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Relevant bibliographies by topics / Cascade reaction

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Academic literature on the topic 'Cascade reaction'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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Journal articles on the topic "Cascade reaction"

1

Lee, Yoo Seok, Koun Lim, and Shelley D. Minteer. "Cascaded Biocatalysis and Bioelectrocatalysis: Overview and Recent Advances." Annual Review of Physical Chemistry 72, no. 1 (2021): 467–88. http://dx.doi.org/10.1146/annurev-physchem-090519-050109.

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Enzyme cascades are plentiful in nature, but they also have potential in artificial applications due to the possibility of using the target substrate in biofuel cells, electrosynthesis, and biosensors. Cascade reactions from enzymes or hybrid bioorganic catalyst systems exhibit extended substrate range, reaction depth, and increased overall performance. This review addresses the strategies of cascade biocatalysis and bioelectrocatalysis for ( a) CO2 fixation, ( b) high value-added product formation, ( c) sustainable energy sources via deep oxidation, and ( d) cascaded electrochemical enzymatic

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Lee, Chi-Sing, Guangyan Du, Gaopeng Wang, et al. "Syntheses of Diverse Natural Products via Dual-Mode Lewis Acid Induced Cascade Cyclization Reactions." Synlett 28, no. 12 (2017): 1394–406. http://dx.doi.org/10.1055/s-0036-1588777.

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The σ/π-binding properties of a series of Lewis acids was studied using DFT calculations. The results led to the identification of Zn(II)/In(III) as a suitable dual-mode Lewis acid for use in promoting cascade cyclization reactions. Based on this finding, we developed three new types of dual-mode Lewis acid induced cascade cyclization reactions and have demonstrated the utilities of each process in natural product synthesis.1 Introduction2 Dual-Mode Lewis Acids3 Prins/Conia-Ene Cascade Reaction and its Applications4 Diels–Alder/Carbocyclization Cascade Reaction and Applications4.1 First Genera

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Becker, Martin, Patrick Nikel, Jennifer N. Andexer, Stephan Lütz, and Katrin Rosenthal. "A Multi-Enzyme Cascade Reaction for the Production of 2′3′-cGAMP." Biomolecules 11, no. 4 (2021): 590. http://dx.doi.org/10.3390/biom11040590.

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Multi-enzyme cascade reactions for the synthesis of complex products have gained importance in recent decades. Their advantages compared to single biotransformations include the possibility to synthesize complex molecules without purification of reaction intermediates, easier handling of unstable intermediates, and dealing with unfavorable thermodynamics by coupled equilibria. In this study, a four-enzyme cascade consisting of ScADK, AjPPK2, and SmPPK2 for ATP synthesis from adenosine coupled to the cyclic GMP-AMP synthase (cGAS) catalyzing cyclic GMP-AMP (2′3′-cGAMP) formation was successfull

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Fateev, Ilja V., Maria A. Kostromina, Yuliya A. Abramchik, et al. "Multi-Enzymatic Cascades in the Synthesis of Modified Nucleosides: Comparison of the Thermophilic and Mesophilic Pathways." Biomolecules 11, no. 4 (2021): 586. http://dx.doi.org/10.3390/biom11040586.

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A comparative study of the possibilities of using ribokinase → phosphopentomutase → nucleoside phosphorylase cascades in the synthesis of modified nucleosides was carried out. Recombinant phosphopentomutase from Thermus thermophilus HB27 was obtained for the first time: a strain producing a soluble form of the enzyme was created, and a method for its isolation and chromatographic purification was developed. It was shown that cascade syntheses of modified nucleosides can be carried out both by the mesophilic and thermophilic routes from D-pentoses: ribose, 2-deoxyribose, arabinose, xylose, and

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Brusa, Alessandro, Debora Iapadre, Maria Edith Casacchia, et al. "Acetaldehyde in the Enders triple cascade reaction via acetaldehyde dimethyl acetal." Beilstein Journal of Organic Chemistry 19 (August 24, 2023): 1243–50. http://dx.doi.org/10.3762/bjoc.19.92.

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Asymmetric organocatalyzed multicomponent reactions represent an important toolbox in the field of organic synthesis to build complex scaffolds starting from simple starting materials. The Enders three-component cascade reaction was a cornerstone in the field and a plethora of organocatalyzed cascade reactions followed. However, acetaldehyde was not shown as a successful reaction partner, probably because of its high reactivity. Herein, we report the Enders-type cascade reaction using acetaldehyde dimethyl acetal, as a masked form of acetaldehyde. This strategy directly converts acetaldehyde,

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Calderini, Elia, Philipp Süss, Frank Hollmann, Rainer Wardenga, and Anett Schallmey. "Two (Chemo)-Enzymatic Cascades for the Production of Opposite Enantiomers of Chiral Azidoalcohols." Catalysts 11, no. 8 (2021): 982. http://dx.doi.org/10.3390/catal11080982.

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Multi-step cascade reactions have gained increasing attention in the biocatalysis field in recent years. In particular, multi-enzymatic cascades can achieve high molecular complexity without workup of reaction intermediates thanks to the enzymes’ intrinsic selectivity; and where enzymes fall short, organo- or metal catalysts can further expand the range of possible synthetic routes. Here, we present two enantiocomplementary (chemo)-enzymatic cascades composed of either a styrene monooxygenase (StyAB) or the Shi epoxidation catalyst for enantioselective alkene epoxidation in the first step, cou

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Gong, Jianxian, Zhen Yang, Yueqing Gu, and Ceheng Tan. "Diversity-Oriented Synthesis of Natural Products via Gold-Catalyzed Cascade Reactions." Synlett 29, no. 12 (2018): 1552–71. http://dx.doi.org/10.1055/s-0037-1610126.

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This account describes our group’s latest research in the field of diversity-oriented synthesis of natural products via gold-catalyzed cascade reactions. We present two general strategies based on gold-catalyzed cycloisomerization: a gold-catalyzed cascade reaction of 1,7-diynes and a pinacol-terminated gold-catalyzed cascade reaction. We highlight our development of synthetic methods for the construction of biologically active natural products by using these two strategies.1 Introduction2 Gold-Catalyzed Cascade Reactions of 1,7-Diynes2.1 Collective Synthesis of C15 Oxygenated Drimane-Type Ses

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Gu, Binjie, Xiaoli Yu, Zhaojun Xu, Feng Pan, and Dawei Wang. "A Single-Step Palladium-Catalysed Synthesis of Naphtho[2,3-b]Benzofuran-6,11-Diones and 2-(Hydroxyphenyl)Naphthalene-1,4-Diones." Journal of Chemical Research 41, no. 10 (2017): 564–68. http://dx.doi.org/10.3184/174751917x15045169836235.

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Palladium-catalysed competitive three-component C–H functionalisation reactions and cascade coupling ring-closing reactions of quinones with iodophenols in dihaloalkanes are described. During initial attempts to conduct C–H functionalisation reactions of quinones with iodophenols in dihaloalkanes, surprisingly a three-component C–H functionalisation reaction was discovered. Furthermore, as the reaction of chloroquinones with iodophenols was in progress, another surprising cascade coupling with ring closure was achieved. This provided an efficient single-step synthesis of naphtho[2,3- b]benzofu

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Bronstein, Lyudmila M., and Valentina G. Matveeva. "Multifunctional Catalysts for Cascade Reactions in Biomass Processing." Nanomaterials 14, no. 23 (2024): 1937. https://doi.org/10.3390/nano14231937.

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Multifunctional catalysts have received considerable attention in the cascade reactions of biomass processing. A cascade (or tandem) reaction is realized when multiple reaction steps that require different catalysts are performed in a one-step process. These reactions require bi- or multifunctional catalysts or catalyst mixtures to serve successfully at each reaction step. In this review article, we discuss the major factors of the catalyst design influencing the structure–property relationships, which could differ depending on the catalyst type. The major factors include the amounts and stren

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Castagnolo, Daniele, and Kate Lauder. "Photo-Biocatalytic Cascades for the Synthesis of Volatile Sulfur Compounds and Chemical Building Blocks." Synlett 31, no. 08 (2020): 737–44. http://dx.doi.org/10.1055/s-0039-1690784.

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Biocatalysis is a branch of catalysis that exploits enzymes to perform highly stereoselective chemical transformations under mild and sustainable conditions. This Synpact highlights how biocatalysis can be used in the synthesis of chiral 1,3-mercaptoalkanols, an important class of compounds responsible for the flavours and aromas of many foods and beverages. The identification of two ketoreductase (KRED) enzymes able to reduce prochiral ketone precursors enantioselectively to 1,3-mercaptoalkanols bearing a C–O stereocentre is presented. In addition, the combination of a photocatalytic thia-Mic

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Dissertations / Theses on the topic "Cascade reaction"

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Rimmington, Stuart. "A radical cascade reaction approach towards Taxol." Thesis, University of Nottingham, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.479330.

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Kinnell, Angela Dawn. "Development of an organo-and enzyme-catalysed cascade reaction." Thesis, University of Leeds, 2010. http://etheses.whiterose.ac.uk/1132/.

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This thesis describes the development of a novel one-pot reaction (Scheme 1). The reaction combines organo- and enzyme-catalysis in an aldol/aldol cascade for the first time. The bicatalytic, three-component assembly involves two aldol reactions: an organocatalysed reaction and an aldol reaction catalysed by an aldolase. The feasibility of the one-pot reaction was evaluated by testing whether the aldol intermediates 3 were substrates for the E192N aldolase variant of Nacetylneuraminic acid lyase. A range of compounds was selected as potential substrates for the enzyme. The synthesis of the com

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Poon, Hon-suen. "Michael initiated cascade reaction sequences and their application in target synthesis." Thesis, University of Southampton, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.246237.

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Marcotte, Joel. "Formal Synthesis of (+/-) Morphine via an Oxy-cope/Claisen/Ene Reaction Cascade." Thèse, Université d'Ottawa / University of Ottawa, 2012. http://hdl.handle.net/10393/23560.

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For years now, opium alkaloids and morphinans have been attractive synthetic targets for numerous organic chemists due to their important biological activity and interesting molecular architecture. Morphine is one of the most potent analgesic drugs used to alleviate severe pain. Our research group maintains a longstanding interest in tandem pericyclic reactions such as the oxy-Cope/Claisen/ene reaction cascade and their application to the total synthesis of complex natural products. Herein we report the ventures towards the formal synthesis of (+/-)-morphine based on the novel tandem oxy- Cope

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Naoe, Saori. "Synthesis of Fused-Ring Compounds through Gold-Catalyzed Cascade Reactions." 京都大学 (Kyoto University), 2016. http://hdl.handle.net/2433/215495.

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Shah, Parin Ajay. "Synthesis of terpenoids using a tandem cationic cascade cyclization-electrophilic aromatic substitution reaction." Diss., University of Iowa, 2018. https://ir.uiowa.edu/etd/6639.

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The terpene and terpenoid family of compounds is considered to be the largest group of natural products. These compounds not only display great diversity in their structural features but are also known to have a multitude of biological activities including but not limited to anti-bacterial, anti-cancer, anti-inflammatory, and anti-HIV properties. Remarkably, all the terpenoids formed in nature come from two molecules viz. isopentenyl pyrophosphate and its isomer, dimethylallyl pyrophosphate both consisting of just five carbons but assembled in many ways. Nature utilizes highly efficient, enzym

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LIN, PENG. "Enzyme cascade reactions on 3D DNA scaffold with dynamic shape transformation." Doctoral thesis, Kyoto University, 2021. http://hdl.handle.net/2433/265209.

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京都大学<br>新制・課程博士<br>博士(エネルギー科学)<br>甲第23437号<br>エネ博第424号<br>新制||エネ||81(附属図書館)<br>京都大学大学院エネルギー科学研究科エネルギー基礎科学専攻<br>(主査)教授森井孝, 教授佐川尚, 教授片平正人<br>学位規則第4条第1項該当<br>Doctor of Energy Science<br>Kyoto University<br>DFAM

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Belletti, Giada. "Organocatalytic Enantioselective Vinylogous Aldol-Lactonization Cascade Reaction of 3-Alkylidene Oxindoles to Trifluoromethyl Ketones." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2017. http://amslaurea.unibo.it/14463/.

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In this work, an highly enantioselective vinylogous aldol-lactonization cascade reaction of 3-alkylidene oxindole to α,β-unsaturated trifluoromethyl ketone, promoted by bifunctional organocatalysts, is presented. The reaction proceed through 1,2-addition followed by cascade lactonization to afford an unsaturated lactone bearing a chiral trifluoromethylated tetrasubstituted carbon stereocenter with high enantioselectivity and moderate yield. Nevertheless, also the two E/Z isomers of the correspondent 1,2-addition product are obtained.

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Pelletier, Sophie Marie-Clémentine. "One-pot nitro-Mannich cascade reactions : new methodologies and synthetic applications." Thesis, University of Oxford, 2011. http://ora.ox.ac.uk/objects/uuid:283641bf-bb4e-48a8-8a28-2e048b8c4ea6.

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Pyrrolidine and pyrrolidinone rings are common motifs found in many biologically active natural products and drugs. Accordingly, our work focuses on the development of new methodologies for their one-pot synthesis. An efficient diastereoselective nitro-Mannich / lactamisation reaction cascade of methyl 3-nitropropanoate with cyclic and acyclic imines for the direct preparation of trans-monocyclic and fused tricyclic pyrrolidinone derivatives was developed. The reaction is easy to perform, broad in scope and tolerates a wide variety of functional groups. For the monocyclic methodology, 28 examp

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Zhu, Koudi. "Model Studies Towards the Total Synthesis of Lyconadin A via An Acyl Radical Cascade Reaction." Diss., CLICK HERE for online access, 2006. http://contentdm.lib.byu.edu/ETD/image/etd1364.pdf.

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Books on the topic "Cascade reaction"

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Xu, Peng-Fei, and Wei Wang, eds. Catalytic Cascade Reactions. John Wiley & Sons, Inc, 2013. http://dx.doi.org/10.1002/9781118356654.

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Müller, Thomas J. J., ed. Metal Catalyzed Cascade Reactions. Springer Berlin Heidelberg, 2006. http://dx.doi.org/10.1007/11603696.

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Larraufie, Marie-Helene. Development of New Radical Cascades and Multi-Component Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-01324-4.

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Vasterman, Peter, ed. From Media Hype to Twitter Storm. Amsterdam University Press, 2018. http://dx.doi.org/10.5117/9789462982178.

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The word media hype is often used as rhetorical argument to dismiss waves of media attention as overblown, disproportional and exaggerated. But these explosive news waves, as well as - nowadays - the twitter storms, are object of scientific research, because they are an important phenomenon in the public area. Sometimes it is indeed 'much ado about nothing' but in many cases these media storms have play an important role in political issues, scandals and crises. Twitter storms sometimes ruin reputations within hours. Although different concepts are used, such as media hypes, news waves, media

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Catalytic Cascade Reactions. John Wiley & Sons Inc, 2014.

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Wei, Wang, and Peng-Fei Xu. Catalytic Cascade Reactions. Wiley & Sons, Incorporated, John, 2013.

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Wei, Wang, and Peng-Fei Xu. Catalytic Cascade Reactions. Wiley & Sons, Limited, John, 2013.

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Wei, Wang, and Peng-Fei Xu. Catalytic Cascade Reactions. Wiley & Sons, Incorporated, John, 2013.

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Wei, Wang, and Peng-Fei Xu. Catalytic Cascade Reactions. Wiley & Sons, Incorporated, John, 2013.

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Wei, Wang, and Peng-Fei Xu. Catalytic Cascade Reactions. Wiley & Sons, Incorporated, John, 2013.

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Book chapters on the topic "Cascade reaction"

1

Petermeier, Philipp, and Selin Kara. "Enzyme Cascade Reaction Engineering." In Enzyme Cascade Design and Modelling. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-65718-5_7.

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Ohashi, Eisaku, Kohei Takeuchi, Keiji Tanino, and Kosuke Namba. "Utilizing the pKa Concept to Address Unfavorable Equilibrium Reactions in the Total Synthesis of Palau’amine." In Modern Natural Product Synthesis. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-1619-7_23.

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AbstractHerein, we introduce the pKa concept as a strategy for proceeding with unfavorable reactions in the total synthesis of palau’amine. The cascade reaction aimed at constructing palau’amine’s ABDE tetracyclic ring core initially encountered poor reproducibility due to an unfavorable equilibrium reaction. However, the addition of 1.0 equivalent of AcOH enabled the progression of the unfavorable equilibrium reaction. In the second-generation synthesis, the improved cascade reaction to construct CDE ring core also initially did not proceed due to an unfavorable equilibrium reaction, but usin

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Ašperger, Smiljko. "Cascade Molecules (Dendrimers)." In Chemical Kinetics and Inorganic Reaction Mechanisms. Springer US, 2003. http://dx.doi.org/10.1007/978-1-4419-9276-5_14.

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Hiessl, Robert, Joscha Kleber, and Andreas Liese. "Enzyme Cascade Reaction Monitoring and Control." In Enzyme Cascade Design and Modelling. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-65718-5_9.

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Voigt, Benjamin, and Rainer Mahrwald. "Organocatalyzed Cascade Reaction in Carbohydrate Chemistry." In Domino and Intramolecular Rearrangement Reactions as Advanced Synthetic Methods in Glycoscience. John Wiley & Sons, Inc., 2016. http://dx.doi.org/10.1002/9781119044222.ch2.

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Mahrwald, Rainer. "Organocatalyzed Cascade Reaction in Carbohydrate Chemistry." In SpringerBriefs in Molecular Science. Springer International Publishing, 2015. http://dx.doi.org/10.1007/978-3-319-17593-5_3.

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Ogura, Akihiro, and Ken-ichi Takao. "Total Syntheses of (+)-Aquatolide and Related Humulanolides." In Modern Natural Product Synthesis. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-1619-7_13.

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AbstractHerein, the total syntheses of (+)-aquatolide, a humulane-derived sesquiterpenoid lactone, and five other related humulanolides are described. The key reactions in these syntheses are a cascade metathesis reaction of cyclobutenecarboxylate to construct a γ-butenolide with an unsaturated aldehyde side chain, an intramolecular Nozaki–Hiyama–Takai–Kishi reaction to form an all-trans-humulene lactone skeleton, and a biosynthesis-inspired [2 + 2] photocycloaddition to provide a bridged 5/5/4/8-ring system. A cycloaddition giving a 5/4/4/7-ring system was also found. In addition, biological

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Zhu, Xiaoli, Chang Feng, and Genxi Li. "Nicking Enzyme-Assisted Branched-Chain RCA Reaction for Cascade DNA Amplification." In Rolling Circle Amplification (RCA). Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-42226-8_5.

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Song, Aiguo, and Wei Wang. "AMINE-CATALYZED CASCADE REACTIONS." In Catalytic Cascade Reactions. John Wiley & Sons, Inc, 2013. http://dx.doi.org/10.1002/9781118356654.ch1.

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Jiang, Jun, and Liu-Zhu Gong. "BRØNSTED ACID-CATALYZED CASCADE REACTIONS." In Catalytic Cascade Reactions. John Wiley & Sons, Inc, 2013. http://dx.doi.org/10.1002/9781118356654.ch2.

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Conference papers on the topic "Cascade reaction"

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David, J. C., Demid Zharenov, Olivier Lourgo, Joseph Cugnon, and Jason Hirtz. "Antimatter-Nucleus reactions with the Liège IntraNuclear Cascade (INCL) code." In International Conference on Exotic Atoms and Related Topics and Conference on Low Energy Antiprotons. Sissa Medialab, 2025. https://doi.org/10.22323/1.480.0006.

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Tauseef, Muhammad Fahad, Muhammad Uzair, and Ghulam Abbas. "Active and Reactive Power Control in Asymmetrical Cascaded Multilevel Inverter." In 2024 3rd International Conference on Emerging Trends in Electrical, Control, and Telecommunication Engineering (ETECTE). IEEE, 2024. https://doi.org/10.1109/etecte63967.2024.10824024.

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Jiang, Yu-Chen, and Jun-Min Wang. "Neural operators of backstepping controller gain kernels for an ODE cascaded with a reaction-diffusion equation." In 2024 43rd Chinese Control Conference (CCC). IEEE, 2024. http://dx.doi.org/10.23919/ccc63176.2024.10661479.

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Kroutil, W., S. Mayer, and K. Faber. "Enzyme-Initiated Domino-(Cascade)-Reaction." In The 4th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01912.

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Flamino, James, and Boleslaw K. Szymanski. "A Reaction-Based Approach to Information Cascade Analysis." In 2019 28th International Conference on Computer Communication and Networks (ICCCN). IEEE, 2019. http://dx.doi.org/10.1109/icccn.2019.8847096.

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Jinhe Wang and Nan Zhang. "Application of cascade control in the polymerase chain reaction." In 2008 3rd IEEE Conference on Industrial Electronics and Applications (ICIEA). IEEE, 2008. http://dx.doi.org/10.1109/iciea.2008.4582914.

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Yang Chen, Zhijiang Shao, Jixin Qian, Kexin Wang, Zhiliang Zhan, and Zuhua Xu. "Dynamic optimization of multivariable endothermic reaction in cascade CSTR." In 2010 8th World Congress on Intelligent Control and Automation (WCICA 2010). IEEE, 2010. http://dx.doi.org/10.1109/wcica.2010.5553780.

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Duarte, H. "The nonelastic reaction code BRIEFF and its intranuclear cascade BRIC." In International Conference on Nuclear Data for Science and Technology. EDP Sciences, 2007. http://dx.doi.org/10.1051/ndata:07384.

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Simões, Juliana B., Ângelo de Fátima, Luiz Claudio A. Barbosa, and Sergio A. Fernandes. "Calixarene Catalyze Cascade Povarov−Hydrogen-Transfer Reaction in Synthesis of Quinolines." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013915211651.

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Zhang, Shanwen, Changqing Yu, and Cong Xu. "Adverse Drug Reaction from Social Media by Cascade Feature Extraction and Meta-Learner." In SPML 2023: 2023 6th International Conference on Signal Processing and Machine Learning. ACM, 2023. http://dx.doi.org/10.1145/3614008.3614046.

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Reports on the topic "Cascade reaction"

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Stoller, R. E., and L. R. Greenwood. Subcascade formation in displacement cascade simulations: Implications for fusion reactor materials. Office of Scientific and Technical Information (OSTI), 1998. http://dx.doi.org/10.2172/335408.

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Ladd, A. J. C. Condensation of ablated first-wall materials in the cascade inertial confinement fusion reactor. Office of Scientific and Technical Information (OSTI), 1985. http://dx.doi.org/10.2172/5841435.

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Wampler, William R., and Samuel M. Myers. Transport-reaction model for defect and carrier behavior within displacement cascades in gallium arsenide. Office of Scientific and Technical Information (OSTI), 2014. http://dx.doi.org/10.2172/1204088.

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Delwiche, Michael, Boaz Zion, Robert BonDurant, Judith Rishpon, Ephraim Maltz, and Miriam Rosenberg. Biosensors for On-Line Measurement of Reproductive Hormones and Milk Proteins to Improve Dairy Herd Management. United States Department of Agriculture, 2001. http://dx.doi.org/10.32747/2001.7573998.bard.

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The original objectives of this research project were to: (1) develop immunoassays, photometric sensors, and electrochemical sensors for real-time measurement of progesterone and estradiol in milk, (2) develop biosensors for measurement of caseins in milk, and (3) integrate and adapt these sensor technologies to create an automated electronic sensing system for operation in dairy parlors during milking. The overall direction of research was not changed, although the work was expanded to include other milk components such as urea and lactose. A second generation biosensor for on-line measuremen

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