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1

Ye, Shuyang, Scott M. Foster, Adam A. Pollit, Susan Cheng та Dwight S. Seferos. "The role of halogens in the catalyst transfer polycondensation for π-conjugated polymers". Chemical Science 10, № 7 (2019): 2075–80. http://dx.doi.org/10.1039/c8sc04808h.

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2

Shi, Xincui, Aiguo Sui, Yongxia Wang, Yuesheng Li, Yanhou Geng, and Fosong Wang. "Controlled synthesis of high molecular weight poly(3-hexylthiophene)s via Kumada catalyst transfer polycondensation with Ni(IPr)(acac)2 as the catalyst." Chemical Communications 51, no. 11 (2015): 2138–40. http://dx.doi.org/10.1039/c4cc08012b.

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3

Kiriy, Anton, Volodymyr Senkovskyy, and Michael Sommer. "Kumada Catalyst-Transfer Polycondensation: Mechanism, Opportunities, and Challenges." Macromolecular Rapid Communications 32, no. 19 (2011): 1503–17. http://dx.doi.org/10.1002/marc.201100316.

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4

Liu, Huai-Hsuan, Wei-Wei Liang, Yu-Ying Lai, et al. "Synthesis of side-chain regioregular and main-chain alternating poly(bichalcogenophene)s and an ABC-type periodic poly(terchalcogenophene)." Chemical Science 11, no. 15 (2020): 3836–44. http://dx.doi.org/10.1039/d0sc00404a.

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Three unsymmetrical diiodobichalcogenophenes SSeI2, STeI2, and SeTeI2 and a diiodoterchalcogenophene SSeTeI2 were prepared to synthesize a new class of polychalcogenophenes with precisely controlled sequences by catalyst-transfer polycondensation.
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5

Xie, Ziyi, Qingyun Wei, Tong Shan, Xiaoyang Zheng, Yi Zhang, and Hongliang Zhong. "Preparing polythiophene derivative with alternating alkyl and thioalkyl side chains via Kumada coupling for efficient organic solar cells." Polymer Chemistry 12, no. 44 (2021): 6456–64. http://dx.doi.org/10.1039/d1py01051d.

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A polythiophene, namely PTST with alternating alkyl and thioalkyl side chains, is prepared by Kumada catalyst-transfer polycondensation. PTST can hierarchically pre-aggregate in solution, and then form a favorable morphology in organic solar cells.
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6

Kobayashi, Saburo, Kaiyu Fujiwara, Dai-Hua Jiang, et al. "Suzuki–Miyaura catalyst-transfer polycondensation of triolborate-type fluorene monomer: toward rapid access to polyfluorene-containing block and graft copolymers from various macroinitiators." Polymer Chemistry 11, no. 42 (2020): 6832–39. http://dx.doi.org/10.1039/d0py01127d.

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We demonstrated that the Suzuki–Miyaura catalyst transfer polycondensation of a triolborate-type fluorene monomer can be an efficient and versatile approach to the synthesis of polyfluorenes (PFs) and PF-containing block and graft copolymers.
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7

Goto, Eisuke, Yuto Ochiai, Chen-Tsyr Lo, Tomoyuki Koganezawa, Mitsuru Ueda, and Tomoya Higashihara. "Synthesis of regioblock copolythiophene by Negishi catalyst-transfer polycondensation using tBu2Zn·2LiCl." Polymer Chemistry 8, no. 39 (2017): 6143–49. http://dx.doi.org/10.1039/c7py01416c.

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Regioblock copolythiohenes consisting of head-to-tail poly(3-hexylthiophene) (HT-P3HT) and head-to-head/tail-to-tail P3HT (HHTT-P3HT) segments could be synthesized by Negishi catalyst-transfer polycondensation (NCTP) using <sup>t</sup>Bu<sub>2</sub>Zn·2LiCl.
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8

Iliescu, Samaranda, Gheorghe Ilia, and Adriana Popa. "Phase transfer catalysis in the synthesis of phosphorus-containing polymers." Journal of the Serbian Chemical Society 70, no. 7 (2005): 951–56. http://dx.doi.org/10.2298/jsc0507951i.

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Polyphosphonates of high molecular weights were prepared from chloromethylphosphonic dichloride (CMPD) and 4,4?-sulfonyldiphenol (SDP) by two-phase interfacial polycondensation (l?l), in an organic solvent-aqueous alkaline solution system, with a phase-transfer catalyst, at ?8 ? ? 0 ?C. Alternative method, namely vapor-liquid interfacial polycondensation (v?l) of the same reagents gave better results (higher inherent viscosities and molecular weights). The polymers were characterized by spectroscopic techniques IR and 1H-NMR. The molecular weights and thermal stability determinations were carr
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9

Kobayashi, Saburo, Mayoh Ashiya, Takuya Yamamoto, et al. "Suzuki–Miyaura Catalyst-Transfer Polycondensation of Triolborate-Type Carbazole Monomers." Polymers 13, no. 23 (2021): 4168. http://dx.doi.org/10.3390/polym13234168.

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Herein, we report the Suzuki–Miyaura catalyst-transfer polycondensation (SCTP) of triolborate-type carbazole monomers, i.e., potassium 3-(6-bromo-9-(2-octyldodecyl)-9H-carbazole-2-yl)triolborate (M1) and potassium 2-(7-bromo-9-(2-octyldodecyl)-9H-carbazole-2-yl) triolborate (M2), as an efficient and versatile approach for precisely synthesizing poly[9-(2-octyldodecyl)-3,6-carbazole] (3,6-PCz) and poly[9-(2-octyldodecyl)-2,7-carbazole] (2,7-PCz), respectively. The SCTP of triolborate-type carbazole monomers was performed in a mixture of THF/H2O using an initiating system consisted of 4-iodobenz
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10

Doubina, Natalia, Anh Ho, Alex K.-Y. Jen, and Christine K. Luscombe. "Effect of Initiators on the Kumada Catalyst-Transfer Polycondensation Reaction." Macromolecules 42, no. 20 (2009): 7670–77. http://dx.doi.org/10.1021/ma901410k.

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11

Tkachov, Roman, Volodymyr Senkovskyy, Hartmut Komber, Jens-Uwe Sommer, and Anton Kiriy. "Random Catalyst Walking along Polymerized Poly(3-hexylthiophene) Chains in Kumada Catalyst-Transfer Polycondensation." Journal of the American Chemical Society 132, no. 22 (2010): 7803–10. http://dx.doi.org/10.1021/ja102210r.

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12

Zhang, Ping, Lin Bo Wu, and Bo Geng Li. "Synthesis of Aromatic Polyesters with Pendent Carboxyl Groups from Diphenolic Acid, Bisphenol a and Isophthaloyl Chloride by Interfacial Polycondensation." Advanced Materials Research 239-242 (May 2011): 2616–19. http://dx.doi.org/10.4028/www.scientific.net/amr.239-242.2616.

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Aromatic polyesters bearing pendent carboxyl functionalities were prepared by interfacial polycondensation of diphenolic acid, bisphenol A and isophthaloyl chloride with tetrabutylammonium chloride as phase transfer catalyst. The copolyester composition was confirmed with HPLC analysis. The polymerization process and composition of the copolyesters were examined by considering influences of reaction temperatures, time, ratio of feeds, agitation speeds.
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13

Sontag, S. Kyle, Nicholas Marshall, and Jason Locklin. "Formation of conjugated polymer brushes by surface-initiated catalyst-transfer polycondensation." Chemical Communications, no. 23 (2009): 3354. http://dx.doi.org/10.1039/b907264k.

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14

Bryan, Zachary J., Ariana O. Hall, Carolyn T. Zhao, Jing Chen, and Anne J. McNeil. "Limitations of Using Small Molecules to Identify Catalyst-Transfer Polycondensation Reactions." ACS Macro Letters 5, no. 1 (2015): 69–72. http://dx.doi.org/10.1021/acsmacrolett.5b00746.

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15

Leone, Amanda K., and Anne J. McNeil. "Matchmaking in Catalyst-Transfer Polycondensation: Optimizing Catalysts based on Mechanistic Insight." Accounts of Chemical Research 49, no. 12 (2016): 2822–31. http://dx.doi.org/10.1021/acs.accounts.6b00488.

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16

Bilbrey, Jenna A., S. Kyle Sontag, N. Eric Huddleston, Wesley D. Allen, and Jason Locklin. "On the Role of Disproportionation Energy in Kumada Catalyst-Transfer Polycondensation." ACS Macro Letters 1, no. 8 (2012): 995–1000. http://dx.doi.org/10.1021/mz3002929.

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17

Zhang, Ping, Lin Bo Wu, and Bo Geng Li. "The Study on the Electrolyte Behavior of Aromatic Polyesters from Diphenolic Acid and Isophthaloyl Chloride." Applied Mechanics and Materials 84-85 (August 2011): 618–21. http://dx.doi.org/10.4028/www.scientific.net/amm.84-85.618.

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The aromatic polyester from diphenolic acid and isophthaloyl chloride was synthesized by interfacial polycondensation with tetrabutylammonium chloride as phase transfer catalyst. The structure was characterized by means of FTIR. The poly(DPA-IPC) solution was titrated by aqueous HCl solution. The titration curves were obtained. The trend of reduced viscosity of solution with concentration was studied. Besides, the stability of poly(DPA-IPC) in aqueous basic solution was discussed.
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18

Qiu, Yunyan, Andria Fortney, Chia-Hua Tsai, et al. "Synthesis of Polyfuran and Thiophene-Furan Alternating Copolymers Using Catalyst-Transfer Polycondensation." ACS Macro Letters 5, no. 3 (2016): 332–36. http://dx.doi.org/10.1021/acsmacrolett.5b00666.

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19

Smith, Mitchell L., Amanda K. Leone, Paul M. Zimmerman та Anne J. McNeil. "Impact of Preferential π-Binding in Catalyst-Transfer Polycondensation of Thiazole Derivatives". ACS Macro Letters 5, № 12 (2016): 1411–15. http://dx.doi.org/10.1021/acsmacrolett.6b00886.

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20

Ono, Robert J., Songsu Kang, and Christopher W. Bielawski. "Controlled Chain-Growth Kumada Catalyst Transfer Polycondensation of a Conjugated Alternating Copolymer." Macromolecules 45, no. 5 (2012): 2321–26. http://dx.doi.org/10.1021/ma300013e.

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21

Bryan, Zachary J., and Anne J. McNeil. "Conjugated Polymer Synthesis via Catalyst-Transfer Polycondensation (CTP): Mechanism, Scope, and Applications." Macromolecules 46, no. 21 (2013): 8395–405. http://dx.doi.org/10.1021/ma401314x.

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22

Huddleston, N. Eric, Anandi Roy, Jenna A. Bilbrey, Yiping Zhao, and Jason Locklin. "Functionalization of Reactive End Groups in Surface-Initiated Kumada Catalyst-Transfer Polycondensation." Macromolecular Symposia 351, no. 1 (2015): 27–36. http://dx.doi.org/10.1002/masy.201300126.

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23

Higashihara, Tomoya. "Nonstoichiometric Migita-Kosugi-Stille Coupling Polycondensation based on Intramolecular Catalyst Transfer System." Journal of Synthetic Organic Chemistry, Japan 81, no. 6 (2023): 574–81. http://dx.doi.org/10.5059/yukigoseikyokaishi.81.574.

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24

Rosy, Antony, Ravindran Sumisha, and C. Mary M. "Synthesis, characterization and thermal studies of cresol based polyphosphate esters." Journal of Indian Chemical Society Vol. 89, May 2012 (2012): 701–3. https://doi.org/10.5281/zenodo.5763531.

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Department of Chemistry, Nirmalagiri College, Kuthuparamba, Kannur-670 701, Kerala, India <em>Manuscript received 06 March 2009, revised 31 August 2010, accepted 23 August 2011</em> Polyphosphate esters were synthesized from cresol phosphorodichloridates and dihydric phenols by interfacial polycondensation using a phase transfer catalyst. The polymers were characterized by IR, <sup>1</sup>H and <sup>31</sup>P NMR spectroscopy and GPC. The thermal stability of the polymers was determined by thermogravimetry.
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25

Liu, Xiao Tian, and Hong Bo Fan. "Novel Chemoenzymatic Synthesis of Triblock Copolymer." Advanced Materials Research 396-398 (November 2011): 2459–62. http://dx.doi.org/10.4028/www.scientific.net/amr.396-398.2459.

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Enzymatic polycondensation of benzyl-2,2-bis(methylol) propionate and sebacic acid has been performed using lipase Novozyme-435 as the catalyst, subsequently enzymatic ring-opening polymerization was reacted by adding ε-caprolactone as the monomer in the same system. Then atom transfer radical polymerization (ATRP) from the macroinitiator combining α-bromoester of styrene was catalyzed by CuCl/2,2’-Dipyridyl to obtain the block copolymer successfully. The polymers obtained in different conditions were analyzed by 1HNMR and GPC.
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26

Bedi, Anjan, Julien De Winter, Pascal Gerbaux, and Guy Koeckelberghs. "Detrimental Ni(0) transfer in Kumada catalyst transfer polycondensation of benzo[2,1-b:3,4-b']dithiophene." Journal of Polymer Science Part A: Polymer Chemistry 54, no. 12 (2016): 1706–12. http://dx.doi.org/10.1002/pola.28026.

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27

Senkovskyy, Volodymyr, Roman Tkachov, Tetyana Beryozkina, et al. "“Hairy” Poly(3-hexylthiophene) Particles Prepared via Surface-Initiated Kumada Catalyst-Transfer Polycondensation." Journal of the American Chemical Society 131, no. 45 (2009): 16445–53. http://dx.doi.org/10.1021/ja904885w.

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28

Yuan, Mingjian, Ken Okamoto, Hugo A. Bronstein, and Christine K. Luscombe. "Constructing Regioregular Star Poly(3-hexylthiophene) via Externally Initiated Kumada Catalyst-Transfer Polycondensation." ACS Macro Letters 1, no. 3 (2012): 392–95. http://dx.doi.org/10.1021/mz3000368.

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29

Wu, Shupeng, Li Huang, Hongkun Tian, Yanhou Geng, and Fosong Wang. "LiCl-Promoted Chain Growth Kumada Catalyst-Transfer Polycondensation of the “Reversed” Thiophene Monomer." Macromolecules 44, no. 19 (2011): 7558–67. http://dx.doi.org/10.1021/ma201192p.

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30

Schiefer, Daniel, Tao Wen, Yingying Wang, et al. "Nickel Catalyst with a Hybrid P, N Ligand for Kumada Catalyst Transfer Polycondensation of Sterically Hindered Thiophenes." ACS Macro Letters 3, no. 7 (2014): 617–21. http://dx.doi.org/10.1021/mz500282j.

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31

Sui, Aiguo, Xincui Shi, Shupeng Wu, Hongkun Tian, Yanhou Geng, and Fosong Wang. "Controlled Synthesis of Polyfluorenes via Kumada Catalyst Transfer Polycondensation with Ni(acac)2/dppp as the Catalyst." Macromolecules 45, no. 13 (2012): 5436–43. http://dx.doi.org/10.1021/ma3009299.

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32

Tsai, Chia-Hua, Andria Fortney, Yunyan Qiu, et al. "Conjugated Polymers with Repeated Sequences of Group 16 Heterocycles Synthesized through Catalyst-Transfer Polycondensation." Journal of the American Chemical Society 138, no. 21 (2016): 6798–804. http://dx.doi.org/10.1021/jacs.6b01916.

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33

Kang, Songsu, Robert J. Ono, and Christopher W. Bielawski. "Controlled Catalyst Transfer Polycondensation and Surface-Initiated Polymerization of a p-Phenyleneethynylene-Based Monomer." Journal of the American Chemical Society 135, no. 13 (2013): 4984–87. http://dx.doi.org/10.1021/ja401740m.

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34

Todd, Alexander D., and Christopher W. Bielawski. "Controlled Synthesis of an Alternating Donor–Acceptor Conjugated Polymer via Kumada Catalyst-Transfer Polycondensation." ACS Macro Letters 4, no. 11 (2015): 1254–58. http://dx.doi.org/10.1021/acsmacrolett.5b00505.

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35

Marshall, Nicholas, S. Kyle Sontag, and Jason Locklin. "Substituted Poly(p-phenylene) Thin Films via Surface-Initiated Kumada-Type Catalyst Transfer Polycondensation." Macromolecules 43, no. 5 (2010): 2137–44. http://dx.doi.org/10.1021/ma902710j.

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36

Beryozkina, Tetyana, Volodymyr Senkovskyy, Elisabeth Kaul, and Anton Kiriy. "Kumada Catalyst-Transfer Polycondensation of Thiophene-Based Oligomers: Robustness of a Chain-Growth Mechanism." Macromolecules 41, no. 21 (2008): 7817–23. http://dx.doi.org/10.1021/ma801660x.

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37

Gong, Yu Mei, Ling Ming Xia, Jing Chuan Song, and Qing Liang. "Synthesis of Poly(3-Hexylthiophene) with High Molecular Weight and Small Polydispersity." Advanced Materials Research 616-618 (December 2012): 1693–96. http://dx.doi.org/10.4028/www.scientific.net/amr.616-618.1693.

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Regioregular head-tail poly(3-hexylthiophenes) (HT-P3HT) with a controlled high molecular weight and a small polydispersity have been synthesized via an improved Kumada catalyst-transfer polycondensation (KCTP) by using the new-prepared hexylmagnesium bromide as the Grignard reagent. As the amount of nickel catalyst dichloro[1,3-diphenylphosphinopropane] nickel (Ni(dppp)Cl2) was 0.5% mol of the amount of monomer 2,5-dibromo-3-hexylthiophene (DBHT) we can obtain a HT-P3HT with a high molecular weight Mn (38 449) and a small polydspersity (1.18). By using of LiCl as a co-catalyst, the regioregul
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38

Wang, Jin, and Tomoya Higashihara. "Effects of catalyst loading amount on the synthesis of poly(3-hexylthiophene) via externally initiated Kumada catalyst-transfer polycondensation." Frontiers of Materials Science 8, no. 4 (2014): 383–90. http://dx.doi.org/10.1007/s11706-014-0261-9.

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39

Senkovskyy, Volodymyr, Irena Senkovska, and Anton Kiriy. "Surface-Initiated Synthesis of Conjugated Microporous Polymers: Chain-Growth Kumada Catalyst-Transfer Polycondensation at Work." ACS Macro Letters 1, no. 4 (2012): 494–98. http://dx.doi.org/10.1021/mz200204g.

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40

Boon, Florian, David Moerman, Danielle Laurencin, et al. "Synthesis of TiO2–Poly(3-hexylthiophene) Hybrid Particles through Surface-Initiated Kumada Catalyst-Transfer Polycondensation." Langmuir 30, no. 38 (2014): 11340–47. http://dx.doi.org/10.1021/la502944g.

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41

Zhao, Chunhui, Kazuhiko Nagura, Masayuki Takeuchi, and Kazunori Sugiyasu. "Twisting poly(3-substituted thiophene)s: cyclopolymerization of gemini thiophene monomers through catalyst-transfer polycondensation." Polymer Journal 49, no. 1 (2016): 133–39. http://dx.doi.org/10.1038/pj.2016.66.

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42

Terayama, Kosuke, Eisuke Goto, and Tomoya Higashihara. "Nonstoichiometric Stille Coupling Polycondensation via an Intramolecular Pd(0) Catalyst Transfer Using Excess Phthalimide Monomer." Macromolecular Chemistry and Physics 219, no. 14 (2018): 1800175. http://dx.doi.org/10.1002/macp.201800175.

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43

Sui, Aiguo, Xincui Shi, Yongxia Wang, Yanhou Geng, and Fosong Wang. "Kumada catalyst transfer polycondensation for controlled synthesis of polyfluorenes using 1,3-bis(diarylphosphino)propanes as ligands." Polymer Chemistry 6, no. 26 (2015): 4819–27. http://dx.doi.org/10.1039/c5py00610d.

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44

Sui, Aiguo, Xincui Shi, Hongkun Tian, Yanhou Geng, and Fosong Wang. "Suzuki–Miyaura catalyst-transfer polycondensation with Pd(IPr)(OAc)2as the catalyst for the controlled synthesis of polyfluorenes and polythiophenes." Polym. Chem. 5, no. 24 (2014): 7072–80. http://dx.doi.org/10.1039/c4py00917g.

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45

Sontag, S. Kyle, Gareth R. Sheppard, Nathan M. Usselman, Nicholas Marshall, and Jason Locklin. "Surface-Confined Nickel Mediated Cross-Coupling Reactions: Characterization of Initiator Environment in Kumada Catalyst-Transfer Polycondensation." Langmuir 27, no. 19 (2011): 12033–41. http://dx.doi.org/10.1021/la202911t.

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46

Terayama, Kosuke, and Tomoya Higashihara. "Nonstoichiometric Stille Coupling Polycondensation via Intramolecular Pd(0) Catalyst Transfer Using Excess Imide-Based Dibromo Monomers." ECS Transactions 88, no. 1 (2018): 351–59. http://dx.doi.org/10.1149/08801.0351ecst.

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47

Wang, Jin, Mitsuru Ueda, and Tomoya Higashihara. "Synthesis of All-Conjugated Donor–Acceptor–Donor ABA-Type Triblock Copolymers via Kumada Catalyst-Transfer Polycondensation." ACS Macro Letters 2, no. 6 (2013): 506–10. http://dx.doi.org/10.1021/mz400143y.

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48

Huang, Weiguo, Linjie Su, and Zhishan Bo. "Hyperbranched Polymers with a Degree of Branching of 100% Prepared by Catalyst Transfer Suzuki−Miyaura Polycondensation." Journal of the American Chemical Society 131, no. 30 (2009): 10348–49. http://dx.doi.org/10.1021/ja9033846.

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49

Tkachov, Roman, Volodymyr Senkovskyy, Hartmut Komber, and Anton Kiriy. "Influence of Alkyl Substitution Pattern on Reactivity of Thiophene-Based Monomers in Kumada Catalyst-Transfer Polycondensation." Macromolecules 44, no. 7 (2011): 2006–15. http://dx.doi.org/10.1021/ma102724y.

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50

Qiu, Yunyan, Jacob Mohin, Chia-Hua Tsai, et al. "Stille Catalyst-Transfer Polycondensation Using Pd-PEPPSI-IPr for High-Molecular-Weight Regioregular Poly(3-hexylthiophene)." Macromolecular Rapid Communications 36, no. 9 (2015): 840–44. http://dx.doi.org/10.1002/marc.201500030.

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