Academic literature on the topic 'C(sp2)−H Alkylation'

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Journal articles on the topic "C(sp2)−H Alkylation"

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Manna, Madhu Sudan, and Santanu Mukherjee. "Organocatalytic Enantioselective Formal C(sp2)–H Alkylation." Journal of the American Chemical Society 137, no. 1 (2015): 130–33. http://dx.doi.org/10.1021/ja5117556.

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Sarkar, Rahul, and Santanu Mukherjee. "Iridium-catalyzed enantioselective olefinic C(sp2)–H allylic alkylation." Chemical Science 12, no. 8 (2021): 3070–75. http://dx.doi.org/10.1039/d0sc06208a.

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The first iridium-catalyzed enantioselective allylic alkylation of an olefinic C(sp<sup>2</sup>)–H bond – that of an α,β-unsaturated carbonyl compound, is developed in cooperation with Lewis base catalysis.
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Zhu, Ru-Yi, Jian He, Xiao-Chen Wang, and Jin-Quan Yu. "Ligand-Promoted Alkylation of C(sp3)–H and C(sp2)–H Bonds." Journal of the American Chemical Society 136, no. 38 (2014): 13194–97. http://dx.doi.org/10.1021/ja508165a.

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Gustafson, Jeffrey, Andrew Dinh, Ryan Noorbehesht, et al. "Toward a Catalytic Atroposelective Synthesis of Diaryl Ethers Through C(sp2)–H Alkylation with Nitroalkanes." Synlett 29, no. 16 (2018): 2155–60. http://dx.doi.org/10.1055/s-0037-1609581.

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We report studies toward a small-molecule-catalytic approach to access atropisomeric diaryl ethers that proceeds through a C(sp2)–H alkylation using nitroalkanes as the alkyl source. A quaternary ammonium salt derived from quinine, containing a sterically hindered urea at the C-9 position, was found to effect atroposelective C(sp2)–H alkylation with moderate to good enantioselectivities across several naphthoquinone-containing diaryl ethers. Products could then be isolated in &gt;95:5 er after one round of trituration. For several substrates that were evaluated, we obtained nitroethylated prod
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Sarkar, Rahul, and Santanu Mukherjee. "Correction: Iridium-catalyzed enantioselective olefinic C(sp2)–H allylic alkylation." Chemical Science 12, no. 8 (2021): 3076. http://dx.doi.org/10.1039/d1sc90022f.

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Zhao, Yating, and Wujiong Xia. "Photochemical C–H bond coupling for (hetero)aryl C(sp2)–C(sp3) bond construction." Organic & Biomolecular Chemistry 17, no. 20 (2019): 4951–63. http://dx.doi.org/10.1039/c9ob00244h.

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This review highlights the recent advances in photochemical (hetero)aryl C(sp<sup>2</sup>)–C(sp<sup>3</sup>) bond construction via C–H bond coupling such as (hetero)arylation of C(sp<sup>3</sup>)–H bonds and alkylation of (hetero)aryl C(sp<sup>2</sup>)–H bonds.
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Singh, Swati, Neha Dagar, and Sudipta Raha Roy. "Photoinduced ligand to metal charge transfer enabling cerium mediated decarboxylative alkylation of quinoxalin-2(1H)-ones." Chemical Communications 58, no. 23 (2022): 3831–34. http://dx.doi.org/10.1039/d2cc00840h.

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Photo-induced decarboxylative alkylation utilizing an inexpensive cerium catalyst has been discussed. Here, we utilized unactivated carboxylic acids for the regiospecific alkylation of the C(sp2)–H bond of heterocycles.
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Manna, Madhu Sudan, and Santanu Mukherjee. "ChemInform Abstract: Organocatalytic Enantioselective Formal C(sp2)-H Alkylation." ChemInform 46, no. 27 (2015): no. http://dx.doi.org/10.1002/chin.201527029.

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Catellani, Marta, Federica Cugini, and Domenico Tiefenthaler. "New pathways of site selective aromatic alkylation of palladium complexes: fragmentation to arenes vs. ring closure to hexahydromethano-fluorenes or -phenanthrenes." Canadian Journal of Chemistry 79, no. 5-6 (2001): 742–51. http://dx.doi.org/10.1139/v01-047.

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Dimeric arylbicycloheptylpalladium halide complexes of type 1 undergo selective alkylation at the aromatic site by reaction with allyl, styryl, and benzyl bromides (RBr) via hexahydromethanopalladafluorenes (2). Ring closure of the resulting palladium complex (7) on sp2 and sp3 C-H bonds of a suitable R group then occurs with formation of hexahydromethanophenanthrene or hexahydromethanofluorene derivatives. Alternatively, substituted arenes derived from bicycloheptene deinsertion are formed. In some cases the latter can be obtained in substantial amounts when methyl isonicotinate is used as li
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Bertho, Sylvain, Ismaël Dondasse, Pascal Retailleau, Cyril Nicolas та Isabelle Gillaizeau. "β-C(sp2)–H alkylation of enamides using xanthate chemistry". New Journal of Chemistry 44, № 17 (2020): 7129–41. http://dx.doi.org/10.1039/d0nj01209b.

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Dissertations / Theses on the topic "C(sp2)−H Alkylation"

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Rousseaux, Sophie. "Palladium-Catalyzed C(sp2)-C(sp3) Bond Formation." Thèse, Université d'Ottawa / University of Ottawa, 2012. http://hdl.handle.net/10393/23058.

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Palladium-catalyzed reactions for carbon-carbon bond formation have had a significant impact on the field of organic chemistry in recent decades. Illustrative is the 2010 Nobel Prize, awarded for “palladium-catalyzed cross couplings in organic synthesis”, and the numerous applications of these transformations in industrial settings. This thesis describes recent developments in C(sp2)-C(sp3) bond formation, focusing on alkane arylation reactions and arylative dearomatization transformations. In the first part, our contributions to the development of intramolecular C(sp3)-H arylation reactions
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Nekkanti, Yelha Phani Kumar. "Ruthenium(II) biscarboxylate-Catalyzed C(sp2)-H and C(sp3)-H Functionalizations by Chelation Assistance." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2016. http://hdl.handle.net/11858/00-1735-0000-002B-7CCA-E.

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Tirler, Carina. "Carboxylate-Assisted Ruthenium(II)-Catalyzed C-H Alkylation and Alkenylation." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2015. http://hdl.handle.net/11858/00-1735-0000-0023-9666-0.

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Crisenza, Giacomo Ercole Martino. "Strategies for selective C-H alkylation and alkenylation of arenes." Thesis, University of Bristol, 2017. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.730852.

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Okumura, Shogo. "Studies on Site-selective C-H Alkylation of Arenes with Alkenes." Kyoto University, 2019. http://hdl.handle.net/2433/242514.

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Obenhuber, Andreas H. [Verfasser]. "Investigation into the chelate assisted activation of non-strained C(sp2)-C(sp2) single bonds using group 8, 9 and 10 transition metal complexes / Andreas H. Obenhuber." München : Verlag Dr. Hut, 2011. http://d-nb.info/1011441535/34.

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Haffemayer, Benjamin. "Development of novel amine-directed Pd(II)-catalysed sp2 and sp3 C-H bond functionalisation processes." Thesis, University of Cambridge, 2013. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.607792.

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Schaal, Petra [Verfasser]. "Palladiumkatalysierte C(sp2)–H-Funktionalisierung : neue Strategien zur selektiven Synthese disubstituierter planar chiraler [2.2]Paracyclophane / Petra Schaal." Aachen : Hochschulbibliothek der Rheinisch-Westfälischen Technischen Hochschule Aachen, 2013. http://d-nb.info/1042548846/34.

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Hofmann, Nora. "Carboxylate-Assisted Ruthenium-Catalyzed C-H Bond meta-Alkylations and Oxidative Annulations." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2013. http://hdl.handle.net/11858/00-1735-0000-0014-D4A4-1.

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Wiest, Johannes Markus [Verfasser]. "Synthesis of Pyrroles and their Application in C-H Alkylation Chemistry / Johannes Markus Wiest." München : Verlag Dr. Hut, 2016. http://d-nb.info/112252482X/34.

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Books on the topic "C(sp2)−H Alkylation"

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McDonald, Stacey L. Copper-Catalyzed Electrophilic Amination of sp2 and sp3 C−H Bonds. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-38878-6.

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Eftekhari-Sis, Bagher. Aromatic C(sp2)−H Dehydrogenative Coupling Reactions. CRC Press, 2019. http://dx.doi.org/10.1201/9780429327957.

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Eftekhari-Sis, Bagher. Aromatic C(sp2)¿h Dehydrogenative Coupling Reactions. Taylor & Francis Group, 2019.

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Eftekhari-Sis, Bagher. Aromatic C(sp2)�h Dehydrogenative Coupling Reactions. Taylor & Francis Group, 2021.

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McDonald, Stacey L. Copper-Catalyzed Electrophilic Amination of sp2 and sp3 C-H Bonds. Springer, 2016.

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McDonald, Stacey L. Copper-Catalyzed Electrophilic Amination of sp2 and sp3 C−H Bonds. Springer, 2018.

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McDonald, Stacey L. Copper-Catalyzed Electrophilic Amination of Sp2 and Sp3 C−H Bonds. Springer London, Limited, 2016.

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Book chapters on the topic "C(sp2)−H Alkylation"

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Khalymbadzha, Igor A., Ramil F. Fatykhov, and Oleg N. Chupakhin. "Functionalization of Aromatic N-Heterocycles via C(sp2)–H/C(sp2)–H CDC Reactions." In Heterocycles via Cross Dehydrogenative Coupling. Springer Singapore, 2019. http://dx.doi.org/10.1007/978-981-13-9144-6_2.

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Kakiuchi, Fumitoshi, and Naoto Chatani. "Ruthenium-Catalyzed Reactions via sp CH, sp2 CH, sp3 CH, and CHalogen Bond Activations." In Ruthenium in Organic Synthesis. Wiley-VCH Verlag GmbH & Co. KGaA, 2005. http://dx.doi.org/10.1002/3527603832.ch9.

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Li, Bin, and Pierre H. Dixneuf. "Ruthenium(II)-Catalysed sp2 C–H Bond Functionalization by C–C Bond Formation." In Ruthenium in Catalysis. Springer International Publishing, 2014. http://dx.doi.org/10.1007/3418_2014_85.

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Jean-Gérard, Ludivine, Rodolphe Jazzar, and Olivier Baudoin. "CH Bond Alkylation (Including Hydroarylation of Alkenes)." In Metal-Catalyzed Cross-Coupling Reactions and More. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527655588.ch19.

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Shang, Rui. "Iron-Catalyzed Directed C(sp2)–H Bond Functionalization with Organoboron Compounds." In Springer Theses. Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-3193-9_11.

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Bruneau, Christian, and Pierre H. Dixneuf. "Ruthenium(II)-Catalysed Functionalisation of C–H Bonds with Alkenes: Alkenylation versus Alkylation." In C-H Bond Activation and Catalytic Functionalization I. Springer International Publishing, 2015. http://dx.doi.org/10.1007/3418_2015_134.

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Bruneau, Christian, and Pierre H. Dixneuf. "Erratum to: Ruthenium(II)-Catalysed Functionalisation of C–H Bonds with Alkenes: Alkenylation versus Alkylation." In C-H Bond Activation and Catalytic Functionalization I. Springer International Publishing, 2015. http://dx.doi.org/10.1007/3418_2015_150.

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Dixneuf, Pierre H., and Jean-François Soulé. "Functionalization of C(sp2)–H Bonds of Arenes and Heteroarenes Assisted by Photoredox Catalysts for the C–C Bond Formation." In Organometallics for Green Catalysis. Springer International Publishing, 2018. http://dx.doi.org/10.1007/3418_2018_22.

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Zhao, Da. "Synthesis of Carborane-Functionalized Heterocycles: Dearomative [2 + 2] Cycloaddition and sp2 C–H Insertion Reaction." In Functionalization of Carborane via Carboryne Intermediates. Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-1569-4_3.

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Dixneuf, Pierre H., and Jean-François Soulé. "Correction to: Functionalization of C(sp2)–H Bonds of Arenes and Heteroarenes Assisted by Photoredox Catalysts for the C–C Bond Formation." In Organometallics for Green Catalysis. Springer International Publishing, 2018. http://dx.doi.org/10.1007/3418_2018_25.

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Conference papers on the topic "C(sp2)−H Alkylation"

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Wang, Xueqiang, Joan G. Donaire, and Ruben Martin. "Metal-Free sp2 and sp3 C-H Functionalization/C-O Bond Forming Reaction." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013815132216.

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Costa, Roberta L. da, and Simon J. Garden. "Phenanthridine derivatives via palladium catalyzed intramolecular functionalization of C(sp2)-H bonds." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013819134214.

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Gallardo-Donaire, Joan, and Ruben Martin. "Cu-catalyzed Mild C(sp2)-H Functionalization Assisted by Carboxylic Acids En Route to Hydroxylated Arenes." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013618124023.

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Davison, Evan, Jessica Otto, Sandeep Kumar, and Randy Maglinao. "Production of Branched Esters via Continuous Alkylation of Fatty Acid Methyl Esters over Montmorillonite and h-zsm5 Catalysts." In 2022 AOCS Annual Meeting & Expo. American Oil Chemists' Society (AOCS), 2022. http://dx.doi.org/10.21748/ezak5028.

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Abstract: Lignocellulosic and waste from the food industry offers a sustainable way to produce alternative transportation fuel and provide fiber and biomaterial. Thermochemical processes can depolymerize lignin into its phenolic monomers which can be upgraded to aromatic hydrocarbons. Fatty acids from food wastes have functional groups to accommodate selective synthesis of chemicals. These characteristics could be utilized as sustainable high-value additive products for fuels and lubricating oils. In the present study, an effective lubricity additive was synthesized via continuous alkylation o
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