Academic literature on the topic 'Cascade Reactions'

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Journal articles on the topic "Cascade Reactions"

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Lee, Yoo Seok, Koun Lim, and Shelley D. Minteer. "Cascaded Biocatalysis and Bioelectrocatalysis: Overview and Recent Advances." Annual Review of Physical Chemistry 72, no. 1 (2021): 467–88. http://dx.doi.org/10.1146/annurev-physchem-090519-050109.

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Enzyme cascades are plentiful in nature, but they also have potential in artificial applications due to the possibility of using the target substrate in biofuel cells, electrosynthesis, and biosensors. Cascade reactions from enzymes or hybrid bioorganic catalyst systems exhibit extended substrate range, reaction depth, and increased overall performance. This review addresses the strategies of cascade biocatalysis and bioelectrocatalysis for ( a) CO2 fixation, ( b) high value-added product formation, ( c) sustainable energy sources via deep oxidation, and ( d) cascaded electrochemical enzymatic
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Cai, Yunfei, Sishi Zhong, and Lei Xu. "Recent Advances on Piancatelli Reactions and Related Cascade Processes." Synthesis 54, no. 03 (2021): 589–99. http://dx.doi.org/10.1055/s-0041-1737125.

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AbstractThe Piancatelli reaction, which is the rearrangement of 2-furylcarbinol to cyclopentenone, involves a key furanoxonium ion intermediate and a furan ring opening-4π electrocyclization process. In recent years, the original oxa-Piancatelli reaction has been extended to a large family of aza- and carbo-Piancatelli reactions and related cascade processes, providing a powerful platform for the construction of diverse functionalized cyclopentenones and polycyclic cyclopentanones. Meanwhile, chiral Brønsted/Lewis acid based catalytic asymmetric approaches to Piancatelli reactions have also be
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Bhunia, Sabyasachi, and Rai-Shung Liu. "Access to molecular complexity via gold- and platinum-catalyzed cascade reactions." Pure and Applied Chemistry 84, no. 8 (2012): 1749–57. http://dx.doi.org/10.1351/pac-con-11-09-13.

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We report recent progress on Au- and Pt-catalyzed cascade reactions to access complicated molecular frameworks. Reported reactions include new cyclization/cycloaddition cascades on carbonyl and epoxide substrates tethered with an allene, alkene, and alkyne. Such substrates enable Au-catalyzed cascade reactions comprising an initial cyclization to form reactive 1,n-dipole that undergoes subsequent cycloadditions with suitable dipolarophiles.
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Lee, Chi-Sing, Guangyan Du, Gaopeng Wang, et al. "Syntheses of Diverse Natural Products via Dual-Mode Lewis Acid Induced Cascade Cyclization Reactions." Synlett 28, no. 12 (2017): 1394–406. http://dx.doi.org/10.1055/s-0036-1588777.

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The σ/π-binding properties of a series of Lewis acids was studied using DFT calculations. The results led to the identification of Zn(II)/In(III) as a suitable dual-mode Lewis acid for use in promoting cascade cyclization reactions. Based on this finding, we developed three new types of dual-mode Lewis acid induced cascade cyclization reactions and have demonstrated the utilities of each process in natural product synthesis.1 Introduction2 Dual-Mode Lewis Acids3 Prins/Conia-Ene Cascade Reaction and its Applications4 Diels–Alder/Carbocyclization Cascade Reaction and Applications4.1 First Genera
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Fateev, Ilja V., Maria A. Kostromina, Yuliya A. Abramchik, et al. "Multi-Enzymatic Cascades in the Synthesis of Modified Nucleosides: Comparison of the Thermophilic and Mesophilic Pathways." Biomolecules 11, no. 4 (2021): 586. http://dx.doi.org/10.3390/biom11040586.

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A comparative study of the possibilities of using ribokinase → phosphopentomutase → nucleoside phosphorylase cascades in the synthesis of modified nucleosides was carried out. Recombinant phosphopentomutase from Thermus thermophilus HB27 was obtained for the first time: a strain producing a soluble form of the enzyme was created, and a method for its isolation and chromatographic purification was developed. It was shown that cascade syntheses of modified nucleosides can be carried out both by the mesophilic and thermophilic routes from D-pentoses: ribose, 2-deoxyribose, arabinose, xylose, and
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Becker, Martin, Patrick Nikel, Jennifer N. Andexer, Stephan Lütz, and Katrin Rosenthal. "A Multi-Enzyme Cascade Reaction for the Production of 2′3′-cGAMP." Biomolecules 11, no. 4 (2021): 590. http://dx.doi.org/10.3390/biom11040590.

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Multi-enzyme cascade reactions for the synthesis of complex products have gained importance in recent decades. Their advantages compared to single biotransformations include the possibility to synthesize complex molecules without purification of reaction intermediates, easier handling of unstable intermediates, and dealing with unfavorable thermodynamics by coupled equilibria. In this study, a four-enzyme cascade consisting of ScADK, AjPPK2, and SmPPK2 for ATP synthesis from adenosine coupled to the cyclic GMP-AMP synthase (cGAS) catalyzing cyclic GMP-AMP (2′3′-cGAMP) formation was successfull
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Ohno, Hiroaki, and Shinsuke Inuki. "Recent Progress in Palladium-Catalyzed Cascade Cyclizations for Natural Product Synthesis." Synthesis 50, no. 04 (2018): 700–710. http://dx.doi.org/10.1055/s-0036-1589165.

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Cascade reactions (also represented as domino reactions) realize the step-economical direct construction of natural product core structures. The use of atom-economical elementary reactions in cascade processes can minimize waste production and avoid prefunctionalization of the substrates. Palladium catalysis, which promotes a variety of atom-economical elementary reactions, has long been used as a powerful approach to the direct formation of complex heterocycles. In this short review, palladium-catalyzed cascade reactions for the construction of core structures of natural products reported in
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Odell, Luke, Mats Larhed, and Linda Åkerbladh. "Palladium-Catalyzed Molybdenum Hexacarbonyl-Mediated Gas-Free Carbonylative Reactions." Synlett 30, no. 02 (2018): 141–55. http://dx.doi.org/10.1055/s-0037-1610294.

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This account summarizes Pd(0)-catalyzed Mo(CO)6-mediated gas-free carbonylative reactions published in the period October 2011 to May 2018. Presented reactions include inter- and intramolecular carbonylations, carbonylative cross-couplings, and carbonylative multicomponent reactions using Mo(CO)6 as a solid source of CO. The presented methodologies were developed mainly for small-scale applications, avoiding the problematic use of gaseous CO in a standard laboratory. In most cases, the reported Mo(CO)6-mediated carbonylations were conducted in sealed vials or by using two-chamber solutions.1 I
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Castagnolo, Daniele, and Kate Lauder. "Photo-Biocatalytic Cascades for the Synthesis of Volatile Sulfur Compounds and Chemical Building Blocks." Synlett 31, no. 08 (2020): 737–44. http://dx.doi.org/10.1055/s-0039-1690784.

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Biocatalysis is a branch of catalysis that exploits enzymes to perform highly stereoselective chemical transformations under mild and sustainable conditions. This Synpact highlights how biocatalysis can be used in the synthesis of chiral 1,3-mercaptoalkanols, an important class of compounds responsible for the flavours and aromas of many foods and beverages. The identification of two ketoreductase (KRED) enzymes able to reduce prochiral ketone precursors enantioselectively to 1,3-mercaptoalkanols bearing a C–O stereocentre is presented. In addition, the combination of a photocatalytic thia-Mic
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Biswal, Swoyam Srirupa, and Vaibhav Wasnik. "Limitations to extracellular concentration sensing through signaling cascades." Journal of Statistical Mechanics: Theory and Experiment 2024, no. 7 (2024): 073501. http://dx.doi.org/10.1088/1742-5468/ad5436.

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Abstract Signaling cascades refer to sequential biochemical reactions that occur in the cytoplasm of living cells in response to the binding of a ligand to a cell surface receptor, triggering a cellular response. Living cells need to sense extracellular concentrations with high precision. In this paper, we study the limitations of extracellular concentration measurement in linear signaling cascades. We find that as long as the cascade is linear and measurement times are much larger or much smaller than the timescales of the cytoplasmic reactions, the error in concentration measurement is indep
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Dissertations / Theses on the topic "Cascade Reactions"

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Dumrongchai, Nuethip. "Palladium Catalyzed Multicomponent Cascade Reactions." Thesis, University of Leeds, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.487516.

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This Thesis is divided into three parts: Introduction (Chapter 1), Result and Discussion (Chapter 2) and Experimental (Chapter 3). The Introduction (Chapter 1) provides a review of the recent literature relating to the 1,3dipolar cycloaddition reactions. It· covers nitrones, azomethine ylides and azomethine imines. The Result and Discussion. section (Chapter 2) deals with the author's work which is . concerned with developing four novel multicomponent cascade reactions. These are (i) a 3- component cascade involving bifunctional aryl halide! Michael acceptors, allene and arriine or sulphona
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Pocock, Ian. "Novel cascade aryne-capture/rearrangement reactions." Thesis, University of Huddersfield, 2014. http://eprints.hud.ac.uk/id/eprint/23743/.

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Arynes are reactive intermediates that have been an academic curiosity for over a century. A recent renaissance of interest in the chemistry of these intermediates can be traced back to the development of ortho-(silyl)aryl triflates as aryne precursors. The application of aryne chemistry outside academia has been precluded by the expense and laborious preparation of these precursors. Diphenyliodonium-2-carboxylate has been shown to be a stable and inexpensive benzyne precursor, however application has been limited due to the high temperature (>160 ºC) and long reaction times required to genera
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Demircan, Aydin. "Cascade reactions involving a furan core." Thesis, University of Sussex, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297561.

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Amjad, ʿAlī. "Cobalt-mediated cascade cyclisation reactions in synthesis." Thesis, University of Nottingham, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.357981.

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Too, Heng Kwee Marie Kathleen Sien Kiow. "Glycomimetics and peptidomimetics via catalytic cascade reactions." Thesis, University of Leeds, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.405741.

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Annis, Michael Colin. "Free radical cascade reactions involving furan rings." Thesis, University of Sussex, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.394991.

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Yap, Aaron J. "Hydrogenolysis, hydrogenation and nanoencapsulation in cascade reactions." Thesis, The University of Sydney, 2012. https://hdl.handle.net/2123/29153.

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Catalytic nanoreactors, prepared by the Layer-by-Layer encapsulation of zeolite H-Beta, were used in the dynamic kinetic resolution (DKR) of 1-phenylethanol and 1-indanol. Yields for both alcohols were clearly above 50%, with ee’s over 85%, indicating successful protection of the pH-sensitive enzyme, candida antarctica lipase B, from the acidic zeolite. Attention proceeded to the DKR of amines, which can involve the undesired hydrogenolysis reaction during the racemisation step. Thus, the phenomenon of hydrogenolysis was investigated. The hydrogenolysis of various amines, imines, and
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Double, Philip John. "Acyl radical cascade reactions : the synthesis of azasteroids." Thesis, University of Nottingham, 1998. http://eprints.nottingham.ac.uk/27769/.

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Our work has been concerned with the synthesis of azasteroid ring systems, utilising acyl radical cascade reactions. Chapter 1 comprises an overview of published work relevant to our studies: an analysis of steroid biosynthesis and synthesis; a review of the use of azasteroids, their biological activity and current synthetic techniques in azasteroid formation. This initial chapter also includes an introduction to published work in the area of nitrogen heterocycle synthesis using radical reactions and finally the use of acyl radicals in synthesis, particularly cascade reactions. Chapter 2 start
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Chaudhry, Sofia Javid. "Application of statistics and robotics to cascade reactions." Thesis, University of Leeds, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.551229.

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My thesis is composed of four themed sections: (1) The introduction reviews the Prins reaction, focusing mainly on the Prins condensation-cyclisation of homoallylic alcohols with aldehydes giving substituted tetrahydropyrans. This section also briefly reviews the Prins reaction giving dihydropyrans and the aza-Prins reaction giving piperidines and dihydropiperidines. (2) The results and discussion section details the author's own work and is further divided into two parts. The first part describes the synthesis of novel homoallylic alcohols and bis-homoallylic alcohols from Pd(O)/ln(O) mediate
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Boehm, Haydn M. "Tandem radical cascade cyclisation reactions in steroid synthesis." Thesis, University of Nottingham, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.364673.

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Books on the topic "Cascade Reactions"

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Xu, Peng-Fei, and Wei Wang, eds. Catalytic Cascade Reactions. John Wiley & Sons, Inc, 2013. http://dx.doi.org/10.1002/9781118356654.

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Müller, Thomas J. J., ed. Metal Catalyzed Cascade Reactions. Springer Berlin Heidelberg, 2006. http://dx.doi.org/10.1007/11603696.

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Larraufie, Marie-Helene. Development of New Radical Cascades and Multi-Component Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-01324-4.

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Vasterman, Peter, ed. From Media Hype to Twitter Storm. Amsterdam University Press, 2018. http://dx.doi.org/10.5117/9789462982178.

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The word media hype is often used as rhetorical argument to dismiss waves of media attention as overblown, disproportional and exaggerated. But these explosive news waves, as well as - nowadays - the twitter storms, are object of scientific research, because they are an important phenomenon in the public area. Sometimes it is indeed 'much ado about nothing' but in many cases these media storms have play an important role in political issues, scandals and crises. Twitter storms sometimes ruin reputations within hours. Although different concepts are used, such as media hypes, news waves, media
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Wei, Wang, and Peng-Fei Xu. Catalytic Cascade Reactions. Wiley & Sons, Incorporated, John, 2013.

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Wei, Wang, and Peng-Fei Xu. Catalytic Cascade Reactions. Wiley & Sons, Limited, John, 2013.

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Wei, Wang, and Peng-Fei Xu. Catalytic Cascade Reactions. Wiley & Sons, Incorporated, John, 2013.

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Wei, Wang, and Peng-Fei Xu. Catalytic Cascade Reactions. Wiley & Sons, Incorporated, John, 2013.

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Wei, Wang, and Peng-Fei Xu. Catalytic Cascade Reactions. Wiley & Sons, Incorporated, John, 2013.

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Catalytic Cascade Reactions. John Wiley & Sons Inc, 2014.

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Book chapters on the topic "Cascade Reactions"

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Zhang, Wei, and Wen-Bin Yi. "Cascade Reactions." In SpringerBriefs in Molecular Science. Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-030-22596-4_3.

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Dürrenberger, Marc, Valentin Köhler, Yvonne M. Wilson, et al. "Cascade Reactions." In Practical Methods for Biocatalysis and Biotransformations 3. John Wiley & Sons, Ltd, 2016. http://dx.doi.org/10.1002/9781118697856.ch08.

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Song, Aiguo, and Wei Wang. "AMINE-CATALYZED CASCADE REACTIONS." In Catalytic Cascade Reactions. John Wiley & Sons, Inc, 2013. http://dx.doi.org/10.1002/9781118356654.ch1.

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Jiang, Jun, and Liu-Zhu Gong. "BRØNSTED ACID-CATALYZED CASCADE REACTIONS." In Catalytic Cascade Reactions. John Wiley & Sons, Inc, 2013. http://dx.doi.org/10.1002/9781118356654.ch2.

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Wang, Yao, and Peng-Fei Xu. "APPLICATION OF ORGANOCATALYTIC CASCADE REACTIONS IN NATURAL PRODUCT SYNTHESIS AND DRUG DISCOVERY." In Catalytic Cascade Reactions. John Wiley & Sons, Inc, 2013. http://dx.doi.org/10.1002/9781118356654.ch3.

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Wang, Yanzhao, and Liming Zhang. "GOLD-CATALYZED CASCADE REACTIONS." In Catalytic Cascade Reactions. John Wiley & Sons, Inc, 2013. http://dx.doi.org/10.1002/9781118356654.ch4.

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Wang, Yanguang, and Ping Lu. "CASCADE REACTIONS CATALYZED BY RUTHENIUM, IRON, IRIDIUM, RHODIUM, AND COPPER." In Catalytic Cascade Reactions. John Wiley & Sons, Inc, 2013. http://dx.doi.org/10.1002/9781118356654.ch5.

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Gao, Hongyin, and Junliang Zhang. "PALLADIUM-CATALYZED CASCADE REACTIONS OF ALKENES, ALKYNES, AND ALLENES." In Catalytic Cascade Reactions. John Wiley & Sons, Inc, 2013. http://dx.doi.org/10.1002/9781118356654.ch6.

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Xu, Peng-Fei, and Hao Wei. "USE OF TRANSITION METAL-CATALYZED CASCADE REACTIONS IN NATURAL PRODUCT SYNTHESIS AND DRUG DISCOVERY." In Catalytic Cascade Reactions. John Wiley & Sons, Inc, 2013. http://dx.doi.org/10.1002/9781118356654.ch7.

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Li, Hexing, and Fang Zhang. "ENGINEERING MONO- AND MULTIFUNCTIONAL NANOCATALYSTS FOR CASCADE REACTIONS." In Catalytic Cascade Reactions. John Wiley & Sons, Inc, 2013. http://dx.doi.org/10.1002/9781118356654.ch8.

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Conference papers on the topic "Cascade Reactions"

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David, J. C., Demid Zharenov, Olivier Lourgo, Joseph Cugnon, and Jason Hirtz. "Antimatter-Nucleus reactions with the Liège IntraNuclear Cascade (INCL) code." In International Conference on Exotic Atoms and Related Topics and Conference on Low Energy Antiprotons. Sissa Medialab, 2025. https://doi.org/10.22323/1.480.0006.

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Jiang, Yu-Chen, and Jun-Min Wang. "Neural operators of backstepping controller gain kernels for an ODE cascaded with a reaction-diffusion equation." In 2024 43rd Chinese Control Conference (CCC). IEEE, 2024. http://dx.doi.org/10.23919/ccc63176.2024.10661479.

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Steavenson, Benjamin R., and Daniel I. Pineda. "Quantum cascade laser absorption tomography via Boltzmann regression for nitrous oxide temperature and concentration in small-diameter reacting flows." In Laser Applications to Chemical, Security and Environmental Analysis. Optica Publishing Group, 2024. https://doi.org/10.1364/lacsea.2024.lth1a.3.

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Laser absorption tomography in the mid-wave infrared is coupled with Boltzmann regression techniques to spatially resolve nitrous oxide concentration and temperature in small-diameter reacting flows relevant to nitrogen-based fuels.
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Barrow, Emma A., Iryna Bennett, Franjo Cecelja, Eduardo Garciadiego-Ortega, Megan Thompson, and Dimitrios Tsaoulidis. "Simulation and Optimisation of Cryogenic Distillation and Isotopic Equilibrator Cascades for Hydrogen Isotope Separation Processes in the Fusion Fuel Cycle." In The 35th European Symposium on Computer Aided Process Engineering. PSE Press, 2025. https://doi.org/10.69997/sct.124889.

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Hydrogen isotope separation is a critical component of the fusion fuel cycle, particularly for achieving the desired purity levels of deuterium and tritium while minimising tritium inventory. This study investigates the cryogenic distillation of hydrogen isotopes, with a focus on the effects of isotopic equilibrium reactions at reduced temperatures and different system configurations. A one-column architecture was analysed to evaluate the impact of feed and side stream equilibrator temperatures and flowrates on separation performance and tritium inventory. Additionally, a two-column architectu
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Oh, Yongseok. "Cascade Production in Gamma N Reactions." In EBAC Workshop on Extractions and Interpretations of Hadron Resonances and Multi-meson Production Reactions with 12 GeV Upgrade, Newport News, VA, May 27, 2010. US DOE, 2010. http://dx.doi.org/10.2172/1996562.

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Rosário Rodrigues, José Augusto, and NatÁlia Maria Polidoro. "Cascade Redox Reactions with allylic alcohols in biocatalysis." In XXIII Congresso de Iniciação Científica da Unicamp. Galoá, 2015. http://dx.doi.org/10.19146/pibic-2015-37703.

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Cugnon, J. "Light Cluster Production in the Cascade Stage of Spallation Reactions." In INTERNATIONAL CONFERENCE ON NUCLEAR DATA FOR SCIENCE AND TECHNOLOGY. AIP, 2005. http://dx.doi.org/10.1063/1.1945229.

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Navarro Vega, Jessica, David Cruz Cruz, and Clarisa Villegas Gómez. "Synthesis and Diversification of Chiral Spirooxindoles via Organocatalytic Cascade Reactions." In ECSOC 2023. MDPI, 2023. http://dx.doi.org/10.3390/ecsoc-27-16100.

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Vicario, Jose Luis, Efraim Reyes Martín, Uxue Uria, Luisa Carrillo Fernández, and Ane Orue. "The Role of Pyranones in Asymmetric Organocatalytic Cascade Reactions." In MOL2NET 2016, International Conference on Multidisciplinary Sciences, 2nd edition. MDPI, 2016. http://dx.doi.org/10.3390/mol2net-02-08014.

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Lete, Esther, Ane Azcargorta, Iratxe Barbolla, Estíbaliz Coya, and Nuria Sotomayor. "Asymmetric Mizoroki-Heck reactions: generation of quaternary stereocenters and cascade cyclizations." In MOL2NET, International Conference on Multidisciplinary Sciences. MDPI, 2015. http://dx.doi.org/10.3390/mol2net-1-a007.

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Reports on the topic "Cascade Reactions"

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Wampler, William R., and Samuel M. Myers. Transport-reaction model for defect and carrier behavior within displacement cascades in gallium arsenide. Office of Scientific and Technical Information (OSTI), 2014. http://dx.doi.org/10.2172/1204088.

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Delwiche, Michael, Boaz Zion, Robert BonDurant, Judith Rishpon, Ephraim Maltz, and Miriam Rosenberg. Biosensors for On-Line Measurement of Reproductive Hormones and Milk Proteins to Improve Dairy Herd Management. United States Department of Agriculture, 2001. http://dx.doi.org/10.32747/2001.7573998.bard.

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The original objectives of this research project were to: (1) develop immunoassays, photometric sensors, and electrochemical sensors for real-time measurement of progesterone and estradiol in milk, (2) develop biosensors for measurement of caseins in milk, and (3) integrate and adapt these sensor technologies to create an automated electronic sensing system for operation in dairy parlors during milking. The overall direction of research was not changed, although the work was expanded to include other milk components such as urea and lactose. A second generation biosensor for on-line measuremen
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