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Dissertations / Theses on the topic 'Butyl methacrylate'

Author: Grafiati

Published: 4 June 2021

Last updated: 9 February 2022

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1

Hakim, Malik. "The copolymerization of butyl acrylate/methyl methacrylate at elevated temperatures." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/tape17/PQDD_0001/MQ36700.pdf.

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2

Harris, Douglas J. (Douglas Jeffrey). "Synthesis and characterization of poly[styrene-block-n-butyl methacrylate]." Thesis, Massachusetts Institute of Technology, 1998. http://hdl.handle.net/1721.1/28189.

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3

Cox-Nowak, Kayleigh. "Synthesis and cell adhesion studies of linear and hyperbranched poly(butyl methacrylate) and poly(t-butyl acrylate)." Thesis, University of Sheffield, 2013. http://etheses.whiterose.ac.uk/4819/.

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A library of polymers/oligomers with three different architectures was synthesised. Short chain, linear oligomers were produced by performing oxidative cleavage on a poly(butyl methacrylate-co-butadiene) polymer. Although butadiene is a gaseous monomer, it was found that careful control over the reaction conditions led to successful copolymerisation in an unpressurised reactor. Hyperbranched polymers of n-butyl methacrylate and t-butyl acrylate were synthesised by RAFT polymerisation with 4-vinylbenzyl-pyrrolecarbodithioate (CTA1) and 4-vinylbenzyl dithiobenzoate (CTA2). A variety of analytica

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4

Emiliani, Laura. "Raft miniemulsion (co)polymerization of methyl methacrylate and n-butyl acrylate." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2015. http://amslaurea.unibo.it/8606/.

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This thesis work is part of a larger synthesis project about alkyd resins from natural sources, copolymerized with methyl acrylate and n-butyl acrylates, which wil be used for coatings purpose. The aim is to control the copolymerization of methyl acrylate and n-butyl acrylate in RAFT miniemulsion. The research was divided into three parts. First the homopolymerization of methyl methacrylate and n-butyl acrylate was studied by varying different parameters such as the amount of surfactant, the amount of initiator, pH, and especially the RAFT agent. Then two macro RAFT agents were synthesized, a

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5

De, Vries Andrew Robert. "The effect of monosaccharide reducing sugars on the atom transfer radical polymerization of n-butyl methacrylate and methyl methacrylate." Thesis, Stellenbosch : Stellenbosch University, 2001. http://hdl.handle.net/10019.1/52519.

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Thesis (MSc)--Stellenbosch University, 2001<br>ENGLISH ABSTRACT: The effect of various organic reducing agents, in the. form of monosaccharide reducing sugars, on the rate of atom transfer radical polymerization (ATRP) of n-butyl methacrylate and methyl methacrylate is reported in this study. The addition of the reducing sugars has a positive effect on the rate of ATRP. Up to 100% increase in the rate of polymerization was recorded, in some cases. These organic reducing agents have little effect on the molecular weight and molecular weight distribution of the polyin-butyl methacrylate) a

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6

Zwolak, Grzegorz Chemical Sciences &amp Engineering Faculty of Engineering UNSW. "Catalytic chain transfer polymerisation in C02-expanded monomers." Awarded by:University of New South Wales. Chemical Sciences & Engineering, 2009. http://handle.unsw.edu.au/1959.4/43548.

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Experimental data on the solubility of CO2 in methyl methacrylate (MMA) and butyl methacrylate (BMA) are reported at temperatures from 308 to 333 K and pressures in the range of 1 to 10 MPa. The corresponding measurements of the volumetric expansion of the liquid phase are also presented. The solubility data are correlated with the Peng-Robinson equation of state using two interaction parameters. Solubilities of CO2 as high as 80 mol% can be attained in both monomers in the range of pressure considered. A near-linear relationship is observed between pressure and liquid-phase composition. The P

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7

Lucente, Ana Glaucia Bogalhos 1984. "Síntese e caracterização de poli (metacrilato de metila-co-metacrilato de butila) para aplicação odontológica." [s.n.], 2015. http://repositorio.unicamp.br/jspui/handle/REPOSIP/266043.

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Orientador: Leila Peres<br>Tese (doutorado) - Universidade Estadual de Campinas, Faculdade de Engenharia Química<br>Made available in DSpace on 2018-08-26T22:00:36Z (GMT). No. of bitstreams: 1 Lucente_AnaGlauciaBogalhos_D.pdf: 2114033 bytes, checksum: ddc1d7f9bcfcce3f7ddfd258b22465d3 (MD5) Previous issue date: 2015<br>Resumo: A falta de um material que viabilize a confecção de uma prótese dentária em um menor número de etapas, economizando tempo e facilitando a vida dos pacientes foi a maior motivação para o desenvolvimento desta tese que se baseia na patente BR n. PI 0602107-7 A: Conjuntos

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8

Lacey, David John. "Controlled synthesis of poly(n-butyl methacrylate)s for diffussion studies by ultra violet microscopy." Thesis, University of Sussex, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.358199.

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9

Bizet, Boris. "Design of Waterborne Isocyanate-free Poly(Hydroxy Urethane)s – Poly(Butyl Methacrylate) Hybrids via Miniemulsion and Properties of the Cast Films." Thesis, Bordeaux, 2020. http://www.theses.fr/2020BORD0019.

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L’objectif de cette these consiste au développement de polymères hybrides en dispersion aqueuse composés de poly(hydroxy uréthane)s – PHUs – issus d’huile végétale, et de poly(méthacrylate de butyle) – PolyBMA. La synthèse de bis-carbonates cycliques issus d’acides gras, ainsi que leur comportement en polymérisation en masse avec des diamines également issues d’acides gras, ont été étudiés dans un premier temps. Il a été montré que la structure du bis-carbonate cyclique influence la microstructure du poly(hydroxy uréthane) formé ainsi que les propriétés des poly(hydroxy uréthane)s résultants.

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10

Leamen, Michael. "Kinetic Investigation and Modelling of Multi-Component Polymer Systems with Depropagation." Thesis, University of Waterloo, 2005. http://hdl.handle.net/10012/885.

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The phenomenon of depropagation or reverse polymerization for multicomponent polymerizations has been studied in detail. The monomer Alpha-Methyl Styrene (AMS) has been copolymerized with Methyl Methacrylate (MMA) and Butyl Acrylate (BA) at temperatures ranging from 60oC to 140oC and the kinetics have been studied in the form of propagation/cross propagation and depropagation parameters. There have been multiple attempts with varying amounts of success in the past to determine the kinetic parameters for depropagating systems including work by Lowry and Wittmer as well as other modelling

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11

Poole, Joyleen. "Functional Oligo(butyl methacrylates) : Synthesis and Cytocompatibility." Thesis, University of Sheffield, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.499970.

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12

Fang, Yuan. "Étude de l'élaboration de nano-particules élastomères et application de celles-ci en tant qu'agents renforçants pour le poly(acide lactique)." Thesis, Université de Lorraine, 2012. http://www.theses.fr/2012LORR0192/document.

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Le poly (acide lactique) (PLA), est un polymère synthétisé à partir de ressources renouvelables, qui est l'objet de beaucoup d'études à l'heure actuelle mais qui souffre d'une faible résistance au choc. Le but de ce travail est de rechercher des pistes permettant la préparation d'un matériau à base de PLA avec une résistance au choc améliorée tout en minimisant la perte de résistance à la traction. Les travaux présentés ici ont étudié le rôle de nanoparticules élastomères de poly (acrylate de butyle) (PBA) chargées de laponite (LRD) (PBA-LRD) ainsi que de nanocomposites coeur-écorce (PBA-LRD)/

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13

Williams, Matthew J. P. "Studies into the control of morphology in methyl methacrylate:n-butyl acrylate latices." Thesis, Lancaster University, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.387429.

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14

Lu, Hung-Chi, and 呂鴻基. "Miniemulsion copolymerization of methyl methacrylate and butyl acrylate." Thesis, 2007. http://ndltd.ncl.edu.tw/handle/07740553057115128418.

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碩士<br>國立臺灣大學<br>材料科學與工程學研究所<br>95<br>The object of this study was to prepare poly(MMA / BA) latex by miniemulsion polymerization. Water insoluble dye (Blue 70) is added in the reaction mixture to investigate the nucleation mechanism during the polymerization. In addition, conversion, fractional conversion, DSC, colloid diameter and zeta potential data were used to investigate the relationship between monomers and particle nucleation mechanism. Besides, Ostwald ripening effect, creaming line and phase separation were used to discuss monomer droplet stability. It is found that empirical equation

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15

Huang, Dao-Hong, and 黃道泓. "Photoresponsive actuators containing poly(n-butyl methacrylate) and chromophore." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/79cqdw.

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16

LIU, CHIA-WEI, and 劉佳威. "Mixed monolayers of modified Polystyrene with Poly(iso-butyl methacrylate)." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/52258740321486925287.

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碩士<br>國立聯合大學<br>化學工程學系碩士班<br>104<br>The study investigated mixed monolayers containing different molecular weight (100,000 g/mol、150,000 g/mol) of Monocarboxylation terminal polystyrene (MPS)、Dicarboxylation terminal polystyrene (DPS) and Poly(iso-butyl methacrylate) (PiBMA). To probe into the basic characteristics of the monolayers by measuring surface pressure-area per molecule(π-A) isotherm、relaxation curves and oscillation curve behavior at three different temperatures(20℃、30℃、40℃). Furthermore, we use the equation to simulate the nucleation and growth model during the relaxation process o

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17

Lee, Kuan-Hui, and 李冠慧. "Synthesis and Characterization of Poly(butyl acrylate-methyl methacrylate)/polyaniline." Thesis, 2004. http://ndltd.ncl.edu.tw/handle/25185704402612812082.

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碩士<br>國立臺灣大學<br>材料科學與工程學研究所<br>92<br>This work is to synthesize complex copolymer of poly (butylacrylate- methyl methacrylate)/polyaniline. By using the method of two-step emulsion polymerization with P(BA-MMA) as core and PANI as shell. First step was to prepare P(BA-MMA) core latex particles from soapless emulsion polymerization. The degree of crosslinking in polymers was controlled by the conc. of crosslinking agent. Second step was to prepare the core-shell latex particles, Poly(BA-MMA)/PANI. The surfactant, SDS was fed into the core emulsion, following by feeding of aniline monomer. A

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18

FOWLER, CANDACE IRENE. "Emulsion Polymerization Using Switchable Surfactants." Thesis, 2011. http://hdl.handle.net/1974/6753.

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The work presented herein focuses on expanding the use of CO2-triggered switchable surfactants in emulsion polymerization of hydrophobic and hydrophilic monomers. Bicarbonate salts of the following compounds were employed as surfactants in the emulsion polymerization of styrene, methyl methacrylate (MMA) and/or butyl methacrylate (BMA): N’-hexadecyl-N,N-dimethylacetamidine (1a), N’-dodecyl N,N-dimethylacetamidine (2a) and N’-(4-decylphenyl)-N,N-dimethylacetamidine (3a). A systematic study of the effects of surfactant and initiator concentrations and solids content on the resulting particle siz

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19

Ming-FuWu and 吳明福. "Preparation of Poly(methyl methacrylate-co-butyl acrylate) Core-Shell Type Rubber." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/23376109102075110096.

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20

Yen, Che-Wei, and 顏哲偉. "Preparation and Property Studies ofPoly(butyl methacrylate-co-styrene)-Clay Nanocomposite Foams via Physical Foaming Process." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/07137155113563991608.

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碩士<br>中原大學<br>化學研究所<br>94<br>Abstract In this study, the organophilic clay used as intercalation agent was prepared by cation exchange method, which is a reaction occurred between the sodium cation of MMT clay and quaternary alkylammonium ions of hexadecyltrimethylammonium bromide. As a typical procedure for the preparation of nanocomposite systems with 0.5, 1.0, 3.0 wt-% clay, an appropriate amount of organophilic clay was first suspended in BMA-St monomer to proceed bulk polymerization. At the end of polymerization, the PBS/clay nanocomposite materials were thus obtained. Subsequently, a

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21

Krishnan, Sitaraman. "Effects of agitation in emulsion polymerization of n-Butyl methacrylate and its copolymerization with N-methylol acrylamide /." Diss., 2002. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3073982.

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22

Pollard, Michael Anthony. "The disorder -to -order phase transition in poly(styrene-block-n-butyl methacrylate): The effect of pressure." 2001. https://scholarworks.umass.edu/dissertations/AAI3027242.

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The effect of hydrostatic pressure on the lower disorder-to-order transition (LDOT) in poly(d-styrene-block-n-butyl methacrylate) having symmetric and asymmetric block lengths was investigated by in situ small-angle neutron scattering (SANS). Currently, linear diblock copolymers having styrenic and methacrylic monomers are the only systems that display a thermally accessible phase transition from the disordered homogeneous melt to the ordered microphase-separated state upon heating. The location of this phase transition was mapped as a function of temperature and pressure by analyzing one dime

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23

Chang, Yih-Her, and 張義和. "Sulfonated Tetracarboxylic Polyester (SMTAPE) Emulsifier：Synthesis, Surfactant Characteristics, and Studies on The Emulsion Polymerization of Butyl Methacrylate/Styrene Monomer." Thesis, 1999. http://ndltd.ncl.edu.tw/handle/02331666243821373135.

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博士<br>國立清華大學<br>化學工程學系<br>87<br>A novel polymeric emulsifier， SSIPM modified tetracarboxylic acid terminated polyester (SMTAPE)was prepared by end-capping sulfopolyester polyol with TMA in this study. The surface characteristics of SMTAPE， the optimum hydrophobic length of SMTAPE for the emulsion polymerization of PBMA， the nucleation mechanism and the surface area occupied by a SMTAPE molecule on a polymer latex particle at room temperatuve were studied by analyzing the surfactant characteristics， the reaction kinetic and the stability of the latices， the consumption of SMTAPE emulsifier duri

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24

Cox-Nowak, K., Ohood Al-Yamani, Colin A. Grant, N. H. Green, and Stephen Rimmer. "Poly(n-butyl Methacrylate) with Primary Amine End Groups for Supporting Cell Adhesion and Proliferation of Renal Epithelial Cells." 2017. http://hdl.handle.net/10454/11542.

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Yes<br>Polymer coatings that support epithelial cell culture have been developed. Ozonolysis and subsequent work up of poly(butyl methacrylate-co-butadiene) copolymers is used to form oligomers with carboxylic acid end groups, which are then further reacted with diamines to provide poly(butyl methacrylate)s with primary amine end groups. The polymers are cast as films and used as cell culture substrates for human dermal fibroblasts and human renal epithelial cells. Fibroblast and epithelial cells adhere and proliferate on acid functional materials but on amine functional films epithelial cells

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25

Butler, Mark James. "Design and in vivo evaluation of the angiogenic potential of a poly(butyl methacrylate-co-methacrylic acid) tissue engineering scaffold." 2005. http://link.library.utoronto.ca/eir/EIRdetail.cfm?Resources__ID=370091&T=F.

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26

Morick, Joachim. "Kinetik von Atom-Transfer Radikalischen Polymerisationen bis zu hohen Drücken." Doctoral thesis, 2012. http://hdl.handle.net/11858/00-1735-0000-000D-F052-2.

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