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1

Man, Wong Wee Choy Wong Chi, Hans Pritzkow, and Walter Siebert. "Notizen: Synthesis and Structure of a 2,4,5-Tris(methylene)-1-bora-3-silacyclopentane Derivative." Zeitschrift für Naturforschung B 46, no. 8 (August 1, 1991): 1127–29. http://dx.doi.org/10.1515/znb-1991-0827.

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3,3-Dimethyl-(e)-1-chlorodimethylsilyl-1-chloro-dimethylaminoboryl-butene-1 (5) reacts with 3,4-dilithio-2,5-dimethyl-2,4-hexadiene in diethylether to give colorless 2-(tert-butylmethy-lene)-4,5-bis(dimethylmethylene)-1-dimethylamino-3-dimethyl-1-bora-3-sila-cyclopentane (4) in 41% yield. The X-ray structure analysis shows a non-planar ring with a small angle C2-Si3-C4 = 94.9(1)°.
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2

Crowder, G. A. "Interpretation of the vibrational spectra of 3,3‐dimethyl‐1‐butene." Journal of Environmental Science and Health . Part A: Environmental Science and Engineering and Toxicology 30, no. 7 (August 1995): 1457–71. http://dx.doi.org/10.1080/10934529509376278.

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3

Crowder, G. A. "Interpretation of the Vibrational Spectra Of 3,3-Dimethyl-1-Butene." Spectroscopy Letters 29, no. 1 (January 1996): 11–25. http://dx.doi.org/10.1080/00387019608001577.

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4

Wong-Chi-Man, Wong-Wee-Choy, Hans Pritzkow, and Walter Siebert. "Notizen: Synthesis and Structure of an 1,3-Dibora-2,5-disilacyclohexane Derivative." Zeitschrift für Naturforschung B 45, no. 11 (November 1, 1990): 1597–99. http://dx.doi.org/10.1515/znb-1990-1124.

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Hydroboration, 3,3-Dimethyl-(e)-1-chlorodimethylsilyl-1-chloro-dimethylaminoboryl-butene-1,1,3-Bis(dimethylamino-2,2,5,5-tetramethyl-4,6-bis-(t-butylethylene)-1,3-dibora-2,5-disilacyclohexaneHydroboration of chlorodimethyl(3.3-dimethylbutynyl)silane with HBCl2/BCl3 yields 3.3-dimethyl-(e)-1-chlorodimethylsilyl-1-dichloroboryl)-butene-1 (1 a), in which a chlorine atom at the boron can be substituted using Me3SiNMe, to give the corresponding chlorodimethylaminoboryl derivative 1 b. Dehalogenation of 1 b with Na/K alloy does not lead to the three-membered ring compound 2, but surprisingly yields the 1,3-dibora-disilacyclohexane derivative 3. The X-ray structure analysis shows a six-membered ring with a chair conformation, a small angle B 1–Si 2–B 1′ = 95.4(1)°, and long Si–B bonds (2.038 Å).
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5

Bautista, F. M., J. M. Campelo, A. Garcia, D. Luna, J. M. Marinas, A. A. Romero, and M. R. Urbano. "Isomerization of 3,3-dimethyl-1-butene over aluminum and chromium orthophosphates." Reaction Kinetics and Catalysis Letters 64, no. 1 (May 1998): 41–48. http://dx.doi.org/10.1007/bf02475368.

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6

Katritzky, Alan R., Yunfeng Fang, and Indra Prakash. "ChemInform Abstract: A Novel Preparation of 3,3-Dimethylbutyraldehyde via Isomerization of 3,3-Dimethyl-1-butene Epoxide." ChemInform 33, no. 18 (May 21, 2010): no. http://dx.doi.org/10.1002/chin.200218091.

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7

Tuaillon, Jacques, Yvon Couture, and Jean Lessard. "Radical reactions of N-haloamides with olefins. XIII. Quantum yields for the photochemical addition of N-halo-N-hydroamides and N-chlorosuccinimide to 3,3-dimethyl-1-butene." Canadian Journal of Chemistry 65, no. 9 (September 1, 1987): 2194–97. http://dx.doi.org/10.1139/v87-367.

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The quantum yield of the photochemically initiated radical chain addition of ZCONHX to 3,3-dimethyl-1-butene increases with Z in the order CH3 < ClCH2 < C2H5O < CCl3 < CF3 and is governed by the transfer step. The quantum yields are similar for N-chloroacetamide and N-chlorosuccinimide but the yield of addition is lower with the latter due to photodecomposition of the 1,2-adduct.
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8

Park, Jaebum, Jinhyung Lee, and Jaegab Lee. "Pulsed MOCVD of Cu Seed Layer Using a (hfac)Cu(3,3-dimethyl-1-butene) Source and H2Reactant." Korean Journal of Materials Research 14, no. 9 (September 1, 2004): 619–26. http://dx.doi.org/10.3740/mrsk.2004.14.9.619.

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9

Deslauriers, Hélène, and Guy J. Collin. "The photolysis of 2,3- and 3,3-dimethyl-1-butene at 147.0 and 184.9 nm." Canadian Journal of Chemistry 63, no. 1 (January 1, 1985): 62–67. http://dx.doi.org/10.1139/v85-011.

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The photofragmentation of 2,3-dimethylbutene and 3,3-dimethylbutene has been studied at 147 and 184.9 nm in the gas phase. The main primary decomposition process at both wavelengths involves the rupture of a β(C—C) bond. The quantum yield for this process is higher than 0.7 at 147 nm and is probably even higher at 184.9 nm. All dimethallyl radicals formed at 147 nm in this process decompose at low pressure, but some of them isomerize from the α,β- to the α,α- structure (and vice versa) — via a 1,4-H transfer — before decomposition. At 184.9 nm, the same primary process is used to get a rough value for the lifetime of the photoexcited molecule, compared with the one made with RRKM calculations by assuming that all the photon energy resides in the vibrational framework of the fundamental electronic state. These lifetimes are about one nanosecond or less.
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10

Nagaraja, C. M., Munirathinam Nethaji, and Balaji R. Jagirdar. "Tris(pyrazolyl)methane Sulfonate Complexes of Iridium: Catalytic Hydrogenation of 3,3-Dimethyl-1-butene." Organometallics 26, no. 25 (December 2007): 6307–11. http://dx.doi.org/10.1021/om700515n.

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11

Mukoid, Cezary, Steven Hawker, Jas Pal S. Badyal, and Richard M. Lambert. "Molecular mechanism of alkene epoxidation: A model study with 3,3-dimethyl-1-butene on Ag(111)." Catalysis Letters 4, no. 1 (1990): 57–61. http://dx.doi.org/10.1007/bf00764871.

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12

Still, Ian W. J., and Donna Kaye T. Wilson. "α-Oxosulfines: reactions with alkenes and alkynes." Canadian Journal of Chemistry 70, no. 3 (March 1, 1992): 964–73. http://dx.doi.org/10.1139/v92-129.

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Thiochroman-4-one 1,1-dioxide has been successfully converted into 3-sulfinylthiochroman-4-one 1,1-dioxide and the reactions of this α-oxosulfine with a series of alkenes have been carefully investigated. The α-oxosulfine was found to react as a Diels–Alder diene with 2-methylpropene, Z- and E-2-butene, 2-ethyl-1-butene, 1-pentene, Z-2-pentene, and cyclopentene and cyclohexene to produce a new group of heterocyclic compounds, the 2,3-dihydro-5H-1,4-oxathiino[3,2-c][1]benzothiopyrans, in yields ranging from 21 to 42%. In all cases, formation of the Diels–Alder adduct was accompanied by a second type of product, identified as the product of electrophilic addition (EA) of a sulfenium species to the alkene, in lesser yields, ranging from 9 to 18%. When the trapping dienophile used was 3,3-dimethyl-1-butene, only the EA adduct was obtained, in 28% yield. Formation of only the EA type of adduct was also observed in reactions of the α-oxosulfine with 2-butyne (21%) and with the thione 2,2,4,4-tetramethylpentane-3-thione (di-tert-butyl thioketone) (16%). Attempts to prepare the α-oxosulfines corresponding to the following ketones are also described: thiochroman-4-one 1-oxide, isothiochromanone and isothiochromanone 2,2-dioxide, tetrahydrothiophen-3-one 1,1-dioxide, 3,3,5,5-tetramethylcyclohexanone, and 2-indanone. Keywords: Diels–Alder, electrophilic addition, sulfenic acid.
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13

Xiang, Peng, and Zhibin Ye. "Copolymerization of Ethylene with Sterically Hindered 3,3-Dimethyl-1-Butene Using a Chain-Walking Pd-Diimine Catalyst." Macromolecular Rapid Communications 31, no. 12 (April 13, 2010): 1083–89. http://dx.doi.org/10.1002/marc.201000014.

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14

Newcomb, Martin, William G. Williams, and Elizabeth L. Crumpacker. "4-bromo-3,3-dimethyl-1-butene: a new probe for radical intermediates in reactions in strongly basic media." Tetrahedron Letters 26, no. 9 (January 1985): 1183–84. http://dx.doi.org/10.1016/s0040-4039(00)98428-4.

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15

Choi, Kyeong-Keun, Sung G. Pyo, Dok Won Lee, and Shi-Woo Rhee. "Metalorganic Chemical Vapor Deposition of Copper Using (Hexafluoroacetylacetonate)Cu(I)(3,3-dimethyl-1-butene) with a Liquid Delivery System." Japanese Journal of Applied Physics 41, Part 1, No. 5A (May 15, 2002): 2962–68. http://dx.doi.org/10.1143/jjap.41.2962.

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16

Choi, Kyeong-Keun, and Shi-Woo Rhee. "Effect of Carrier Gas on Chemical Vapor Deposition of Copper with (Hexafluoroacetylacetonate)Cu[sup (I)](3,3-Dimethyl-1-butene)." Journal of The Electrochemical Society 148, no. 7 (2001): C473. http://dx.doi.org/10.1149/1.1375168.

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17

Rhee, Shi-Woo. "Property of HexafluoroacetylacetonateCu(I) (3,3-Dimethyl-1-butene) as a Liquid Precursor for Chemical Vapor Deposition of Copper Films." Electrochemical and Solid-State Letters 3, no. 3 (1999): 135. http://dx.doi.org/10.1149/1.1390980.

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18

Borisov, A. V., V. K. Belsky, T. V. Goncharova, G. N. Borisova, V. K. Osmanov, Zh V. Matsulevich, N. G. Frolova, and E. D. Savin. "Sulfenyl Halides in the Synthesis of Heterocycles. 2. Cyclization in Reactions of Hetarenesulfenyl Chlorides with 3,3-Dimethyl-1-butene." Chemistry of Heterocyclic Compounds 41, no. 6 (June 2005): 771–77. http://dx.doi.org/10.1007/s10593-005-0219-z.

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19

Jia, Hong-Peng, Yasemin Kaya, Catherine Chow, Mostafa Taoufik, and Elsje Alessandra Quadrelli. "C-H Bond Activation of Benzene, Toluene, 3,3-Dimethyl-1-butene and Methane by Silica-Supported TaVImido Amido Surface Complex." Zeitschrift für anorganische und allgemeine Chemie 641, no. 1 (September 29, 2014): 56–60. http://dx.doi.org/10.1002/zaac.201400178.

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20

KARMAL, S. "Role of the support in the skeletal isomerization of 3,3-dimethyl-1-butene on oxided and sulfided CoMo/Al2O3 catalysts." Journal of Catalysis 130, no. 1 (July 1991): 212–19. http://dx.doi.org/10.1016/0021-9517(91)90105-d.

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21

Lee, Sungwoo, Jihyung Woo, Eunkyoung Nam, Donggeun Jung, Jaeyoung Yang, Heeyeop Chae, and Hyoungsub Kim. "Effects of Deposition Plasma Power on Properties of Low Dielectric-Constant Plasma Polymer Films Deposited Using Hexamethyldisiloxane and 3,3-Dimethyl-1-butene Precursors." Japanese Journal of Applied Physics 48, no. 10 (October 20, 2009): 106001. http://dx.doi.org/10.1143/jjap.48.106001.

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22

Stang, Peter J., and Kenneth A. Roberts. "Electrophilic additions to alkynyl tosylates. Formation of vinyl 1,1-(bis esters) and related compounds. X-ray structure determination of (E)-1-chloro-1-(tosyloxy)-3,3-dimethyl-1-butene." Journal of Organic Chemistry 52, no. 23 (November 1987): 5213–17. http://dx.doi.org/10.1021/jo00232a028.

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23

Alipour, Aidin, Jafar Javanmardi, Ali Eslamimanesh, and Amir H. Mohammadi. "Phase Equilibria of Clathrate Hydrates in (Methane + Cyclooctane + Water), (Methane + 3,3-Dimethyl-1-butene + Water), (Methane + 2-Pentanone + Water), or (Methane + 3-Pentanone + Water) Systems." Journal of Chemical & Engineering Data 58, no. 11 (October 24, 2013): 3179–82. http://dx.doi.org/10.1021/je4006344.

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24

Kang, Sang-Woo, Sang-Ho Han, and Shi-Woo Rhee. "(hfac)Cu(I)(MP) (hfac=hexafluoroacetylacetonate, MP=4-methyl-1-pentene) and (hfac)Cu(I)(DMB) (DMB=3,3-dimethyl-1-butene) for the chemical vapor deposition of copper film." Thin Solid Films 350, no. 1-2 (August 1999): 10–13. http://dx.doi.org/10.1016/s0040-6090(99)00346-6.

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25

Toyir, J., M. Leconte, G. P. Niccolai, and J. M. Basset. "Hydrogenolysis and Homologation of 3,3-Dimethyl-1-butene on Ru/SiO2 Catalyst: Implications for the Mechanism of Carbon-Carbon Bond Formation and Cleavage on Metal Surfaces." Journal of Catalysis 152, no. 2 (April 1995): 306–12. http://dx.doi.org/10.1006/jcat.1995.1084.

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26

Sinehbaghizadeh, Saeed, Jafar Javanmardi, and Amir H. Mohammadi. "Phase stability conditions of clathrate hydrates in the (methane + 3-methyl-1-butanol + water), (methane + 3,3-dimethyl-2-butanone + water) and (methane + 2,3-dimethyl-2-butene + water) systems: Experimental measurements and thermodynamic modeling." Journal of Chemical Thermodynamics 125 (October 2018): 64–70. http://dx.doi.org/10.1016/j.jct.2018.05.006.

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27

Kim, Kwansoo, Youngjo Tak, and Kijung Yong. "Effect of the cyclic delivery of (hexafluoroacetylacetonate)Cu[sup (I)] ×(3,3-dimethyl-1-butene) pulse and Ar purge gas on the low temperature copper metalorganic chemical vapor deposition." Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures 22, no. 2 (2004): 528. http://dx.doi.org/10.1116/1.1651109.

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28

Cedeño, David L., and Eric Weitz. "An Experimental Determination of the Cr−DMB (DMB = 3,3-Dimethyl-1-butene) Bond Energy in Cr(CO)5(DMB): Effects of Alkyl Substitution on Chromium−Olefin Bond Energies in Cr(CO)5(olefin) Complexes." Journal of Physical Chemistry A 106, no. 18 (May 2002): 4651–60. http://dx.doi.org/10.1021/jp013912b.

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29

Wang, Jiaqiang, and Eric Weitz. "A Gas-Phase Study of the Kinetics of Formation of Fe(CO)3DMB, Fe(CO)3(DMB)2, and Fe(CO)4DMB: The Bond Dissociation Enthalpy for Fe(CO)3(DMB)2(DMB = 3,3-dimethyl-1-butene)." Journal of Physical Chemistry A 105, no. 22 (June 2001): 5410–19. http://dx.doi.org/10.1021/jp010061z.

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30

"NICKEL-CATALYZED, GEMINAL DIMETHYLATION OF ALLYLIC DITHIOACETALS: (E)-1-PHENYL-3,3-DIMETHYL-1-BUTENE." Organic Syntheses 74 (1997): 187. http://dx.doi.org/10.15227/orgsyn.074.0187.

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31

Park, Jaebum, Heejung Yang, and Jaegab Lee. "Pulsed MOCVD of Cu Seed Layer using a (Hfac)Cu(3,3-Dimethyl-1-Butene) Source Plus H2 Reactant." MRS Proceedings 812 (2004). http://dx.doi.org/10.1557/proc-812-f3.21.

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AbstractPulsed metalorganic chemical vapor deposition (MOCVD) of conformal copper seed layers, for the electrodeposition Cu films, has been achieved by an alternating supply of a Cu(I) source and H2 reactant at the deposition temperatures of 50 - 100°C. The Cu thickness increased proportionally to the number of cycle, and the growth rate was in the range of 3.5 to 8.2 A /cycle, showing the ability to control the nano-scale thickness. As-deposited films show highly smooth surfaces even for more than 100nm. In addition, about a 90% step coverage was obtained inside trenches, with an aspect ratio greater than 30:1. H2, introduced as a reactant gas, can play an active role in achieving highly conformal coatings, with increased grain sizes.
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32

NEWCOMB, M., W. G. WILLIAMS, and E. L. CRUMPACKER. "ChemInform Abstract: 4-BROMO-3,3-DIMETHYL-1-BUTENE: A NEW PROBE FOR RADICAL INTERMEDIATES IN REACTIONS IN STRONGLY BASIC MEDIA." Chemischer Informationsdienst 16, no. 29 (July 23, 1985). http://dx.doi.org/10.1002/chin.198529143.

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33

Borisov, A. V., V. K. Belsky, T. V. Goncharova, G. N. Borisova, V. K. Osmanov, Zh V. Matsulevich, N. G. Frolova, and E. D. Savin. "Sulfenyl Halides in the Synthesis of Heterocycles. Part 2. Cyclization in Reactions of Hetarenesulfenyl Chlorides with 3,3-Dimethyl-1-butene." ChemInform 37, no. 20 (May 16, 2006). http://dx.doi.org/10.1002/chin.200620037.

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34

Al-Rubaye, Abeer Fauzi, Mohanad Jawad Kadhim, and Imad Hadi Hameed. "Determination of Bioactive Chemical Composition of Methanolic Leaves Extract of Sinapis arvensis Using GC-MS Technique." INTERNATIONAL JOURNAL OF TOXICOLOGICAL AND PHARMACOLOGICAL RESEARCH 9, no. 02 (May 1, 2017). http://dx.doi.org/10.25258/ijtpr.v9i02.9055.

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Plants play an important role in providing food for humans. Among plants economic significance medicinal and aromatic plants which played a critical where it used as therapeutic agents to a long time. Thirty bioactive phytochemical compounds were identified in the methanolic extract of Sinapis arvensis: Erythritol , Nitro-2-propanol , Cyclopentanemethylamine ,2-isopropylidene-N,N,5-trimethyl, Furfural , 3-(1,3-Dihydroxyisopropyl)-1,5,8,11- tetraoxacyclotridecane , 3-Azabutyl-1-ol,4-cyclopropyl-3,3-dimethyl-,bromide , 1-Butene , 4-isothiocyanato- , 2,4- Difluorobenzene , 1-benzyloxy- , Eicosanoic acid , phenylmethyl ester , α-D-Glucopyranoside ,O-α-D-glucopyranosyl- (1.fwdarw.3)-β- , Trigonelline , 4H-Pyran-4-one ,2,3-dihydro-3,5-dihydroxy-6-methyl , Estragole , Pentanenitrile , 5- (methylthio)- , 5-Hydroxymethylfurfural , Eugenol , Maltose , 2H-Thiopyran-3,5-diol ,tetrahydro-4-nitro-,monoacetate ( ester) , Tetraacetyl-d-xylonic nitrile , 3,6-Diazahomoadamantan-9-one Hydrazone , 9,10-Secocholesta-5,7,10(19)- triene-3,24,25-triol , (3β,5Z,7E)- , 13-Heptadecyn-1-ol , Tributyl acetylcitrate , E)-13-Docosenoic acid , Phthalic acid , decyl oct-3-yl ester , γ-Tocopherol , Desoxo-9x-hydroxy-7-ketoingol 3,8,9,12-tetraacetate , Campesterol , γ-Sitosterol , . The identification of phytochemical compounds is based on the peak area, retention time molecular weight, molecular formula, MS Fragment- ions and Pharmacological actions.
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35

STANG, P. J., and K. A. ROBERTS. "ChemInform Abstract: Electrophilic Additions to Alkynyl Tosylates. Formation of Vinyl 1,1-Bisesters and Related Compounds. X-Ray Structure Determination of E-1-Chloro-1-(tosyloxy)-3,3-dimethyl-1-butene." ChemInform 19, no. 17 (April 26, 1988). http://dx.doi.org/10.1002/chin.198817144.

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