Academic literature on the topic 'Carbohydrate derivatives of ketones'

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Journal articles on the topic "Carbohydrate derivatives of ketones"

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Henderson, Alexander S., John F. Bower, and M. Carmen Galan. "Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis." Org. Biomol. Chem. 12, no. 45 (2014): 9180–83. http://dx.doi.org/10.1039/c4ob02056a.

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Versatile syntheses of C2-linked and C<sub>2</sub>-symmetric carbohydrate-based NHC·HCls from functionalised amino-carbohydrate derivatives are reported. The corresponding Rh complexes were evaluated in asymmetric hydrosilylation of ketones.
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Maram, Lingaiah, and Fujie Tanaka. "Mannich Reactions of Carbohydrate Derivatives with Ketones To Afford Polyoxy-Functionalized Piperidines." Organic Letters 21, no. 4 (2019): 1165–69. http://dx.doi.org/10.1021/acs.orglett.9b00105.

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SHARIPOV, B. T., A. N. DAVYDOVA, and F. A. VALEEV. "SYNTHESIS OF CARBOHYDRATE BLOCKS FOR 2'.3'-DIDEOXYNUCLEOSIDES FROM LEVOGLUCOSENONE." Izvestia Ufimskogo Nauchnogo Tsentra RAN, no. 4 (December 11, 2020): 33–39. http://dx.doi.org/10.31040/2222-8349-2020-0-4-33-39.

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Nucleosides containing five-membered deoxy-carbohydrates in the glycosidic part, such as zalcitabine, 2'.3'-dideoxyuridine, stavudine, are widely used in acquired immunodeficiency syndrome (AIDS). A number of 2'.3'-dideoxynucleosides is an effective inhibitor of type-1 immunodeficiency virus (HIV-1) in humans. Levoglucosenone and cyrene (dihydrolevoglucosenone) are unique compounds, optically pure ketones of carbohydrate nature obtained from renewable bio-raw materials and available by pyrolysis of any cellulose-containing materials. They are promising carbohydrates for the production of modif
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Kim, Chang Soo, Yanuar Philip Wijaya, Kevin J. Smith, and Elod L. Gyenge. "Electrocatalytic Upgrading of Biomass Fast Pyrolysis Oil." ECS Meeting Abstracts MA2022-01, no. 27 (2022): 2452. http://dx.doi.org/10.1149/ma2022-01272452mtgabs.

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Attempts to electrocatalytically upgrade bio-oil have been made in recent years. Mostly, the ECH (Electrocatalytic Hydrogenation) experiments of bio-oil were done using fixed bed electrode configurations at room temperatures and low current densities (&lt;100 cm-2). The main goal was to demonstrate the viability of ECH as a bio-oil stabilization strategy, mainly through reduction of carbonyl contents (aldehydes and ketones) which could cause polymerization. High temperature may promote condensation polymerization of fast pyrolysis oil, low-temperature ECH is therefore considered a promising ap
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Bella, Maroš, Bohumil Steiner, Vratislav Langer, and Miroslav Koóš. "Reaction of selected carbohydrate aldehydes with benzylmagnesium halides: benzyl versus o-tolyl rearrangement." Beilstein Journal of Organic Chemistry 10 (August 20, 2014): 1942–50. http://dx.doi.org/10.3762/bjoc.10.202.

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The Grignard reaction of 2,3-O-isopropylidene-α-D-lyxo-pentodialdo-1,4-furanoside and benzylmagnesium chloride (or bromide) afforded a non-separable mixture of diastereomeric benzyl carbinols and diastereomeric o-tolyl carbinols. The latter resulted from an unexpected benzyl to o-tolyl rearrangement. The proportion of benzyl versus o-tolyl derivatives depended on the reaction conditions. Benzylmagnesium chloride afforded predominantly o-tolyl carbinols while the application of benzylmagnesium bromide led preferably to the o-tolyl carbinols only when used in excess or at higher temperatures. Th
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Park, Min-Kyung, Soyeon Lee, and Young-Suk Kim. "Effects of pH and Osmotic Changes on the Metabolic Expressions of Bacillus subtilis Strain 168 in Metabolite Pathways including Leucine Metabolism." Metabolites 12, no. 2 (2022): 112. http://dx.doi.org/10.3390/metabo12020112.

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Bacillus subtilis is often exposed to diverse culture conditions with the aim of improving hygiene or food quality. This can lead to changes in the volatile metabolite profiles related to the quality of fermented foods. To comprehensively interpret the associated metabolic expressions, changes in intracellular primary and extracellular secondary volatile metabolites were investigated by exposing B. subtilis to an alkaline pH (BP, pH 8.0) and a high salt concentration (BS, 1 M). In particular, B. subtilis was cultured in a leucine-enriched medium to investigate the formation of leucine-derived
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Lee, Sang, Young Hwang, Moon Kim, Myung Chung, and Young-Suk Kim. "Comparison of Volatile and Nonvolatile Compounds in Rice Fermented by Different Lactic Acid Bacteria." Molecules 24, no. 6 (2019): 1183. http://dx.doi.org/10.3390/molecules24061183.

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The production of rice-based beverages fermented by lactic acid bacteria (LAB) can increase the consumption of rice in the form of a dairy replacement. This study investigated volatile and nonvolatile components in rice fermented by 12 different LABs. Volatile compounds of fermented rice samples were analyzed using gas chromatography-mass spectrometry (GC-MS) combined with solid-phase microextraction (SPME), while nonvolatile compounds were determined using gas chromatography-time-of-flight/mass spectrometry (GC-TOF/MS) after derivatization. The 47 identified volatile compounds included acids,
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Silva, Jadyellen Rondon e., Anderson de Oliveira Souza, Italo Curvelo dos Anjos, Geilly Mara Silva de Pádua, Lucas Campos Curcino Vieira, and Bibiana Mozzaquatro Gai. "Evaluation of chalcones derivatives in lipid peroxidation reduction induced by Fe2+/EDTA in vitro." Research, Society and Development 12, no. 1 (2023): e16012139541. http://dx.doi.org/10.33448/rsd-v12i1.39541.

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Reactive oxygen species (ROS), when in excess, cause damage to biomolecules (DNA, lipids, carbohydrates, and proteins), which are related to several pathologies. There is a growing study of substances that act to inhibit or reduce the action of these ROS. Chalcones are aromatic ketones with a naturally occurring and easily synthesized α,β-unsaturated system. In this work, we investigated the in vitro protective action of a new class of chalcones functionalized by the thiobarbituric acid reactive substances (TBARS) assay. The most promising molecule (Chalcone E) was submitted to the DPPH radica
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Davydova, Anna N., Bulat T. Sharipov, and Farid A. Valeev. "Hydroxyderivatives of levoglucosenone in reactions of enantioselective reduction of 1,3-diphenylpropan-1-one." Butlerov Communications 63, no. 9 (2020): 19–25. http://dx.doi.org/10.37952/roi-jbc-01/20-63-9-19.

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The enantioselective reduction of prochiral ketones is an important method for the preparation of enanti-enriched secondary alcohols, which can serve as starting materials for optically active compounds. Chiral metal hydride reagents, such as lithium aluminum hydride (LiAlH4) and sodium borohydride (NaBH4), modified with chiral ligands, have been developed to effect enantioselective reduction. However, in most cases, derivatives are used to obtain chiral hydride reagents, which are rare and hardly available. Therefore, the search for more accessible and effective derivatives suitable for the m
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Rachmawati, S. H., I. Widiastuti, S. Ridhowati, A. Umami, I. Vandiwinata, and S. D. Lestari. "Characterization of flavor-related compounds and sensory profiles of four fermented fish products prepared from silver rasbora (Rasbora argyrotaenia) and anchovy (Stolephorus sp.)." Food Research 8, Supplementary 2 (2024): 162–69. http://dx.doi.org/10.26656/fr.2017.8(s2).131.

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Fermented fish products are grouped into salt and salt-carbohydrate types based on the fermentation substrate. A series of biochemical reactions on the substrate affects the flavor characteristics of the resulting products. This study compared the amino acids, fatty acids, and volatile compound profiles of four fermented fish products: bekasam, rusip, fish paste, and fish sauce made from silver rasbora and anchovy. The quantitative descriptive analysis (QDA) was carried out to determine the sensory profiles of those products. The results indicated that rusip and bekasam, which belong to salt-c
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Dissertations / Theses on the topic "Carbohydrate derivatives of ketones"

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Brown, Martyn A. "Phosphorus and arsenic carbohydrate derivatives." Thesis, University of Aberdeen, 1993. http://digitool.abdn.ac.uk/R?func=search-advanced-go&find_code1=WSN&request1=AAIU552502.

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A series of O-diphenylphosphinyl monosaccharide derivatives, e.g. 1,2:5,6-di-O-cyclohexylidene-3-O-diphenyl phosphinyl--D-glucofuranose [60], has been synthesised by reaction of a free hydroxy group in a sugar with Ph_2PCl. C-Diphenylphosphinyl and diphenylarsino derivatives, e.g. methyl 4,6-O-benzylidene-3-deoxy-3-C-diphenylarsino--D-altropyranoside [89], were synthesised via reaction of Ph2PLi or Ph2AsLi with p-tosyl, mesyl, epoxy or carbonyl substituted sugar reagents. Steric factors play a large part in determining the reactivity of the precursor sugars towards the phosphorous or arsenic n
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Liang, Yi. "Carbohydrate Derivatives in Antibiotics Research." DigitalCommons@USU, 2009. https://digitalcommons.usu.edu/etd/298.

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In this study, we investigated the potential applications of carbohydrates in the development of new antibiotics. To tackle the problem of multidrug-resistant variants of M. tuberculosis (MDR-TB), we investigated the biosynthesis pathways of trehalose, which has contributed to significant drug resistance. Some new methods were developed for the synthesis of potential inhibitors (6-azido-trehalose and 6,6'-diazido-trehalose) that have been designed to imitate the intermediate molecule (trehalose 6-phosphate, TPP) of OtsA-OtsB pathway. At the same time, some new antibacterial agents based on tre
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Komsta, Zofia Aleksandra. "1,2-metallate rearrangement of carbohydrate derivatives." Thesis, University of Leeds, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.534826.

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Rice, David Cunningham. "Solid-phase synthesis of carbohydrate derivatives." Thesis, University of Edinburgh, 2000. http://hdl.handle.net/1842/11310.

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Novel linker <i>N</i>-({[4-(3-aminopropylcarbamoyl)phenyl]ethysulphanyl}methyl)-2-phenylacetamide 87 has been developed which is compatible with a range of reactions (e.g. base oxidation, alkylation), can be cleaved under mild conditions and has the ability to release alcohols and amines. An efficient synthesis of the linker has been devised and attachment to a variety of solid supports (Tentagel, polystyrene) has been achieved. (Fig. 9966A). As a general building block 2-acetamido-3, 4-di-<i>O</i>-acetyl-2-deoxy-<i>N</i>-(fluoren-9-yl-methoxycarbonyl)-b-D-glucopyranosylamine 106 was synthesis
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Rufino, Helena Clara de Assuncao Rufino. "Synthesis and studies of stannylated carbohydrate derivatives." Thesis, University of Aberdeen, 1998. http://digitool.abdn.ac.uk/R?func=search-advanced-go&find_code1=WSN&request1=AAIU530772.

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A series of carbohydrate derivatives were prepared and their structural determination was made by NMR spectroscopy. The molecular structures of 1,2-<I>O</I>-isopropylidene-5-<I>O-p-</I>tosyl-α-D-xylofuranose (1) and 1,2-<I>O</I>-isopropylidene-3,5-di-<I>O</I>-<I>p-</I>tosyl-α-D-xylo-furanose (2) was determined by X-ray single-crystal diffraction. All the carbohydrate derivatives were used as precursors for the synthesis of stannylated carbohydrate derivatives. The synthesis of these stannylated carbohydrate derivatives were carried out using two methods: (i) the reaction of triphenylstannyl-li
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Barker, William D. "Photoannulation and ring closing metathesis of carbohydrate derivatives." Thesis, University of Leicester, 2000. http://hdl.handle.net/2381/30040.

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The 'chiron approach' is a well-recognised technique for converting carbohydrates and other naturally occurring compounds into new chiral target molecules. The success of this area of chemistry can be attributed to the vast array of novel methods for transforming carbohydrates that have been developed over the last 50 years. Chapter 1 describes some of the key discoveries and pioneers within the field of carbohydrate annulation. As part of the Jenkins groups' on-going studies into the development of new methods for carbohydrate annulation, we have demonstrated the ease in which simple carbohyd
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Teissier, Vincent. "Enzymatic synthesis and applications of polymerisable carbohydrate derivatives." Thesis, University of Reading, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.394514.

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Herpin, Timothee Felix. "Some new reactions of anomeric difluoromethylene carbohydrate derivatives." Thesis, University College London (University of London), 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.336240.

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Chambers, Nick. "Asymmetric heterogeneous reduction over modified supported metal catalysts." Thesis, Keele University, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.323719.

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Reich, Melanie T. "Studies towards the synthesis of carbohydrate derivatives of neocarzinostatin." Thesis, University of Sussex, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.324151.

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Books on the topic "Carbohydrate derivatives of ketones"

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Stephen, Hanessian, ed. Preparative carbohydrate chemistry. Marcel Dekker, 1997.

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1956-, Sanghvi Yogesh S., Cook P. Dan 1944-, American Chemical Society. Division of Carbohydrate Chemistry., and American Chemical Society Meeting, eds. Carbohydrate modifications in antisense research. American Chemical Society, 1994.

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E, Davison B., Ferrier R. J, and Furneaux R. H, eds. Carbohydrate chemistry: A review of the literature published during 1983 : Mono-, di-, and tri-saccharides and their derivatives. Royal society of chemistry, 1985.

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Hanessian, Stephen. Preparative Carbohydrate Chemistry. Taylor & Francis Group, 1997.

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Hanessian, Stephen. Preparative Carbohydrate Chemistry. Taylor & Francis Group, 1997.

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Martin, Robert. Aromatic Hydroxyketones : Preparation and Physical Properties : Vol.1 : Hydroxybenzophenones Vol.2 : Hydroxyacetophenones I Vol.3: Hydroxyacetophenones II ... Hydroxypivalophenones and Derivatives. Springer, 2017.

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Williams, N. R. Carbohydrate Chemistry: Mono-, Di-, and Tri-Saccharides and Their Derivatives (Carbohydrate Chemistry). Royal Society of Chemistry, 1985.

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Reich, Melanie T. Studies towards the synthesis of carbohydrate derivatives of neocarzinostatin. 2000.

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Stewart, Vincent Evans 1913. Derivatives of Piperazine and Morpholine I: Addition to Alpha, Beta-Unsaturated Ketones. Creative Media Partners, LLC, 2021.

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Hyde, Parker, Vincent J. Miller, and Jeff S. Volek. Keto-Adaptation in Health and Fitness. Edited by Dominic P. D’Agostino. Oxford University Press, 2016. http://dx.doi.org/10.1093/med/9780190497996.003.0038.

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When dietary carbohydrate is restricted and protein consumed in moderation, the evolutionarily-conserved ketogenic metabolic machinery awakens. After just a few days circulating ketones increase by an order of magnitude, and over several weeks there is a profound shift away from glucose as the primary energy substrate to the preferred use of fatty acids and ketones. This metabolic process is known as keto-adaptation. The deemphasis on insulin-dependent glucose uptake into cells and concomitant increase in fat oxidation has important implications in management of insulin resistance and its seco
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Book chapters on the topic "Carbohydrate derivatives of ketones"

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Stoppok, Eberhard, and Klaus Buchholz. "The Production of 3-Keto-Derivatives of Disaccharides." In Carbohydrate Biotechnology Protocols. Humana Press, 1999. http://dx.doi.org/10.1007/978-1-59259-261-6_22.

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Wrolstad, Ronald E. "Classifying, Identifying, Naming, and Drawing Sugars and Sugar Derivatives." In Food Carbohydrate Chemistry. John Wiley & Sons Inc., 2013. http://dx.doi.org/10.1002/9781118688496.ch1.

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Casas-Solvas, J. M., A. Vargas-Berenguel, and M. Malanga. "Synthesis of 2I-O-Propargylcyclo­Maltoheptaose and Its Peracetylated and Hepta(6-O-Silylated) Derivatives." In Carbohydrate Chemistry. CRC Press, 2021. http://dx.doi.org/10.1201/9781351256087-14.

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Griffiths, H. R., and J. Lunec. "Investigating the effects of oxygen free radicals on carbohydrates in biological systems." In Free Radicals. Oxford University PressOxford, 1996. http://dx.doi.org/10.1093/oso/9780199635603.003.0013.

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Abstract Carbohydrates are a large family of related molecules defined as polyhydroxy aldehydes or ketones, and their derivatives. They perform a diverse range of biological functions, both in their own right, in the derivation of energy for cellular maintenance and survival, or as conjugates to larger macromolecules such as proteins or lipids. In addition, the 5-C sugar deoxyribose is an integral component of the DNA backbone and its oxygenated form is critical to the integrity of RNA.
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Mash, E. A. "3.14 Synthetically Derived Chiral Auxiliaries: Uses of Derivatives of Non-Carbohydrate Aldehydes and Ketones in Asymmetric Synthesis." In Comprehensive Chirality. Elsevier, 2012. http://dx.doi.org/10.1016/b978-0-08-095167-6.00314-1.

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Landais, Y., and J. M. Vincent. "Coupling Reactions between Carboxylic Acid Derivatives and Imine Derivatives." In Ketones. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-026-00597.

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Desmale, D. "Synthesis from Hydrazone Derivatives." In Ketones. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-026-00228.

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Desmale, D. "Hydrolysis of Hydrazone Derivatives." In Ketones. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-026-00229.

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Desmale, D. "Synthesis from Enol Derivatives." In Ketones. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-026-00295.

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Constantieux, T., and J. Rodriguez. "1,2-Diols and Derivatives." In Ketones. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-026-00351.

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Conference papers on the topic "Carbohydrate derivatives of ketones"

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Cabrera-Escribano, F., M. Gómez-Guillén, P. Borrachero, I. Vázquez-Férnandez, S. Jatunov, and A. Franconetti. "New fluorescent amino carbohydrate derivatives." In The 15th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2011. http://dx.doi.org/10.3390/ecsoc-15-00695.

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Chouteau, Franck, Andy Falshaw, and Michael Coady. "NOVEL PHLORIZIN DERIVATIVES AS TRANSPORT INHIBITORS." In XXIst International Carbohydrate Symposium 2002. TheScientificWorld Ltd, 2002. http://dx.doi.org/10.1100/tsw.2002.707.

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Franconetti, Antonio, Manuel Gómez-Guillén, Pastora Borrachero, and Francisca Cabrera-Escribano. "Structural studies of phenylhydrazine integration in carbohydrate derivatives." In The 15th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2011. http://dx.doi.org/10.3390/ecsoc-15-00693.

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Kajihara, Yasuhiro, Naoki Yamamoto, Daisuke Kamiyama, and Tatsuo Miyazaki. "SYNTHESIS OF CMP-FLUORO-NEUAC DERIVATIVES AND ITS STABILITY IN THE SOLUTION." In XXIst International Carbohydrate Symposium 2002. TheScientificWorld Ltd, 2002. http://dx.doi.org/10.1100/tsw.2002.653.

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Benjes, Paul A., Manfred Dromowicz, George C. Slim, and Olga V. Zubkova. "SYNTHESIS OF DI-SULFATED DI- AND TRISACCHARIDE DERIVATIVES RELATED TO CHONDROITIN SULFATE." In XXIst International Carbohydrate Symposium 2002. TheScientificWorld Ltd, 2002. http://dx.doi.org/10.1100/tsw.2002.659.

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Lillelund, Vinni H., Tore Hardlei, and Mikael Bols. "TOWARDS ARTIFICIAL GLYCOSIDASES: SYNTHESIS OF BETA-CYCLODEXTRIN DERIVATIVES USING A PROTECTED CYCLODEXTRIN." In XXIst International Carbohydrate Symposium 2002. TheScientificWorld Ltd, 2002. http://dx.doi.org/10.1100/tsw.2002.748.

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Yamada, Kuriko, Susumu Nishiguchi, Atsushi Toda, Kenji Monde, and Shin-Ichiro Nishimura. "EFFICIENT SYNTHESIS OF OLIGOSACCHARIDE DERIVATIVES USING IMMOBILIZED GLYCOSYLTRANSFERASES AND WATER-SOLUBLE PRIMER POLYMERS." In XXIst International Carbohydrate Symposium 2002. TheScientificWorld Ltd, 2002. http://dx.doi.org/10.1100/tsw.2002.651.

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Sandula, Jozef, Darina Slamenova, Livia Krizkova, et al. "ANTIGENOTOXIC AND ANTIOXIDATIVE EFFECTS OF FUNGAL (1->3)-BETA-D-GLUCAN DERIVATIVES." In XXIst International Carbohydrate Symposium 2002. TheScientificWorld Ltd, 2002. http://dx.doi.org/10.1100/tsw.2002.676.

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Kato, Rumiko, Kazuaki Akasaka, and Hiroshi Ohrui. "CARBOHYDRATE BASED CHIRAL FLUORESCENT LABELING REAGENTS; 2-DEOXY-2-(2,3-ANTHRACENEDICARBOXIMIDO)-D-GLUCOPYRANOSYL DERIVATIVES." In XXIst International Carbohydrate Symposium 2002. TheScientificWorld Ltd, 2002. http://dx.doi.org/10.1100/tsw.2002.525.

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Yamashita, Mitsuji, L. Nagaprasada Rao, V. Krishna Reddy, et al. "STEREOSPECIFIC EPOXIDATION OF 2-PHOSPHOLENE HETERO SUGAR ANALOGS--- PREPARATION OF NOVEL ANHYDRO PHOSPHA SUGAR DERIVATIVES." In XXIst International Carbohydrate Symposium 2002. TheScientificWorld Ltd, 2002. http://dx.doi.org/10.1100/tsw.2002.654.

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