Academic literature on the topic 'Catalysis'

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Journal articles on the topic "Catalysis"

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Zhao, Xiaodan, and Lihao Liao. "Modern Organoselenium Catalysis: Opportunities and Challenges." Synlett 32, no. 13 (2021): 1262–68. http://dx.doi.org/10.1055/a-1506-5532.

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AbstractOrganoselenium catalysis has attracted increasing interest in recent years. This Cluster highlights recent key advances in this area regarding the functionalization of alkenes, alkynes, and arenes by electrophilic selenium catalysis, selenonium salt catalysis, selenium-based chalcogen-bonding catalysis, and Lewis basic selenium catalysis. These achievements might inspire and help future research.1 Introduction2 Electrophilic Selenium Catalysis3 Selenonium Salt Catalysis4 Selenium-Based Chalcogen-Bond Catalysis5 Lewis Basic Selenide Catalysis6 Conclusion
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Zhou, Wen-Jun, Da-Gang Yu, Yi-Han Zhang, Yong-Yuan Gui, and Liang Sun. "Merging Transition-Metal Catalysis with Photoredox Catalysis: An Environmentally Friendly Strategy for C–H Functionalization." Synthesis 50, no. 17 (2018): 3359–78. http://dx.doi.org/10.1055/s-0037-1610222.

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Transition-metal-catalyzed C–H functionalization is already a useful tool in organic synthesis, whilst the rapid development of photoredox catalysis provides new pathways for C–H functionalization with high selectivity and efficiency under mild reaction conditions. In this review, recent advances in C–H functionalization through merging transition­-metal catalysis with photoredox catalysis are discussed.1 Introduction2 Merging Nickel Catalysis with Photoredox Catalysis3 Merging Palladium Catalysis with Photoredox Catalysis4 Merging Cobalt Catalysis with Photoredox Catalysis5 Merging Photoredox
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Dagorne, Samuel. "Recent Developments on N-Heterocyclic Carbene Supported Zinc Complexes: Synthesis and Use in Catalysis." Synthesis 50, no. 18 (2018): 3662–70. http://dx.doi.org/10.1055/s-0037-1610088.

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The present contribution reviews the synthesis, reactivity, and use in catalysis of NHC–Zn complexes reported since 2013. NHC-stabilized Zn(II) species typically display enhanced stability relative to common organozinc species (such as Zn dialkyls), a feature of interest for the mediation of various chemical processes and the stabilization of reactive Zn-based species. Their use in catalysis is essentially dominated by reduction reactions of various unsaturated small molecules (including CO2), thus primarily involving Zn–H and Zn–alkyl derivatives as catalysts. Simple NHC adducts of Zn(II) dih
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Fañanás-Mastral, Martín, Eva Rivera-Chao, and Laura Fra. "Synergistic Bimetallic Catalysis for Carboboration of Unsaturated Hydrocarbons." Synthesis 50, no. 19 (2018): 3825–32. http://dx.doi.org/10.1055/s-0037-1610434.

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Synergistic bimetallic catalysis has become a very efficient tool for the selective carboboration of unsaturated hydrocarbons. This synthetic approach is based on the use of a catalytically generated boron-substituted organocopper nucleophile in a cross-coupling reaction catalyzed by a second transition metal. This way, hydrocarbons can be used as pro-nucleophiles in this type of transformations thus rendering a clean and operationally simple alternative to the traditional cross-coupling methodologies. This review provides a summary of the developments on this topic and discusses both the synt
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Ding, Bo, Qilin Xue, Hong-Gang Cheng, Qianghui Zhou, and Shihu Jia. "Recent Advances in Catalytic Nonenzymatic Kinetic Resolution of Tertiary Alcohols." Synthesis 54, no. 07 (2021): 1721–32. http://dx.doi.org/10.1055/a-1712-0912.

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AbstractThe kinetic resolution (KR) of racemates is one of the most widely used approaches to access enantiomerically pure compounds. Over the past two decades, catalytic nonenzymatic KR has gained popularity in the field of asymmetric synthesis due to the rapid development of chiral catalysts and ligands in asymmetric catalysis. Chiral tertiary alcohols are prevalent in a variety of natural products, pharmaceuticals, and biologically active chiral compounds. The catalytic nonenzymatic KR of racemic tertiary alcohols is a straightforward strategy to access enantioenriched tertiary alcohols. Th
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Kaplunenko, Volodymyr, and Mykola Kosinov. "Electric field - induced catalysis. Laws of field catalysis." InterConf, no. 26(129) (October 18, 2022): 332–51. http://dx.doi.org/10.51582/interconf.19-20.10.2022.037.

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Abstract.The article explores a new type of catalysis - electric field catalysis. The laws of field catalysis are given. The characteristics of the electric field are determined, which set the values of the characteristics of the field catalysis. Field catalysis and field catalyst do not fit into the traditional definition of catalysis and catalyst, which may require a revision of the terminology of catalysis. The field is a more versatile catalyst compared to material catalysts, both in terms of its application to a wider range of chemical reactions, and in the ability to control the rate and
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Khan, Mohammad Niyaz, and Ibrahim Isah Fagge. "Kinetics and Mechanism of Cationic Micelle/Flexible Nanoparticle Catalysis: A Review." Progress in Reaction Kinetics and Mechanism 43, no. 1 (2018): 1–20. http://dx.doi.org/10.3184/146867818x15066862094905.

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The aqueous surfactant (Surf) solution at [Surf] > cmc (critical micelle concentration) contains flexible micelles/nanoparticles. These particles form a pseudophase of different shapes and sizes where the medium polarity decreases as the distance increases from the exterior region of the interface of the Surf/H2O particle towards its furthest interior region. Flexible nanoparticles (FNs) catalyse a variety of chemical and biochemical reactions. FN catalysis involves both positive catalysis ( i.e. rate increase) and negative catalysis ( i.e. rate decrease). This article describes the mechani
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Williams, Ian H. "Catalysis: transition-state molecular recognition?" Beilstein Journal of Organic Chemistry 6 (November 3, 2010): 1026–34. http://dx.doi.org/10.3762/bjoc.6.117.

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The key to understanding the fundamental processes of catalysis is the transition state (TS): indeed, catalysis is a transition-state molecular recognition event. Practical objectives, such as the design of TS analogues as potential drugs, or the design of synthetic catalysts (including catalytic antibodies), require prior knowledge of the TS structure to be mimicked. Examples, both old and new, of computational modelling studies are discussed, which illustrate this fundamental concept. It is shown that reactant binding is intrinsically inhibitory, and that attempts to design catalysts that fo
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Shubina, Tatyana E., and Timothy Clark. "Catalysis of the Quadricyclane to Norbornadiene Rearrangement by SnCl2 and CuSO4." Zeitschrift für Naturforschung B 65, no. 3 (2010): 347—r369. http://dx.doi.org/10.1515/znb-2010-0319.

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Ab initio and density-functional theory (DFT) calculations have been used to investigate the model rearrangements of quadricyclane to norbornadiene catalysed by single CuSO4 and SnCl2 molecules. The isolated reactions with the two molecular catalysts proceed via electron-transfer catalysis in which the hydrocarbon is oxidised, in contrast to systems investigated previously in which the substrate was reduced. The even-electron SnCl2-catalysed reaction shows singlet-triplet two-state reactivity. Solvation by a single methanol molecule changes the mechanism of the rearrangement to a classical Lew
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Hidayati, Nur, Rahmah Puspita Sari, and Herry Purnama. "Catalysis of glycerol acetylation on solid acid catalyst: a review." Jurnal Kimia Sains dan Aplikasi 23, no. 12 (2021): 414–23. http://dx.doi.org/10.14710/jksa.23.12.414-423.

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Biodiesel is a substitute fuel that is environmentally friendly, biodegradable, and sustainable. The need for biodiesel continues to increase. Biodiesel is made through the process of transesterification of triglycerides and alcohol. Glycerol is a side-effect of biodiesel products with a capacity of 10% of the total weight of its production. Glycerol is the simplest glyceride compound and has several functions as a primary ingredient in chemical production. Through acetylation, glycerol is converted to a material that has a higher sale value. Both homogeneous and heterogeneous catalysts are th
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Dissertations / Theses on the topic "Catalysis"

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Liu, Hongying. "Syntheses, structures, and catalysis of polynuclear metal complexes." Diss., Georgia Institute of Technology, 1989. http://hdl.handle.net/1853/30561.

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Cunje, Alwin. "Noble gases and catalysis." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape3/PQDD_0012/NQ59125.pdf.

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Clarke, Richard John. "Mesopore immobilised bis(oxazoline) catalysts for enantioselective catalysis." Thesis, University of Birmingham, 2003. http://etheses.bham.ac.uk//id/eprint/3578/.

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Mesoporous silica materials have the potential to replace many conventional silicas for uses such as supports for heterogeneous catalysis and absorbents. The large pore size and high surface area make them ideal for supporting bulky organometallic catalysts for enantioselective reactions. We have immobilised chiral bis(oxazoline) metal complexes onto the surfaces of some of these versatile supports (MCM-41 and MCM-48) via different tethering strategies. The resulting heterogeneous catalysts were shown to be highly active in the enantioselective cyclopropanation of styrene with ethyl diazoaceta
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Rosenthal, Daniel Jay. "Estimating the acid site density of silica-alumina by infrared spectroscopy using a selective reactant poison." Thesis, Georgia Institute of Technology, 1985. http://hdl.handle.net/1853/10222.

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Richardson, John Michael. "Distinguishing between surface and solution catalysis for palladium catalyzed C-C coupling reactions: use of selective poisons." Diss., Georgia Institute of Technology, 2008. http://hdl.handle.net/1853/22704.

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This work focuses on understanding the heterogeneous/homogeneous nature of the catalytic species for a variety of immobilized metal precatalysts used for C-C coupling reactions. These precatalysts include: (i) tethered organometallic palladium pincer complexes, (ii) an encapsulated small molecule palladium complex in a polymer matrix, (iii) mercapto-modified mesoporous silica metalated with palladium acetate, and (iv) amino-functionalized mesoporous silicas metalated with Ni(II). As part of this investigation, the use of metal scavengers as selective poisons of homogeneous catalysis is intr
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Reddy, P. K. "Exploration of catalysts and catalysis under near working conditions." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2018. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/4577.

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Beckler, Robert Kendall. "Polynuclear metal complexes as model mixed oxide catalysts." Diss., Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/11897.

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Damian, Karen Serena. "Pd catalysed synthesis of phosphines for homogeneous catalysis." Thesis, St Andrews, 2009. http://hdl.handle.net/10023/907.

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Jenkins, Patrick L. "Electrochemical and catalytic investigation of catalysis by gold." Thesis, Cardiff University, 2005. http://orca.cf.ac.uk/56012/.

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The performance of gold/graphite as an oxidation catalyst has been investigated in an electrochemical cell (electrooxidation at ambient temperature and pressure) and in a high pressure reactor (conventional catalytic oxidation typically at 3 bar and 333 K). A range of gold/graphite catalysts having various metal loadings were prepared and characterised by cyclic voltammetry (CV), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). The technique of lead underpotential deposition (Pdupd) was used to reveal the presence of {111}, {100}, and {110} facets in the surf
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Xu, Jiahui. "Catalytic properties of nano ceria in heterogeneous catalysis." Thesis, University of Oxford, 2010. http://ora.ox.ac.uk/objects/uuid:02e68ff9-ce28-475a-bd08-6b60bcda64e7.

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There have been many applications of cerium oxide in oxidation catalysis but the understanding of its role in catalysis is rather limited. This research is concerned with the use of nano-size cerium oxide in methane steam reforming reaction. It is found that addition of cerium oxide to the commercial supported Ni catalysts can dramatically reduce the undesirable carbon deposition (through surface oxidation), which is thermodynamically favorable under low steam conditions. In order to understanding the fundamental role of oxidation activity of the cerium oxide, different sizes of nano-crystalli
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Books on the topic "Catalysis"

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1937-, Anderson James A., and Fernández Garcia Marcos, eds. Supported metals in catalysis. Imperial College Press, 2005.

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Ma, Zhen, and Sheng Dai, eds. Heterogeneous Gold Catalysts and Catalysis. Royal Society of Chemistry, 2014. http://dx.doi.org/10.1039/9781782621645.

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International Symposium on Catalyst Deactivation (8th 1999 Brugge, Belgium). Catalyst deactivation 1999: Proceedings of the 8th International Symposium, Brugge, Belgium, October 10-13, 1999. Elsevier, 1999.

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Wijngaarden, R. J. Industrial catalysis: Optimizing catalysts and processes. Wiley-VCH, 1998.

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1934-, Davis Burtron H., and Occelli Mario L. 1942-, eds. Fischer-Tropsch synthesis, catalysts and catalysis. Elsevier, 2007.

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J, Thomas W., ed. Principles and practice of heterogeneous catalysis. VCH, 1996.

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Hideo, Kurosawa, and Yamamoto Akio 1930-, eds. Fundamentals of molecular catalysis. Elsevier, 2003.

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Spivey, James J., ed. Catalysis. Royal Society of Chemistry, 2007. http://dx.doi.org/10.1039/9781847558442.

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Spivey, James, Yi-Fan Han, and K. Dooley, eds. Catalysis. Royal Society of Chemistry, 2014. http://dx.doi.org/10.1039/9781782620037.

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Bond, G. C., and G. Webb, eds. Catalysis. Royal Society of Chemistry, 1985. http://dx.doi.org/10.1039/9781847553195.

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Book chapters on the topic "Catalysis"

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Pennington, John. "Catalysts and Catalysis." In An Introduction to Industrial Chemistry. Springer Netherlands, 1996. http://dx.doi.org/10.1007/978-94-011-0613-9_12.

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Pennington, J. "Catalysts and Catalysis." In an introduction to Industrial Chemistry. Springer US, 1991. http://dx.doi.org/10.1007/978-1-4615-6438-6_11.

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Gao, Yuanfeng, Hong Lv, Yongwen Sun, Han Yao, Ding Hu, and Cunman Zhang. "Enhancement of Acidic HER by Fe Doped CoP with Bimetallic Synergy." In Proceedings of the 10th Hydrogen Technology Convention, Volume 1. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-99-8631-6_45.

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AbstractCompared to single metal site catalysis, the bimetallic synergistic strategy can exploit the complementary ability of different active sites for active species uptake and desorption to develop excellent catalysts. Pure phase metal phosphides are a disadvantage as a promising electrocatalyst for platinum-free hydrogen precipitation with either too strong or too weak adsorption of hydrogen. Here, synthetic Fe-doped CoP particles anchored with MWCNTs, which exhibited excellent catalytic performance for HER, required an overpotential of 123 mV to reach 10 mA cm−2, with a Tafel slope of 58.
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Hofmann, Andreas. "Catalysis." In Physical Chemistry Essentials. Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-74167-3_7.

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Teh, Swe Jyan, Tong Ling Tan, Chin Wei Lai, and Kian Mun Lee. "Catalysis." In Carbon Nanostructures. Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-95603-9_5.

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Jobic, Hervé. "Catalysis." In Neutron Scattering Applications and Techniques. Springer International Publishing, 2015. http://dx.doi.org/10.1007/978-3-319-06656-1_2.

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Pavlidis, Ioannis V. "Catalysis." In Graphene Oxide. John Wiley & Sons, Ltd, 2016. http://dx.doi.org/10.1002/9781119069447.ch12.

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Schmiermund, Torsten. "Catalysis." In The Chemistry Knowledge for Firefighters. Springer Berlin Heidelberg, 2022. http://dx.doi.org/10.1007/978-3-662-64423-2_36.

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Urdă, Adriana, and Ioan-Cezar Marcu. "Catalysis." In New Frontiers in Nanochemistry. Apple Academic Press, 2020. http://dx.doi.org/10.1201/9780429022944-4.

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Job, Georg, and Regina Rüffler. "Catalysis." In Physical Chemistry from a Different Angle. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-15666-8_19.

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Conference papers on the topic "Catalysis"

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Dunlop, A. K. "Catalysis and Inhibition in Oxygen Scavenging." In CORROSION 1986. NACE International, 1986. https://doi.org/10.5006/c1986-86176.

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Abstract The catalysis of oxygen scavenging reactions can be placed in two categories, 1) those depending on a free radical chain mechanism and 2) those in which a catalytic intermediate redox cycle is involved. Sulfite scavenging exemplifies the first category as the free radical chain mechanism is the only one effective in this system. This mechanism makes the sulfite system susceptible to a great variety of inhibiting effects. However, mechanistic understanding is available to solve such problems. Hydrazine can provide examples in each category. Catalysis via the hydroquinone/quinone cycle
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Shafiee, Parisa, Mitra Jafari, Julia Schowarte, Bogdan Dorneanu, and Harvey Arellano-Garcia. "Streamlining Catalyst Development through Machine Learning: Insights from Heterogeneous Catalysis and Photocatalysis." In The 35th European Symposium on Computer Aided Process Engineering. PSE Press, 2025. https://doi.org/10.69997/sct.135551.

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Catalysis design and reaction condition optimization are considered the heart of many chemical and petrochemical processes and industries; however, there are still significant challenges in these fields. Advances in machine learning (ML) have provided researchers with new tools to address some of these obstacles, offering the ability to predict catalyst behaviour, optimal reaction conditions, and product distributions without the need for extensive laboratory experimentation. In this contribution, the potential applications of ML in heterogeneous catalysis and photocatalysis are explored by an
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Zhang, Aihua. "EXPERIMENTAL STUDY ON THE APPLICATION OF MACHINE LEARNING METHOD IN CATALYTIC MATERIALS." In Topics In Chemical & Material Engineering (TCME). Volkson Press, 2023. http://dx.doi.org/10.26480/smmp.01.2023.24.27.

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Machine learning has emerged as a powerful tool for analyzing complex data sets and making predictions in a wide range of applications, including catalysis. Bycombining statistical methods, algorithms, and computational power, machine learning can help identify patterns and relationships in catalytic systems that are difficult or impossible to discern using traditional approaches. This can lead to more efficient and effective catalyst design, optimization, and prediction of catalytic activity. Machine learning has already been successfully applied to various aspects of catalysis, including cat
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MOISEEV, ILYA I. "METAL COMPLEX CATALYSIS OF OXIDATION REACTIONS: CATALYSIS WITH PALLADIUM COMPLEXES." In Proceedings of the NIOK (Netherlands Institute for Catalysis Research) Course on Catalytic Oxidation. WORLD SCIENTIFIC, 1995. http://dx.doi.org/10.1142/9789814503884_0010.

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GRUBBS, ROBERT H. "HOMOGENEOUS CATALYSIS: ORGANOMETALLIC CATALYSIS AND ORGANOCATALYSIS." In 24th International Solvay Conference on Chemistry. WORLD SCIENTIFIC, 2018. http://dx.doi.org/10.1142/9789813237179_0001.

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Karakurkchi, A., N. Sakhnenko, M. Ved, I. Parsadanov, and S. Menshov. "Nanostructured Oxide-Metal Catalysts for Intra-Cylinder Catalysis." In 2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP). IEEE, 2018. http://dx.doi.org/10.1109/nap.2018.8914840.

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THOMAS, JOHN MEURIG. "HETEROGENOUS CATALYSIS AND CHARACTERIZATION OF CATALYST SURFACES." In 24th International Solvay Conference on Chemistry. WORLD SCIENTIFIC, 2018. http://dx.doi.org/10.1142/9789813237179_0019.

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Wüthrich, Kurt, R. H. Grubbs, T. Visart de Bocarmé, and Anne De Wit. "Heterogeneous Catalysis and Characterization of Catalyst Surfaces." In 24th International Solvay Conference on Chemistry. WORLD SCIENTIFIC, 2018. http://dx.doi.org/10.1142/9789813237179_others02.

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VEDRINE, JACQUES C. "HETEROGENEOUS OXIDATION CATALYSIS ON METALLIC OXIDES." In Proceedings of the NIOK (Netherlands Institute for Catalysis Research) Course on Catalytic Oxidation. WORLD SCIENTIFIC, 1995. http://dx.doi.org/10.1142/9789814503884_0003.

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SHELDON, R. A. "HETEROGENEOUS CATALYSIS OF LIQUID PHASE OXIDATIONS." In Proceedings of the NIOK (Netherlands Institute for Catalysis Research) Course on Catalytic Oxidation. WORLD SCIENTIFIC, 1995. http://dx.doi.org/10.1142/9789814503884_0009.

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Reports on the topic "Catalysis"

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Ravindra Datta, Ajeet Singh, Manuela Serban, and Istvan Halasz. Supported Molten Metal Catalysis. A New Class of Catalysts. Office of Scientific and Technical Information (OSTI), 2006. http://dx.doi.org/10.2172/889459.

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Delgass, William Nicholas, Mahdi Abu-Omar, James Caruthers, Fabio Ribeiro, Kendall Thomson, and William Schneider. Catalysis Science Initiative: Catalyst Design by Discovery Informatics. Office of Scientific and Technical Information (OSTI), 2016. http://dx.doi.org/10.2172/1260972.

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Campbell, Charles T., Abhaya K. Datye, Graeme A. Henkelman, et al. EMSL and Institute for Integrated Catalysis (IIC) Catalysis Workshop. Office of Scientific and Technical Information (OSTI), 2011. http://dx.doi.org/10.2172/1016448.

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Smith, K. J., and E. C. Sanford. Progress in catalysis. Natural Resources Canada/ESS/Scientific and Technical Publishing Services, 1992. http://dx.doi.org/10.4095/304511.

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George A. Kraus. Center for Catalysis. Office of Scientific and Technical Information (OSTI), 2005. http://dx.doi.org/10.2172/838426.

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Alivisatos, A. P., Gabor A. Somorjai, and Peidong Yang. Plasmonic-Enhanced Catalysis. Defense Technical Information Center, 2012. http://dx.doi.org/10.21236/ada576759.

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Chen, Jingguang, Anatoly Frenkel, Jose Rodriguez, et al. Dedicated Beamline Facilities for Catalytic Research. Synchrotron Catalysis Consortium (SCC). Office of Scientific and Technical Information (OSTI), 2015. http://dx.doi.org/10.2172/1171708.

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Rioux, Robert M. Dynamic Chemical and Structural Changes of Heterogeneous Catalysts Observed in Real Time: From Catalysis-Induced Fluxionality to Catalytic Cycles. Defense Technical Information Center, 2014. http://dx.doi.org/10.21236/ada613847.

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Betty, Rita G., Mark D. Tucker, Gretchen Taggart, et al. Enhanced Micellar Catalysis LDRD. Office of Scientific and Technical Information (OSTI), 2012. http://dx.doi.org/10.2172/1096958.

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Kung, Harold H. Nanoconfinement Effects in Catalysis. Office of Scientific and Technical Information (OSTI), 2016. http://dx.doi.org/10.2172/1325204.

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