Academic literature on the topic 'Catastrophic inversion'
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Journal articles on the topic "Catastrophic inversion"
Campbell, Scott B., Todd Larson, Niels M. B. Smeets, Ula El-Jaby, and Timothy F. L. McKenna. "Miniemulsification by catastrophic phase inversion." Chemical Engineering Journal 183 (February 2012): 534–41. http://dx.doi.org/10.1016/j.cej.2011.12.092.
Full textMalhotra, Varun, Rajinder Pal, and Saeed Alhassan. "Catastrophic Phase Inversion of Emulsions Stabilized by Amphiphilic Nanoparticles." Journal of Nanofluids 7, no. 1 (February 1, 2018): 30–36. http://dx.doi.org/10.1166/jon.2018.1440.
Full textLv, Guojun, Fumin Wang, Wangfeng Cai, and Xubin Zhang. "Characterization of the emulsions formed by catastrophic phase inversion." Colloids and Surfaces A: Physicochemical and Engineering Aspects 450 (May 2014): 141–47. http://dx.doi.org/10.1016/j.colsurfa.2014.03.023.
Full textBouchama, F., G. A. van Aken, A. J. E. Autin, and G. J. M. Koper. "On the mechanism of catastrophic phase inversion in emulsions." Colloids and Surfaces A: Physicochemical and Engineering Aspects 231, no. 1-3 (December 2003): 11–17. http://dx.doi.org/10.1016/j.colsurfa.2003.08.011.
Full textSajjadi, Shahriar, Fatemeh Jahanzad, and Michael Yianneskis. "Catastrophic phase inversion of abnormal emulsions in the vicinity of the locus of transitional inversion." Colloids and Surfaces A: Physicochemical and Engineering Aspects 240, no. 1-3 (June 2004): 149–55. http://dx.doi.org/10.1016/j.colsurfa.2004.03.012.
Full textZang, Duyang, and Paul S. Clegg. "Relationship between high internal-phase Pickering emulsions and catastrophic inversion." Soft Matter 9, no. 29 (2013): 7042. http://dx.doi.org/10.1039/c3sm00133d.
Full textNienow, A. W. "Break-up, coalescence and catastrophic phase inversion in turbulent contactors." Advances in Colloid and Interface Science 108-109 (May 2004): 95–103. http://dx.doi.org/10.1016/j.cis.2003.10.020.
Full textThakur, Rajeev K., C. Villette, J. M. Aubry, and G. Delaplace. "Dynamic emulsification and catastrophic phase inversion of lecithin-based emulsions." Colloids and Surfaces A: Physicochemical and Engineering Aspects 315, no. 1-3 (February 2008): 285–93. http://dx.doi.org/10.1016/j.colsurfa.2007.08.017.
Full textBains, Upinder, and Rajinder Pal. "Rheology and Catastrophic Phase Inversion of Emulsions in the Presence of Starch Nanoparticles." ChemEngineering 4, no. 4 (October 19, 2020): 57. http://dx.doi.org/10.3390/chemengineering4040057.
Full textDunstan, Timothy S., Paul D. I. Fletcher, and Saeed Mashinchi. "High Internal Phase Emulsions: Catastrophic Phase Inversion, Stability, and Triggered Destabilization." Langmuir 28, no. 1 (December 19, 2011): 339–49. http://dx.doi.org/10.1021/la204104m.
Full textDissertations / Theses on the topic "Catastrophic inversion"
Schneider, Alice [Verfasser], Claus A. M. [Akademischer Betreuer] Seidel, and Rybinski Wolfgang [Akademischer Betreuer] von. "Mechanismen der Catastrophic Phase Inversion in Emulsionen aus Polydimethylsiloxanen und Wasser / Alice Schneider. Gutachter: Claus A. M. Seidel ; Wolfgang von Rybinski." Düsseldorf : Universitäts- und Landesbibliothek der Heinrich-Heine-Universität Düsseldorf, 2012. http://d-nb.info/101920205X/34.
Full textGalindo, Alvarez Johanna Maria. "Étude de l'inversion de phase catastrophique lors de l'émulsification de produits visqueux." Thesis, Vandoeuvre-les-Nancy, INPL, 2008. http://www.theses.fr/2008INPL015N/document.
Full textThis study deals with the description and understanding of catastrophic phase inversion during high viscous oil emulsification, through the analysis of the effects of formulation and process variables on the dispersed phase fraction at which the inversion is triggered and on the involved mechanisms. The simultaneous follow – up in situ of viscosity and conductivity measurements allowed, from a process point of view, to emphasize on the effect that the aqueous phase addition rate has on the formation of multiple w/O/W emulsions. Due to the formation of w/o/W emulsions, the volume of the effective dispersed phase greatly increases while at the same time, if the aqueous phase is added by very small fractions inversion of the w/o/W system can occur. In relation with formulation, an increase in oil viscosity greatly increased the tendency of the oily phase to become the dispersed phase. At the same time, it promoted the formation of highly concentrated emulsions (about 80 to 95 % in volume) after the inversion had occurred. The microscopical follow-up of emulsion morphology by means of squeezing flow, allowed us to establish the conditions and mechanisms that lead to partial or complete inversion. Even though literature sources lead us believe that inversion will occur through the “inclusion/escape” mechanism, experimental results showed that the relative viscosity between the phases promoted inversion through the mechanism of “agglomeration – coalescence” rather than “inclusion/escape”. A mathematical model based on population balances and on the fractal nature of multiple emulsions allowed us to describe the multiples drop size and effective dispersed phase evolution until inversion phenomena
Barros, Frederico Macedo Fernandes. "Structuration and rheology of Pickering emulsions by the interaction of particles with different degrees of hydrophobicity." Thesis, Le Mans, 2016. http://www.theses.fr/2016LEMA1032.
Full textPickering emulsions have gained interest in many fields of research due their properties like higher stability and versatility. Special attention has been given to the processing of complex and original systems which can be obtained by using different particles. This study consists in the analysis of the different physicochemical parameters of particles, liquid media as well dispersion systems, and their relationship with emulsions structural and mechanical behavior in order to predict and modulate the emulsions characteristics. We studied extensively for the first time the phase diagram of catastrophic and transitional phase inversion of Pickering emulsions. We used silica particles with different structure and hydrophobicity. In particular we showed that mixing particles with different hydrophobicity can finely modulate the phase inversion as well the rheological and structural properties of the emulsions. The manufacturing of emulsified membranes based on previous Pickering emulsions was proposed as an example of the use of these systems as templates for the design of complex materials
Carli, Cynthia de. "Nanoemulsões encapsulando quercetina produzidas pelo método do ponto de inversão da emulsão (EIP): estabilidade físico-química e avaliação da atividade antioxidante in vitro e em produto cárneo." Universidade de São Paulo, 2017. http://www.teses.usp.br/teses/disponiveis/74/74132/tde-14062017-113435/.
Full textQuercetin is a flavonoid with recognized high antioxidant activity Due to this fact, the food industry has been trying to use it as an alternative as a preservative in food matrices. However, incorporating quercetin into food formulations may be challenging due to its relative degree of hydrophobicity. Encapsulation methods in nanoemulsions may render the protection of the flavonoid viable, as well as enable its dispersibility in aqueous media. The objective of the present study was to produce nanoemulsions (oil phase: sunflower oil) encapsulating quercetin by the emulsion inversion point method (EIP), determining operating parameters that enable a future process scale-up. A case study on the incorporation of nanodispersions into chicken patê was also carried out. The production parameters evaluated were: type and concentration of surfactant (SOR ratio, surfactant:oil ratio), soybean oil concentration, cosolvent concentration and stirring speed. Nanoemulsions were produced using two different surfactants, Tween 80 and Brij 30. The percentages of encapsulated quercetin were 0.15 and 0.30% (m / m). Among these, the concentration of 0.30% was the most feasible for application in chicken pâté, since it presented better droplet size distribution (hydrodynamic diameter), did not present significant variation of lipid oxidation and higher capacity of preserving encapsulated quercetina for a period of 90 days. The interfacial tension values obtained show that quercetin lowered the interfacial tension of the system, which may indicate that quercetin forms a complex with the surfactants used, a fact that decisively influences its location in the nanodroplets. Among the formulations tested in chicken pâté containing quercetin, only the formulation using free quercetin did not show good acceptance evaluation on the color and taste itens. Such an evaluation was important as it justifies the need for the incorporation of quercetin into nanoemulsions in order to not cause significant sensorial changes in the product.
Bronner, Cyrille. "Utilisation des données opérationnelles pour l'aide à la décision en situation accidentelle impliquant une substance dangereuse : application à l'identification du terme source." Saint-Etienne, EMSE, 2008. http://www.theses.fr/2008EMSE0021.
Full textIn the event of a major chemical accident, often only uncertain and inaccurate facts are available to the fire-fighters and crisis management units, which makes a diagnosis of the situation difficult. Further, the emission source (initial conditions) is often badly known in the first instant but is however absolutely necessary to have a global view of the event and predict its development to take good decisions and to limit consequences. This research work aims at developing, for the emergency first responders, methodologies and decision-making support tools, specific to chemical accidents. This thesis addresses two problems, in one hand to identify the a priori unknown chemical substance, in the other hand to assess the source term (rate, quantity …). To identify an unknown chemical substance or, at least, the associated hazards, the developed method consists in using data collected in situ which can be descriptive data (as colour, odour) or symptoms observed on victims. On these bases, a methodology and a software have been developed to make easier the exploitation of operational data, taking into account inherent uncertainty and inaccuracy, in particular by using the probability theory. In addition to the identification of the chemical substance, consequences assessment requires to know precisely the source term. So, an inverse method has been proposed to evaluate the source term by using the observed or/and measured consequences (overpressures, concentrations …). This method is based on a genetic algorithm coupled with an analytic explosion model. The algorithm was then validated on two accidents (AZF and Nitrochimie sites) and provides good estimations of the mass of the explosive having detonated. The benefit of our method is its ability to solve problem with more than one unknown parameter, e. G. The explosive mass together with the location of the epicentre of the explosion which could not be possible with methods usually used
Rondón, González Marianna. "Inversion de phase d'émulsions induite par agitation." Thesis, 2007. http://www.theses.fr/2007INPL017N/document.
Full textThis study deals with the catastrophic phase inversion produce by continuous stirring of an abnormal water-oil-surfactant system, without internal phase addition, in order to prepare concentrated and fine water-in-oil emulsions. The simultaneous conductivity and viscosity measurements of the system under stirring show that generally, the inversion takes place through the formation of a multiple w/O/W emulsion in which a portion of the external phase is continuously included as droplets in the dispersed phase drops. Consequently, the dispersed phase apparent volume increases until a critical value is reached and the inversion is triggered. In order to control this process, the influence of formulation, composition and stirring variables on the inversion mechanism and on its characteristic parameters is studied. The data collected can be used to prepare, in a minimal time, emulsions with required properties, by controlling the formulation and process conditions
Books on the topic "Catastrophic inversion"
Vaessen, Gerardus Eberhard Johannes. Predicting catastrophic phase inversion in emulsions. Eindhoven: University of Eindhoven, 1996.
Find full textBook chapters on the topic "Catastrophic inversion"
Perazzo, Antonio, and Valentina Preziosi. "Catastrophic Phase Inversion Techniques for Nanoemulsification." In Nanoemulsions, 53–76. Elsevier, 2018. http://dx.doi.org/10.1016/b978-0-12-811838-2.00003-5.
Full textConference papers on the topic "Catastrophic inversion"
Pavlou, Dimitrios G., and Muk Chen Ong. "Damping Effect on the Wave Propagation in Carbon Steel Pipelines Under Fluid Hammer Conditions." In ASME 2016 35th International Conference on Ocean, Offshore and Arctic Engineering. American Society of Mechanical Engineers, 2016. http://dx.doi.org/10.1115/omae2016-54194.
Full textPougatch, Konstantin, and Martha Salcudean. "Computational Investigation of Liquid Spray Dispersion Modification by Conical Nozzle Attachments." In ASME 2010 3rd Joint US-European Fluids Engineering Summer Meeting collocated with 8th International Conference on Nanochannels, Microchannels, and Minichannels. ASMEDC, 2010. http://dx.doi.org/10.1115/fedsm-icnmm2010-31037.
Full textLyon, Matthew. "Systematic Approach to Catastrophic Inversions of Epoxy Emulsions." In Virtual 2021 AOCS Annual Meeting & Expo. American Oil Chemists' Society (AOCS), 2021. http://dx.doi.org/10.21748/am21.278.
Full textPougatch, Konstantin, Martha Salcudean, and Jennifer McMillan. "Average Droplet Diameter Spatial Distribution in a Spray After Gas-Assisted Atomization." In ASME 2010 International Mechanical Engineering Congress and Exposition. ASMEDC, 2010. http://dx.doi.org/10.1115/imece2010-39737.
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