Academic literature on the topic 'Carbonyle'

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Journal articles on the topic "Carbonyle"

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Laurence, Christian, Michel Berthelot, and Maryvonne Helbert. "Stéréochimie de la liaison hydrogène sur le groupe carbonyle." Spectrochimica Acta Part A: Molecular Spectroscopy 41, no. 7 (January 1985): 883–92. http://dx.doi.org/10.1016/0584-8539(85)80220-8.

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Grandi, M., C. Assoun, G. Numico, and R. Canuto. "Iron-carbonyle: Preliminary results on breast and lung cancer." Biomedicine & Pharmacotherapy 47, no. 6-7 (November 1993): 279. http://dx.doi.org/10.1016/0753-3322(93)90210-c.

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Darchen, André, El Kbir Lhadi, and Henri Patin. "Etude cinétique de la réaction thermique de remplacement d'un carbonyle, par un ligand L, dans des complexes carbéniques binucléaires du fer carbonyle." Journal of Organometallic Chemistry 363, no. 1-2 (March 1989): 137–49. http://dx.doi.org/10.1016/0022-328x(89)88047-7.

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Guihéneuf, Georges, Christian Bénard, Abdeljalil Lachkar, and Maryvonne Luçon. "Interaction entre le groupe carbonyle et les hétéroatomes des acétates d'éthyle α-substitués." Canadian Journal of Chemistry 63, no. 9 (September 1, 1985): 2343–48. http://dx.doi.org/10.1139/v85-388.

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Infrared spectra of ethyl α-aminoacetates show three bands in the carbonyl region. Solvent effects show that this is not due to Fermi resonance. These spectra can be interpreted using a model that considers the interactions between the nitrogen lone pair and the carbonyl group. The existence of an equilibrium between the conformers caused by the different orientations of the nitrogen lone pair with respect to the carbonyl group can be forecast. This model enables the interpretation of the carbonyl absorptions of the α-substituted (methoxy and ethoxy) ethyl acetates.
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Kern, J. M., D. Martina, and M. P. Heitz. "Methode electrochimique de liberation d'un ligand organique de son complexe de fer carbonyle." Tetrahedron Letters 26, no. 6 (January 1985): 737–40. http://dx.doi.org/10.1016/s0040-4039(00)89124-8.

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van Meerssche, M., P. Piret, J. Meunier-Piret, and Y. Degrève. "Structure Moléculaire de Trois Complexes du Fer-Carbonyle Avec L'Acétylène et Ses Dérivés." Bulletin des Sociétés Chimiques Belges 73, no. 9-10 (September 2, 2010): 824–32. http://dx.doi.org/10.1002/bscb.19640730912.

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ROUSSELLE, D., and F. RAVEL. "Etude du rôle de la microstructure sur les propriétés électromagnétiques du fer ex-carbonyle." Le Journal de Physique IV 02, no. C3 (December 1992): C3–65—C3–71. http://dx.doi.org/10.1051/jp4:1992309.

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Patin, Henri, Boguslaw Misterkiewicz, Jean-Yves Le Marouille, and Abdelhamid Mousser. "Complexes binucleaires de fer carbonyle liaison σ-metal-carbone: Synthese, etude structurale et proprietes." Journal of Organometallic Chemistry 314, no. 1-2 (October 1986): 173–84. http://dx.doi.org/10.1016/0022-328x(86)80362-x.

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Kreiter, Cornelius G., Wolfgang Michels, and Martin Wenz. "Gehinderte Ligandbewegungen in Übergangsmetallkomplexen, XXXIII. (η2- und η4-Dien)[2-(η5-cyclopentadienyl)ethyl]molybdän-Carbonyle." Chemische Berichte 119, no. 6 (June 1986): 1994–2005. http://dx.doi.org/10.1002/cber.19861190620.

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Piron, J., P. Piret, J. Meunier-Piret, and M. van Meerssche. "Complexes du Fer-Carbonyle Avec L'acétylène et ses Dérivés. V. Structure de Fe2(CO)6 · (CH3C2CH3)2CO." Bulletin des Sociétés Chimiques Belges 78, no. 1-2 (September 2, 2010): 121–30. http://dx.doi.org/10.1002/bscb.19690780115.

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Dissertations / Theses on the topic "Carbonyle"

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Millot, Nicolas. "Syntheses et reactivites de nouveaux complexes (cyclohexadiene) fer carbonyle." Paris 11, 1998. http://www.theses.fr/1998PA114801.

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CHERKAOUI, HASSAN. "Synthese et reactivite de nouveaux complexes heterodiene-fer-carbonyle." Rennes 1, 1993. http://www.theses.fr/1993REN10160.

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Nous decrivons dans ce memoire la synthese, l'etude structurale et la reactivite de deux nouveaux types de complexes heterodienes bifonctionnalises fer carbonyles, l'heteroatome de l'heterodiene etant un atome d'oxygene ou d'azote. Quant l'heteroatome est un oxygene, la complexation est directe; l'action du difernonacarbonyle sur le fragment organique conduit a des complexes di et tetrahaptacoordines (sauf dans le cas ou r=och#3, le carbonyle de l'ester n'intervient pas dans la coordination avec le metal). Lorsqu'il y a eu competition de la complexation entre deux sites (deux aldehydes ou aldehyde cetone), une etude cinetique a ete realisee (r=h, ph) a l'aide de la rmn du proton, ce qui a permis de determiner la vitesse du changement de site de complexation, et ainsi de preciser la position de l'equilibre thermodynamique des complexes fer tricarbonyles. L'utilisation synthetique de ces complexes semble limitee par la grande labilite de la coordination du motif fer carbonyle avec l'heterodiene organique. Quand l'heteroatome est un azote, l'obtention des complexes d'azadienes bifonctionnalises fer carbonyles est realisee par la reaction d'aza-wittig evitant la presence de la molecule d'eau dans le milieu reactionnel: la condensation du complexe #2 ou #4 portant une fonction aldehyde libre avec un iminophosphoranne (r=-ch#2ph, -ph)
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Roblou, Emmanuel. "Réactivité des hydrures anioniques de chrome carbonyle vis-à-vis des composés phosphorés et des dérivés carbonylés α,ß-insaturés." Toulouse 3, 2002. http://www.theses.fr/2002TOU30153.

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Stanciulescu, Maria. "La stéréochimie de l'addition nucléophile sur la fonction carbonyle : effet antipériplanaire." Thesis, University of Ottawa (Canada), 1985. http://hdl.handle.net/10393/4952.

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Passelaigue, Elisabeth. "Evaluation de complexes hydruroanioniques du fer carbonyle : oxacarbonylation régiosélective de structures acryliques." Toulouse 3, 1989. http://www.theses.fr/1989TOU30180.

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La fonctionnalisation regioselective de l'acrylate d'ethyle en methylmalonate correspondant peut realisee par une reaction en deux etapes mettant en jeu un complexe hydruroanionique, khfe(co)#4. Toutefois, la reaction n'est pas catalytique et les rendements sont faibles. Cette reaction a ete optimisee puis etudiee afin de comprendre les mecanismes mis en jeu et d'essayer de mettre au point un processus catalytique. Toutefois, les essais catalytiques se sont reveles infructueux. L'analyse des raisons de cet echec a conduit a envisager l'hydrocarboxylation catalytique de sels de l'acide acrylique en acide methylmalonique en milieu aqueux. L'etude et la mise au point de cette reaction ont permis d'atteindre 30 cycles. Un cycle catalytique a ete propose et l'etape limitante a ete determinee. Cette reaction d'hydrocarboxylation de l'acide acrylique en acide methylmalonique constitue le premier exemple de fonctionnalisation catalytique de l'acide acrylique en position 2. Elle est realisee dans des conditions tres douces avec une regioselectivite totale, a l'aide d'un systeme catalytique extremement simple
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Ngono, Bernadette. "Organométalliques à carbonyle masqué : quelques propriétés du lithio-1 triméthylsiloxy-2 éthylène." Rouen, 1989. http://www.theses.fr/1989ROUES021.

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La condensation du lithio-1 triméthylsiloxy-2 éthylène avec les chlorotrialkylsilanes et le triflate de t-butyldiméthylsilyle conduit aux éthers d'énols silyles -silyles. L'hydrolyse acide de ces derniers permet d'isoler le t-butyldiméthylsilyl acétaldéhyde. D'autre part, la condensation du lithio-1 triméthylsiloxy-2 éthylène avec les chlorures d'acides non énolisables conduit a des esters d'énols de -cétoaldéhydes
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Mousser, Abdelhamid. "Cristallochimie et réactivité des complexes du fer-carbonyle à ligands xanthates et dithioesters." Grenoble 2 : ANRT, 1987. http://catalogue.bnf.fr/ark:/12148/cb37608227w.

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Aplincourt, Philippe. "Etude théorique de processus chimiques et photochimiques impliquant l'oxyde de carbonyle dans l'atmosphère." Nancy 1, 1999. http://www.theses.fr/1999NAN10234.

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L'oxyde de carbonyle le plus simple, H2COO, joue un rôle important dans la chimie de l'atmosphère en raison de son implication dans les processus de pollution urbaine de l'air. Ce composé très réactif est généré dans la basse atmosphère lors de la réaction d'ozonolyse des alcènes. Il peut ensuite, soit subir des réactions unimoléculaires d'isomérisation et de décomposition, soit réagir avec d'autres molécules de la troposphère. A l'heure actuelle, très peu de données expérimentales sont disponibles sur l'oxyde de carbonyle en raison de l'instabilité importante de cette molécule. Par conséquent, la mise en oeuvre de calculs de chimie quantique s'avère nécessaire pour l'étude de sa structure et de sa réactivité. Le travail que nous avons mené s'inscrit dans ce cadre et vise à une meilleure connaissance de la réactivité chimique mais aussi photochimique de H2COO dans l'atmosphère. [. . . ]
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Mousser, Abdelhamid. "Cristallochimie et reactivite des complexes du fer-carbonyle a ligands xanthates et dithioesters." Rennes 1, 1987. http://www.theses.fr/1987REN10081.

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Etude des complexes dinucleaires issus des reactions de complexation des coordinats r**(1)xcs::(2)r**(2) par fe::(2)(co)::(9). Structures cristallines des complexes (2) (ro-cs)(sch::(3))fe::(2)(co)::(6) et de leurs derives mono et desubstitues par un coordinat plus donneur que co(po(he::(3)) ou me::(3)cnc) et etude de la regioselectivite et de la stereoselectivite du remplacement de co par l. La fragmentation du coordinat organique dans les complexes (co) (ro-ccs)sch::(3))fe::(2)(co) montre que ces complexes se rearrangent pour conduire aux complexes (z). Etude statistique sur la liaison fe-fe et discussion
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Saïed, Okba. "Étude de la complexation simultanée d'un groupe carbonyle par deux sites acides de Lewis." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape10/PQDD_0002/NQ38831.pdf.

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Books on the topic "Carbonyle"

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Racht, James J. Carbondale. Charleston, S.C: Arcadia Pub., 2010.

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Jorge, Juanes, ed. Carbonell. México: Impresiones Aéreas, 2001.

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Simpson, Charles Q. Linear semibridging carbonyls. Ithaca, N.Y: Cornell Theory Center, Cornell University, 1991.

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Core carbonyl chemistry. Oxford: Oxford University Press, 1997.

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Takeda, Takeshi. Modern carbonyl olefination. Weinheim: Wiley-VCH, 2004.

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Carbonne. [France: s.n.], 1985.

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S, J. Llop. Miquel Carbonell. [Barcelona]: Gal Art, 1994.

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Sater, Steven. Carbondale dreams. New York: Dramatists Play Service, 1991.

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Tucker, Maurice E., and Robin G. C. Bathurst, eds. Carbonate Diagenesis. Oxford, UK: Blackwell Publishing Ltd., 1990. http://dx.doi.org/10.1002/9781444304510.

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Tucker, Maurice E., James Lee Wilson, Paul D. Crevello, J. Rick Sarg, and J. Fred Read, eds. Carbonate Platforms. Oxford, UK: Blackwell Publishing Ltd., 1986. http://dx.doi.org/10.1002/9781444303834.

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Book chapters on the topic "Carbonyle"

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Bomhard, Ernst. "Alkohole, Phenole und Carbonyle." In Toxikologie, 97–125. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2011. http://dx.doi.org/10.1002/9783527635542.ch5.

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Atwood, Jim D., and Jerome B. Keister. "By Reactions of Carbonyls with Carbonyl Anions." In Inorganic Reactions and Methods, 41–42. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145296.ch35.

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Gooch, Jan W. "Carbonyl." In Encyclopedic Dictionary of Polymers, 118. New York, NY: Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_1947.

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Cleaves, Henderson James. "Carbonyl." In Encyclopedia of Astrobiology, 1. Berlin, Heidelberg: Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-27833-4_237-4.

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Cleaves, Henderson James. "Carbonyl." In Encyclopedia of Astrobiology, 377–78. Berlin, Heidelberg: Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-662-44185-5_237.

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Cleaves, Henderson James. "Carbonyl." In Encyclopedia of Astrobiology, 249. Berlin, Heidelberg: Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-11274-4_237.

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Pruchnik, Florian P., and Stan A. Duraj. "Metal Carbonyls." In Organometallic Chemistry of the Transition Elements, 23–127. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2076-8_2.

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Calderazzo, F. "Cobalt Carbonyls." In Inorganic Reactions and Methods, 348–49. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145319.ch136.

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Calderazzo, F. "Nickel Carbonyls." In Inorganic Reactions and Methods, 351–52. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145319.ch138.

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Gooch, Jan W. "Carbonyl Group." In Encyclopedic Dictionary of Polymers, 119. New York, NY: Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_1950.

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Conference papers on the topic "Carbonyle"

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Tao, R. "ELECTRORHEOLOGICAL FLUIDS: MECHANISMS, PROPERTIES, STRUCTURE, TECHNOLOGY AND APPLICATIONS." In Carbondale, Illinois. WORLD SCIENTIFIC, 1992. http://dx.doi.org/10.1142/9789814537902.

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Dagaut, Philippe, Yuri Bedjanian, Guillaume Dayma, Fabrice Foucher, Benoît Grosselin, Manolis Romanias, and Roya Shahla. "Emission of Carbonyl and Polyaromatic Hydrocarbon Pollutants From the Combustion of Liquid Fuels: Impact of Biofuel Blending." In ASME Turbo Expo 2018: Turbomachinery Technical Conference and Exposition. American Society of Mechanical Engineers, 2018. http://dx.doi.org/10.1115/gt2018-75136.

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The combustion of conventional fuels (Diesel and Jet A-1) with 10–20% vol. oxygenated biofuels (ethanol, 1-butanol, methyl octanoate, rapeseed oil methyl ester, diethyl carbonate, tri(propylene glycol)methyl ether, i.e., CH3(OC3H6)3OH, and 2,5-dimethylfuran) and a synthetic paraffinic kerosene was studied. The experiments were performed using an atmospheric pressure laboratory premixed flame and a four-cylinder four-stroke Diesel engine operating at 1500 rpm. Soot samples from kerosene blends were collected above a premixed flame for analysis. Polyaromatic hydrocarbons (PAHs) were extracted from the soot samples. After fractioning, they were analyzed by high-pressure liquid chromatography (HPLC) with UV and fluorescence detectors. C1 to C8 carbonyl compounds were collected at the Diesel engine exhaust on 2,4-dinitrophenylhydrazine coated cartridges (DNPH) and analyzed by HPLC with UV detection. The data indicated that blending conventional fuels with biofuels has a significant impact on the emission of both carbonyl compounds and PAHs adsorbed on soot. The global concentration of 18 PAHs (1-methyl-naphthalene, 2-methyl-naphthalene, and the 16 US priority EPA PAHs) on soot was considerably lowered using oxygenated fuels, except 2,5-dimethylfuran. Conversely, the total carbonyl emission increased by oxygenated biofuels blending. Among them, ethanol and 1-butanol were found to increase considerably the emissions of carbonyl compounds.
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Acevedo, Helmer, Jose Tamara, and Felipe Rodriguez. "Effect of Anhydrous and Hydrous Ethanol on Performance and Non-Regulated Emissions of an HCCI Engine." In ASME 2012 Internal Combustion Engine Division Fall Technical Conference. American Society of Mechanical Engineers, 2012. http://dx.doi.org/10.1115/icef2012-92144.

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The automotive sector is currently undergoing drastic changes, driven by the need to simultaneously meet increasingly stringent environmental regulations and achieve more efficient operation over a wide range of engine speeds and loads, while satisfying customer demands in terms of performance, safety, and reliability. In this study an HCCI engine is evaluated for performance and regulated and non-regulated emissions with anhydrous and hydrous ethanol. The Standard EPA Method 8315A was used to determine free carbonyl compounds by derivatization with 2,4-dinitrophenyhydrazine (DNPH). Carbonyls have been measured in emissions using DNPH impregnated cartridges and chemical analyses used high performance liquid chromatography (HPLC). Through the load range achievable, naturally aspirated lean anhydrous ethanol requires high intake temperatures. Although NOx emissions are lower with the use of hydrous ethanol, these emissions are much lower with the use of dry ethanol. The penalty of the use hydrous ethanol is an increase of unburned hydrocarbons and carbon monoxide. Total aldehyde emissions are seen to diminish when an HCCI combustion is carried out with hydrous ethanol. Our analysis gives evidence that HCCI engines can run efficiently on hydrous ethanol fuel and that utilizing hydrous ethanol fuel in HCCI engines improves the energy balance of ethanol production.
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"Front Matter." In First International Symposium on Carbonate Sand Beaches. Reston, VA: American Society of Civil Engineers, 2002. http://dx.doi.org/10.1061/9780784406403.fm.

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"Index." In First International Symposium on Carbonate Sand Beaches. Reston, VA: American Society of Civil Engineers, 2002. http://dx.doi.org/10.1061/9780784406403.in.

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Wozencraft, Jennifer M., and Jennifer L. Irish. "SHOALS Surveys and Carbonate Beaches." In First International Symposium on Carbonate Sand Beaches. Reston, VA: American Society of Civil Engineers, 2002. http://dx.doi.org/10.1061/40640(305)3.

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Halley, Robert B. "11 Things a Geologist Thinks an Engineer Should Know About Carbonate Beaches." In First International Symposium on Carbonate Sand Beaches. Reston, VA: American Society of Civil Engineers, 2002. http://dx.doi.org/10.1061/40640(305)1.

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Hardaway, Jr., C. Scott, and James R. Gunn. "Shoreline Protection: Design Guidelines for Pocket Beaches in Chesapeake Bay, USA." In First International Symposium on Carbonate Sand Beaches. Reston, VA: American Society of Civil Engineers, 2002. http://dx.doi.org/10.1061/40640(305)10.

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Kos'yan, Ruben D., Vladimir M. Peshkov, Nikolay V. Yesin, and Sergey Yu Shcherbakov. "Carbonate Beaches of the Eastern Part of the Sea of Azov under Anthropogenic Impact." In First International Symposium on Carbonate Sand Beaches. Reston, VA: American Society of Civil Engineers, 2002. http://dx.doi.org/10.1061/40640(305)11.

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Calhoun, R. Scott, and Michael E. Field. "Beach and Reef-Flat Sediments along the South Shore of Molokai, Hawaii." In First International Symposium on Carbonate Sand Beaches. Reston, VA: American Society of Civil Engineers, 2002. http://dx.doi.org/10.1061/40640(305)12.

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Reports on the topic "Carbonyle"

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Benson, J. M., F. F. Hahn, and E. B. Barr. Acute inhalation toxicity of carbonyl sulfide. Office of Scientific and Technical Information (OSTI), December 1995. http://dx.doi.org/10.2172/381394.

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Robert, F. Quartz-carbonate vein gold. Natural Resources Canada/ESS/Scientific and Technical Publishing Services, 1995. http://dx.doi.org/10.4095/208002.

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Cutler, A. R. Metal Carbonyl-Hydrosilane Reactions and Hydrosilation Catalysis. Office of Scientific and Technical Information (OSTI), April 2001. http://dx.doi.org/10.2172/833810.

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Jansa, L. F. Lithostratigraphy 10: carbonate buildup morphology. Natural Resources Canada/ESS/Scientific and Technical Publishing Services, 1991. http://dx.doi.org/10.4095/210648.

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Yuh, C. Y., C. M. Haung, and R. Johnsen. Carbonate fuel cell matrix strengthening. Office of Scientific and Technical Information (OSTI), December 1995. http://dx.doi.org/10.2172/171342.

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Cutler, A. R. Selective transformation of carbonyl ligands to organic molecules. Office of Scientific and Technical Information (OSTI), May 1992. http://dx.doi.org/10.2172/5021885.

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Salad Hersi, O., and D. Lavoie. Pre-Cairnside Formation carbonate-rich sandstone: evidence for a Cambrian carbonate platform in southwestern Quebec? Natural Resources Canada/ESS/Scientific and Technical Publishing Services, 2000. http://dx.doi.org/10.4095/211172.

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Kishore K. Mohanty. Dilute Surfactant Methods for Carbonate Formations. Office of Scientific and Technical Information (OSTI), March 2004. http://dx.doi.org/10.2172/910178.

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Kishore K. Mohanty. Dilute Surfactant Methods for Carbonate Formations. Office of Scientific and Technical Information (OSTI), June 2004. http://dx.doi.org/10.2172/910179.

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Kishore K. Mohanty. Dilute Surfactant Methods for Carbonate Formations. Office of Scientific and Technical Information (OSTI), October 2005. http://dx.doi.org/10.2172/890025.

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