3544959.

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Abstract An investigation of the effects of polystyrene—polyisobutylene linear triblock and three-arm star block thermoplastic elastomers on the processability and properties of butyl and bromobutyl rubbers was undertaken. All properties improved, with the exception of bromobutyl adhesion, which remained acceptable. The green strength of raw polymer blends improved by 30–80% and 5–20% improvement was seen on the carbon black compounds. Die swell was reduced by as much as 60% for compounds containing a triarm-star block. Tear strength doubled and air permeability decreased (by about) 20–40%. Fa
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11

Sarlin, Essi, Ari Rosling, Mari Honkanen, et al. "EFFECT OF ENVIRONMENT ON BROMOBUTYL RUBBER–STEEL ADHESION." Rubber Chemistry and Technology 93, no. 2 (2019): 429–44. http://dx.doi.org/10.5254/rct.19.80455.

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ABSTRACT Optimizing the maintenance cycles of rubber-lined components is of great importance. Especially for the industry sectors operating under demanding conditions, challenges in the lifetime evaluation of rubber linings may cause apparent premature failures. Thus, understanding the effect of environmental factors on the performance and durability of rubber linings, as well as on the weakest links of the structure in certain environments, is essential. The performances of bromobutyl rubber and rubber–steel interfaces after exposure to different environments, namely, high temperature (95 °C)
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12

Junwei Zhou, Zhifei Chen, Fangang Zeng, et al. "Effect of Solvent Polarity on Bromobutyl Rubber Isomerization." Russian Journal of Physical Chemistry A 93, no. 13 (2019): 2687–93. http://dx.doi.org/10.1134/s0036024419130405.

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13

Hoyt, Michelle A., and C. M. Balik. "Diffusivity of a drug preservative in bromobutyl rubber." Polymer Engineering & Science 36, no. 14 (1996): 1862–68. http://dx.doi.org/10.1002/pen.10582.

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14

Fong, C. F. Chan Man, Y. Li, D. De Kee, and J. Bovenkamp. "Mathematical Model of Diffusion of Solvents in Rubbers." Rubber Chemistry and Technology 71, no. 2 (1998): 285–88. http://dx.doi.org/10.5254/1.3538484.

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Abstract The chemical potential associated with the diffusion through polymeric systems is assumed to be a function of the concentration and the stress induced by the swelling. The flux for such a model is calculated and is found to be in agreement with the experimental data involving acetone, dichloromethane, and toluene through natural rubber, bromobutyl rubber, and nitrile rubber.
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15

Cheng, D. M., I. J. Gardner, H. C. Wang, C. B. Frederick, A. H. Dekmezian, and P. Hous. "Spectroscopic Studies of the Structures of Butyl and Bromobutyl Rubbers." Rubber Chemistry and Technology 63, no. 2 (1990): 265–75. http://dx.doi.org/10.5254/1.3538257.

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Abstract The 1H-NMR results show that the majority of the isoprene units of butyl rubber are incorporated in 1,4 addition. Approximately 6% of the isoprene units undergo 1,2 enchainment. Based on our study of blends of polyisoprene with polyisobutylene, 1H-NMR provides an excellent method for determining isoprene unsaturation in butyl rubber. Furthermore, based on 1H-NMR measurement, FTIR procedures have been developed to quantify the isoprene content of butyl polymers and the concentrations of the three major bromobutyl isomers.
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16

Pazur, Richard J., and T. Mengistu. "EFFECT OF THERMO-OXIDATION ON PERMEATION RESISTANCE OF BROMOBUTYL COMPOUNDS." Rubber Chemistry and Technology 90, no. 1 (2017): 195–206. http://dx.doi.org/10.5254/rct.16.83750.

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ABSTRACT The impact of thermo-oxidation on the permeation process in a series of BIIR or bromobutyl compounds has been investigated. Methyl salicylate (MS) was used as the simulating chemical agent, and the permeation rate was measured gravimetrically using vapometers. Heat aged samples at 120 °C increased in stiffness with an accompanying decline in ultimate properties and network chain density. A reduction in permeability was found, driven primarily by the reduced solubility of MS in the thermo-oxidized BIIR matrix. The formation of a secondary oxidized chain network has been proposed to exp
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17

Dutta, Naba K., and D. K. Tripathy. "Miscibility Studies in Blends of Bromobutyl Rubber and Natural Rubber." Journal of Elastomers & Plastics 25, no. 2 (1993): 158–79. http://dx.doi.org/10.1177/009524439302500204.

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18

Aminabhavi, Tejraj M., Ravindra S. Munnolli, and J. Dale Ortego. "Sorption and diffusion of n-alkanes into bromobutyl rubber membranes." Polymer International 36, no. 4 (1995): 353–63. http://dx.doi.org/10.1002/pi.1995.210360408.

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19

Maysa, AM. "Radiation vulcanization of thermoplastic low-density polyethylene/bromobutyl rubber blends." Journal of Thermoplastic Composite Materials 27, no. 3 (2012): 364–78. http://dx.doi.org/10.1177/0892705712446168.

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20

Singh, Shyam K., Lindsay A. Summers, and Larry A. Hick. "Synthesis of Quaternary Salts from 4,7-Phenanthroline and Dibromoalkanes." Zeitschrift für Naturforschung B 43, no. 6 (1988): 785. http://dx.doi.org/10.1515/znb-1988-0624.

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Abstract4,7-Phenanthroline, Quaternary Salts, Dibromoalkanes 4,7-Phenanthroline reacts with dibromoalkanes to afford 4-bromoalkyl-4,7-phenanthrolinium bromides. 4-(3-Bromo-propyl)-and 4-(4-bromobutyl)-4,7-phenanthrolinium bromides on heat-ing afford the corresponding 4,4'-(alkanediyl)-bis-4,7-phenanthrolinium diquaternary salts whereas 4-(5-bromopentyl)-and 4-(6-bromohexyl)-4,7-phenanthrolinium bromides give the corresponding bridged diquaternary salts which are the first representatives of new heterocyclic ring systems.
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21

Rodgers, Brendan, Scott Solis, Nitin Tambe, and Bharat B. Sharma. "Alkylphenol Disulfide Polymer Accelerators and the Vulcanization of Isobutylene Based Elastomers." Rubber Chemistry and Technology 81, no. 4 (2008): 600–624. http://dx.doi.org/10.5254/1.3548222.

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Abstract Vulcanization of isobutylene/isoprene copolymer (butyl rubber) using sulfur and organic accelerators is facilitated by the presence of the carbon-carbon double bond in the copolymer isoprenyl unit. The low number of unsaturated monomer units, usually in the order of 2%, has traditionally necessitated use of ultra-fast accelerators such as tetramethyl thiuram disulfide (TMTD) or zinc dimethyldithiocarbamate (ZMDC). Use of such accelerators can result in formation of nitrosamines which may be undesirable. There are a number of alternatives to thiuram and dithiocarbamate cure systems suc
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22

Chen, X., K. Bastow, B. Goz, L. Kucera, S. L. Morris-Natschke, and K. S. Ishaq. "Boronic Acid Derivatives Targeting HIV-1." Antiviral Chemistry and Chemotherapy 7, no. 2 (1996): 108–14. http://dx.doi.org/10.1177/095632029600700208.

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A series of novel boronic acid derivatives containing either a pyrimidine or purine base was synthesized. The preparation involved the condensation of 4-bromobutyl boronic acid with the appropriate base. These acyclic nucleosides were designed as potential antiviral agents especially targeting the human immunodeficiency virus. Two analogues, 6-chloro-9-(4-dihydroxyborylbutyl)purine and 2,6-dichloro-9-(4-dihydroxyborylbutyl)purine, exhibited EC50 values of 7.7 μM and 0.99 μM, respectively, in an HIV-1 syncytial plaque reduction assay.
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23

Zhang, Xu-Yang, Bing-Ni Liu, Ping-Bao Wang, and Deng-Ke Liu. "Crystal structure of 9-(4-bromobutyl)-9H-fluorene-9-carboxylic acid." Acta Crystallographica Section E Structure Reports Online 70, no. 10 (2014): o1118—o1119. http://dx.doi.org/10.1107/s1600536814019564.

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The title compound, C18H17BrO2, is a key intermediate in the synthesis of lomitapide mesylate, a microsomal triglyceride transfer protein inhibitor. Its asymmetric unit contains two independent molecules with slightly different conformations; the mean planes of the 4-bromobutyl and carboxylate groups in the two molecules form dihedral angles of 24.54 (12) and 17.10 (18)°. In the crystal, carboxylate groups are involved in O—H...O hydrogen bonding, which leads to the formation of two crystallographically independent centrosymmetric dimers. Weak intermolecular C—H...O interactions further link t
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24

Kumar, S., S. Chattopadhyay, R. Padmanabhan, et al. "Tailoring permeation characteristics of bromobutyl rubber with polyepichlorohydrin and graphene nanoplatelets." Materials Research Express 2, no. 10 (2015): 105007. http://dx.doi.org/10.1088/2053-1591/2/10/105007.

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25

Bhaumik, Tapan K., B. R. Gupta, and Anil K. Bhowmick. "Cut-growth behaviour of EPDM-bromobutyl rubber blends under repeated stressing." Journal of Materials Science 22, no. 12 (1987): 4336–42. http://dx.doi.org/10.1007/bf01132026.

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26

Edwards, D. C. "A High-Performance Curing System for Halobutyl Elastomers." Rubber Chemistry and Technology 60, no. 1 (1987): 62–77. http://dx.doi.org/10.5254/1.3536122.

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Abstract 1. In halobutyl elastomers, zinc oxide interacts synergistically with aromatic amine antioxidants such as APDA 86, DPPD, or DNPD, to produce fast, tight cures. 2. In the case of DNPD, compound storage stability appears to be satisfactory, and the resistance to scorch at processing temperatures is ample. 3. The cure behavior of these systems, particularly in bromobutyl, is exceptionally favorable: a rapid rise to a remarkably flat plateau. 4. The vulcanizates exhibit excellent thermal stability (compression set) and excellent ozone resistance. Measurable elastic properties are retained
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27

Le, H. H., S. Hait, A. Das, et al. "Self-healing properties of carbon nanotube filled natural rubber/bromobutyl rubber blends." Express Polymer Letters 11, no. 3 (2017): 230–42. http://dx.doi.org/10.3144/expresspolymlett.2017.24.

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28

Bhaumik, T. K., B. R. Gupta, and Anil K. Bhowmick. "Tack and green strength of filled blends of bromobutyl and EPDM rubbers." Journal of Adhesion Science and Technology 1, no. 1 (1987): 227–38. http://dx.doi.org/10.1163/156856187x00238.

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29

Solomon, M., and R. W. Hostoffer. "Allergic Reaction and Anaphylaxis to IVIg when Administered Through Bromobutyl Vial Closure." Journal of Allergy and Clinical Immunology 119, no. 1 (2007): S15. http://dx.doi.org/10.1016/j.jaci.2006.11.073.

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30

Lu, Na, Mei Shen, Zhanfeng Hou, Prakashan K, and Zhenxiang Xin. "Effectiveness of different kinds of antioxidants in resin-cured bromobutyl rubber vulcanizates." Advances in Polymer Technology 37, no. 6 (2017): 2075–84. http://dx.doi.org/10.1002/adv.21865.

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31

Xiao, S., D. De Kee, and J. Bovenkamp. "Effect of Gasoline Contamination on the Permeation of Organic Liquids through Rubber Membranes." Rubber Chemistry and Technology 72, no. 4 (1999): 758–68. http://dx.doi.org/10.5254/1.3538832.

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Abstract The effect of gasoline and oil contamination on the barrier properties of natural rubber, nitrile rubber and bromobutyl rubber have been experimentally studied for the following organic environmental contaminants: dichloromethane, acetone and toluene. Oil contamination has little effect on the subsequent transport of these organic penetrants. However, gasoline contamination alters the subsequent transport behavior of these organic penetrants, depending on the nature of the rubber and the contamination conditions. Nitrile rubber experiences minor effects, while natural rubber is severe
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32

Xu, Zhao-Dong, Si Suo, Jun-Tao Zhu, and Ying-Qing Guo. "Performance tests and modeling on high damping magnetorheological elastomers based on bromobutyl rubber." Journal of Intelligent Material Systems and Structures 29, no. 6 (2017): 1025–37. http://dx.doi.org/10.1177/1045389x17730909.

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A new kind of magnetorheological elastomer with the matrix of the bromobutyl rubber is developed. The magnetoviscoelasticity properties of the magnetorheological elastomer specimens are investigated with respect to different magnetic fields, displacement amplitudes, and frequencies under sinusoidal loadings. The experimental results show that the shear storage modulus and the loss factor of magnetorheological elastomers increase with the increasing magnetic field, excitation frequency, and the weight fraction of particles, but decrease with the increasing strain amplitude, and the magnetorheol
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33

Shin, Ildong, Janos Szamosi, and Singa Tobing. "Two-Level Factorial Study of the Rheology and Foaming of Bromobutyl Rubber Solutions." International Journal of Polymeric Materials 15, no. 2 (1991): 103–6. http://dx.doi.org/10.1080/00914039108031527.

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34

Le, Hong Hai, Frank Böhme, Aladin Sallat, et al. "Triggering the Self-Healing Properties of Modified Bromobutyl Rubber by Intrinsically Electrical Heating." Macromolecular Materials and Engineering 302, no. 4 (2016): 1600385. http://dx.doi.org/10.1002/mame.201600385.

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35

Vitiello, R., R. Tesser, R. Turco, E. Santacesaria, G. Compagnone, and M. Di Serio. "A critical review on analytical methods and characterization of butyl and bromobutyl rubber." International Journal of Polymer Analysis and Characterization 22, no. 4 (2017): 348–60. http://dx.doi.org/10.1080/1023666x.2017.1297887.

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36

Waddell, Walter H., R. Christopher Napier, and Donald S. Tracey. "Nitrogen Inflation of Tires." Rubber Chemistry and Technology 82, no. 2 (2009): 229–43. http://dx.doi.org/10.5254/1.3548247.

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Abstract Inflation pressure retention (IPR as a loss rate) is a key predictive parameter to improving tire durability. Improved Tire IPR, manifested as reduced percent pressure loss per month values, has statistically been shown to be a direct result of innerliner compounds made with increasing amounts of halobutyl rubber when used as a direct replacement for natural rubber if other variables are constant. Roadwheel performance of tires is highest when using 100-phr of halobutyl rubber in the innerliner compound. This affords a tire with desirably low IPR loss rate values, desirably low tire i
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37

Kratochvíl, Bohumil, Alexandr Jegorov, Svetlana Pakhomova, et al. "Crystal Structures of Cyclosporin Derivatives: O-Acetyl-(4R)-4-(E-2-butyl)-4,N-dimethyl-L-threonyl-cyclosporin A and O-Acetyl-(4R)-4-[E-2-(4-bromobutyl)]-4,N-dimethyl-L-threonyl-cyclosporin A." Collection of Czechoslovak Chemical Communications 64, no. 1 (1999): 89–98. http://dx.doi.org/10.1135/cccc19990089.

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The structures of O-acetyl-(4R)-4-(E-2-butyl)-4,N-dimethyl-L-threonyl-cyclosporin A (1) and O-acetyl-(4R)-4-[E-2-(4-bromobutyl)]-4,N-dimethyl-L-threonyl-cyclosporin A (2) were determined by X-ray diffraction methods and compared with the structure of related cyclosporins. In contrast to expectation, neither the acetylation nor the subsequent bromination of 1 affects the conformation and packing of cyclosporins in the solid state. Both compounds are isomorphous and crystallize in the orthorhombic space group P212121 with a = 12.936(2) Å, b = 15.590(2) Å, c = 36.280(3) Å, and a = 12.916(3) Å, b
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38

Li, Pei-Ying, Kai-Yu Cheng, Xiu-Cheng Zheng, Pu Liu, and Xiu-Juan Xu. "Facile synthesis of water-soluble graphene-based composite: Non-covalently functionalized with chitosan-ionic liquid conjugation." Functional Materials Letters 09, no. 03 (2016): 1650045. http://dx.doi.org/10.1142/s1793604716500454.

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Chitosan-ionic liquid conjugation (CILC), which was prepared through the reaction of 1-(4-bromobutyl)-3-methylimidazolium bromide (BBMIB) with chitosan, was firstly used to prepare functionalized graphene composite via the chemical reduction of graphene oxide (GO). The obtained water soluble graphene-based composite was characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), ultraviolet-visible (UV–Vis) spectroscopy and so on. CILC-RGO showed excellent dispersion stability in water at
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39

Sankaran, Kumar, Partheban Manoharan, Sofana Reka S, and Santanu Chattopadhyay. "A brief insight into the prediction of water vapor transmissibility in highly impermeable hybrid nanocomposites based on bromobutyl/epichlorohydrin rubber blends." Open Chemistry 16, no. 1 (2018): 1207–13. http://dx.doi.org/10.1515/chem-2018-0124.

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AbstractThe present work proposes a schematic model for predicting the water vapor transmissibility in hybrid nanocomposites based on bromobutyl (BIIR)/epichlorohydrin (CO) rubber blends. Morphology study reveals the exfoliation of nanoclay and development of hybrid nanostructures in the rubber nanocomposites. A unique correlation between water vapor transmissibility and gas (oxygen) permeability through the rubber nanocomposites has been systematically derived. The prediction of relative water vapor transmissibility was achieved by considering the polar path along with the existing tortuous p
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40

Kurbanova, N. I., N. Ya Ishchenko, and A. M. Kuliev. "Composite Materials Based on Binary Mixtures of Bromobutyl- and Butadiene-Nitrile Rubbers with Polyisoprene." International Polymer Science and Technology 32, no. 2 (2005): 11–15. http://dx.doi.org/10.1177/0307174x0503200203.

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41

Patra, P. K., and C. K. Das. "Studies on the Influence of Cure System on the Shrinkability of Polyolefin-Bromobutyl Blends." Journal of Elastomers & Plastics 30, no. 3 (1998): 230–44. http://dx.doi.org/10.1177/009524439803000304.

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42

Dutta, Naba K., D. Khastgir, and D. K. Tripathy. "The effect of carbon black concentration on the dynamic mechanical properties of bromobutyl rubber." Journal of Materials Science 26, no. 1 (1991): 177–88. http://dx.doi.org/10.1007/bf00576049.

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43

Zhang, Weixuan, Yan Zhang, Guangzhao Yang, et al. "Wearable and self-powered sensors made by triboelectric nanogenerators assembled from antibacterial bromobutyl rubber." Nano Energy 82 (April 2021): 105769. http://dx.doi.org/10.1016/j.nanoen.2021.105769.

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44

Waddell, Walter H., Julie H. Kuhr, and Robert R. Poulter. "Evaluation of Isobutylene-Based Elastomers in a Model Winter Tire Tread." Rubber Chemistry and Technology 76, no. 2 (2003): 348–64. http://dx.doi.org/10.5254/1.3547748.

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Abstract The performance of butyl, chlorobutyl, bromobutyl, and brominated isobutylene-co-para-methylstyrene (BIMS) rubbers were evaluated versus a solution-polymerized styrene-butadiene rubber with 20% bound styrene in model winter tire tread formulations containing natural rubber and butadiene rubber. Isobutylene-based elastomer performance was compared in carbon black-filled and silane-coupled silica-filled systems. Based on laboratory dynamic properties predictive of wet and winter traction, and on DIN abrasion index values, BIMS is the elastomer of choice affording increased tangent delta
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45

Zhang, Zhen-Xiu, Xiao-pei Zhao, Bin Sun, Zhen-guo Ma, Zhen Xiang Xin, and K. Prakashan. "Synergistic effects of kaolin and talc in a bromobutyl rubber compound for syringe plunger application." Journal of Elastomers & Plastics 49, no. 1 (2016): 12–22. http://dx.doi.org/10.1177/0095244315620915.

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The effectiveness of separate and combined incorporation of two natural, inexpensive, and nontoxic filler materials, kaolin and talc, at their various proportions in a bromobutyl rubber (BIIR) compound for a medical syringe plunger was investigated. The dispersion of kaolin was finer and more homogeneous than talc in BIIR. The curing was also enhanced in the presence of kaolin than talc. The difference in dispersion as well as reinforcing effects of the different fillers were reflected in the dynamic mechanical properties of the compounds. Tensile properties of the compounds were not significa
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46

Antonio, Yulia, Ma Elizabeth De La Cruz, Edvige Galeazzi та ін. "Oxidative radical cyclization to pyrroles under reducing conditions. Reductive desulfonylation of α-sulfonylpyrroles with tri-n-butyltin hydride". Canadian Journal of Chemistry 72, № 1 (1994): 15–22. http://dx.doi.org/10.1139/v94-004.

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1-(2-Bromobenzyl)-2-alkanesulfonylpyrroles (1c, 1d) and 1-(4-bromobutyl)-2-methylsulfonfylpyrrols (8) undergo oxidative radical cyclization with partial or complete reductive desulfonylation to the pyrrolizidine derivatives 5 and 9 by an AIBN initiated reaction with tri-n-butyltin hydride. These cyclizations are suggested to proceed via a pseudo SRN1 process involving radical addition to the α position of the pyrrole nucleus not bearing the sulfonyl group. Reductive removal of the alkylsulfonyl moiety is proposed to occur in a second process after completion of the oxidative radical cyclizatio
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Kotal, Moumita, Shib Shankar Banerjee, and Anil K. Bhowmick. "Functionalized graphene with polymer as unique strategy in tailoring the properties of bromobutyl rubber nanocomposites." Polymer 82 (January 2016): 121–32. http://dx.doi.org/10.1016/j.polymer.2015.11.044.

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48

Bhaumik, T. K., B. R. Gupta, and A. K. Bhowmick. "Tack and Green Strength of Blends of Bromobutyl and EPDM Rubbers. I. Unfilled Gum Blends." Journal of Adhesion 24, no. 2-4 (1987): 183–98. http://dx.doi.org/10.1080/00218468708075426.

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Ohbi, D. S., T. S. Purewal, T. Shah, and E. Siores. "Crosslinking reaction mechanism of diisopropyl xanthogen polysulfide accelerator in bromobutyl elastomer for medical device applications." Journal of Applied Polymer Science 107, no. 6 (2007): 4013–20. http://dx.doi.org/10.1002/app.27618.

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Rattanasom, N., S. Prasertsri, and K. Suchiva. "Mechanical properties, thermal stability, gas permeability, and phase morphology in natural rubber/bromobutyl rubber blends." Journal of Applied Polymer Science 113, no. 6 (2009): 3985–92. http://dx.doi.org/10.1002/app.30451.

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