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Relevant bibliographies by topics / Buchwald-Hartwig reaction

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Journal articles

Academic literature on the topic 'Buchwald-Hartwig reaction'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 April 2022

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Journal articles on the topic "Buchwald-Hartwig reaction"

1

Heravi, Majid M., Zohreh Kheilkordi, Vahideh Zadsirjan, Masumeh Heydari, and Masoumeh Malmir. "Buchwald-Hartwig reaction: An overview." Journal of Organometallic Chemistry 861 (April 2018): 17–104. http://dx.doi.org/10.1016/j.jorganchem.2018.02.023.

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2

Mishra, Vaibhav, and Tejpal Singh Chundawat. "Pd Catalyzed N1/N4 Arylation of Piperazine for Synthesis of Drugs, Biological and Pharmaceutical Targets: An Overview of Buchwald Hartwig Amination Reaction of Piperazine in Drug Synthesis." Current Organic Synthesis 15, no. 2 (2018): 208–20. http://dx.doi.org/10.2174/1570179415666171206151603.

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Background: Substituted piperazine heterocycles are among the most significant structural components of pharmaceuticals. N1/N4 substituted piperazine containing drugs and biological targets are ranked 3rd in the top most frequent nitrogen heterocycles in U.S. FDA approved drugs. The high demand of N1/N4 substituted piperazine containing biologically active compounds and U.S. FDA approved drugs, has prompted the development of Pd catalyzed C-N bond formation reactions for their synthesis. Buchwald-Hartwig reaction is the key tool for the synthesis of these compounds. Objective: This review prov

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3

Laschat, Sabine, Philipp Seubert, Marcel Freund, et al. "Buchwald–Hartwig versus Microwave-Assisted Amination of Chloroquinolines: En Route to the Pyoverdin Chromophore." Synlett 31, no. 12 (2020): 1177–81. http://dx.doi.org/10.1055/s-0040-1707810.

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The reaction of 2-chloro-6,7-dimethoxy-3-nitroquinoline with a series of amines and aminoalkanoates under basic microwave-mediated conditions and under Buchwald–Hartwig amination conditions is reported. The microwave irradiation favored the reaction with amines, resulting in yields of up to 80%, whereas amino acid functionalization gave yields comparable to those of Buchwald–Hartwig amination. tert-Butyl (2R)-4-[(6,7-dimethoxy-3-nitroquinolin-2-yl)amino]-2-hydroxybutanoate was successfully cyclized to the pyoverdin chromophore, a subunit of siderophores.

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4

Kimyashov, Alexander A., Alexander V. Syromolotov, and Dmitry S. Ryashincev. "Study of Buchwald-Hartwig reaction with catalysts based on monovalent copper." Butlerov Communications 58, no. 4 (2019): 62–65. http://dx.doi.org/10.37952/roi-jbc-01/19-58-4-62.

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Many natural substances and drugs includes N-aryl-substituted heterocycles. These substances can be synthesized in various conditions, one of which is the amination of Buchwald-Hartwig. In this reaction formation of N-substituted anilines was observed as the resalt of the interaction between aryl halides and tin amides in palladium catalysis condition. It was discovered by Buchwald and Hartwig in 1994. In 1996, toxic amides of tin and P(o-Tol)3 were replaced by amines and chelating diphosphines. Due to high yields and good reproducibility, Buchwald-Hartwig amination is the attractive method fo

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5

Beverina, Luca, Luca Vaghi, Alessandro Sanzone, Mauro Sassi, Simone Pagani, and Antonio Papagni. "Synthesis of Fluorinated Acridines via Sequential Micellar Buchwald–Hartwig Amination/Cyclization of Aryl Bromides." Synthesis 50, no. 08 (2018): 1621–28. http://dx.doi.org/10.1055/s-0036-1591937.

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Fluorinated unsymmetrical acridines are efficiently prepared by means of a tandem micellar Buchwald–Hartwig amination followed by an acid-promoted cyclization. The overall process is advantageous with respect to previously described protocols both in terms of efficiency and sustainability. The role of the cosolvent in the amination step is highlighted, demonstrating that rather than resorting to highly expensive catalysts, Buchwald–Hartwig aminations can be straightforwardly carried out by tuning the reaction site polarity.

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6

Sá, Sofia, Manoj B. Gawande, Alexandre Velhinho, et al. "Magnetically recyclable magnetite–palladium (Nanocat-Fe–Pd) nanocatalyst for the Buchwald–Hartwig reaction." Green Chem. 16, no. 7 (2014): 3494–500. http://dx.doi.org/10.1039/c4gc00558a.

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7

Liu, Yan, Jia Yuan, Zi-Fei Wang, et al. "Application of a 2-aryl indenylphosphine ligand in the Buchwald–Hartwig cross-coupling reactions of aryl and heteroaryl chlorides under the solvent-free and aqueous conditions." Organic & Biomolecular Chemistry 15, no. 27 (2017): 5805–10. http://dx.doi.org/10.1039/c7ob01199g.

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An efficient solvent-free and aqueous protocol for the Buchwald–Hartwig cross-coupling reaction has been developed. Notably, the catalytic system also efficiently catalyzed the reaction under aqueous conditions.

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8

Ageshina, Alexandra A., Grigorii K. Sterligov, Sergey A. Rzhevskiy, et al. "Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald–Hartwig reaction under solvent-free conditions." Dalton Transactions 48, no. 10 (2019): 3447–52. http://dx.doi.org/10.1039/c9dt00216b.

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9

Arisawa, Mitsuhiro, Mohammad Al-Amin, Tetsuo Honma, et al. "Formation of self-assembled multi-layer stable palladium nanoparticles for ligand-free coupling reactions." RSC Advances 5, no. 1 (2015): 676–83. http://dx.doi.org/10.1039/c4ra11215f.

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10

Saikia, Pallabi, Gitarthi Sharma, Sanjib Gogoi, and Romesh C. Boruah. "Cascade imination, Buchwald–Hartwig cross coupling and cycloaddition reaction: synthesis of pyrido[2,3-d]pyrimidines." RSC Advances 5, no. 30 (2015): 23210–12. http://dx.doi.org/10.1039/c5ra00725a.

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