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Academic literature on the topic 'Carbon Isotopes; Isotopic analysis; Organic residues'
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Journal articles on the topic "Carbon Isotopes; Isotopic analysis; Organic residues"
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Witt, Bradd. "Century-scale environmental reconstruction by using stable carbon isotopes: just one method from the big bag of tricks." Australian Journal of Botany 50, no. 4 (2002): 441. http://dx.doi.org/10.1071/bt02006.
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The field of 'historical ecology' is coming to maturity at a time when we, in Australia, are reflecting on our relationship with, and place in, the land. After an essentially ahistorical approach to land use we are now attempting to place land management into the context of environmental change since and immediately preceding Western European settlement. This volume reflects an emerging concern that, collectively, non-indigenous Australians have no 'environmental history'. One component of 'living in' rather than 'battling against' the land is developing a sense of our history. Without an oral narrative that is commonly shared, attempts to develop the story of environmental change have to be based on retrospective and reconstructive research. This volume captures part of this movement to develop an environmental narrative and context for our future relationship with the land. There are many methodological approaches to reconstructing a story of the past, from local knowledge and oral history to the 'high-tech' and hard sciences. This paper reviews methods that apply stable carbon isotope techniques to reconstruct environmental change. Although well suited to environmental history, carbon isotope techniques remain under-utilised in the Australian context. Here I review applications to highlight the strengths and limitations of carbon isotope techniques in the reconstruction of century-scale vegetation change. There have been two dominant applications of carbon isotope techniques to environmental reconstruction. These applications fall broadly into either stable carbon isotope analysis of organic matter in soils and sediments, or inferences of environmental states have been drawn from carbon isotope analysis of animal tissues and residues. The main strength of stable carbon isotope techniques is that they can be spatially precise while integrating a range of environmental information into one isotopic signal. This integrative strength is at the same time one of the major limitations of carbon isotope techniques because floristic (taxonomic) resolution is low.
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Magioncalda, Roberto, Christian Dupuis, Dominique Blamart, Muriel Fairon-Demaret, Michel Perreau, Maurice Renard, Janine Riveline, Marc Roche, and Edward Keppens. "L'excursion isotopique du carbone organique (delta 13 C org ) dans les paleoenvironnements continentaux de l'intervalle Paleocene/Eocene de Varangeville (Haute-Normandie)." Bulletin de la Société Géologique de France 172, no. 3 (May 1, 2001): 349–58. http://dx.doi.org/10.2113/172.3.349.
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Abstract The late Palaeocene carbon isotope excursion (C.I.E.) is often regarded as the best means of correlating marine and continental deposits. The few isotopic studies carried out in continental environments were based on pedogenic carbonate [Koch et al., 1992], or on organic matter. Sinha [1997] took up this subject starting from the outcrops on the coast of the English Channel at Varangeville, where marine sequences biostratigraphically constrain the isotopic excursion. His work documents a negative delta 13 C org excursion value approximately -27 per mil PDB. The present work points out that it is necessary to study more complete sections than those studied by Sinha. A section named Phare d'Ailly has been sampled in detail (figs. 1, 2, 3). In this section, for which detailed analysis of sedimentology, palaeontology and organic matter facies establish the continental nature of the palaeoenvironment, isotopic analysis of organic matter reveals a very negative delta 13 C org excursion value approximately -30 per mil PDB. The P/E interval synthesized in figure 2 shows three main groups, the stratigraphy of which is strongly constrained between the calcareous nannofossil Zones NP8 and NP11. The marine Thanetian facies belong to Zones NP8 and NP9. Above, the "Sparnacian" (Mont Bernon Group) is divided into 5 units referred to as SP. Unit SP2 is attributed to the Peckichara disermas Charozone, equivalent to Zone NP9. For unit SP4, an indirect correlation with Zone NP10 may be deduced. The upper part of the Varangeville Formation is known for its nannofossil association attributed to Zone NP11. We may conclude from these observations that the sparnacian sediments are synchronous with NP9-10 Zones and that they are effectively located in the time interval of the delta 13 C excursion. The SP1 and SP2 sediments were analysed for carbonate content, grain size distribution, clay mineralogy and total organic content (T.O.C.), using standard laboratory methods (fig. 3). An optical specification of the organic matter has been obtained from semiquantitative analysis of the organic matter facies. The survey of macro- and microfossils has supplied complementary supports for isotopic analysis (seed, wood and charcoal). The isotopic measurements were carried out on the bulk sediment and on complementary supports with a mass spectrometer in continuous flow delta + (Finnigan Mat). The measurement precision is better than 0.1 per mil and the reproducibility is about 0.15 per mil. Washing residues provide Gasteropoda, Bivalvia, Ostracoda, Characea, as well as fruits and seeds, microcodiums and otolith. All the palaeontological data illustrate a continental biota of a pure lacustrine environment, quiet and shallow, in a hot and humid climate. The organic matter facies analysis confirms the absence of any marine influence and documents a palaeoenvironment of lakes and ponds having an anoxic floor. Thus the carbon of the organic matter is considered to be continental and their isotopic variations linked to those of the atmospheric carbon.
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Hanke, U. M., L. Wacker, N. Haghipour, M. W. I. Schmidt, T. I. Eglinton, and C. P. McIntyre. "Comprehensive radiocarbon analysis of benzene polycarboxylic acids (BPCAs) derived from pyrogenic carbon in environmental samples." Radiocarbon 59, no. 4 (July 17, 2017): 1103–16. http://dx.doi.org/10.1017/rdc.2017.44.
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ABSTRACTCompound-specific radiocarbon analysis (CSRA) of benzene polycarboxylic acids (BPCAs) yields molecular-level, source-specific information necessary to constrain isotopic signatures of pyrogenic carbon. However, the purification of individual BPCAs requires a multistep procedure that typically results in only microgram quantities of the target analyte(s). Such small samples are highly susceptible to contamination by extraneous carbon, which needs to be minimized and carefully accounted for in order to yield accurate results. Here, we undertook comprehensive characterization and quantification of contamination associated with molecular radiocarbon (14C) BPCA analyses through systematic processing of multiple authentic standards with both fossil and modern 14C signatures at various concentrations. Using this approach, we precisely apportion the contribution of extraneous carbon with respect to the four implemented subprocedures. Assuming a constant source and quantity of extraneous carbon we correct and statistically evaluate uncertainties in resulting 14C data. Subsequently, we examine the results of triplicate analyses of reference materials representing four different environmental matrices (sediment, soil, aerosol, riverine natural organic matter) and apportion their BPCA sources in terms of carbon residues derived from biomass or fossil fuel combustion. This comprehensive approach to CSRA facilitates retrieval of robust 14C data, with application in environmental studies of the continuum of pyrogenic carbon.
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Fuller, Mark E., Linnea Heraty, Charles W. Condee, Simon Vainberg, Neil C. Sturchio, J. K. Böhlke, and Paul B. Hatzinger. "Relating Carbon and Nitrogen Isotope Effects to Reaction Mechanisms during Aerobic or Anaerobic Degradation of RDX (Hexahydro-1,3,5-Trinitro-1,3,5-Triazine) by Pure Bacterial Cultures." Applied and Environmental Microbiology 82, no. 11 (March 25, 2016): 3297–309. http://dx.doi.org/10.1128/aem.00073-16.
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ABSTRACTKinetic isotopic fractionation of carbon and nitrogen during RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) biodegradation was investigated with pure bacterial cultures under aerobic and anaerobic conditions. Relatively large bulk enrichments in15N were observed during biodegradation of RDX via anaerobic ring cleavage (ε15N = −12.7‰ ± 0.8‰) and anaerobic nitro reduction (ε15N = −9.9‰ ± 0.7‰), in comparison to smaller effects during biodegradation via aerobic denitration (ε15N = −2.4‰ ± 0.2‰).13C enrichment was negligible during aerobic RDX biodegradation (ε13C = −0.8‰ ± 0.5‰) but larger during anaerobic degradation (ε13C = −4.0‰ ± 0.8‰), with modest variability among genera. Dual-isotope ε13C/ε15N analyses indicated that the three biodegradation pathways could be distinguished isotopically from each other and from abiotic degradation mechanisms. Compared to the initial RDX bulk δ15N value of +9‰, δ15N values of the NO2−released from RDX ranged from −7‰ to +2‰ during aerobic biodegradation and from −42‰ to −24‰ during anaerobic biodegradation. Numerical reaction models indicated that N isotope effects of NO2−production were much larger than, but systematically related to, the bulk RDX N isotope effects with different bacteria. Apparent intrinsic ε15N-NO2−values were consistent with an initial denitration pathway in the aerobic experiments and more complex processes of NO2−formation associated with anaerobic ring cleavage. These results indicate the potential for isotopic analysis of residual RDX for the differentiation of degradation pathways and indicate that further efforts to examine the isotopic composition of potential RDX degradation products (e.g., NOx) in the environment are warranted.IMPORTANCEThis work provides the first systematic evaluation of the isotopic fractionation of carbon and nitrogen in the organic explosive RDX during degradation by different pathways. It also provides data on the isotopic effects observed in the nitrite produced during RDX biodegradation. Both of these results could lead to better understanding of the fate of RDX in the environment and help improve monitoring and remediation technologies.
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Ramnarine, R., C. Wagner-Riddle, K. E. Dunfield, and R. P. Voroney. "Contributions of carbonates to soil CO2 emissions." Canadian Journal of Soil Science 92, no. 4 (May 2012): 599–607. http://dx.doi.org/10.4141/cjss2011-025.
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Ramnarine, R., Wagner-Riddle, C., Dunfield, K. E. and Voroney, R. P. 2012. Contributions of carbonates to soil CO 2 emissions. Can. J. Soil Sci. 92: 599–607. Carbon dioxide (CO2) is released in soil as a by-product of microbial and root respiration, but soil carbonates may also be a source of CO2 emissions in calcareous soils. Global estimates of inorganic carbon range from 700 to 900 Pg as carbonates stored in soils, representing a significant potential source of CO2 to the atmosphere. While previous studies have focused on the total CO2 efflux from the soil, our goal was to identify the various sources and their contribution to total CO2 emissions, by measuring the isotopic signature of the CO2 emitted from the soil. Calcareous Luvisolic silt loam soil samples were obtained from conventional tillage (CT) and no-tillage (NT) plots in southern Ontario, Canada. Soil samples (root- and residue-free) were laboratory-incubated for 14 d and the isotopic signature of the CO2 (δ13CCO2) released was analyzed using isotope ratio mass spectrometry. Isotopic measurement was essential in quantifying the abiotic CO2 production from carbonates, due to the unique δ13C signature of carbonates and soil organic matter. A two-end member mixing model was used to estimate the proportion of CO2 evolved from soil carbonates and soil organic matter decomposition. Analysis of emitted CO2 collected after the 14-d incubation indicate that the proportion of CO2 originating from soil inorganic carbon was 62 to 74% for CT soil samples, and 64 to 80% for NT soil samples. Further work is recommended in the quantification of CO2 emissions from calcareous soils, and to determine the transferability of laboratory results to field studies.
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Barešić, Jadranka, Sanja Faivre, Andreja Sironić, Damir Borković, Ivanka Lovrenčić Mikelić, Russel N. Drysdale, and Ines Krajcar Bronić. "The Potential of Tufa as a Tool for Paleoenvironmental Research—A Study of Tufa from the Zrmanja River Canyon, Croatia." Geosciences 11, no. 9 (September 7, 2021): 376. http://dx.doi.org/10.3390/geosciences11090376.
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Tufa is a fresh-water surface calcium carbonate deposit precipitated at or near ambient temperature, and commonly contains the remains of macro- and microphytes. Many Holocene tufas are found along the Zrmanja River, Dalmatian karst, Croatia. In this work we present radiocarbon dating results of older tufa that was found for the first time at the Zrmanja River near the Village of Sanaderi. Tufa outcrops were observed at different levels, between the river bed and up to 26 m above its present level. Radiocarbon dating of the carbonate fraction revealed ages from modern, at the river bed, up to 40 kBP ~20 m above its present level. These ages fit well with the hypothesis that the Zrmanja River had a previous surface connection with the Krka River, and changed its flow direction toward the Novigrad Sea approximately 40 kBP (Marine Isotope Stage 3). Radiocarbon AMS dating of tufa organic residue yielded a maximum conventional age of 17 kBP for the highest outcrop position indicating probable penetration of younger organic material to hollow tufa structures, as confirmed by radiocarbon analyses of humin extracted from the samples. Stable carbon isotope composition (δ13C) of the carbonate fraction of (−10.4 ± 0.6)‰ and (−9.7 ± 0.8)‰ for the Holocene and the older samples, respectively, indicate the autochthonous origin of the carbonate. The δ13C values of (−30.5 ± 0.3)‰ and (−29.6 ± 0.6)‰ for organic residue, having ages <500 BP and >5000 BP, respectively, suggest a unique carbon source for photosynthesis, mainly atmospheric CO2, with an indication of the Suess effect in δ13C during last centuries. The oxygen isotopic composition (δ18O) agrees well with deposition of tufa samples in two stages, the Holocene (−8.02 ± 0.72‰) and “old” (mainly MIS 3 and the beginning of MIS 2) (−6.89 ± 0.34‰), suggesting a ~4 °C lower temperature in MIS 3 compared to the current one.
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Choy, Kyungcheol, Ben A. Potter, Holly J. McKinney, Joshua D. Reuther, Shiway W. Wang, and Matthew J. Wooller. "Chemical profiling of ancient hearths reveals recurrent salmon use in Ice Age Beringia." Proceedings of the National Academy of Sciences 113, no. 35 (August 30, 2016): 9757–62. http://dx.doi.org/10.1073/pnas.1606219113.
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Current approaches to reconstruct subsistence and dietary trends in ancient hunter-gatherer societies include stable isotope analyses, but these have focused on human remains, cooking pottery, and food residues, which are relatively rare in the archaeological record. In contrast, short-term hearths are more ubiquitous worldwide, and these features can provide valuable evidence for ancient subsistence practices, particularly when faunal remains are not preserved. To test the suitability of hearths for this purpose, we conducted multiple chemical analyses: stable carbon and nitrogen isotope analyses of total organic matter (expressed as δ13C and δ15N values) and compound-specific carbon isotope analyses of individual fatty acids (δ13C16:0 and δ13C18:0) from 17 well-preserved hearths present in three occupations dating between ∼13,200–11,500 calibrated years B.P. at the Upward Sun River (USR) site in central Alaska. We combined δ15N and δ13CFA data in a Bayesian mixing model (stable isotope analysis in R) with concentration dependency to each hearth. Our model values were tested against faunal indices, indicating a strong positive relationship between marine proportional contributions to each hearth and salmon abundance. Results of the models show substantial anadromous salmon use in multiple USR components, indicating recurrent use of the site for salmon processing during the terminal Pleistocene. Our results demonstrate that salmonid and freshwater resources were more important for late Pleistocene hunter-gatherers than previously thought and highlight the potential of chemical profiling of hearth organic residues for providing greater geographic and temporal insights into resource use by prepottery societies.
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Megens, Luc, Johannes Van Der Plicht, and Jan W. De Leeuw. "Molecular, Radioactive and Stable Carbon Isotope Characterization of Estuarine Particulate Organic Matter." Radiocarbon 40, no. 2 (1997): 985–90. http://dx.doi.org/10.1017/s0033822200018956.
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Organic matter in sediments and suspended matter is a complex mixture of constituents with different histories, sources and stabilities. To study these components in a suspended matter sample from the Ems-Dollard Estuary, we used combined molecular analysis with pyrolysis/gas chromatography/mass spectrometry and stable and radioactive carbon isotope analyses of the bulk and separated chemical fractions. Carbohydrates and proteins, ca. 50% of the total organic carbon (TOC), are much younger than the bulk sample and have a somewhat higher δ13C value. Lipids and the final residue are considerably older and have lower δ13C values. The final residue, ca. 17% of the total carbon, consists mainly of aliphatic macromolecules that could be derived from algae or terrestrial plants. The δ13C value points to a marine origin.
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Kayler, Z. E., M. Kaiser, A. Gessler, R. H. Ellerbrock, and M. Sommer. "Application of δ<sup>13</sup>C and δ<sup>15</sup>N isotopic signatures of organic matter fractions sequentially separated from adjacent arable and forest soils to identify carbon stabilization mechanisms." Biogeosciences 8, no. 10 (October 17, 2011): 2895–906. http://dx.doi.org/10.5194/bg-8-2895-2011.
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Abstract. Identifying the chemical mechanisms behind soil carbon bound in organo-mineral complexes is necessary to determine the degree to which soil organic carbon is stabilized belowground. Analysis of δ13C and δ15N isotopic signatures of stabilized OM fractions along with soil mineral characteristics may yield important information about OM-mineral associations and their processing history. We anlayzed the δ13C and δ15N isotopic signatures from two organic matter (OM) fractions along with soil mineral proxies to identify the likely binding mechanisms involved. We analyzed OM fractions hypothesized to contain carbon stabilized through organo-mineral complexes: (1) OM separated chemically with sodium pyrophosphate (OM(PY)) and (2) OM occluded in micro-structures found in the chemical extraction residue (OM(ER)). Because the OM fractions were separated from five different soils with paired forest and arable land use histories, we could address the impact of land use change on carbon binding and processing mechanisms. We used partial least squares regression to analyze patterns in the isotopic signature of OM with established mineral and chemical proxies indicative for certain binding mechanisms. We found different mechanisms predominate in each land use type. For arable soils, the formation of OM(PY)-Ca-mineral associations was identified as an important OM binding mechanism. Therefore, we hypothesize an increased stabilization of microbial processed OM(PY) through Ca2+ interactions. In general, we found the forest soils to contain on average 10% more stabilized carbon relative to total carbon stocks, than the agricultural counter part. In forest soils, we found a positive relationship between isotopic signatures of OM(PY) and the ratio of soil organic carbon content to soil surface area (SOC/SSA). This indicates that the OM(PY) fractions of forest soils represent layers of slower exchange not directly attached to mineral surfaces. From the isotopic composition of the OM(ER) fraction, we conclude that the OM in this fraction from both land use types have undergone a different pathway to stabilization that does not involve microbial processing, which may include OM which is highly protected within soil micro-structures.
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Šoberl, Lucija, Andreja Žibrat Gašparič, Mihael Budja, and Richard P. Evershed. "Early herding practices revealed through organic residue analysis of pottery from the early Neolithic rock shelter of Mala Triglavca, Slovenia." Documenta Praehistorica 35 (December 31, 2008): 253–60. http://dx.doi.org/10.4312/dp.35.19.
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A collection of pottery from the early Neolithic site of Mala Triglavca was analysed with the aim of obtaining insights into vessel use and early animal domestication and husbandry practices in the Adriatic region. Total lipid extracts were submitted to gas chromatography (GC), GC-mass spectrometry (GC-MS) and GC-combustion-isotope ratio MS (GC-C-IRMS) in order to obtain molecular and stable carbon isotope signatures as the basis for determining the nature and origins of the residues. The extracts were dominated by degraded animal fats. The majority (70%) of the total lipid extracts displayed intact triacylglycerol distributions attributable to ruminant adipose and dairy fats, which were subsequently confirmed through C16:0 and C18:0 fatty acid δ13C values.
Dissertations / Theses on the topic "Carbon Isotopes; Isotopic analysis; Organic residues"
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Craig, O. E., R. B. Allen, A. Thompson, R. E. Stevens, Valerie J. Steele, and Carl P. Heron. "Distinguishing wild ruminant lipids by gas chromatography/combustion/isotope ratio mass spectrometry." 2012. http://hdl.handle.net/10454/5945.
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NoRATIONALE: The carbon isotopic characterisation of ruminant lipids associated with ceramic vessels has been crucial for elucidating the origins and changing nature of pastoral economies. delta(13)C values of fatty acids extracted from potsherds are commonly compared with those from the dairy and carcass fats of modern domesticated animals to determine vessel use. However, the processing of wild ruminant products in pottery, such as deer, is rarely considered despite the presence of several different species on many prehistoric sites. To address this issue, the carbon isotope range of fatty acids from a number of red deer (Cervus elaphus) tissues, a species commonly encountered in the European archaeological record, was investigated. METHODS: Lipids were extracted from 10 modern red deer tissues obtained from the Slowinski National Park (Poland). Fatty acids were fractionated, methylated and analysed by gas chromatography/combustion/isotope ratio mass spectrometry (GCCIRMS). The delta(13)C values of n-octadecanoic acid and n-hexadecanoic acid, and the difference between these values (Delta(13)C), were compared with those from previously published ruminant fats. RESULTS: Nine of the ten deer carcass fats measured have Delta(13)C values of less than -3.3 per thousand, the threshold previously used for classifying dairy products. Despite considerable overlap, dairy fats from domesticated ruminants with Delta(13)C values less than -4.3 per thousand are still distinguishable. CONCLUSIONS: The finding has implications for evaluating pottery use and early pastoralism. The processing of deer tissues and our revised criteria should be considered, especially where there is other archaeological evidence for their consumption.
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Mukherjee, A. J., Alex M. Gibson, and R. P. Evershed. "Trends in pig product processing at British Neolithic Grooved Ware sites traced through organic residues in potsherds." 2008. http://hdl.handle.net/10454/6111.
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NoGas chromatography (GC), GC-mass spectrometry (GC-MS) and GC-combustion-isotope ratio MS (GC-C-IRMS) analyses of absorbed and surface lipid residues preserved in potsherds were used to explore the extent of pig product processing exploitation in the later British Neolithic Grooved Ware tradition. Assessments were made regarding whether porcine lipids were associated with specific Grooved Ware traits, i.e. decoration, substyle, geographical area and type of site. Two hundred and twenty-two Grooved Ware potsherds were analysed, 70% of which contained lipid concentrations considered significant (>5 μg g−1). All the lipid residues were dominated by animal fats, although plant and beeswax were also detected in a small number of extracts. δ13C values of the major fatty acid components of degraded animal fats (C16:0 and C18:0) were determined for 126 extracts and used to assign ruminant or porcine origins to the residues; 16% of these were found to have a predominantly porcine isotope signature. Statistical associations with pig exploitation were shown to exist with substyle, geographical area and site type, whereas, no relationship was seen between decoration and the type of commodity processed. Intact triacylglycerols were preserved in 19% of the sherds; half of these had distributions consistent with the identifications based on δ13C values, the remainder differed either due to the presence of mixed commodities or because lower molecular weight homologues had been lost due to degradation. In addition to the detection of pig exploitation, results from lipid residue analysis showed a good correlation with faunal assemblages, suggesting that stable isotope analysis may be used as a proxy for animal exploitation at sites where bones have not survived.