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Journal articles on the topic 'Carbazol'

Author: Grafiati

Published: 4 June 2021

Last updated: 13 February 2022

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1

Luparello, Claudio, Ilenia Cruciata, Andreas C. Joerger, et al. "Genotoxicity and Epigenotoxicity of Carbazole-Derived Molecules on MCF-7 Breast Cancer Cells." International Journal of Molecular Sciences 22, no. 7 (2021): 3410. http://dx.doi.org/10.3390/ijms22073410.

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The carbazole compounds PK9320 (1-(9-ethyl-7-(furan-2-yl)-9H-carbazol-3-yl)-N-methylmethanamine) and PK9323 (1-(9-ethyl-7-(thiazol-4-yl)-9H-carbazol-3-yl)-N-methylmethanamine), second-generation analogues of PK083 (1-(9-ethyl-9H-carbazol-3-yl)-N-methylmethanamine), restore p53 signaling in Y220C p53-mutated cancer cells by binding to a mutation-induced surface crevice and acting as molecular chaperones. In the present paper, these three molecules have been tested for mutant p53-independent genotoxic and epigenomic effects on wild-type p53 MCF-7 breast adenocarcinoma cells, employing a combinat

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2

Sridharan, Makuteswaran, and Karnam J. R. Prasad. "Syntheses of Substituted Furo- and Pyrano-[2,3-a]carbazoles from 2-Cinnamoyl-1-hydroxycarbazoles." Zeitschrift für Naturforschung B 63, no. 9 (2008): 1112–16. http://dx.doi.org/10.1515/znb-2008-0916.

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Reaction of 2-cinnamoyl-1-hydroxycarbazoles 2a - d, with phenacyl bromide, mercuric acetate and H2O2/NaOH under different reaction conditions yielded 2-benzoyl-3-styryl-furo[2,3-a]carbazoles 3a-d, 2-benzylidene-furo[2,3-a]carbazol-3(10H)-ones 4a - d and 3-hydroxy-2-phenylpyrano- [2,3-a]carbazol-4(11H)-ones 5a - d, respectively.

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3

Prabakaran, Kumaresan, and Karnam Jayaramapillai Rajendra Prasad. "Synthesis of biogenetically possible 3-substituted pyrano-[2,3-a]carbazoles." Journal of Chemical Research 2009, no. 10 (2009): 619–22. http://dx.doi.org/10.3184/030823409x12523375431104.

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3-Substituted pyrano[2,3- a]carbazol-2(11 H)-ones have been synthesised by the reaction of 1-hydroxy-carbazole-2-carbaldehyde with malononitrile, ethyl cyanoacetate, Meldrum's acid, (carbethoxymethylene)triphenylphosphorane, ethyl benzoylacetate and phenylacetonitrile.

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4

Murali, Karunanidhi, Hazel A. Sparkes, Baskaran Vijaya Pandiyan, and Karnam Jayarampillai Rajendra Prasad. "Synthesis, photophysical properties and DFT analysis of highly substituted pyrido carbazole-based “push pull” chromophores." New Journal of Chemistry 41, no. 16 (2017): 8242–52. http://dx.doi.org/10.1039/c7nj00643h.

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A series of new fluorescent pyrido[2,3-a]carbazole derivatives were synthesized based on a four component reaction with 2,3,4,9-tetrahydro-1H-carbazol-1-one, malononitrile, and aryl/heteroaryl aldehydes in presence of NaOEt.

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5

Wantulok, Jakub, Daniel Swoboda, Jacek E. Nycz, et al. "Direct Amination of Nitroquinoline Derivatives via Nucleophilic Displacement of Aromatic Hydrogen." Molecules 26, no. 7 (2021): 1857. http://dx.doi.org/10.3390/molecules26071857.

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The vicarious nucleophilic substitution of hydrogen (VNS) reaction in electron-deficient nitroquinolines was studied. Properties of all new products have been characterized by several techniques: MS, HRMS, FTIR, GC-MS, electronic absorption spectroscopy, and multinuclear NMR. The structures of 4-chloro-8-nitroquinoline, 8-(tert-butyl)-2-methyl-5-nitroquinoline, 9-(8-nitroquinolin-7-yl)-9H-carbazole and (Z)-7-(9H-carbazol-9-yl)-8-(hydroxyimino)quinolin-5(8H)-one were determined by single-crystal X-ray diffraction measurements. The 9-(8-nitroquinolin-7-yl)-9H-carbazole and (Z)-7-(9H-carbazol-9-y

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6

Konidena, Rajendra Kumar, Kyung Hyung Lee, and Jun Yeob Lee. "Molecular design featuring carbazole-decorated 15H-diindolo[2,3-b:1′,2′,3′-lm]carbazole for improved efficiency and lifetime of thermally activated delayed fluorescence emitters." Journal of Materials Chemistry C 8, no. 7 (2020): 2491–99. http://dx.doi.org/10.1039/c9tc05855a.

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7

Ravikumar, Krishnan, Balasubramanian Sridhar, Jagadeesh Babu Nanubolu, Venkatasubramanian Hariharakrishnan, and Bandi Venugopal Rao. "Frovatriptan salts of aliphatic carboxylic acids." Acta Crystallographica Section C Crystal Structure Communications 69, no. 4 (2013): 428–35. http://dx.doi.org/10.1107/s0108270113005878.

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The interaction of the antimigraine pharmaceutical agent frovatriptan with acetic acid and succinic acid yields the salts (±)-6-carbamoyl-N-methyl-2,3,4,9-tetrahydro-1H-carbazol-3-aminium acetate, C14H18N3O+·C2H3O2−, (I), (R)-(+)-6-carbamoyl-N-methyl-2,3,4,9-tetrahydro-1H-carbazol-3-aminium 3-carboxypropanoate monohydrate, C14H18N3O+·C4H5O4−·H2O, (II), and bis[(R)-(+)-6-carbamoyl-N-methyl-2,3,4,9-tetrahydro-1H-carbazol-3-aminium] succinate trihydrate, 2C14H18N3O+·C4H4O42−·3H2O, (III). The methylazaniumyl substitutent is oriented differently in all three structures. Additionally, the amide grou

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8

Kim, Jae Eun, Jun Hee Kim, Wonbo Sim, and Jai Young Lee. "9-[3-(Carbazol-9-yl)-5-methylphenyl]carbazole." Acta Crystallographica Section E Structure Reports Online 69, no. 6 (2013): o828. http://dx.doi.org/10.1107/s1600536813011641.

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9

Kumar, V., J. Reisch, and A. Wickramasinghe. "Glycomaurin and Glycomaurrol, New Carbazole Alkaloids From Glycosmis mauritiana (Rutaceae) Bark." Australian Journal of Chemistry 42, no. 8 (1989): 1375. http://dx.doi.org/10.1071/ch9891375.

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The stem bark of Glycosmis mauritiana contained the acridone alkaloids noracronycine and des-N- methylacronycine, and two new carbazole alkaloids, 3,3,10-trimethyl-3,7-dihydropyrano[2,3-c] carbazole (glycomaurin) and 6-methyl-4-(3′-methylbut-2′-enyl)carbazol-3-ol (glycomaurrol), whose structures were confirmed by synthesis and by cyclization to dihydroglycomaurin respectively. Glycomaurin has a ring system which has not been previously found in nature.

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10

Asiri, Abdullah M., Osman I. Osman, Saad H. Al-Thaqafy та Salman A. Khan. "Optical properties and fluorescence quenching of carbazole containing (D–π–A) push–pull chromophores by silver nanoparticles: a detailed insight via an experimental and theoretical approach". RSC Advances 7, № 14 (2017): 8402–14. http://dx.doi.org/10.1039/c6ra25741k.

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(4Z)-4-[(9-Ethyl-9H-carbazol-3-yl)methylidene]-2-phenyl-1,3-oxazol-5(4H)-one (ECPO) was prepared by the one-pot multi-component reaction of 9-ethyl-9H-carbazole-3-carbaldehyde, hippuric acid, anhydrous sodium acetate and acetic anhydride under microwave irradiation.

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11

Wang, Hui, Wen-Mo Liu, Jun Zhang, Jie-Ying Wu, and Yu-Peng Tian. "A tetranuclear organotin compound consisting of a core of three fused Sn2O2rings." Acta Crystallographica Section C Structural Chemistry 70, no. 2 (2014): 185–88. http://dx.doi.org/10.1107/s2053229614000758.

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The crystal structure of the tetranuclear organotin compound 1,1,3,3,5,5,7,7-octabutyl-7-((E)-2-cyano-3-{9-[2-(2-methoxyethoxy)ethyl]-9H-carbazol-3-yl}prop-2-enoyloxy)-4,8-dimethyl-2,4,6,8-tetroxa-1,3,5,7-tetrastannatricyclo[4.2.0.02,5]oct-3-yl (E)-2-cyano-3-{9-[2-(2-methoxyethoxy)ethyl]-9H-carbazol-3-yl}prop-2-enoate, [Sn4(C4H9)8(C21H19N2O4)2(CH3O)2(μ3-O)2], consists of a core of three fused Sn2O2rings. The central ring consists of two Sn atoms each coordinated by twon-butyl chains, two μ3-bridging O atoms and one μ2-bridging methanolate O atom. The peripheral Sn2O2rings consist of one of the

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12

Choi, Kyung Hyun, Jae Min Kim, Won Jae Chung, and Jun Yeob Lee. "Effects of Substitution Position of Carbazole-Dibenzofuran Based High Triplet Energy Hosts to Device Stability of Blue Phosphorescent Organic Light-Emitting Diodes." Molecules 26, no. 9 (2021): 2804. http://dx.doi.org/10.3390/molecules26092804.

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High triplet energy hosts were developed through the modification of the substitution position of carbazole units. Two carbazole-dibenzofuran-derived compounds, 9,9′-(dibenzo[b,d]furan-2,6-diyl)bis(9H-carbazole) (26CzDBF) and 4,6-di(9H-carbazol-9-yl)dibenzo[b,d]furan (46CzDBF), were synthesized for achieving high triplet energy hosts. In comparison with the reported hole transport type host, 2,8-di(9H-carbazol-9-yl)dibenzo[b,d]furan (28CzDBF), 26CzDBF and 46CzDBF maintained high triplet energy over 2.95 eV. The device performances of the hosts were evaluated with electron transport type host,

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13

Çiçek, Baki, Merve Çağlı, Remziye Tülek, and Ali Teke. "Synthesis and optical characterization of bipod carbazole derivatives." Heterocyclic Communications 26, no. 1 (2020): 148–56. http://dx.doi.org/10.1515/hc-2020-0111.

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AbstractIn this study, some new biscarbazole derivatives were synthesized for the purpose of being used in OLED technologies and related areas. The following compounds: {1,2-bis(2-(3,6-diphenyl-9H-carbazole-9-yl) ethoxy)ethane (C-1), bis[2-(2-(3,6- diphenyl-9H-carbazole-9-yl) ethoxy)etyl]ether (C-2), bis[2-(2-(3,6-di(naphthalene-1-yl)-9H-carbazol-9-yl)ethoxy)etyl]ether (C-3) and bis [2-(2-(3,6-di(naphthalene-2-yl)-9H-carbazol-9-yl)ethoxy) ethyl]ether (C-4) were synthesized by Suzuki-Miyaura Cross Coupling reactions. The structural properties of the synthesized compounds were characterized by F

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14

Lifshits, Liubov M., Bruce C. Noll, and Jeremy K. Klosterman. "A supramolecular approach for designing emissive solid-state carbazole arrays." Chemical Communications 51, no. 58 (2015): 11603–6. http://dx.doi.org/10.1039/c5cc03515e.

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Reactions of 5-(9H-carbazol-9-yl)-isophthalate and metal salts provide laminar metal organic frameworks (MOFs) wherein interlayer interactions of the pendant carbazoles engender extended aromatic stacks or non-stacked structures with enhanced solid-state emission.

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15

Bordei Telehoiu, Alexandra T., Diana C. Nuță, Miron T. Căproiu, et al. "Design, Synthesis and In Vitro Characterization of Novel Antimicrobial Agents Based on 6-Chloro-9H-carbazol Derivatives and 1,3,4-Oxadiazole Scaffolds." Molecules 25, no. 2 (2020): 266. http://dx.doi.org/10.3390/molecules25020266.

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In this paper, we aimed to exploit and combine in the same molecule the carbazole and the 1,3,4-oxadiazole pharmacophores, to obtain novel carprofen derivatives, by using two synthesis pathways. For the first route, the following steps have been followed: (i) (RS)-2-(6-chloro-9H-carbazol-2-yl)propanonic acid (carprofen) treatment with methanol, yielding methyl (RS)-2-(6-chloro-9H-carbazol-2-yl)propanoate; (ii) the resulted methylic ester was converted to (RS)-2-(6-chloro-9H-carbazol-2-yl)propane hydrazide (carprofen hydrazide) by treatment with hydrazine hydrate; (iii) reaction of the hydrazid

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16

Tang, Huai Jun, Li Ying Wei, Qian Luo, Xian Wang Shen, and Chang Li Liu. "Effect of 1-(9-Ethyl-9H-carbazol-3-yl)-4,4,4-trifluorobutane-1,3-dione on Properties of Luminescent Europium (III) Complexes." Advanced Materials Research 834-836 (October 2013): 215–20. http://dx.doi.org/10.4028/www.scientific.net/amr.834-836.215.

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In order to understand the effect of β-diketone ligands containing carbazole group on luminescent europium (III) complexes, a series of europium (III) complexes (Phen)Eu (DBM)3-nLnwith 1-(9-Ethyl-9H-carbazol-3-yl)-4,4,4-trifluorobutane-1,3-dione (L) were synthesized and investigated contrastively (n = 0, 1, 2, 3; DBM: dibenzoylmethane; Phen: 1,10-phenanthroline). The results show amorphous nature, glass transition temperatures and luminescent intensity can be improved obviously by 1-(9-ethyl-9H-carbazol-3-yl)-4,4,4-trifluorobutane-1,3-dione, at the same time, their thermal decomposition temper

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17

Karaaslan, Cigdem, Hande Gurer-Orhan, Sibel Suzen, et al. "Behaviour of 9-Ethyl-9H-carbazole Hydrazone Derivatives Against Oxidant Systems." Croatica chemica acta 92, no. 1 (2019): 87–94. http://dx.doi.org/10.5562/cca3481.

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Antioxidants are helpful in prevention of several diseases related with oxidative stress including neurodegenerative disorders. In recent studies, carbazoles were given proof of promising antioxidant activities. In this article, 9-ethyl-9H-carbazole hydrazone derivatives were synthesized, characterized and their in vitro antioxidant activity and possible cytotoxic effects were investigated. Furthermore, protective effect of the synthesized derivatives against amyloid β-induced damage in PC12 neuronal cells was examined by using MTT assay. The newly synthesized carbazoles were found to have rad

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18

Ma, Qing Yu, Rui Fang Guan, Guo Zhong Li, and Deng Xu Wang. "Design, Synthesis and Photophysical Properties of Novel Tetrahedral Carbazole-Bridged Silanes with Benzimidazole Groups." Applied Mechanics and Materials 268-270 (December 2012): 23–27. http://dx.doi.org/10.4028/www.scientific.net/amm.268-270.23.

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Two novel luminescent molecules based on tetrahedral silicon core with the carbazole and benzimidazole groups, bis(6-(1H-benzo[d]imidazol-1-yl)-9-ethyl-9H-carbazol-3-yl)dimethylsilane (1) and bis(6-(1H-benzo[d]imidazol-1-yl)-9-ethyl-9H-carbazol-3-yl)diphenylsilane (2), were designed, synthesized and fully characterized by IR, 1H NMR, 13C NMR and elemental analysis. Thermal results show that these compounds have high thermal stability and glass-transition temperature (Tg). The results based on the photophysical properties and molecular calculations reveal that they are fluorescent with emission

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19

Lifshits, Liubov M., Varun Singh, Matthias Zeller, and Jeremy K. Klosterman. "Ethyl 4-(9H-carbazol-9-yl)benzoate: fivefold superstructure with ten crystallographically independent molecules refined from a twinned crystal." Acta Crystallographica Section C Structural Chemistry 72, no. 11 (2016): 901–9. http://dx.doi.org/10.1107/s2053229616015825.

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The photophysical properties of organic fluorophores are sensitive to the local sterics of the surrounding environment. Restriction of torsional motion in aggregates and crystals can give rise to enhanced emissive behavior.N-Aryl-substituted carbazoles serve an essential role as ubiquitous host matrices for organic light-emitting diodes, due to their large band gaps and high triplet energies, and so studies connecting photophysical behaviors with detailed crystallographic structural information are important. To elucidate the structural changes involved in the excited-state charge-transfer pro

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20

Golubeva, I. S., N. P. Yavorskaya, L. V. Ektova, et al. "ANTITUMOR ACTIVITY OF SOME DERIVATIVES OF INDOLO[2,3-A]CARBAZOLES N-GLYCOSIDES WITH XYLOSE CARBOHYDRATE RESIDUE." Russian Journal of Biotherapy 19, no. 4 (2020): 86–93. http://dx.doi.org/10.17650/1726-9784-2020-19-4-86-93.

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Introduction. The search for new antineoplastic agents in a series of indolo[2,3-a]-carbazole derivatives is an urgent and promising direction, since compounds with antitumor activity have been found in this class. In the chemical fusion laboratory, N.N. Blokhin National Medical Research Center оf the Ministry of Health of Russia has developed an original and effective method for the synthesis of glycosides of indolo[2,3-a]-pyrrolo[3,4-c]carbazoles, which makes it possible to synthesize derivatives of N-glycosides of indolo[2,3-a]carbazoles with different substituents in the heterocyclic parts

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21

Gruzdev, Matvey, Ulyana Chervonova, Arkadiy Kolker, et al. "Dendritic Iron(III) Carbazole Complexes: Structural, Optical, and Magnetic Characteristics." Materials 14, no. 18 (2021): 5445. http://dx.doi.org/10.3390/ma14185445.

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This paper focuses on the synthesis, structural characterization, and study of the optical, magnetic, and thermal properties of novel architectures combining metal ions as magnetoactive centers and photoactive blocks formed by carbazole units. For this purpose, a series of azomethine complexes of the composition [Fe(L)2]X (L = 3,6-bis[(3′,6′-di-tert-butyl-9-carbazol)-9-carbazol]benzoyloxy-4-salicylidene-N′-ethyl-N-ethylenediamine, X = NO3−, Cl−, PF6−) were synthesized by the reaction of metal salts with Schiff bases in a mixture of solvents. The UV–Vis absorption properties were studied in dic

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22

Jasztold-Howorko, Ryszard, Włodzimierz Doroszkiewicz, Gabriela Bugla-Płoskońska, Alain Croisy, and Daniele Carrez. "The Synthesis and Bioloqical Properties of a 1-(2-Methylpyridin-4-yl) Olivacine Derivative." Scientia Pharmaceutica 73, no. 3 (2005): 101–12. http://dx.doi.org/10.3797/scipharm.aut-05-09.

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Starting from 2-(6-methoxy-1-methyl-9H-carbazol-2-yl)ethylamine and 2-methylisonicotinic acid, 9-hydroxy-5,6-dimethyl-1-(2-methylpyridin-4-yl)-6H-pyrido[4,3-b]carbazole (5) was obtained. The new compound showed significant cytostatic activity for cultured L1210 cells and no inhibition of growth of the E. coli O56 strain was observed. The bactericidal activity of normal human serum against E. coli O56 was not affected by the examined compound 5 and its isomer 4.

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23

Guo, Huixia, Xiaohua Xi, Renxiang Yan та Xiaoquan Lu. "Theoretical study on the effect of different π-linker on the performance of sensitizer in carbazole-based dyes". Journal of Theoretical and Computational Chemistry 17, № 02 (2018): 1850019. http://dx.doi.org/10.1142/s0219633618500190.

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Derived from diarylamine sensitizer diphenyl-(7-pyridin-4-yl-9H-carbazol-2-yl)-amine (N13), a series of novel D[Formula: see text]A carbazole-based organic dye sensitizers with different [Formula: see text]-linkers were designed for searching more effective sensitizers in dye-sensitized solar cells (DSSCs) design. Optimized geometries, electronic structure, and other parameters, which can evaluate the performance of DSSCs effectively and intuitively, were theoretically calculated by density functional theory (DFT) and time-dependent DFT methods at the M06/6-31G(d,p) level. The results indicate

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24

Salifou, Alkassoum, Michael E. Johnson, and Dhanapalan Nagarathnam. "3-(Carbazol-2-yl)- and 3-(Carbazol-3-yl)-dl-alanines." Synthetic Communications 23, no. 17 (1993): 2435–42. http://dx.doi.org/10.1080/00397919308011129.

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25

Viktor, Milata, Kada Rudolf, and Lokaj Ján. "Carbazol-9-yl-methanol." Molbank 2004, no. 1 (2004): M354. http://dx.doi.org/10.3390/m354.

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Sridharan, Makuteswaran, Lucas K. Beagle, Matthias Zeller, and Karnam Jayarampillai Rajendra Prasad. "Syntheses of Pyrazolo-, Isoxazolo-, Pyrido- and Pyrimido-Carbazoles from 2-(3′,4′-Dimethoxybenzylidene)-2,3,4,9-Tetrahydrocarbazol-1-Ones." Journal of Chemical Research 2008, no. 10 (2008): 572–77. http://dx.doi.org/10.3184/030823408x361110.

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Mixed aldol condensation of 2,3,4,9-tetrahydrocarbazol-1-ones with 3,4-dimethoxybenzaldehyde (veratraldehyde) yielded 2-(3′,4′-dimethoxybenzylidene)-2,3,4,9-tetrahydrocarbazol-1-ones. These enones on reaction with hydrazine hydrate, hydroxylamine hydrochloride, malononitrile and guanidinium nitrate under different conditions yielded the corresponding pyrazolo[3,4-a]-, isoxazolo[3,4-a]-, pyrido[2,3-a]-, and pyrimido[4,5-a]-carbazoles respectively. The molecular and crystal structure of 2-(3′,4′-dimethoxybenzylidene)-2,3,4,9-tetrahydro-1H-carbazol-1-one resolved by single crystal X-ray diffracti

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27

Khadir Fall, Serigne Abdou, Saïd Achamlale, Younas Aouine, Asmae Nakkabi, Hassane Faraj, and Anouar Alami. "Diethyl [(4-{(9H-carbazol-9-yl)methyl}-1H-1,2,3-triazol-1-yl)(benzamido)methyl]phosphonate." Molbank 2020, no. 4 (2020): M1167. http://dx.doi.org/10.3390/m1167.

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The title compound, diethyl [(4-{(9H-carbazol-9-yl)methyl}-1H-1,2,3-triazol-1-yl)(benzamido)methyl]phosphonate, was synthesized with excellent yield and high regioselectivity through 1,3-dipolar cycloaddition reaction between the α-azido diethyl amino methylphosphonate and the heterocyclic alkyne, 9-(prop-2-yn-1-yl)-9H-carbazole. The cyclization reaction by “click chemistry” was carried out in a water/ethanol solvent mixture (50/50), in the presence of copper sulfate pentahydrate and catalytic sodium ascorbate. The characterization of the structure of the resulting 1,4-regioisomer was performe

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Krawczyk, Przemysław, Beata Jędrzejewska, Klaudia Seklecka, Joanna Cytarska, and Krzysztof Z. Łączkowski. "Effect of the Chloro-Substitution on Electrochemical and Optical Properties of New Carbazole Dyes." Materials 14, no. 11 (2021): 3091. http://dx.doi.org/10.3390/ma14113091.

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Carbazole derivatives are the structural key of many biologically active substances, including naturally occurring and synthetic ones. Three novel (E)-2-(2-(4-9H-carbazol-9-yl)benzylidene)hydrazinyl)triazole dyes were synthesized with different numbers of chlorine substituents attached at different locations. The presented research has shown the influence of the number and position of attachment of chlorine substituents on electrochemical, optical, nonlinear, and biological properties. The study also included the analysis of the use of the presented derivatives as potential fluorescent probes

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Sharma, Divyanshu, Nitin Kumar, and Devender Pathak. "Synthesis, characterization and biological evaluation of some newer carbazole derivatives." Journal of the Serbian Chemical Society 79, no. 2 (2014): 125–32. http://dx.doi.org/10.2298/jsc130123069s.

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A series of novel 5-((9H-carbazol-9-yl)methyl)-N-((substituted phenyl)(piperazin-1-yl)methyl)-1,3,4-oxadiazol-2-amine (4a-4o) derivatives was synthesized by starting with carbazole which on reaction with ethyl choloroacetate yielded ethyl 2-(9H-carbazole-9-yl)acetate (1), compound (1) on reaction with semicarbazide followed by cyclisation with sulphuric acid gave 5-((9H-carbazole-9-yl)-1,3,4-oxadiazol-2-amine (3) which through Mannich reaction with piperazine and a variety of aromatic aldehydes in the presence of acetic acid yielded the titled compounds (4a-4o). The structures of compounds wer

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30

Hsiao, Sheng-Huei, and Shu-Wei Lin. "Electrochemical synthesis of electrochromic polycarbazole films from N-phenyl-3,6-bis(N-carbazolyl)carbazoles." Polymer Chemistry 7, no. 1 (2016): 198–211. http://dx.doi.org/10.1039/c5py01407g.

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Ashok, Dongamanti, Sidda Ravi, Vijaya Lakshmi, and Arram Ganesh. "One-pot synthesis of carbazole based 3-hydroxy-4H-chromen-4-ones by modified Algar-Flynn-Oyamada reaction and their antimicrobial activity." Journal of the Serbian Chemical Society 80, no. 11 (2015): 1361–66. http://dx.doi.org/10.2298/jsc141203051a.

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A new series of 2-(9-ethyl-9H-carbazol-3-yl)-3-hydroxy-4Hchromen-4-ones have been synthesized from substituted 2-hydroxy acetophenones and 9-ethyl-9H-carbazole-3-carbaldehyde using NaOH and H2O2 by modified Algar-Flynn-Oyamada reaction. In this method flavonols are synthesized without isolating chalcones in good yields (70-82%). The structures of the compounds were established on the basis of 1H-NMR, 13CNMR, FT-IR and mass spectral and analytical data. All the compounds were evaluated for their antimicrobial activity against bacteria such as Staphylococus aureus, Bacillus subtilis, Escherichia

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32

Zaini, Muhamad Fikri, Ibrahim Abdul Razak, Wan Mohd Khairul та Suhana Arshad. "Structural, Hirshfeld and DFT studies of conjugated D–π–A carbazole chalcone crystal". Acta Crystallographica Section E Crystallographic Communications 76, № 3 (2020): 387–91. http://dx.doi.org/10.1107/s2056989020002054.

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A new conjugated carbazole chalcone compound, (E)-3-[4-(9,9a-dihydro-8aH-carbazol-9-yl)phenyl]-1-(4-nitrophenyl)prop-2-en-1-one (CPNC), C27H18N2O3, was synthesized using a Claisen–Schmidt condensation reaction. CPNC crystallizes in the monoclinic non-centrosymmetric space group Cc and adopts an s-cis conformation with respect to the ethylenic double bonds (C=O and C=C). The crystal packing features C—H...O and C—H...π interactions whose percentage contribution was quantified by Hirshfeld surface analysis. Quantum chemistry calculations including geometrical optimization and molecular electrost

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33

Zhong, Quanjie, Shenye Liu, Jiayi Zhu, et al. "Theoretical and experimental research on the third-order nonlinear optical properties of the N-6-hydroxy-hexyl-4-azophenyl-carbazol." Journal of Nonlinear Optical Physics & Materials 26, no. 02 (2017): 1750027. http://dx.doi.org/10.1142/s0218863517500278.

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The third-order nonlinear optical properties of the N-6-hydroxy-hexyl-4-azophenyl-carbazol have been investigated both theoretically and experimentally. Using Z-scan method with a femtosecond laser (440[Formula: see text]nm, 190[Formula: see text]fs), the third-order nonlinear optical properties of the N-6-hydroxy-hexyl-4-azophenyl-carbazol were determined. The second-order hyperpolarizability [Formula: see text] of the experiment result was found to be [Formula: see text][Formula: see text]esu. We have also calculated the second-order hyperpolarizability based on the sum-over-states (SOS) met

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34

Gu, Wei-Jin, Zi-Ting Lin, and Bing-Xiang Wang. "(9H-Carbazol-9-ylmethyl)diethylamine." Acta Crystallographica Section E Structure Reports Online 66, no. 12 (2010): o3245. http://dx.doi.org/10.1107/s1600536810047197.

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35

Lai, Wing In, Man Pan Leung, Pui Ying Choy, and Fuk Yee Kwong. "Sterically Hindered Amination of Aryl Chlorides Catalyzed by a New Carbazolyl-Derived P,N-Ligand-Composed Palladium Complex." Synthesis 51, no. 13 (2019): 2678–86. http://dx.doi.org/10.1055/s-0037-1611534.

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A family of 2-(9H-carbazol-9-yl)phenyl-based phosphine ligands were synthesized and their efficacy in promoting the steric hindered Buchwald–Hartwig amination was evaluated. In the presence of Pd(OAc)2 (0.03–1.0 mol%) associated with the newly developed a carbazolyl-derived phosphine ligand, the synthesis of tetra-ortho-substituted diarylamines proceeded smoothly with excellent product yields (up to 99%). A remarkable result was obtained even for the coupling of highly sterically congested 2,6-diisopropylaniline and hindered 2-chloro-1,3,5-triisopropylbenzene (96% isolated yield). A possible d

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36

Stalindurai, K., C. Ramalingan, B. Sridhar, and S. Selvanayagam. "Crystal structure of 9-butyl-3-(9-butyl-9H-carbazol-3-yl)-9H-carbazole." Acta Crystallographica Section E Structure Reports Online 70, no. 12 (2014): o1283—o1284. http://dx.doi.org/10.1107/s1600536814025367.

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In the title carbazole derivative, C32H32N2, the molecule resides on a crystallographic twofold axis, which runs through the central C—C bond. The carbazole ring system is almost planar, with a maximum deviation of 0.041 (1) Å for one of the ring-junction C atoms. The crystal packing is stabilized by C—H...π interactions only, which form aC(7) chain-like arrangement along [110] in the unit cell.

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37

SALIFOU, A., M. E. JOHNSON, and D. NAGARATHNAM. "ChemInform Abstract: 3-(Carbazol-2-yl)- and 3-(Carbazol-3-yl)-dl-alanines (V), (VII)." ChemInform 25, no. 40 (2010): no. http://dx.doi.org/10.1002/chin.199440138.

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38

Noland, Wayland E., Christopher D. Brown, Kenneth J. Tritch, and Andrew K. Schneerer. "Access to polycyclic carbazoles from ring-fused 2-(9H-carbazol-1-yl)anilines." Synthetic Communications 50, no. 9 (2020): 1388–95. http://dx.doi.org/10.1080/00397911.2020.1740739.

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39

Kumaran, T. Saravana, A. Prakasam, P. Vennila, S. Parveen Banu, and G. Venkatesh. "New Carbazole-Based Organic Dyes with Various Acceptors for Dye-Sensitized Solar Cells: Synthesis, Characterization, DSSCs Fabrications and DFT Study." Asian Journal of Chemistry 33, no. 7 (2021): 1541–50. http://dx.doi.org/10.14233/ajchem.2021.23197.

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The molecular configuration, synthesis and characterization of (E)-3-(6-bromo-9-phenyl-9H-carbazol- 3-yl)acrylic acid (BPA), (E)-3-(6-bromo-9-phenyl-9H-carbazol-3-yl)-2-cyanoacrylic acid (BPCA) and (E)-N′-((6-bromo-9-phenyl-9H-carbazol-3-yl)methylene)-2-cyanoacetohydrazide (BPCH) configured D-π-A sensitizers and the sensitizers are used in DSSCs. Dye molecules are described by FT-IR, NMR and UV-Vis analysis. The study shows that the non-planar structure of BPA, BPCA and BPCH can effectively slow down the aggregation and conjugation of the dye. Computed vibrational modes are compared with obser

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40

Kanakaraju, Devagi, Cherie A. Motti, Beverley D. Glass, and Michael Oelgemöller. "Photolysis and TiO2-catalysed degradation of diclofenac in surface and drinking water using circulating batch photoreactors." Environmental Chemistry 11, no. 1 (2014): 51. http://dx.doi.org/10.1071/en13098.

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Environmental context Diclofenac, a common non-steroidal anti-inflammatory drug, is not completely removed from surface and drinking water by conventional treatment methods. Consequently, this drug is present in the aquatic environment and has been subsequently linked to toxic effects on organisms. We show that photolysis and TiO2-catalysed degradation in circulating batch reactors efficiently results in diclofenac removal under a variety of conditions. These photochemical methods thus may lead to more effective water treatment processes. Abstract The occurrence of diclofenac (DCF) as an emerg

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Xie, Min-Hao, Pei Zou, Yong-Jun He, Ya-Ling Liu, and Biao Huang. "2-(Carbazol-9-yl)acetic acid." Acta Crystallographica Section E Structure Reports Online 65, no. 11 (2009): o2860. http://dx.doi.org/10.1107/s1600536809043463.

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42

Kishbaugh, T. L. S., Gordon W. Gribble, and Jerry P. Jasinski. "9-(Phenylsulfonyl)-9H-carbazol-2-ol." Acta Crystallographica Section E Structure Reports Online 63, no. 5 (2007): o2472—o2473. http://dx.doi.org/10.1107/s160053680701745x.

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43

Saritha, Rajendhiran, Sesuraj Babiola Annes, and Subburethinam Ramesh. "Metal-free, regioselective, visible light activation of 4CzIPN for the arylation of 2H-indazole derivatives." RSC Advances 11, no. 23 (2021): 14079–84. http://dx.doi.org/10.1039/d1ra02372a.

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44

Wu, Jing, Dongping Wang, Haolong Wang, Fan Wu, Xincheng Li, and Boshun Wan. "Facile synthesis of 5H-benzo[b]carbazol-6-yl ketones via sequential reaction of Cu-catalyzed Friedel–Crafts alkylation, iodine-promoted cyclization, nucleophilic substitution and aromatization." Org. Biomol. Chem. 12, no. 35 (2014): 6806–11. http://dx.doi.org/10.1039/c4ob00815d.

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45

Deacon, GB, CM Forsyth, and BM Gatehouse. "Organoamido- and Aryloxo-Lanthanoids. I. The Preparation and Characterization of Some Lanthanoid(II) Organoamides, and the X-Ray Crystal Structure of cis-Bis(Carbazol-9-Yl)Tetrakis(tetrahydrofuran)europium(II)." Australian Journal of Chemistry 43, no. 5 (1990): 795. http://dx.doi.org/10.1071/ch9900795.

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Reaction of carbazole ( Hcbz ) or 2-phenylindole ( Hpin ) with bis ( pentafluorophenyl )-ytterbium or -europium in tetrahydrofuran ( thf ) gives the complexes M( cbz )2( thf )4 (M = Yb or Eu ) or Yb (pin)2( thf )4. From treatment of lanthanoid metals with bis ( pentafluorophenyl )mercury and 2-phenylindole, 2,3,4,5-tetraphenylpyrrole ( Htpp ) or carbazole , the complexes M(pin)2( thf )4 (M = Yb , Eu or Sm ), M( tpp )2( thf )3 (M = Yb or Sm ) and Yb ( cbz )2( thf )4 have been isolated. Desolvation of M(pin)2( thf )4 under vacuum yields Yb (pin)2( thf ) and Sm (pin)2( thf )3. Oxidation of Sm (pi

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46

Olgaç, Remziye, Yasemin Baygu, Burak Yıldız, Yaşar Gök, Baybars Köksoy, and Mahmut Durmuş. "Synthesis, characterization and photochemical properties of metallo porphyrazines substituted with alkyl linked carbazole, benzoazepine and phenothiazine moieties." Journal of Porphyrins and Phthalocyanines 21, no. 09 (2017): 599–610. http://dx.doi.org/10.1142/s1088424617500596.

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Novel octa-phenotiazine, octa-benzoazepine and octa-carbazole substituted magnesium(II) (MgPz-I-III) and zinc(II) (ZnPz-I-III) porphyrazines were synthesized from 2,3-bis[6-(4a,10a-dihydro-phenothiazin-10-yl)-hexylsulfanyl]-but-2-enedinitrile (5), 2,3-bis [6-(4a,11a-dihydro-dibenzo[b,f]azepin-5-yl)-hexysulfan-yl]-but-2-enedinitrile (8) and 2,3-bis(6-carbazol-9-yl-hexylsulfanyl)-but-2-enedinitrile (10), respectively. These dinitrile derivatives 5, 8 and 10 were also prepared by the reaction of 1,2-dicyano-1,2-ethylenedithiolate di-sodium salt (4) with 10-(6-bromohexyl)-10H-phenothiazine (3), 5-

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47

Averkiev, Boris B., Iryna Davydenko, Xu Wang, Stephen Barlow, and Seth R. Marder. "Crystal structure of 5,6-bis(9H-carbazol-9-yl)benzo[c][1,2,5]thiadiazole: distortion from a hypothetical higher-symmetry structure." Acta Crystallographica Section C Structural Chemistry 73, no. 4 (2017): 319–24. http://dx.doi.org/10.1107/s2053229617003035.

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Nucleophilic substitution of F atoms in 5,6-difluorobenzo[c][1,2,5]thiadiazole (DFBT) for carbazole could be potentially interesting as a novel way of synthesizing building blocks for new conjugated materials for applications in organic chemistry. The crystal structures of 5,6-bis(9H-carbazol-9-yl)benzo[c][1,2,5]thiadiazole (DCBT), C30H18N4S, and its hydrate, C30H18N4S·0.125H2O, were investigated using single-crystal X-ray analysis. The hydrate contains two symmetry-independent DCBT molecules. The dihedral angles between the plane of the central benzothiadiazole fragment and that of the carbaz

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48

Zubatyuk, Roman I., Oleg I. Kharanenko, Oleg V. Shishkin, Vladimir I. Dulenko, and Alexander V. Kibalny. "1,2-Bis(carbazol-9-ylmethylene)-3,4-diphenylcyclobutane." Acta Crystallographica Section E Structure Reports Online 60, no. 2 (2004): o301—o302. http://dx.doi.org/10.1107/s1600536804001813.

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49

Öncüoğlu, Serkan, Nefise Dilek, Yavuz Ergün, and Tuncer Hökelek. "(4,9-Dimethyl-9H-carbazol-3-yl)methanol." Acta Crystallographica Section E Structure Reports Online 70, no. 3 (2014): o346—o347. http://dx.doi.org/10.1107/s1600536814003845.

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In the title compound, C15H15NO, the carbazole skeleton includes a methanol group at the 3-position. The indole ring system is almost planar [maximum deviation = 0.045 (2) Å]. In the crystal, O—H...O hydrogen bonds link the molecules into zigzag chains along theb-axis direction. There are weak C—H...π interactions within the chains and linking neighbouring chains forming sheets lying parallel to (001).

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50

Xie, Yu-Zhong, Jing-Yi Jin, and Xiao-Chun Qu. "Polymorph of 4-(carbazol-9-yl)benzonitrile." Acta Crystallographica Section E Structure Reports Online 68, no. 4 (2012): o1199. http://dx.doi.org/10.1107/s1600536812012457.

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The asymmetric unit of the title compound, C19H12N2, contains two independent molecules with a similar structure. In the two molecules, the dihedral angles between the carbazole ring system and the benzene ring are 47.9 (5) and 45.4 (4)°, similar to the value of 47.89 (6)° found in the previously reported structure [Saha & Samanta (1999).Acta Cryst.C55, 1299–1300]. In the crystal, there is a weak C—H...N hydrogen bond between the two independent molecules.

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