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Relevant bibliographies by topics / Carbenoid use in synthesis

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Academic literature on the topic 'Carbenoid use in synthesis'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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Journal articles on the topic "Carbenoid use in synthesis"

1

Cuevas-Yañez, Erick, Juan Manuel Serrano, Gloria Huerta, Joseph M. Muchowski, and Raymundo Cruz-Almanza. "Copper carbenoid mediated N-alkylation of imidazoles and its use in a novel synthesis of bifonazole." Tetrahedron 60, no. 42 (October 2004): 9391–96. http://dx.doi.org/10.1016/j.tet.2004.08.009.

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SATOH, Tsuyoshi. "Exploitation of the Chemistry of Magnesium Carbenoids and Their Use in Organic Synthesis." YAKUGAKU ZASSHI 129, no. 9 (September 1, 2009): 1013–23. http://dx.doi.org/10.1248/yakushi.129.1013.

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Haigh, David. "Rhodium carbenoid O-H insertion reactions with phenols; A facile method for the synthesis of trialkyl 2-aryloxyphosphonoacetates and their use in the preparation of 2-aryloxy-3-phenylpropanoates." Tetrahedron 50, no. 10 (March 1994): 3177–94. http://dx.doi.org/10.1016/s0040-4020(01)81116-9.

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HAIGH, D. "ChemInform Abstract: Rhodium Carbenoid O-H Insertion Reactions with Phenols; a Facile Method for the Synthesis of Trialkyl 2-Aryloxyphosphonoacetates and Their Use in the Preparation of 2-Aryloxy-3-phenylpropanoates." ChemInform 25, no. 29 (August 19, 2010): no. http://dx.doi.org/10.1002/chin.199429076.

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Matsumoto, Kozo, Yoshitaka Aoki, Koichiro Oshima, Kiitiro Utimoto, and Noorsaadah Abd Rahman. "Lithium carbenoids induced ring enlargement of silacyclobutane into 2-halo-1-silacyclopentane and its use in organic synthesis." Tetrahedron 49, no. 38 (September 1993): 8487–502. http://dx.doi.org/10.1016/s0040-4020(01)96257-x.

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MATSUMOTO, K., Y. AOKI, K. OSHIMA, K. UTIMOTO, and N. A. RAHMAN. "ChemInform Abstract: Lithium Carbenoids Induced Ring Enlargement of Silacyclobutane into 2- Halo-1-silacyclopentane and Its Use in Organic Synthesis." ChemInform 25, no. 2 (August 19, 2010): no. http://dx.doi.org/10.1002/chin.199402208.

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Ma, Xiaochu, Stefan M. Cooper, Fan Yang, Wenhao Hu, and Herman O. Sintim. "Alkaloid Synthesis via Carbenoid Intermediates." Current Organic Chemistry 20, no. 1 (October 26, 2015): 82–101. http://dx.doi.org/10.2174/1385272819666150810225759.

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8

Buck, Richard T., Paul A. Clarke, Diane M. Coe, Martin J. Drysdale, Leigh Ferris, David Haigh, Christopher J. Moody, Neil D. Pearson, and Elizabeth Swann. "The Carbenoid Approach to Peptide Synthesis." Chemistry - A European Journal 6, no. 12 (June 16, 2000): 2160–67. http://dx.doi.org/10.1002/1521-3765(20000616)6:12<2160::aid-chem2160>3.0.co;2-y.

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Chalifoux, Wesley A., and Rik R. Tykwinski. "Polyyne synthesis using carbene/carbenoid rearrangements." Chemical Record 6, no. 4 (2006): 169–82. http://dx.doi.org/10.1002/tcr.20081.

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Tezuka, Yasuyuki, Yasufumi Nakayama, Koh Ushizaka, and Kiyokazu Imai. "Carbenoid polycondensation. 2. Synthesis of unsaturated polyesters through the polycondensation of carbenoid intermediates." Macromolecules 26, no. 5 (September 1993): 921–25. http://dx.doi.org/10.1021/ma00057a007.

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Dissertations / Theses on the topic "Carbenoid use in synthesis"

1

Sheppard, A. "The use of carbenoids in #beta#-lactam synthesis." Thesis, University of Manchester, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.380525.

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Hrytsak, Michael D. "The use of rhodium carbenoid insertion reactions in organic synthesis." Thesis, University of Ottawa (Canada), 1987. http://hdl.handle.net/10393/21296.

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Babu, Suresh Dhandayutham. "Part~A. Synthesis of optically active alpha-substituted acids. Part~B. The use of rhodium carbenoid reactions in organic synthesis." Thesis, University of Ottawa (Canada), 1991. http://hdl.handle.net/10393/7955.

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Part A. Chapter 1. The Sharpless epoxidation product from E-4-phenyl-2-butene-1-ol and diethyl D-tartrate was converted into L-($-$)-phenylalanine in three steps. After completion of the above synthesis Sharpless published an extensive study of the synthesis of $\alpha$-amino acids via essentially the same route. Therefore the project was abandoned. Optically active 2-arylpropionic acids such as 2-phenylpropionic acid, 2-napthylpropionic acid, and 2-(4-isobutylphenyl)-propionic acid (Ibuprofen) were synthesized in two steps from Sharpless epoxidation products. Part B. Chapter 2. The synthesis of 4-carboethoxy-4,6-dihydro-thieno (3,4-b) thiophene 5,5-dioxide and 4-phenyl analogue, precursors to thiophene xylylenes, are reported. Attempts to trap the carboethoxy substituted xylylene with electron rich or electron poor dienophiles failed and only dimers were produced. In contrast, the phenyl substituted xylylene gave moderate yields of Diels-Alder adducts in trapping experiments with dienophiles such as dimethylacetylene dicarboxylate, dimethyl fumarate, and benzoquinone. Chapter 3. Several additional examples of a conceptually new route to 1,3-dihydrobenzothiophene-2,2-dioxides from $\alpha$-diazo-$\beta$-sulfonyl esters via a formal rhodium carbenoid insertion into an aromatic C-H bond is reported. Our attempts to extend the scope of this reaction to include insertion into furan derivatives failed. We obtained very unusual furan ring opened products. When the same rhodium carbenoid reactions were carried out with $\alpha$-diazo-$\beta$-ketoamides, 2-hydroxy-3-acetylindole derivatives were formed. Chapter 4. In order to gain insight into the rhodium carbenoid reaction mechanism, the diazo precursors to 1,3-dihydrobenzothiophene-2,2-dioxide, 2-indanone, and 2-tetralone which were mono substituted at the ortho position of the aromatic ring were synthesized and the hydrogen/deuterium isotope effects were measured. The observed isotope effects ranged from 3.3-4.9. Furthermore, deuterium NMR indicated that scrambling had occurred during the cyclization step. These data have been interpreted to show that these rhodium carbenoid reactions should be considered as electrophilic aromatic substitution reactions.

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Bégis, Guillaume. "Studies on the generation and use of functionalised organozinc carbenoids for the synthesis of aminocyclopropanes and related congeners." Thesis, University College London (University of London), 2004. http://discovery.ucl.ac.uk/1446526/.

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The present thesis describes a range of studies on the generation and reactivity of organozinc carbenoid species possessing adjacent nitrogen functionality for the preparation of aminocyclopropanes and related congeners. This thesis opens with two distinct introductory reviews. The first one focuses on the description of the different general methods already available for the synthesis of aminocyclopropanes. The second one is concerned with the generation and reactivity of organozinc carbenoids encountered in the literature. The results and discussion chapter firstly describes the successful generation of an organozinc carbenoid from an acetal moiety contiguous to a nitrogen atom of a simple cyclic amide using a mixture of zinc amalgam and chlorotrimethylsilane. This new organometallic species is found to undergo cyclopropanation reactions with a range of alkenes to yield amidocyclopropanes. Subsequent studies directed towards the design of carbenoid precursors which can lead to the preparation of primary aminocyclopropanes are then discussed. A method for the synthesis of chiral protected aminocyclopropanes in two steps from their corresponding alkenes is described. An investigation of the preparation of N-substituted cyclopropyl amino alcohols and acids is presented. From this study, an N-substituted cyclopropyl glycine derivative is prepared. Finally, this thesis discusses the attempted palladium-catalysed cross-coupling reactions between amino cyclopropylsilanes and aryl iodides and the successful Tamao-Fleming oxidation of the carbon-silicon bond of vicinal amino cyclopropylsilanols to give the corresponding amino cyclopropanols. The thesis terminates with a full description of the experimental procedures used and the compounds prepared.

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Adero, Philip O. "Heterocycle Synthesis via Rhodium (II)-Catalyzed Azido Carbenoid Cyclization." Youngstown State University / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1348595887.

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Tuckett, Mark William. "Applications of zirconium chemistry to organic synthesis." Thesis, University of Southampton, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.310484.

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Main, Calver A. "Novel titanium carbenoid reagents : diversity orientated synthesis of indoles and spirocycles." Thesis, University of Glasgow, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.502007.

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A new synthetic strategy for the preparation of a 96-member library of 2,5-disubstituted indoles involving traceless cleavage from resin is presented. A boronate-bearing titanium alkylidene was prepared and used to convert 8 resin-bound esters into immobilised enol ethers. Cleavage from resin in mild acid with concomitant cyclisation yielded boronate-bearing indoles. Capitalising on the immobilised boronate functionality in enol ethers, Suzuki cross-coupling reactions were performed with 12 aryl iodides to give a 96-member library after cleavage from resin with mild acid, 79 members of the library were confirmed to be 2,5-disubstituted indoles. Also reported is the use of tertiary butyllithium and 2-isopropoxy-4,4,i,5-tetramethyl-l,3,2-dioxaborolane to convert an aiyl bromide into an arylboronate in the presence of a dithiane, with simultaneous reduction of an aryl azide to an amine. In a similar route, we synthesised dithiane for the attempted conversion of resin-bound esters into functionalised 7-azaindoles after cleavage from resin. Further investigation with a different ortho-nitrogen protecting group may yet prove successful.

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Krowiak, Steven A. "Synthesis of cyclic ethers : a tandem carbenoid insertion and ylide rearrangement strategy." Thesis, University of Nottingham, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.387858.

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Pavlyuk, Oksana M. "Synthesis of Nitrogen-Containing Heterocycles via Carbenoid Insertion/Ring-Closing Metathesis Sequence." Ohio University / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1303761092.

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Swain, Nigel Alan. "C H insertion approach to the total synthesis of furofuran lignans and their heterocyclic analogues." Thesis, University of Southampton, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.288472.

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Books on the topic "Carbenoid use in synthesis"

1

Aloui, Mahmoud. Use of carbohydrates in pseudo-sugar synthesis. Salford: University of Salford, 1992.

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2

Kobayashi, Shū, ed. Lanthanides: Chemistry and Use in Organic Synthesis. Berlin, Heidelberg: Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/3-540-69801-9.

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3

Schore, Jennifer. Synthesis of program interventions to reduce hospital use. Princeton, NJ: Mathematica Policy Research, Inc., 1992.

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4

Markle, R. A. Synthesis of aromatic polyimides for use as solid sorbents. Research Triangle Park, N.C: U.S. Environmental Protection Agency, Research and Development, Environmental Monitoring Systems Laboratory, 1986.

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5

Edward, Park Rolla, United States. Agency for Health Care Policy and Research., and Rand Corporation, eds. Variations in the use of cesarean sections: Literature synthesis. Santa Monica, CA: RAND, 1995.

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6

Voaden, Mark Jonathan. The use of silicon substituted dienes in organic synthesis. Manchester: University of Manchester, 1995.

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7

United States. Federal Highway Administration, Parsons, Brinckerhoff, Quade & Douglas, and United States. Environmental Protection Agency, eds. Land use forecasting case studies: A synthesis and summary. [Washington, D.C.?]: U.S. Dept of Transportation, Federal Highway Administration, 2000.

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8

Medeiros, Edna Faria de. The use of pyrylium salts in natiral product synthesis. Norwich: University of East Anglia, 1993.

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9

Markle, R. A. Synthesis of aromatic polyimides for use as solid sorbents. Research Triangle Park, N.C: U.S. Environmental Protection Agency, Research and Development, Environmental Monitoring Systems Laboratory, 1986.

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10

Nezhat, Lida. Use of sulphoxides for the asymmetric synthesis of saturated heterocycles. Salford: University of Salford, 1988.

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Book chapters on the topic "Carbenoid use in synthesis"

1

Illés, Éva. "Synthesis." In Understanding Context in Language Use and Teaching, 68–79. 1. | New York: Routledge, 2020.: Routledge, 2020. http://dx.doi.org/10.4324/9780429274589-4.

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2

Bolton, M. "Synthesis and conclusions." In Conservation and the Use of Wildlife Resources, 253–69. Dordrecht: Springer Netherlands, 1997. http://dx.doi.org/10.1007/978-94-009-1445-2_15.

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3

Barton, D. H. R. "The Functionalization of Saturated Hydrocarbons by Gif Chemistry. Part 1. Use of Superoxide and of Hydrogen Peroxide. Part 2. Use of t-Butylhydroperoxide (TBHP)." In Chemical Synthesis, 589–99. Dordrecht: Springer Netherlands, 1996. http://dx.doi.org/10.1007/978-94-009-0255-8_26.

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Howse, P. E., I. D. R. Stevens, and O. T. Jones. "Synthesis of pheromones." In Insect Pheromones and their Use in Pest Management, 226–45. Dordrecht: Springer Netherlands, 1998. http://dx.doi.org/10.1007/978-94-011-5344-7_7.

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5

Kurup, Pran, and Taher Abbasi. "Design Re-Use using DesignWare." In Logic Synthesis Using Synopsys®, 263–78. Boston, MA: Springer US, 1995. http://dx.doi.org/10.1007/978-1-4757-2370-0_8.

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Kurup, Pran, and Taher Abbasi. "Design Re-use Using DesignWare." In Logic Synthesis Using Synopsys®, 263–82. Boston, MA: Springer US, 1997. http://dx.doi.org/10.1007/978-1-4613-1455-4_10.

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Gao, Jinlong, and Jianglong Chen. "Demystifying the Inequality in Urbanization in China Through the Lens of Land Use." In Spatial Synthesis, 257–83. Cham: Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-52734-1_16.

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Kjær, Niels Them, and Henning Lund. "Synthetic use of Electroinduced Hydrogen Abstraction." In Novel Trends in Electroorganic Synthesis, 431–34. Tokyo: Springer Japan, 1998. http://dx.doi.org/10.1007/978-4-431-65924-2_128.

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9

Huang, Ying-Ting, Jinn-Jong Wong, Cheng-Jyun Huang, Chia-Ling Li, and Guang-Way Bill Jang. "2,5-Furandicarboxylic Acid Synthesis and Use." In Chemicals and Fuels from Bio-Based Building Blocks, 191–216. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2016. http://dx.doi.org/10.1002/9783527698202.ch8.

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Kim, Charles, and Girish Krishnan. "Synthesis through Use of Building Blocks." In Handbook of Compliant Mechanisms, 123–46. Oxford, UK: John Wiley & Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118516485.ch9.

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Conference papers on the topic "Carbenoid use in synthesis"

1

Rebić, Teodora, Lazar Dražeta, and Borivoje Đokić. "THE USE OF SELECTION METHODS IN HOSPITALITY." In Synthesis 2015. Belgrade, Serbia: Singidunum University, 2015. http://dx.doi.org/10.15308/synthesis-2015-672-674.

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Bašić, Ana, and Predrag Popović. "Risk assessment methodology in the use of mobile phones." In Synthesis 2015. Belgrade, Serbia: Singidunum University, 2015. http://dx.doi.org/10.15308/synthesis-2015-232-237.

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Knežević, Goranka, Isidora Ljumović, and Vladan Pavlović. "Access to financial sources in Serbia: the use of mezzanine instruments." In Synthesis 2015. Belgrade, Serbia: Singidunum University, 2015. http://dx.doi.org/10.15308/synthesis-2015-419-422.

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Radivojević, Vladimir, and Tanja Stanišić. "The Use of the Internet in Direct Marketing: Advantages, Results and Limitations." In Synthesis 2015. Belgrade, Serbia: Singidunum University, 2015. http://dx.doi.org/10.15308/synthesis-2015-603-605.

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Choi, Wonshik, S. Jeong, and S. Kang. "Optical Imaging with the Use of a Scattering Lens." In Signal Recovery and Synthesis. Washington, D.C.: OSA, 2014. http://dx.doi.org/10.1364/srs.2014.stu2f.1.

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Flynn, David S., Douglas A. Vechinski, Bradley T. Blume, Abinash C. Dubey, and Ned H. Witherspoon. "Minefield image synthesis tool." In SPIE's 1995 Symposium on OE/Aerospace Sensing and Dual Use Photonics, edited by Abinash C. Dubey, Ivan Cindrich, James M. Ralston, and Kelly A. Rigano. SPIE, 1995. http://dx.doi.org/10.1117/12.211318.

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Bhaskararao, P., S. J. Eady, and J. H. Esling. "Use of triphones for demisyllable-based speech synthesis." In [Proceedings] ICASSP 91: 1991 International Conference on Acoustics, Speech, and Signal Processing. IEEE, 1991. http://dx.doi.org/10.1109/icassp.1991.150390.

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Mundhenk, T. Nathan, David R. Gerwe, and Yang Chen. "High Precision Object Segmentation and Tracking for use in Super Resolution Video Reconstruction." In Signal Recovery and Synthesis. Washington, D.C.: OSA, 2011. http://dx.doi.org/10.1364/srs.2011.smb2.

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Pascazio, Vito, and Giancarlo Ferraiuolo. "On the Use of Gaussian Markov Random Fields in Microwave Tomography: the Quadratic Case." In Signal Recovery and Synthesis. Washington, D.C.: OSA, 2001. http://dx.doi.org/10.1364/srs.2001.smc3.

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Bergman, Elad, Adi Sheinfeld, Sharon Gilead, and Avishay Eyal. "The use of optical waveform synthesis in photoacoustic measurements." In 2008 IEEE 25th Convention of Electrical and Electronics Engineers in Israel (IEEEI). IEEE, 2008. http://dx.doi.org/10.1109/eeei.2008.4736598.

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Reports on the topic "Carbenoid use in synthesis"

1

Klaehn, John R. Synthesis of Phosphazenes for Use as Vaccine Adjuvants. Office of Scientific and Technical Information (OSTI), October 2011. http://dx.doi.org/10.2172/1027852.

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Christe, K. O., W. W. Wilson, A. Vij, V. Vij, and J. A. Sheehy. Use of Fluorine Chemistry for the Synthesis of Polynitrogen Compounds. Fort Belvoir, VA: Defense Technical Information Center, April 2000. http://dx.doi.org/10.21236/ada409532.

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Kouvetakis, John. The use of Novel Precursor Chemistry for Synthesis of Superhard Materials. Fort Belvoir, VA: Defense Technical Information Center, January 2001. http://dx.doi.org/10.21236/ada392127.

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Chen, Erdong, Jennifer Brown, and Andrew Tarko. Use of Barriers in Rural Open Road Conditions—A Synthesis Study. Purdue University, October 2012. http://dx.doi.org/10.5703/1288284314670.

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Ayres, Benjamin. Use of Soybean Lecithin in Shape Controlled Synthesis of Gold Nanoparticles. Portland State University Library, January 2000. http://dx.doi.org/10.15760/etd.628.

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Kaya, Abidin. Potential Use of Tire Rubber and Ebonite in Asphalt: Synthesis Study. West Lafayette, IN: Purdue University, 1992. http://dx.doi.org/10.5703/1288284314201.

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Kolpakov, Alexander. Synthesis of Research on the Use of Idle Reduction Technologies in Transit. Tampa, FL: University of South Florida, October 2015. http://dx.doi.org/10.5038/cutr-nctr-rr-2014-05.

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Kabalka, G. W. Synthesis and in-vivo detection of boronated compounds for use in BNCT. Office of Scientific and Technical Information (OSTI), February 1991. http://dx.doi.org/10.2172/6296640.

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Kabalka, G. Synthesis and in-vivo detection of boronated compounds for use in BNCT. Office of Scientific and Technical Information (OSTI), January 1992. http://dx.doi.org/10.2172/5376288.

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Kabalka, G. Synthesis and in-vivo detection of boronated compounds for use in BNCT. Office of Scientific and Technical Information (OSTI), April 1990. http://dx.doi.org/10.2172/7151243.

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